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By LeRoy R. Curwick

This Bureau of Mines report presents the results of a study conducted to assess the domestic availability of chromium from superalloy and cast heat- and corrosion-resistant alloy scrap material. Six alloy classes included in this survey were investment cast, hardfacing, and wrought nickel- and cobalt-base alloys, wrought nickel-iron-base alloys, and heat- and corrosion-resistant alloy castings. Data were collected for 1976 on metallic scrap generation, use patterns, and production practices for these alloy producing and using industries. A model was developed that allowed an assessment of the materials flow circuits within the industries that produce these alloys. The types, amounts, sources, secondary products, and ultimate destinations of chromium- containing metallic scrap for the six alloy classes were determined. Regarding the overall recycling efficiency of these alloy producing and using industries, of the 580.9 million pounds of scrap generated from these six alloy classes in 1976, about 72 percent (416.8 million pounds) was remelted by the same alloy-producing industries, about 18 percent (104.9 million pounds) was downgraded into stainless and low-alloy steels, about 3 percent (19.7 million pounds) was exported, and about 7 percent (39.5 million pounds) was lost through landfill or other disposal or service wastage. The lost material is primarily contaminated oxides for which recovery is currently uneconomic. However, the 124.6 million pounds of scrap material downgraded or exported in 197b contained potentially recoverable critical strategic elements. The amount of scrap material lost to the six alloy-producing industries in this manner contained 22.1 million pounds of chromium, 53.4 million pounds of nickel, 5.9 million pounds of cobalt, 35.9 million pounds of iron, and 7.3 million pounds of other alloying elements.

Jan 1, 1980

By Martin B. Zimmerman

It is becoming evident that traditional methods of econometric analysis are inadequate in estimating-the long-run supply of minerals. Econometrics is limited to extracting estimates from observations of the theory predicts that the least cost deposits will be exploited first.1 The estimation of parameters from past data then must lead to biased projections of the future. Mining conditions in the future will be worse than in the past and it is the impact of the future conditions on cost that we need to know. In this paper we present a methodology for dealing with this problem. We estimate a "cumulative cost" function that yields the long-run marginal cost of mining as a function of cumulative output produced over time.2 This is relatively easy to do for coal mining in the United States where exploration for new deposits is not a major factor in supply. The first step of the procedure relates cost to the rate of output and to the geological conditions of the mine. The second step combines geological information on remaining deposits with the cost function to yield the cumulative cost function. A central theme of both these steps is the interaction of economics with geology. The best deposits are selected first and in each step of the estimation allowance must be made for this fact. The problem of depletion is part of the general problem of structural change. The change through depletion in the nature of the exploitable mineral stock is only one factor that calls for an analysis sensitive to the changing circumstances of the industry. The factors impinging most heavily on the coal industry today are the strict environmental regulations legislated

Jan 1, 1977

By Frank R. Barnako

Coal mining is a hazardous occupation, but tremendous progress has been made in reducing accidental injuries and deaths in the mines. Let us take a look at the hazards in coal mining and the accident record. COAL MINE SAFETY TODAY Underground coal mining creates underground open areas, rooms, and haulageways. The roof (top) and ribs (sides) become highly stressed, and because coal and slate are very weak in tension or compression they frequently fail and fall from the roof and ribs unexpectedly. This is the most hazardous condition miners must cope with underground, and it has consistently produced the greatest number of fatal injuries in the coal mining industry. Only very sophisticated equipment, but which is not yet practical for use underground, is able to detect the buildup of stresses that may eventually lead to a roof or rib fall. Today's miner still looks for fresh cracks in the roof or rib, listens for the "drummy" sound, and feels vibrations from loose material in the roof, when tapped with a sounding stick, in order to find material which may fall. Once located, it is barred down, but if this is not possible, it is then secured to prevent it from falling. The next great& hazard is the equipment used to mine or haul coal. It is large, heavy, reacts quickly to its controls and is operated in con- fined areas with low lighting levels. The record of the last few years shows that fatalities attributable to mining and hauling equipment are about equally divided. Thorough training as part of a complete safety program is necessary to teach employees the hazards of loose roof, rib, and machine operation in order that they can work in the safest way possible. Unless there is such a program, the trade is learned by trial and error with a resulting tragic.

Jan 1, 1973

The current understanding of the mechanics of rock fracturing during smooth blasting is largely empirical and qualitative due to an inability to model the dynamic process at the fundamental level. In order to overcome this difficulty, a numerical simulation of smooth blasting is performed using the Dynamic Lattice Network Model. This model is capable of simulating material inhomogeneities and the dynamic evolution of fragmentation at the micromechanical level. In this study, smooth blasting techniques are numerically analyzed to characterize the development of the damage rock zone during explosive fracturing.

Jan 1, 1995

By Aziz N

The objective of the paper is to develop an understanding of the influence of caving on powered support rating by examining the geology and support performance at two sites which represent the current extremes in support rating, ie 6/240 Ton supports operating in the Hirst Seam at Solsgirth Colliery, Scotland, and 4/900 Tonne supports operating in the Bulli Seam, West Cliff Colliery, Australia. A conceptual model is introduced which considers the coal ahead of the face, the powered support, and the caved waste to be three yielding foundations which interact to control the subsidence of the roof strata. Different caving mechanisms are identified for the strata of the Hirst and Bulli Seams, ihese mechanisms being related to rock properties, ie to the palaeogeography and depositional conditions at each site, producing caved wastes with different yield characteristics. The results obtained for convergence and support reaction during production cycles at both sites are analysed to show the manner in which support reaction is developed, indicating the importance of high setting load densities in the Bulli Seam. Evaluation of the work done on the subsiding roof strata during typical production cycles by two of the yielding foundations, ie the powered support and the caved waste immediately behind the powered support, is used to further demonstrate the influence of caving mechanisms on support rating.

Jan 1, 1986

By C. A. Heiland

The following summary is written for the benefit of the practical operator in the nonmetallic field who wishes to know what geophysics has done and may be expected to do in his line of work. His problem is quite different from that of the geophysicist who has operated with various or all methods and has followed the literature, and who is assumed to be familiar with the geologic possibilities and limitations of each method. This article is not written for the latter, although he may be interested in the four or five hitherto unpublished surveys described. To the operator, on the other hand, geophysics is only secondary. His problem is to determine which geophysical method is best suited to his special needs. If he wanted to know, however, which method could be used to locate a certain material of given physical properties, building stone, for instance, he would have to wade through a tremendous amount of geophysical literature, bibliographies and articles, before he could find what he wanted. Therefore, the purpose of this summary is to present the geological problems first and then to discuss the comparative merits of the geophysical methods that can be, or have been, applied. Choice of Geophysical Methods in Oil, Civil and Mining Engineering In the first two of these fields, the geological problems are not nearly so complex as in the metal and nonmetallic mining fields. The selection of the correct geophysical method in these fields is not nearly so difficult for the operator. For oil prospecting, his problems have been discussed exhaustively by E. DeGolyer.(1) † In civil engineering (foundation and ground-water work), the usefulness of electrical methods has been so well established that there is hardly any choice of other methods at present. The situation may be changed in the future with the perfection of the seismic reflection method for shallow depths. In the mining field the operator and often the geophysicist himself finds difficulty in determining which method is best suited for a given

Jan 1, 1934

By D. J. MacDonald

This U.S. Bureau of Mines report reviews published information on synthetic berlinite (AlP04) and suggests experimental conditions requisite for its production. Berlinite is a piezoelectric material with potential use as a substitute for quartz in the crystal oscillators, which are components of electronic and electroacoustic equipment. Information gathered here (mostly from published sources) includes historical background, physical properties, end-use applications, criteria of quality, and physio-chemical factors involved in berlinite crystal growth. It is concluded that growing large high-quality berlinite crystal would require high-purity starting materials in an autoclave equipped with a noncorrodible liner and operated with temperature control of ±O.OO5 ac over a range of 250 to 350 ac.

Jan 1, 1995

By James H. Fletcher

Much data and experience has been accumulated, especially in the last 5 or 6 years, to show that modern roof trusses, both of the Birmingham type and the bolt-and-channel type, perform well to support certain kinds of coal mine roof. For some time now, roof trusses of the Birmingham type have been effective in controlling thick shale roof, which tends to sag and fall over a period of about eight weeks. These falls leave dame-shaped cavities which are reminiscent of the pressure arch theory of roof failure. Lately there has also been significant interest in supporting some longwall panel entries with channel and-bolt systems. These systems utilize two vertical center bolts and two 45 degree end bolts through a heavy gage channel. Both types of truss systems have long bolts, which require 8 to 9 Foot holes on a 45 degree angle, and point anchor resin bolts, which utilize a 2 or 3 foot rebar grouted in a thin annulus of polyester resin. Consequently, many coal mining people have been impressed with the very good anchorage characteristics and tensionability features of these systems. However, the same people have been proportionately dismayed to find that very often the most difficult part of introducing a trussing program to a mine is deciding on the machine specifications which determine the truss installation rate. The purpose of this paper is to indicate aspects of truss bolter design and use which are not shared by roofbolter design and its vertical pattern of bolts. Of the two types of drill units conventionally accepted, arm feed units and mast units, only one 15 judged suitable. While the arm feed unit offers low collapsed height with a long drill feed length, a great attribute for low seam use, it has not lent itself to being rolled over to a 45 degree angle. One reason for this inability is that many items which are conventionally mounted on the arm feed unit cannot be allowed to rotate with the unit. These items include drilling controls, tool Cray, lights, canopy or safety post, panic bar, and stab jack(s). If these items were independent of the arm feed drilling unit, they would have to be out of the way of the boom arms, links, and feed cylinder as the unit moves. To ease this problem, the arm feed unit can be made very short and even mounted across the machine. However, the resulting short feed length is undesirable. Several short drill steel extensions are required to drill a relatively long hole, making this procedure time-consuming as well as increasing the likelihood of drilling a crooked hole. Another reason for abandonment of the arm feed unit is that a very stiff drill guide (or "centralizer") is required to start the hole. Using the mast tilt control, the roof bolter operator will force the bit against the roof and will rotate the bit without feeding to cut sideways into the roof to form a hole face. Omission of this step often results in the skidding of the bit toward the rib. To date, no such sturdy drill guide has been designed for an arm feed drill unit. The mast style unit has been the most successful design for angle drilling. It is easily rolled over to a 45 degree angle or to 90 degrees and, on single head models, often has been made to roll through 180 degrees. The mast style is compact, in plain view and is easily fitted with heavy duty manual or hydraulically operated drill guides. It can be mounted directly on a machine chassis, or onto a swinging boom, or onto a slider arrangement in a broad variety of configurations which will accommodate controls, tool trays, stab and roof support jacks, lights, canopies, and panic bars. The only significant difficulty with mast drilling units occurs in lower mining heights when desirable low mast height is accompanied by undesirable short feed length. While the lead extension in the drill string can be as large as the mining height will allow, a short feed length will permit only the use of shorter middle extensions and drivers, and perhaps will. require the use of two different length wrenches. The associated problem is the relatively short distance from the drillhead to the drillguide. This distance is further shortened when raising the drillhead to get the bit to the roof. One might keep longer lead extensions on the machine; drill a vertical pocket for the bit, starting the angle hole at this pocket; or modify the mast. If the mast is made so that the distance from the drillhead to the drillguide remains constant while the mast extends, after which the drillhead travels up the mast, the shorter mast can be made to start the hole more easily. However, short teed length will still result in longer drilling time. It is obvious from these points that a proper choice of mast is simply the highest one which will be moved easily in the given mining height. This, of course, goes against the grain of most experienced coal mining people who realize that a relatively small decrease in mining height can create a problem correctable only with the purchase and installation of shorter masts. If the mining

Jan 1, 1982

By Bruno Rodrigues Henriques

O entendimento, controle e otimização do rendimento de aço líquido, em uma aciaria LD, é uma tarefa complexa e desafiadora. Qualquer projeto que se disponha a otimizar o rendimento de aço líquido irá se deparar com enormes dificuldades técnicas e operacionais. A despeito de todas as dificuldades e em função da importância do rendimento de aço líquido, uma vez que o mesmo tem forte impacto no custo de produção, toda aciaria procura manter essa variável de processo sob estrito controle. Esse trabalho se propõe a mostrar todas as etapas da condução de um projeto, desenvolvido e implantado em 2014, que tinha como foco entender, controlar e otimizar o rendimento de aço liquido. Durante o desenvolvimento do projeto, foi encontrado um total de 19 desvios e foram implementadas 23 ações corretivas. O valor do rendimento, que antes do projeto estava em torno de 91,6%, evoluiu para uma média de 93,5% em 2015 e 2016. Esse aumento de 1,9%, em média, no valor do rendimento de aço líquido, proporcionou uma expressiva redução no custo de produção na aciaria.

Aug 17, 2017

By G. J. Heuer, J. N. Dew, G. C. Clark

The effect on well behavior of partial permeability barriers, changes in producing rates and well spacings have been calculated through use of a radial, unsteady-state, two-phase-flow mathematical model. This model allows for variations in permeabilities and porosities with distance from the wellbore. The numerical methods necessary to solve the problem require use of a highspeed digital computer, in this case an IBM 704. In each instance, pressure and saturation gradients, gas-oil ratios and recoveries around a well producing by solution-gas drive have been calculated as a function of time and distance from the wellbore. Comparisons are made to show the effect of changes in producing rate and of varying permeability near the wellbore and out in the formation on the production and pressure history of the well. The effect of different well spacings on producing rate and ultimate recovery is considered. Although the mathematical description of the reservoir is simplified in comparison to an actual reservoir, the results do give some insight into the difficult problem of spacing and proration in a heterogeneous solution-gas-drive reservoir. Results show that for the cases considered spacing has little effect on ultimate recovery and that permeability barriers removed from the well decrease producing rate for a period of time but have only a small effect on ultimate production. INTRODUCTION The effect of spacing and producing rate on the production characteristics and ultimate recovery of a well producing by the solution-gas-drive mechanism have been topics of interest to the oil industry for many years and the subject of many hearings before state regulatory bodies. The problem is very complicated because of the difficulty of simulating in the laboratory a reservoir producing by the solution-gas-drive mechanism under anything like normal field conditions. This paper gives the initial results of a study aimed at determining the effect of these factors on production from reservoirs simulated by a mathematical model. Two-phase, unsteady-state equations are used to calculate pressures, saturations, and rates of oil and gas flow as a function of time and distance from the wellbore. The model is radial, and reservoir properties may be varied with distance from the wellbore. A decrease in permeability at a given distance results in a low-permeability ring concentric with the wellbore through which all the fluids from more distant portions of the reservoir must flow. The current mathematical model allows for variation of permeability, porosity and saturations as a function of distance from the well. Any desired drainage radius for the well may be selected. Drainage radii of 745 and 1,053 ft, which correspond to 40- and 80-acre spacing, were chosen for the calculations which follow. A large amount of the input data has been held constant. No investigation was made into the effect of changes in fluid properties and relative permeability characteristics on oil and gas production behavior. Fluid properties and relative permeabilities are essentially those of the White Mesa portion of the Greater Aneth area in southeastern Utah. A recently concluded hearing before the Utah Oil and Gas Conservation Commission to determine spacing for the field aroused interest in the possible effect of permeability constrictions located some distance from the well on production and recovery. This interest stimulated the present study. In this paper, no attempt has been made to simulate any field production characteristics exactly. Only the solution-gas-drive mechanism has been investigated, and production by liquid expansion has not been considered. This investigation is exploratory in nature but does give some insight into the problems of spacing and proration in a solution-gas-drive field having permeability variations. THE MATHEMATICAL MODEL The mathematical model is similar to that proposed by West, Garvin and Sheldon.' Approximately the same techniques have been used in arriving at a solution. The equations are nonlinear, partial differential equations which have been known for some time. The particular equations used for this study neglect the effects of capillary pressure and gravitational forces. The advent of modern digital computing equipment has made their solution practical. Basically, the method solves for pressure, saturations, and oil and gas flow rates as a function of distance and time. In our model, distance to the

By Alberto Eloy Anduze Nogueira

A pelotização é o método de aglomeração de minério que oferece o melhor custo benefício. No processo, é necessária a adição de um aglomerante para conseguir as propriedades desejadas. Entre estes, o cimento é um dos destaques pela facilidade e custo. A adição de pozolânicos no concreto na construção civil para o aumento da resistência é de longa data. Neste trabalho, se estuda o efeito da adição de 1% de SiO2 ou bentonita na mistura das pelotas autorredutoras. Realizam-se ensaios de compressão a frio, compressão após tratamento térmico 950°C, Teste de abrasão a quente, teste de quedas, além de difração de raios-X. Como resultados obteve-se um incremento da resistência a compressão a frio e a abrasão a quente com a adição da bentonita, porém com ambos pozolânicos tem-se uma perda de 50% na resistência a compressão após tratamento térmico a 950°C.

Aug 1, 2018

By T. T. Chen

Kidd Creek continuously-cast copper anodes are characterized by high levels of Se, Pb and Ag; the anode slimes constituents and their morphologies are controlled by both the anode composition and the casting process. Hollow Cu2Se spheroids and tube-like structures, enveloping Cu-Pb-As oxide and/or Cu2O, are present in the as-cast copper. During electrolysis, the selenides are liberated from the copper and accumulate in the slimes layer; the Cu2O and Cu-Pb-As oxide react rapidly with the electrolyte to form soluble species and PbSO4. Silver, which is present mostly as a solid solution in the anode copper, is also liberated during electrolysis and reacts with the Cu2Se to form (Cu,Ag)2Se. The ultimate composition of the selenides in the slimes layer depends mostly on the Ag and Se contents, but various other elements, including Au and Te, are also structurally incorporated. Although the selenides are the major Ag carrier, metallic silver also is present. A thin layer of Cu2O crystals sometimes forms at the copper surface, and may affect anode passivation. Copper sulphate is a common constituent and serves to agglomerate the slimes. Copper sulphate is present on both passivated and non-passivated anodes, but that observed on the passivated metal is present as a thick compact layer. Copper powder is associated with CuSO4.5H2O only on passivated surfaces.

Jan 1, 1987

By J. V. Batty

The Bureau of Mines devised techniques involving the use of beta-and gamma-ray-emitting radioisotopes and successfully adapted these techniques to the density of mineralized flotation froths) the rate of flow of finely ground ore pulps) and the residence time of pulps in processing circuits. Specifically, the water and mineral loads of flotation froths were continuously measured by determining the proportion of a constant-strength beam of beta rays that was absorbed by the froth column. Continuous measurement of the rate of flow of an ore pulp was accomplished by measuring the changing width of a free-falling stream of the pulp with a collimated beam of beta rays. The residence time of solids in conditioning and resin-in-pulp circuits was accurately measured by following the progress through these circuits of a portion of the pulp that had been tagged with the gamma-emitting Ag110 radioisotope.

Jan 1, 1966

By Bonifacio Degay, Mike Lovitt

PT Freeport Indonesia is a block cave mine that now utilizes an advanced undercut method to set up the min in the Deep Ore Zone (DOZ). In this method a slice of rock (undercut) is broken such that it sits on top of the drawbell level. The drawbells are developed to channel the broken ore into the extraction level and to enable the caving orebody to be drawn out in an even and controlled manner. These drawbells are difficult to form due to the small amount of void that can be developed in the low strength rock before firing. Starting with two rises of 2m square, the void ratio for the entire drawbell around 6%, which would normally result in a frozen and unproductive blast. Orica -Mining Services have worked with PT Freeport in a collaborative effort to find a solution to the mining problem. With excellent control of timing of the blasting it is possible to get fluid flow of blasted rock out of the draw points such that more void can be made available for blasting the remaining parts of the drawbell. The i-konTM electronic blasting system gives the exacting control of timing within the blast to achieve this Dynamic Void Generation (DVG). The solution stops the need to charge close to brows in the drawbells and reduces the cost and time related to developing initial blast voidage. This paper identifies the results of the trials including design, photographic evidence and vibration analysis. The flexibility and accurate timing of this electronic blasting system has enabled single hole initiation rather than 4 or more holes being initiated together, thereby reducing the damaging vibrations to the extraction level.

Jan 1, 2004

By Donald J. Hill

To be successful, every organization within the mining industry must involve itself in researching and evaluating methods of loss control. The appraisal and evaluation of accidents and injuries is required to determine the costs of loss producing practices and conditions. This involves all of an organizations disciplines that concern themselves with a more efficient and cost effective organization. To come to know the cost of your safety program or how much is expended yearly for each employee on safety; to know what your safety costs are per man-hour or per ton-produced; to know what the health, medical and compensation costs are for any given incident are just a few of the important facts and figures that the safety management of a given organization needs to know to operate in the mining industry today.

Jan 1, 1984

By M. F. Hawkes, R. F. Mehl

The rate of isothermal transformation of austenite to pearlite depends upon the rate of nucleation, N, and the rate of growth, G, of pearlite in austenite. Values of N are given in terms of the number of nuclei forming in unit time per unit grain boundary area of unreacted austenite; values of C are given in terms of the linear rate of radial growth. Variations in the isothermal rate with temperature result from variation of N and G with temperature. Depth of hardening of a steel depends fundamentally upon values of N and G; changes in carbon and alloy content effect changes in N and G and thus affect depth of hardening. Quantitative studies are available on N and G for the formation of pearlite in plain carbon eutectoid steels.3 Systematic studies in this field are necessary if the phenomena are to be well enough known to furnish a proper basis for full rationalization and for theory. Accordingly, the studies are continuing, both with respect to the effect of alloying elements upon the values of N and G in the formation of pearlite and to the values of N and G for the formation of ferrite in hypoeutectoid steels. The present paper is the first relating to the effect of alloying elements upon the values of N and G for pearlite. It offers special interest since cobalt is known to have an anomalous effect upon the rate of formation of pearlite, accelerating it, whereas all other elements retard it.4 It will be shown that cobalt increases both N and G for pearlite and that this effect is inherent in the Fe-Co-C system and not dependent upon factors relating to austenite heterogeneity nor upon any recognizable adventitious factor. Inasmuch as the rate of diffusion of carbon in austenite and the interlamellar spacing of pearlite are variables related to G and possibly to N (in a manner not yet certain), measurements of the effect of cobalt upon them are also reported here. In the course of the work, measurements were made on the effect of cobalt upon the marten-site temperature and these are given. COBALT AS AN ALLOYING ELEMENT IN STEEL Properties of Cobalt Cobalt resembles iron more closely than does any other chemical element. Its atomic number is 27, hence it is the element immediately following iron in the periodic system. The two differ in atomic structure only in the fact that cobalt contains seven electrons instead of six in the third, or transition, level of .the third shell. The next shell, which is the

Jan 1, 1948

By M. F. Hawkes, R. F. Mehl

The rate of isothermal transformation of austenite to pearlite depends upon the rate of nucleation, N, and the rate of growth, G, of pearlite in austenite. Values of N are given in terms of the number of nuclei forming in unit time per unit grain boundary area of unreacted austenite; values of C are given in terms of the linear rate of radial growth. Variations in the isothermal rate with temperature result from variation of N and G with temperature. Depth of hardening of a steel depends fundamentally upon values of N and G; changes in carbon and alloy content effect changes in N and G and thus affect depth of hardening. Quantitative studies are available on N and G for the formation of pearlite in plain carbon eutectoid steels.3 Systematic studies in this field are necessary if the phenomena are to be well enough known to furnish a proper basis for full rationalization and for theory. Accordingly, the studies are continuing, both with respect to the effect of alloying elements upon the values of N and G in the formation of pearlite and to the values of N and G for the formation of ferrite in hypoeutectoid steels. The present paper is the first relating to the effect of alloying elements upon the values of N and G for pearlite. It offers special interest since cobalt is known to have an anomalous effect upon the rate of formation of pearlite, accelerating it, whereas all other elements retard it.4 It will be shown that cobalt increases both N and G for pearlite and that this effect is inherent in the Fe-Co-C system and not dependent upon factors relating to austenite heterogeneity nor upon any recognizable adventitious factor. Inasmuch as the rate of diffusion of carbon in austenite and the interlamellar spacing of pearlite are variables related to G and possibly to N (in a manner not yet certain), measurements of the effect of cobalt upon them are also reported here. In the course of the work, measurements were made on the effect of cobalt upon the marten-site temperature and these are given. COBALT AS AN ALLOYING ELEMENT IN STEEL Properties of Cobalt Cobalt resembles iron more closely than does any other chemical element. Its atomic number is 27, hence it is the element immediately following iron in the periodic system. The two differ in atomic structure only in the fact that cobalt contains seven electrons instead of six in the third, or transition, level of .the third shell. The next shell, which is the

Jan 1, 1948

Investigation of standard tests used to establish the decrepitation rating of Western Australian iron ore showed scatter in results which could be reduced by textural type sampling. Testing of individual textural types resulted in separation.of a range of decrepitation behaviour patterns. No unique correlation was established between water content in goethite, or between any single mechanism and breakage in shock heating. The latter depends rather on several mechan- isms whose operation is controlled by the texture of the ore. Texture studies were used successfully to predict decrepitation behaviour which could be related to orebody structure for mine planning, and blending for sales or processing requirements.

Jan 1, 1973

By H. Hahn, B. H. Kear, K. Kan, S. C. Danforth, G. Skandan, W. Chang

"A new chemical synthetic process for the production of non-agglomeratednano structured ceramic (n-ceramic) powders, starting from metalorganic precursors, is described. The process combines rapid thermal decomposition of a precursor/carrier gas stream in a hot tubular reactor with rapid condensation of the product particle species on a cold substrate. Critical to the success of this Chemical Vapor Condensation (CVC) process are (1) a low concentration of precursor compound in the carrier gas, (2) rapid expansion of the gas stream through an uniformly heated tubular reactor under a reduced inert gas pressure of 1-35 mbar, and (3) rapid quenching of the gas phase nucleated clusters or nanoparticles as they exit from the reactor tube. A wide variety of metal organic precursors is available commercially, all of which can be utilized in the CVC process to produce n-ceramic powders, including single phase, multiphase and multicomponent systems.The CVC process has been used to synthesize non-agglomerated n-SiCxNy and n-ZrOxCy powders, with controlled particle size in the range 2-20 nm. Heat treatment of the assynthesized n-powders in various high purity gas streams causes compositional and structural modifications, including particle purification and crystallization, as well as transformation to a whisker-like morphology. Thus, as-synthesized amorphous n-SiCxNy particles transform to (1) cubic n-SiC particles, when heated in flowing argon at temperatures> 1350 °C, (2) hexagonal n-Si3N4 whiskers, when heated in flowing NH3IH2 at 1400 °C, and (3) cubic nSiC whiskers, when heated in flowing H2 at 1400 °C.Non-agglomerated n-ceramic powders form uniformly dense powder compacts by cold pressing, which can be sintered to theoretical density at temperatures as low as 0.5 Tm' For example, full densification ofn-Zr02 powder compacts under free sintering conditions can be achieved at 1125 °C."

Jan 1, 1994

By Jack R. Woodyard

Scientists at the U.S. Bureau of Mines are studying iron aluminides as possible substitutes for stainless steels to reduce the Nation's dependence on imported strategic and critical materials. In a Bureau investigation on the mechanical properties of Fe-28Al, it was found that the material's machining properties were significantly improved at slow tool and feed speeds. Machining techniques normally used for brittle materials failed or were costly. Further experiments using a 5-in (12.7-cm) mill cutter with carbide inserts, operating dry at minimum machining speeds, produced visually smooth sample surfaces with no tool damage. As a result of these experiments and a review of published data on hydrogen embrittlement of iron aluminide under tension, non-water-based (e.g., sulfur-based) lubricants were chosen for production machining. Four-flute, 3/4-in (19-mm) carbide end mills were used at slow speed under lubrication. This latter procedure reduced tool wear and breakage by a factor of 2. Machined surfaces and specimen cross sections were analyzed by scanning electron microscopy to detect microcracking. Tensile tests gave the expected yield and ultimate strengths, indicating that no degradation by low-speed machining occurred. This study extends this work to show that the alloy can be machined at higher speeds using high-speed steel end mills, and that water-soluble cutting oil is a suitable lubricant and coolant.

Jan 1, 2010