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By E. T. C. Spooner, Ioannou S. E.

"Abstract- The Dixie Zone Au-Ag deposit is a low sulfidation (adularia-sericite) epithermal system located 1.4 km from the producing Ken Snyder mine (7.0 M oz Au equivalent reserve/resource), Midas Mining District, north-central Nevada. This WNW striking, steep south dipping, fault system is hosted by mid-Miocene (17 Ma to 14 Ma) felsic volcanic rocks that were erupted from a vent(s) to the northeast. The system was mineralized by approximately 250 ± 20°C (n = 86), near-neutral pH, ascending fluids of predominantly meteoric origin [volatile corrected salinity = 0.52 ± 0.35 eq.wt% NaCl (n = 86)]. Bulk analytical fluid inclusion gas chromatography identified a mineralizing fluid volatile composition of 99.68 ± 0.18 mole % H2O, 0.16 ± 0.09 mole % CO2, 0.11 ± 0.05 mole percent N2, 0.05 ± 0.04 mole % CH4, and 0.01 ± 0.01 mole % CnHn+i (n = 7). Sulfur species were not analyzed due to absorption within the chromatography system; however, a H2S concentration of 16 ppm to 160 ppm molar is estimated. The volatile content contributes approximately 50% of the microthermometrically measured freezing point depression. Cl- concentrations up to approximately 9000 ppm suggest an additional, probably magmatic, fluid component.Ascending fluids were channelled along approximately NW striking faults related to the same primary extension (17 Ma to 14 Ma) responsible for Nevada basin and range physiography. Boiling induced by CO2 effervescence led to precipitation of Au and Ag over a 150 m vertical interval. At the time, this interval was about 460 m below the water table (approximately 38 bars), but because of erosion, it is now within 90 m of the surface. A Ag:Au ratio of 25:1 has been calculated for the Dixie Zone."

Jan 1, 2000

By Ross Seedsman

There are many models for how roof bolts behave, one of which is prevention of shear along bedding. The basis of this model is that a roof beam will not delaminate if bedding parallel shear can be prevented. A key point in such a model is that bedding discontinuities are present naturally in the roof and that mining induced stresses do not generate new surfaces. The presence of these discontinuities means that the rock mass must be modelled as a transversely isotropic material if continuum codes are used. A limit-equilibrium type design method for specifying roof bolts is being developed using voussoir beam and excess shear force concepts. The method incorporates much of what operators know intrinsically about roof reinforcement, and allows mining engineers to focus on the key uncertainty - the frequency and location of bedding surfaces in the immediate roof. Areas where more research is required are highlighted.

Jan 1, 2000

By D. R. East

Recent experiences within certain sectors of the international mining industry suggest an underestimation of the environmental risks associated with the design of mine waste-management facilities. These experiences show that the technical and managerial challenges of responsible mine waste management is not always fully appreciated. Unfortunately, the image of the mining industry's environmental performance is negatively impacted by a relatively few number of failures. This negative view overrides the many positive contributions made by the majority of mining companies. The fact that these failures continue to occur in developed and developing countries is indeed re¬markable and indicates a degree of risk-taking approaching unacceptable levels. The design requirements for tailings storage facilities are, in many cases, more demanding than those of conventional water dams because seepage of fluids that contain dissolved metals may pose a greater threat than the mere loss of water.

Jan 1, 2000

By S Latchireddi

Close circuiting autogenous and semi-autogenous mills is an energy efficient way of grinding and a number of operations have utilised this in the design of their comminution circuits. Owing to the large flow of slurry through the mill that results from operating this way the grates and pulp lifters have to be designed to cope. However, the literature has little or no information on how grate and pulp lifter size and design are related to their ability to remove slurry from the mill. Over the last few years the JKMRC has been researching this area and has developed relationships between grate/pulp lifter design and flowrate capacity. At the same time it has determined the major causes of pulp lifter inefficiency and a solution to preventing this inefficiency (the Twin Chamber Pulp Lifter). This paper describes the models that have been developed through this program and uses industrial scale data to illustrate their accuracy. Results from the industrial trials of the Twin Chamber Pulp Lifter are also presented.

Jan 1, 2000

By Yi Luo

Subsurface strata movements and deformations associated with underground mining activities could cause problems to subsurface structures and water bodies. By incorporating the methods for surface subsidence prediction with the subsidence parameters derived from collected subsurface subsidence data, methods have been proposed for the prediction of final and dynamic subsurface movements and deformations induced by underground longwall mining. Two new' types of strata deformations in the field of subsidence research, vertical and total strains that could he useful in assessing subsidence influences to the subsurface structures and water bodies, have peen introduced.

Jan 1, 2000

By Kazuhiro Nisizono, Takashi Kuroki, Nobuyuki Mori, Keisaku Ogi

"The improvement of critical current density and mechanical property is essential to the practical application of the superconductive oxides. A solidification technique is developed in this study for the growth of columnar or single Y123 crystal with finely dispersed Y211 and Ag particles through a monotecto-peritectic reaction of Li.(Ba-Cu-Ag-0 rich liquid)+ Y211-+ Y123+Lz(Ag rich liquid). The large solidification rate and temperature gradient can refine the Ag and Y211 particles. But Ag-free region is widely formed along the crystal growth direction in the central part of the Y123 cell. Since this phenomenon occurs because of the cellular growth, it is necessary to narrow Y123 cell width or to grow Y123 crystal with flat freezing interface. By controlling crystal growth direction using a seed crystal, Y123 columnar or single crystal with uniformly dispersed fine Ag particles are obtained. The· behavior of Ag and Y211 particles during the solidification of Y123 crystal is simulated by the peritectic growth model of faceted Y123 crystals.IntroductionY-Ba-Cu-0 superconducting oxide (YBCO) with high critical temperature also has excellent superconducting characteristic under the high magnetic field. The critical current density (Jc) has been enhanced by ·using unidirectional-solidification technique, which can overcome the weak-link problem at grain boundaries and control the crystal orientation and the distribution of Y211 particles which give effective magnetic flux pinning centers in the Yl23 matrix [1-4].In addition to improving superconducting properties, it is necessary to improve mechanical property for the practical application. The silver addition to the melt-textured YBCO superconducting oxide has been reported as the effective method to improve mechanical properties without degrading superconducting properties. Since the material properties are considered to be largely affected by silver particle size, form, dispersion state etc. in the Y123 phase, it is important to control Ag distribution in YBCO/Ag composites. Besides, it is also reported that the silver addition improve the corrosion resistance to the water and CO2 [5,6]. Nishizono et al. [7-9] have reported that the silver distribution in the YBCO/Ag composites is largely affected by the solidification condition, but yet some unclear points are also remained. YBCO has been also fabricated by the zone melting method [10-12], and Furuya et al. [5] and Hirano et al. [13] have reported the fabrication of silver added YBCO composites, but the distribution and behavior of Ag are not investigated in detail"

Jan 1, 2000

By J. N. Kondo, M. Hara, T. Smida, N. Ooto, K. Domen

"A porous material composed of two-dimensional anionic sheets of a layered perovskite, KSrNb30 10, was studied as photocatalyst for the production of Hz in the presence of alcohol sacrificial donors. Colloidal single and multi-layered HSr2Nb30 10 sheets were formed by intercalating ietra(n-buthylammonium) cations into the interlayeres of H+-exchanged KSr2Nb30 10 (HSr2Nb30 10), and addition of HN03 solution to the colloidal suspension precipitated the porous materials in which HSrNb30 10 sh~ets rand~mly stuck together. Original HSr2Nb30 10 before exfoliation had a BET surface area of 1 m2 g-1, whereas the surface area of a porous material prepared under optimal conditions exceeded 100 m2 g-1. The porous HSr2Nb30 10 had considerably higher photocatalytic'activitie8 for oxidation of 1-propanol and 1-buthanol than HSr2Nb39io, indicating that in the porous materials many niobate sheets are available for decomposition of these large alcohols.IntroductionQuite a research effort has gone into the design and study of porous materials. Such materials with large surface areas would have applications in highly efficient adsorbents or catalytic reactions.We have been studying photocatalytic reaction by cation-exchangeable layered metal oxides, where alkali metal cations are intercalated into the interlayers of inorganic sheets.[1,2] There are several advantages to using layered compounds rather than bulk powders for photocatalysis. Layered compound is rich in variety, in addition, modifications of them are easily performed by exchanging alkali metal cations in the inter layers for H + or other metal cations. The most important advantage is that some layered compounds have considerably high photocatalytic activities than bulk catalysts because the electrons and holes generated in each thin inorganic sheet readily reach interlayer spaces as reaction sites at the illterlayer spaces. It should be very important for further improvements· of layered photocatalysts to utilize two-dimensional inorganic sheets effectively."

Jan 1, 2000

By T P. Medhurst

In many cases mine design is the most important driver of the profitability of a mining project, however to reach an æoptimumÆ mine plan many compromises have to be made. Some of the fundamental profit (and loss) drivers relate to stoping methods and stope design parameters. Inevitably trade-offs have to be made between the stability of underground openings, ground support costs and production efficiency. This paper looks at the role of geomechanics in the mine planning and design process. The concepts of æcontrollable lossesÆ and æuncontrollable lossesÆ are developed as a means of partitioning ground control costs. A stope design example is given which provides a method of examining mining costs, and includes a decision making element in order to quantify geotechnical impacts and select stope dimensions. The method also provides a general framework as a means of balancing ground control costs against maximising returns from an underground mining project.

Jan 1, 2000

By Hiroyuki Sano, Chikabumi Yamauchi, Mitsuru Tanahashi, Toshiharu Fujisawa, Shin-ya Iwahori

"Pyrometallurgical process using Cu2O-based slag was proposed as a recycling process for copper scrap. However, it is difficult to remove nickel from copper by oxidative refining. Therefore, it is necessary to reduce the concentration of nickel in copper before the oxidative refining. In the present work, the copper enrichment stage in this recycling process, where copper scrap melt is separated into the Fe-C-Cu melt and the molten copper, was taken up and the compositions of both melts were measured. Based on the above results, the distribution ratios of nickel between the Fe-C-Cu melt and the molten copper were calculated. Furthermore, the optimum condition of copper enrichment stage was discussed from the viewpoint of nickel removal and copper recovery. The possibility of recovering 4N-purity copper by using this recycling process was confirmed.IntroductionRecycling is well known as a method for saving resources and reducing environmental damage. More than 99% of copper is used in metallic form - as metal or copper alloys[l]. High-grade copper scrap is directly re-melted and reused, while low-grade copper scrap is transported to copper smelters to be pyrorefined and electrorefined. Nevertheless, a great amount of copper is being stockpiled in the cities and should be recycled in the near future. At that time, the current recycling process will face new problems due to the increases in the recycling rate to the smelters. This includes insufficient combustion heat to melt copper scrap and ·almost no benefit in electrorefining because the scrap does not contain gold and silver. Thus, an alternative pyrometallurgical method for copper scrap refining will be required."

Jan 1, 2000

By V. V. Khristenko, V. I. Dubodelov, V. A. Seredenko, B. A. Kyryyevsky, H. V. Seredenko

"During the last decades investigators of many countries shows an increased interest to alloys which are characterized by miscibility gap in a liquid state. It is connected with essential possibilities of control of structurization in such alloys because of the melt at certain temperature parameters is · emulsion with disperse phase inclusions. These ensure essential influence ·on structurizations.The certain inclusions can play a role of lubrication ensuring ""wearless"" process. The sizes of inclusions of this phase can be rather large proportional to sizes of strengthening phase (up to 1000 nm). Other inclusions ensure process of strengthening of a main material. In this case requests to a dispersibility character of distribution and structure of such inclusions are much higher.The multicomponent alloys of system of copper - (Fe - Cr - C)- alloy concern to the number of advanced compositions. The copper alloys with structure of a type of a ""frozen emulsion"" in which strengthening phase· is a chromium pig-iron are characterized by high thermal stability in the extreme operating conditions. The mechanism of inclusions forming is emulsifying of a melt in miscibility gap at temperatures close to temperature of binodal under superimposition of external effects.The main complexity of producing of ware from such alloys is .a providing in their structure of necessary dispersible inclusions uniformly distributed all over the volume. Thanks to a selective action of electromagnetic fields on liquid phases with various electroconductivity relative velocity of phases is created and is regulated the ratio of their ""apparent"" specific gravity is changed. Excitation of pulsing force effects with the certain frequency on interphase surface allow actively to influence on process of a dispersion of a liquid metal medium."

Jan 1, 2000

By C A. Fleming, C J. Ferron, P T. OÆ

A new process is described which allows for direct recovery of base and precious metals (Au and PGMÆs) from sulphide concentrates or other feedstocks. The process was developed initially for application to ores or concentrates that are too low-grade for economic treatment by the conventional smelting and matte leaching process (for PGMÆs). It is now believed that the process may be widely applicable to a variety of materials including PGM concentrates containing high amounts of chromium or magnesium. Operating conditions have been identified under which gold, the PGMÆs and the base metals dissolve simultaneously in a pressure leaching autoclave. The product of this leaching process can then be treated by one of several flowsheets, of which the preferred will likely involve solid/liquid separation, followed by precipitation (or adsorption on activated carbon) of gold and the PGMÆs, followed by copper solvent extraction/electrowinning. Depending on the concentrations of nickel and cobalt, the copper raffinate would either be partially recycled to the autoclave to allow Ni/Co concentrations to build up, or it would proceed directly to a Ni/Co refinery. This paper deals with the pressure leaching process and the recovery of gold and the PGMÆs from the pressure leach product.

Jan 1, 2000

By Osvaldo Bascur

Large metallurgical complexes have more data than a small city and much of it is "real time," changing rapidly as internal and external conditions evolve. As corporations buy and sell assets and reengineer their staff, the structures and tools that were used to understand these data are lost. This results in significant deterioration in the ability to maintain a "smart" operation. The solution is to use the sophisticated new tools built for the Internet so as to leverage information in a familiar browser format that people can use and understand. This paper describes the use of Internet technologies with plant data. Examples are drawn from existing industrial sites. Users must project where this technology will lead - standing still is the most dangerous philosophy and the only one guaranteed to be obsolete. These examples show the way to leverage existing workers with information technology.

Jan 1, 2000

By G. Riverin, C. Simard, W. D. Stevens

"An on-line technique to measure the efficiency of decoating I delacquering processes is being developed by Alcan' s Arvida R & D Centre. Decoating processes are used to remove moisture and coatings from shredded coated material such as Used Beverage Containers (UBC) before melting. Complete removal has been demonstrated to maximize metal recovery. Quantifying the weight of carbon and organic residue adhering to the shred surfaces is very difficult to measure directly, as the material can be highly folded. The technique developed indirectly measures the residue remaining by analysing the concentration of CO evolved in the decoater end zone exhaust gas.A commercial CEMS (Continuous Emission Monitoring System) incorporating an infrared type CO gas analyser was modified for on-line process exhaust gas analysis. Both pilot and plant trials had demonstrated that the CO concentration measured was inversely proportional to the efficiency of the organic removal achieved. As the quality of coated purchased scrap can be highly variable in moisture and organic content, continuous measurement should permit adjusting the feed rate and other decoater process parameters to the quality of decoating required."

Jan 1, 2000

By Th. Probst, M. Reuter, H. Orbon, U. Boin, J. Vonken, P. Vonk

Although secondary aluminum industry is well established in the world, the recycling process still requires further development to adequately control the process for a higher aluminum yield and a better product quality. In the present paper, recyclabilities of different aluminum scraps have been experimentally studied. Four types of commercial scraps were characterized and melted at 800 - 900 °C to recover 'aluminum metal with the protection salt flux of NaCl-KCl-Na3AlF6 under nitrogen atmosphere. According to the results, the difficulty of recycling aluminum scrap depends on the cleanness and the ratio of surface area to body volume. More non-metallic contaminates and higher ratio of surface area to body volume usually led to a lower metal yield. Usually cast ingots gave better results than rolling mill cuttings under similar conditions. Bottle caps can be recycled more easily than the margarine foil. The effect of temperature was not as significant as the composition of salt flux. The addition of cryolite was essential for a better metal recovery, especially for the scraps with higher surface area. Recycling

Jan 1, 2000

By C. Allen, A. Roy, J. W. Evans

A spouted bed electrode (SBE) has been used, in laboratory experiments, to electrowin zinc from zinc chloride electrolytes with the objective of determining the suitability of this electrode for commercial application. Zinc was successfully electrowon at current densities ranging up to 4,38 lA/m2, which are an order of magnitude larger than those used at present in the zinc industry. Current efficiencies, for the cell with the SBE, have been as high as 90% and DC energy consumption as low as 2.8 kWh/kg zinc deposited. The performance of the cell has been measured as a function of current density, anode type, cell diaphragm, addition of tributyl ammonium chloride and purging of the electrolyte (to remove dissolved chlorine).

Jan 1, 2000

The notion of wayfinding, as conceptualized by planners, geographers, and psychologists, denotes the ability of an individual to move from one point to another through physical space. In order to achieve this movement, a person relies on a cognitive map of spatial representations [Passini 1984]. Which features of this cognitive mapping will be stressed depend, in part, on the researcher's perspective. A planner, for instance, would tend to emphasize the effect of physical structures on mobility. A psychologist, on the other hand, might focus on individual differences in how human minds encompass and represent physical space [Evans et al. 1984]. There is yet another dimension to wayfinding that needs consideration, and it rests upon the idea that reality, as experienced by human beings, is mediated: "[People] have preselected and preinterpreted this world by a series of commonsense constructs ... which help them find their bearings in their natural and socio-cultural environment and to come to terms with it" [Schutz 1967]. These "common sense constructs" are arrived at socially and constitute the agreed-upon schemas that guide people's everyday activities. According to this principle, cognition is governed by some nonlogical factors that reflect not only individual procedures but collective ones as well. These group strategies, which are shaped by shared rules and values, influence "the information gathered, the ways it is processed, the inferences that are drawn, the options that are being considered, and those that are finally chosen" [Etzioni 1992]. From this perspective, cognitive maps, rather than being individual-centered templates of environmental images [Rovine and Weisman 1989] or representations of spatial relationships [Evans 1980], are partially group-centered schematic processes. As such, they are subject to reinterpretation, revision, and outside intervention [Kaplan and Kaplan 1982]. As intermediaries between the environment and behavior, cognitive maps serve as bases for decision-making. Traditionally, it has been assumed that good maps facilitate correct decisions, which in turn leads to optimal performance during wayfinding [Hunt 1984]. Given the argument that there is a social (non¬cognitive) facet to cognitive mapping, however, this image of a cognitive map as some sort of static reference construct that motivates individual action is too narrow and mechanistic. If cognition involves less a knowledge of the environ¬ment than it does the process of "giving it meaning through imposing an order on it" [Rapoport 1976], then wayfinding behavior is not j ust a function of setting and individual differences, but is also a function of one's "normative-affective" structure [Etzioni 1992]. Rapoport [1976] used such an assumption as the base for a set of hypotheses about the connection between "external demands" and "organismic factors." One significant assertion deriving from Rapoport's ideas is that environmental

Jan 1, 2000

By Dan Marshall, David H. Watkinson

Abstract - Cobalt, Ontario, is renowned for the 12.6 billion grams (445 million ounces) of silver produced from the area since discovery in 1903 by workers of the Timiskaming and Northern Ontario Railway. Native silver generally occurs with cobalt arsenides and sulfosalts in near-vertical carbonate veins cutting the Huronian sedimentary rocks of the Gowganda Formation, the Archean metavolcanics and/or the Nipissing diabase. All major deposits have been found within a few hundred meters of the unconformity between the Archean and Huronian rocks in general proximity to the Nipissing diabase and volcanogenic sulfide mounds within the Archean meta-volcanics. Silver has been mobilized from one or more of the local country rocks by hyper-saline brines and deposited in or near zones of mixing where the saline brines encounter paleometeoric water transported to depth along the unconformity or local structures. Previous work has shown that chloride complexes are the dominant ligands responsible for silver transport. These hypersaline brines, represented as halite-bearing fluid inclusions at room temperature, have been trapped as primary fluid inclusions within vein minerals. Pressure-temperature conditions of vein formation have been derived from mineral equilibria, maximum lithostat and fluid-inclusion studies. These data are consistent with vein formation occurring over the temperature range 300°C to 350°C, with pressures constrained between 60 Mpa and 136 Mpa (600 bars and 1360 bars).

Jan 1, 2000

By Mikiya Tanaka, Mikio Kobayashi, Mansour A. S. A1Ghamdi, Kenji Tatsumi, Yukinori Saiki, Hirotaka Senba

"In order to recover nickel ion in a spent electroless nickel - phosphorus alloy plating bath and, at the same time, to remove impurities such as iron and zinc, the applicability of solvent extraction with LlX84I as the extractant has been investigated using actual spent solution. Although the extraction efficiency of nickel from the spent solution is considerably lower than that from the nickel sulfate-nitrate solution, nickel in the spent solution is selectively extracted with high efficiency at the pH of 6 - 7. The extracted nickel is effectively stripped by sulfuric acid at a pH of less .than· 3. On the basis of these results, a· flowsheet for recovering nickel from the spent solution is proposed Chemical equilibrium calculations of the spent solution has shown that the complex formations of nickel with anions such as lactate and phosphonate ions become predominant in the pH range between 2 and 6. This results in the depression of nickel extraction efficiency from the spent solution as compared with that from the .nickel sulfate-nitrate solution. By combining these aqueous equilibrium calculations with the· extraction model considering the extraction stoichiometry and the aggregation of the extractant in the organic phase, the extraction behavior of nickel is quantitatively predicted.IntroductionElectroless plating is indispensable for the recent advanced industries such as the electronic and mechanical industries. Electroless plating baths are repeatedly used by supplying the metal salts; however, the accumulation of the counter anions of the metal ions, the components formed by the oxidation of the reducing reagents in the plating baths, and the metal ions as impurities dissolved from the surface of the objective materials degrades the· quality of the plating. Thus, the baths are finally treated by a precipitation method to form a large amount of metal sludge, which is disposed in dumping sites. Therefore, from the standpoints of environmental protection and resource preservation, it is highly desired to establish a recycling process of the plating baths with minimum emission. Solvent extraction seems to be one of the 'suitable methods to recover metals from the spent electroless plating baths, because the concentration of the metal ion in the baths is relatively high, which is advantageous to solvent extraction as compared with the ion-exchange and adsorption methods. Some studies about the application of solvent extraction have already been carried out using simulated spe11t electroless plating baths [1-3]."

Jan 1, 2000

By Yoshihiko Maeda

"Although Japanese mining industry once had been a polluter of toxic heavy metals and gasses, it has been struggling for improvement of environment at mining and smelting facilities under the strict Japanese regulations. Through these efforts, the industry has developed various environmental technologies to be applied in other industries and society.Recycling of metal scraps, for example, has been conducted at smelting facilities. Treatment of hazardous waste, cleanup of contaminated soil and management of landfill are other examples of application of mining and smelting technologies and facilities. In accordance with the worldwide environmental concerns, the industry has become one of the leading industries to promote ""Sustainable Development"", and it is expected further contribution in reducing various environmental burdens to earth by utilizing its mining and smelting technologies and facilities. Some of the examples of these applications are presented in this paper.IntroductionDowa Mining Co., Ltd., established in 1984, is known as one of the ~op Japanese producer of nonferrous metals. Base on its special expertise in the mining and smelting of complex ores, it has expanded its business areas to downstream activities ranging from highly purified metals and alloys, electronics materials, chemicals and related various businesses. Dowa Mining now is becoming more active in the field of waste treatment and recycling.Dowa Mining had operated some mines until 1980th, located at the western part and northern part of Honshuu Island in Japan; the former is pyrite mine while the later is ""Black Ore"" mine,· a complex sulfide ore composed of high grade of copper,· silver, lead and zinc. However, due to the strong yen began in1985; Dowa Mining closed its mining operation in 1994, and has sifted to mining operations in Mexico."

Jan 1, 2000

By Ken-ichi Machida

"Surface modification of R-Fe-N intermetallic compounds was made to improve their magnetic property and nitrogenabsorbing ability, arid high-performance resin-bonded magnets and nitrogen storage materials were developed: Surface coating for Sm2Fe11Nx by the zinc metal produced via photodecomposition of Zn(C2Hs)2 was effective to avoid the further oxidation in the molding process of the fine powders for bonded magnets and the resulting (BH)max values were improved to -186 kJm-3. Meanwhile, R2Fe17 as the mother compounds for RzFe11Nx was highly active for decomposition of NH3 molecule and subsequent nitrogen absorption as metal nitrides. Furthermore, even inert Nz molecule was dissociated on them by impregnating Ru metal and the resulting nitrogen atoms were absorbed in the crystal lattice of R2Fe17. These results demonstrated that the nitrogen storage system was established by cycling the nitrogenation and hydrogenation of RzFe11/R2Fe11Nx materials.IntroductionProcessing for rare earth metals and intermetallic compounds requires well-controlled conditions in order to avoid the oxygen contamination involved in it due to their high reactivity, as causes the serious damage for materials such as magnets, metal hydride for hydrogen storage, and so on. Rare earth-iron intermetallic compounds, R2Fe17, provide the corresponding metal nitrides (R2Fe11Nx) by heating in N2 or a mixed gas stream ofNH3-H2 [l] and, among them, Sm2Fe11N3 has been particularly noted as one of the promising materials for high-performance permanent magnets such as bonded ones [2- 6]. Usually, the nitrogenation for Sm2Fe17 is made in Nz, but it needs the much more hard conditions of reaction pressure (-10 MPa), temperature (-550°C) and time (-72 h) than the nitrogenation in the NH3-H2 mixture [l]. In the latter case, a significant amount of nitrogen can be interstitial introduced in· the R2Fe17 crystal lattice (x=-7) under the more moderate conditions than in N2 (at 0.1 MPa and -450°C for -3 h) [3-6] and then, in a similar manner as metal hydride systems [7], the excess nitrogen in RzFe1 7Nx (x>3) is reversibly desorbed by heating at a temperature around 500°C in Ar to form the RzFe11N3 compounds. This behavior of nitrogen absorption and desorption has a close relation to the sites for nitrogen in the crystal lattices."

Jan 1, 2000