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By Y Yang

This paper discusses various issues surrounding the metallurgical control for furnaces, especially focusing on processes with long time-constants and æmetallurgical memoriesÆ. Examples will focus on furnaces accepting particulate and sometimes ill-defined feeds, eg submerged-arc furnaces, blast furnaces, secondary scrap smelting operations, recycling operations, waste incinerators, etc. Generally, because of the usually higher metallurgical time constant of these furnaces, these reactors have to be controlled in a feed-forward manner by the use of a hybrid of æblack boxÆ or empirical and ægrey boxÆ semi-empirical first principles metallurgical modelling and simulation techniques in a supervisory metallurgical control capacity.

Jan 1, 2000

By U. K. Custred

Who We Are Farmland Hydro (FHLP) is a Limited Partnership formed by Farmland Industries, the largest U.S. farmers’ cooperative, located in Kansas City, MO, and Norsk Hydro, a large Norwegian company engaged in fertilizer, petroleum and the specialty metals industry. Both of our parent companies have a long history of commitment to the fertilizer industry. This year, Farmland Industry celebrates its 71st year in the business, and Norsk Hydro celebrates its 100th operating year! We employ approximately 300 associates in Central Florida. What We Do Farmland has been active in Hardee County, FL since the 1970’s as a large landowner and citrus grower. We plan to expand this activity into phosphate rock mining. The phosphate rock produced here will be shipped to our nearby chemical fertilizer complex in Polk County, where we produce quality phosphate products - liquid and granular fertilizers. Of the phosphate rock mined, 90% is used to make fertilizer. Other uses include animal feed, vitamins, medicine, light bulbs, soft drinks, film, flame resistant fabric, optical glass, toothpaste, bone china and other consumer products.

Jan 1, 2000

By Masahiro Yoshimura, Sergiy Korablov

"Hydi-othermal corrosion ofTiN, TlAlN and CrN PVD films (3 µm thick) deposited on SUS-304 substrate was studied in 100MPa water in 20-950°C temperature range up , to 750h. The beginning temperature of their reaction was determined as 200°c for TiN and TiAlN and 500°C for CrN films, which are quite low in comparison with that of air oxidation of those powders. Very thin oxide scales. of TinO; n-I homologous series phases were formed above 300°C. TiO2 anatare. is observed for TIN and TiAlN films at 400°C. The· feature of hydrothermal corrosion of CrN films seems to be CrNxOy phase formation.Distinguishable weight changes were observed at higher temperature than 700°C for TiN, 750°C for· TiAlN and 800°C for CrN respectively. Hydrothermal corrosion kinetics .was constructed to calculate the activation energy of hydrothermal corrosions. On the base of obtained data, hydrothermal corrosion resistance was as follows: TiN – TiAlN - CrN. Facetted oxide crystals were formed at higher temperature than 500°C for TiN, TiAlN and 850°C forCrN.IntroductionThe metallic nitride (TiN; TiAlN, CrN) PVD films have high hardness, strength and wear resistance. Therefore these films are widely used in industry for wear resistij.nce application such as cutting tools and die molds. Their performances depend on not only the mechanical properties but also corrosion resistance of coated films. High temperature oxidation of metalliq nitride and nitride films was well studied [1-5]. However there are no reliable data concerning the .corrosion resistance of coated nitride materials. In high-temperature and high-pressure water. There are a few reports on hydrothermal corrosion of nitride films [6,7]. The increase of corrosion resistance of CVD films was observed in following succession TiC - TiCNO - TiCN - TiN at 300-680°C temperature interval and I 00 MPa pressure water according to data of the first report. Kawana et al. [7] have reported about excellent corrosion resistance of CrN films under 290°C and 8, 6 MPa water during I 000 h in the circulating type experimental loop. The films thickness was about 7-10 µm in both cases. However it remains unclear the chemical state of the surface species and especially in-depth distribution, oxide scale thickness and its growth, and defects formation in the oxide film."

Jan 1, 2000

By A. Anttila, S. Persson

The grinding mill is probably the most common unit operation in mineral processing. There is, however, much that can still be done in the way of optimization. This paper discusses the results of a well-controlled pilot-scale test in which the performance of a tumbling mill equipped with a conventional rubber lining and lifter bars was compared to a tumbling mill equipped with a smooth rubber lining of the magnetic type. The results indicate that the smooth lining is about 14% more effective with respect to energy consumption. By optimizing the size of the grinding media, the mill capacity can be increased in many grinding operations. In this specific case, grinding with a -20-mm ball charge required 26% less grinding energy than grinding with a -30-mm ball charge. The energy savings can, in most cases, be converted to an increase in capacity. The wear of the grinding media is difficult to assess over a short test period, but the results suggest that the wear is somewhat less when a smooth lining is used. A determination of the wear of the linings was not included in this study, but it is generally accepted that the use of magnetic linings reduces the lining costs dramatically. Computer simulation using the Millsoft code developed by Mishra et al. confirms and explains the increased effectiveness of comminution when a smooth lining and smaller grinding balls are used.

Jan 1, 2000

By K. Gie Tan, Frank Wright

"Misty Mountain Gold Limited (MGL - TSE VSE, MGLCF - NASDAQ) of Vancouver, owns the Harmony Gold Project located in the Queen Charlotte Islands of British Columbia. The deposit contains a mineable reserve of 2.3 million ounces of gold, at a 1.2 g/t cut-off and an average grade of 2.1 1 g/t Au.Discovered in 1970 and frequently investigated by previous owners, full-scale production has not yet occurred because of the complex metallurgy of the deposit. Recent process studies that were completed in six months at Process Research Associates Ltd. (PRA) of Vancouver resulted in significant improvements to the project viability. The work involved detailed mineral processing studies aimed at achieving a marketable concentrate. An option for bio-oxidation and cyanidation to allow on-site dor6 production was also investigated.The main findings at PRA followed the front-end recovery of finely divided free gold (Au) by gravity concentration. Approximately 20% of Au reported to less than 0.2% of the mass, resulting in a grade exceeding 500g/t Au. The resulting gravity tailing provided a uniform feed for flotation evaluation. The optimization of this step allowed for a reasonable primary grind size of 80% passing (&) 50pm. Efficient slime’s rejection was made possible by flotation at a reduced pulp density, and pre-oxidized sulphides were reactivated with Na,S. The regrinding of the bulk flotation concentrate followed by up to five stages of cleaning resulted in a combined gravity + flotation product of 50g/t Au with 82% recovery in less than 4% of the feed mass.Further studies indicated that the flotation concentrate was amenable also to tank bio-oxidation. At 65% sulphide oxidation the gold recovery improved from less than 70% to 90% by cyanide extraction using CIL (carbon in leach). This compares to less than 45% gold recovery from whole-ore cyanidation in several previous studies. Heap leaching may also be considered for lower grade material. PRA’s methodical approach and consistent results dispelled the uncertainty about predicting the material behavior for the Harmony Property."

Jan 1, 2000

By Daryl L. Gusey, John T. Neubert, Matthew A. Sares

The Colorado Geological Survey completed an inventory of environmental degradation associated with abandoned and inactive mines on National Forest System lands in Colorado. In the course of the inventory, areas with naturally occurring acid rock drainage were also noted. Approximately 18,000 abandoned mine- related features were inventoried, including about 900 features that are considered significant enough environmental problems to warrant further investigation. Water quality data, such as pH and conductivity were gathered at all features where water was present, such as draining adits, seepage at the toe of dumps and tailings, and standing water in shafts. Samples were taken where field tests indicated low pH andlor high conductivity, including several areas with naturally occurring acid rock drainage. Samples were analyzed for dissolved and total metals, and for selected anions. All mine locations and data collected by the field geologists were entered on field forms and, subsequently, into a computer database and GIS format. With the information provided by the inventory, the Forest Service, in cooperation with other agencies, has been able to prioritize abandoned mines for reclamation. In most cases, cleanup is approached on a watershed basis. Mines in priority watersheds have been selected for reclamation first. Watersheds where studies prerequisite to cleanup are occurring include the upper Anirnas River, Willow Creek (tributary to the upper Rio Grande), Chalk Creek (tributary to the upper Arkansas River), the Uncompahgre River, and the Alamosa River. During the inventory, evidence of naturally occurring water quality degradation was found in areas where little or no evidence of mining activity exists. These areas include the upper Alamosa River, the Middle Fork of Mineral Creek, Peekaboo Gulch, and Handcart Gulch. Water from these natural sources has been found to significantly exceed Colorado water quality standards for several metals.

Jan 1, 2000

By Hiroshi Ono

"By newly developed ICP method, trace amounts of As(III), As(V) .,Sb(III) and Sb(V) were precisely determined within accuracy of sub ng/ml. As(III) and Sb(III) were separated from As(V) and Sb(V) by extracting into ·xylene as diethyldithiocarbamate complexes using diethylammonium diethyldithiocarbamate (DDDC), and then back-extracted into nitric acid for a quantitative determiruition by ICP-AES equipped with hydridegeneration system The recoveries of As(III) and Sb(III) were satisfactory throughout the extraction with 0.04mol/l DDDC in xylene from lmol/l hydrochloric acid solution and the back-extraction with 7 mol/l nitric acid. As(V) and Sb(V) were reduced to As(III) and Sb(III) by ascorbic acid and potassium iodide, and their quantities were determined as mentioned above. The detection limits were found to be 0.58ng/ml for As(III), 0.63ng/ml for Sb(III) using 50ml of a sample. The proposed method was applied to analysis of the real sample.Introduction In drain, arsenic(AS) concentration is prescribed below 0.lmg/l, so As must be removed. As is existed at .the form of As(III) or As(V) in solution. For t1Jeir difference of chemic;µ property, it is not easy to remove As in solution. So it is an urgent necessity to develop for determining concentration of As(III) and As(V). Antimony( Sb) has resemblance .chemical property to As. So Sb was experimented the same as As.The separation and determination of As(III) and As(V) have been carried out using several methods, such as ICP after copreclpitating separation, HPLC, direct hydride generation atomic absorption. However these methods have some problems. One of main problems is that HPLC and direct hydride generation atomic absorption methods are influenced by coexisting elements."

Jan 1, 2000

By Mitsuhiro Ohtaki, Tetsuzo Arakawa, Fujio Murata

Refining of Zn from aluminum scrap melt by some vacuum distillation processes was studied to promote aluminum scrap recycling. Effects of distillation conditions, such as melt temperature, vacuum pressure and holding time, on Zn distillation behavior were investigated theoretically and experimentally by 0.3kg/ch scale vacuum resistance furnace. Three methods to increase the surface-area/volume ratio of liquid metal, such as gas atomizing, mechanical atomizing and mechanical stirring, were tested to increase the Zn distillation rate in 5kg/ch scale vacuum resistance-furnace. It was easy to lower the remaining Zn content to less than 0.1 wt% within one minute by mechanical stirring method. A water-model simulation experiment indicated that a significant agitation of the melt by stirring would be effective to increase the distillation rate. Continuous agitation vacuum distillation process (CA VP) has been designed and the pilot plant is now in construction.

Jan 1, 2000

By R. L. Grayson

In 1995, the United States Congress abolished the Bureau of Mines in the US Department of Interior. But Congress preserved the safety and health research functions being performed at the Pittsburgh and Spokane Research Centers. These functions were transitionally housed in the US Department of Energy before permanently merging with the National Institute for Occupational Safety and Health (NIOSH), Department of Health and Human Services, in October 1996. Since the rnerger of the former Bureau of Mines with NIOSH, there has been an active evaluation of ongoing research activities, significant interaction with stakeholders, and the development of a process leading to "data-informed" priority setting. This paper reviews the current surveillance information concerning the level of injury and disease from mining work and discusses how research priorities are evolving to improve the contribution of research to the prevention of injury and disease.

Jan 1, 2000

The following is a summary of some of the companies that were exhibiting their products and services at MINExpo INTERNATIONAL 2000. Atlas Copco develops, manufactures and markets rock drilling tools, tunneling and mining equipment, and surface and geotechnical drilling equipment. The company provides a line of drilling products, including production drilling rigs, rock reinforcement bolts and rock drills. Atlas Copco’s Boomer is a series of high-capacity drill rigs that provides economy, production capacity and reliability

Jan 1, 2000

By Gilles A. Tremblay

Acidic drainage has been long recognized to be the largest environmental liability facing the Canadian mining industry and to a lesser extent the public through abandoned mines. The Mine Environment Neutral Drainage (MEND) Program was the first initiative formed in 1989 to develop scientifically-based technologies to combat acidic drainage. This 9-year volunteer program reduced the liability by several hundreds of million dollars and established Canada as the recognized leader in research and development on acidic drainage for metal mines. MEND 2000 is a three-year program that started in 1998. The key to MEND 2000 is technology transfer- providing state-of-the-art information and technology developments to users. MEND-developed technologies are being verified by long-term monitoring of large-scale field tests. Maintaining linkages with a number of foreign government and industry-driven programs is also important to the successful completion of the program. Through these efforts a further reduction of the environmental liability associated with acidic drainage will be realized.

Jan 1, 2000

By Robert L. Runkel, Kenneth E. Bencala, Briant A. Kimball

Thousands of abandoned and inactive mines are located in environmentally sensitive mountain watersheds. Cost-effective remediation of mining sites in these watersheds requires knowledge of the most significant sources of metals to surface waters. The significance of a given source not only depends upon the concentrations of a toxic metal, but also on the total mass, or load of metal added to the stream. To determine loads, we combined tracer-injection methods, to provide reliable discharge measurements on a watershed scale, with synoptic sampling, to provide spatially detailed concentration data. The resulting load profiles indicate which sources have the greatest effect on streams, where natural attenuation of metal loads occurs, and where ground-water inflows are located. This is part of the information needed for planning remediation of mine-drainage effects. The approach is illustrated by comparing zinc loading curves from three watersheds affected by mine drainage.

Jan 1, 2000

By R. J. Hickson

From 1993 through 1999 Cyprus Amax Minerals Company successfully completed eight major construction projects around the world. Six greenfield mines were brought into production, an ongoing operation was completely modernized, and an environmental issue was appropriately remediated. The projects stretched over three continents, from arctic Russia to the Atacama Desert, from 16,000feet to sea level, from city suburbs to remote wilderness, from a low of $130 million to over $1 billion. Open pit and underground; mill and leach; gold, copper, molybdenum, and coal were all encompassed. The breadth of diversity experience from these projects inspired Cyprus Amax to create a “best practices” project management protocol, to steer corporate expansion into the next millenium. This paper summarizes those best practices, while high-lighting project management pitfalls to avoid.

Jan 1, 2000

By E V. Man, O N. Savassi, J-P Franzidis

In flotation, the property that is exploited to effect the separation of a mineral from an ore is referred to as its floatability. Assessment and quantification of ore floatability is of fundamental importance in modelling and simulation of flotation circuits. This paper describes the design, construction and operation of a new laboratory flotation rig that has been developed at the Julius Kruttschnitt Mineral Research Centre (JKMRC) to determine the floatability of different ores on a small-sale. The rig is designed for continuous operation. The major features of the rig are highlighted in this paper. An unique characteristic of the rig is a 9.1 L conditioning vessel. This provides a mixing regime close to plug-flow which avoids complications such as different collector coverages for similarly sized particles (which would considerably increase the complexity of ore floatability determination). The main advantages of this rig when compared to conventional batch flotation cells include better control of the chemical environment and the ability to determine froth recovery, entrainment and water recovery with increased accuracy. Preliminary tests undertaken with a high-grade lead/zinc ore from BHP Cannington are presented demonstrating the good level of reproducibility obtainable in operating the equipment.

Jan 1, 2000

By G. Brackebusch, S. J. Jung

Backfilling techniques are widely used in large-scale underground mines. Massive pillars, which have been left in place for stability, limit mining activity. Backfilling allows safe recovery of the ore remaining in pillars and assures long term stability. In deep mines expected high stress can be relieved with the backfill. Initially, waste rock was used to fill the openings with mixed results. The need to improve safety and reduce costs has prompted the industry to investigate alternatives. Hydraulic filling with Portland cement added has shown considerable promise, but little has been done to define the parameters of design effective system. The purpose of this study is to determine the relationship between backfill and mining components that can be used to effectively design a best-case hydraulic backfill.

Jan 1, 2000

By R Miller, D Hawcroft

The business environment is never still and there has been enormous change in demand, technology and opportunity during the last decade. In order to succeed it is necessary for organisations to change the way work is planned, scheduled and carried out. This is necessary just to survive over time. The success or failure of the business is strongly influenced by people; the way they work, the way they are guided and their feelings about being part of both a team, as well as an organisation. Our Sustainable Integrated Management System (SIMS) philosophy is built on the belief that people want to be constructive and creative and it is their environment and working relationships that influence how their energies are directed.

Jan 1, 2000

By Fuzail Siddiqui

"The SIDMIN program aims at filling the mineral processor’s need to know the deportment of ‘minerals of interest’ not just ‘elements of interest’ that pass through the processing plants. Generally, chemistry is used as a tool of routine monitoring on site. Mineralogy, which is relatively much slower, is used more as a tool of research and post mortem investigations and these services are usually provided by a distant facility. The SIDMIN program enables site management to receive chemical and quantitative mineralogical reports on their critical samples daily, simultaneously and affordably.The author developed the SIDMIN program at ZCCM Nchanga Division where it continues to be a powerful tool for monitoring the efficiency of operations. Outlines are given of procedures for quick sample preparation and quantification of significant minerals in process samples. A specimen report is presented, which shows the format of reporting the contributions of individual minerals to metal losses at critical stages of the circuit. It is shown that SIDMIN provides timely information to management, about trends and abrupt changes in the quality of ore, and its processing, in a way never achievable by chemical analyses alone. This greatly helps in resolving the age-old problem of ‘bad ore’ or ‘bad operations’ on a day-by-day basis. For example increase in copper mica in the feed indicates excessive ore dilution during mining. Increased loss of free sulphides was traced to insufficient reagent conditioning time at the Concentrator. Persistent losses of leachable oxides at the Tailings Leach Plant were traced to inadequate leach residence time.SIDMIN is affordable because it can be implemented using basic optical microscopes, minimal quantities of micro-chemical reagents and custom trained site staff who demonstrate good colour perception and an ability to follow laid down procedures consistently."

Jan 1, 2000

By G S. B Karunatillake

Following a pre-feasibility study, Mount Isa Mines commenced a feasibility study on the deposit of the George Fisher Mine in May 1997. Board approval was granted in May 1998 to construct a 2.5 million tonne per annum mine and to upgrade existing concentrator and smelter facilities. The world-class George Fisher zinc-lead-silver deposit is located approximately 22 kilometres north of the city of Mount Isa, in north-west Queensland and is 2.6 kilometres north of the existing Hilton Mine. It will be a large-scale underground mine, sustaining a profitable zinc-lead-silver business in Mount Isa for at least ten years. This paper will outline the details of the mine that was developed during the feasibility and design phase. It will include a description of the mining methods, ventilation, fill, ore handling, services and infrastructure. The utilisation of existing assets and the development of innovative ideas were essential to the successful economic development of the George Fisher Mine.

Jan 1, 2000

By Gregg A. Swayre, Roger N. Clark, Stephen J. Sutley, Kathleen S. Smith

Imaging spectroscopy is a relatively new remote sensing tool that provides a rapid method to screen entire mining districts for potential sources of surface acid drainage. An imaging spectrometer known as the Airborne Visible/InfraRed Imaging Spectrometer (AVIRIS) measures light reflected from the surface in 224 spectral channels from 0.4 - 2.5 µm. Spectral data from this instrument were used to evaluate mine waste at the California Gulch Superfluid Site near Leadville, Colorado. Here, the process of pyrite oxidation at the surface produces acidic water that is gradually neutralized as it drains away from mine waste, depositing a central jarosite zone surrounded by a jarosite + goethite zone, in turn surrounded by a goethite zone with a discontinuous hematite rim zone. Leaching tests show that pH is most acidic in the jarosite and jarosite + goethite zones and is near-neutral in the goethite zone. Measurements indicate that metals leach from minerals and amorphous materials in the jarosite + goethite and jarosite zones at concentrations 10 - 50 times higher than from goethite zone minerals. Goethite zones that fully encircle mine waste may indicate some attenuation of leachate metals and thus reduced metal loading to streams. The potential for impact by acidic drainage is highest where streams intersect the jarosite and jarosite + goethite zones. In these areas, metal-rich acidic dace runoff may flow directly into streams. The U.S. Environmental Protection Agency estimates (U.S. EPA, 1998) that mineral maps made from AVIRIS data at Leadville have accelerated remediation efforts by two years and saved over $2 million in cleanup costs.

Jan 1, 2000

By R. L. McNearny, K. A. Barker

Four numerical models written with the "PFC2D " program were compared against four similar physical models. The numerical models were constrained numerically to closely follow the caving behavior of the physical models. Results from the numerical analyses closely simulated both the granular and blocky behaviors of the physical models, including bridging and interlocking of the simulated orebody during draw. The drawdown patterns and the rate of draw developed during numerical modeling also closely simulated the physical models. The same assumptions and governing parameters used in analyzing the first four models were applied to an additional model. The fifth model employed a completely different, uneven, draw sequence than the other four models, allowing the material to flow in a more granular manner with a demonstrated instability of the undercut sections between each drawpoint opening. Drawdown patterns and behavior of the numerical material of the first four models progressed at uneven and inconsistent rates, similar to those seen in the physical models. By inspection, the overall shape and flow lines of both the numerical and physical models were close in the area removed and in the flow characteristics. The fifth model proved to be the most unstable of all the models tested, with poor correlation to the physical models. The uneven draw sequence, coupled with an additional frictionless wall condition and an added drawpoint, caused the material to flow in a very granular manner. Information generated by this study can be used as a first approach in determining the proper draw rate, drawpoint spacing and undercut thickness for a block-caving operation. Numerical models are often difficult to predict and interpret. However, this study should increase the confidence level for use of the PFC2D program in the future.

Jan 1, 2000