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Geopolymerization is a process by which Al-Si minerals undergo dissolution and polymerization in an alkaline solution to form a monolithic material with a high mechanical strength (Davidovits, 1991; 1994). In this study, Na-feldspar (albite) and K-feldspar (microcline) have been selected to investigate their abilities to undergo geopolymerization. The interaction between alkali metals present in the alkali-feldspars and alkali metal cations contained in alkaline solution during geopolymerization has also been studied. It has been found that both albite and microcline can be applied in geopolymerization to produce geopolymers with a high compressive strength. Although the dissolution of M-feldspar (where M = Na and/or K) in concentrated MOH solution is inhibited when the alkali metal cations of the alkaline solution differ from the alkali metals structured in M-feldspar, the resulting geopolymers are found to demonstrate a higher compressive strength. Moreover, a proper molar ratio of Si/Al in the geopolymeric gel phase and a higher average hardness of the undissolved particles remaining in the geopolymers are found to greatly increase the ultimate compressive strength of the geopolymers.

Jan 1, 2002

Mine rehabilitation is a sustainability issue that has been revisited ad infinitum; however, the persistent lack of demonstrated on-the-ground performance and an increasingly intractable rehabilitation liability in Queensland continue to erode the credibility of the mining industry and regulatory bodies. For at least ten years the need to change the current, process-based approach to rehabilitation to an outcomes-based approach has been apparent. The ISO 14001 series temporarily diverted attention from this important point, however it would appear the limitations of an ISO 14001 approach are now more widely accepted. It is proposed that a successful outcomes-based approach cannot be achieved without meaningful community engagement. The apparently intractable nature of the rehabilitation issue will continue to generate conflict and criticism unless all stakeholders are encouraged to participate in the process of developing robust and practical outcomes for rehabilitation. Sharing the responsibility will ensure the best possible outcome. It is important to recognise the valuable resources inherent in community groups, many of whose committed volunteers have considerable expertise in relevant areas. Community groups should not be seen as adversaries but as allies in the process of solving problems that affect the wider community. Several projects that can be seen as test cases for the engagement of stakeholders exist, and in this paper the process of achieving multiple stakeholder engagement in the context of Environmentally Sustainable Development is discussed.

Jan 1, 2002

By E. S. Peterson, M. K. Harrup, K. A. Dolbeare, J. E. Wey

Efficient methods for removal of copper from heap leach solutions without mobile organic phases are a current mining industry need. To satisfy this need a selective, high-capacity, durable solid material is required. The INEEL has developed a set of materials based upon current solvent extraction chelates that provide selective copper concentration in the presence of high concentrations of iron. In contrast to conventional solvent extractions, our strategy anchors the chelators to a non-polymeric solid substrate through the use of a custom designed linker molecule. The fundamental synthetic routes to these materials have already been established and attachment to the solid surfaces achieved in an efficient manner. Our continuing research is focused on the optimization of the synthetic pathways to these solid materials and the evaluation of their copper capturing capabilities.

Jan 1, 2002

By K. S. E. Forssberg, S. Subramanian, Hanumantha K. Rao

The dispersion characteristics of apatite and magnetite minerals have been assessed based on zeta-potential measurements, using various inorganic and organic reagents, namely sodium silicate, sodium tripolyphosphate, sodium hexametaphosphate and lignin sulphonate. These results highlight that apatite is dispersed to a greater extent vis-à-vis magnetite. Further, the dispersion efficiency of the phosphate reagents is better than that of sodium silicate or lignin sulphonate, for both apatite and magnetite. Batch flotation tests on a high phosphate magnetite ore from Kiruna indicate that higher apatite recovery with minimum phosphorous loss to the magnetite fraction can be achieved using sodium silicate as a dispersant. Although comparable dephosphorization can be attained with lignin sulphonate dispersant, the recovery of magnetite in the non-float fraction is lower, possibly due to the adverse synergistic effect of this organic reagent with the Atrac collector, resulting in the flotation of magnetite. The high intensity conditioning of pulp for up to 30 min resulted in better apatite flotation with <0.015% phosphorous in the magnetite product.

Jan 1, 2002

By Arthur E. Morris

Process modeling software is used extensively in process engineering, but there is a notable lack of affordable software for educational uses. This paper describes two educationally oriented software programs for thermochemical modeling of processes involving metals, minerals, and ceramic materials. Both programs run as Excel@ spreadsheet files. The first is FREED, a thermodynamic database program containing datafiles for 2500 species. It contains the entire U. S. Bureau of Mines and most of the U. S. Geological Survey database, plus data for scores of other species drawn from various sources. Several modules are available for manipulating and viewing the data. The second program is THERBAL, for making thermodynamic calculations using FREED data. Equilibrium calculations can be made for systems with non-ideal solutions, for a specified set of pressure, temperature, and input amounts of reactants. An optional heat balance is also calculated. The results are displayed as tables or charts in Excel worksheets. Examples of the use of THERBAL will be given for the reforming of natural gas for DRI production, DRI production, and EAF steelmaking. Some observations will be made on its use in the classroom. The development of FREED and THERBAL was initially carried out at the Department of Metallurgical Engineering, University of Missouri - Rolla as part of a project to preserve and enhance the Bureau of Mines database. The current versions were developed privately by the authors.

Jan 1, 2002

By P J. White, J V. Lawless

Low-sulphidation epithermal gold deposits, which form in quasi-hydrostatic convective hydrothermal systems, frequently contain chalcedony within high-grade ore, which has been interpreted to be a crystallisation product of amorphous silica. To deposit amorphous silica rather than another silica polymorph at elevated temperatures requires very high silica concentrations, because of its relatively high solubility. Only extreme boiling caused by decompression followed by wall rock heating upon structural dilation, can achieve this. As gold deposits with amorphous silica it must be produced by the same mechanism, particularly since extreme boiling is also a very effective mechanism for gold deposition. Recent developments support this view; the first is the detailed isotopic analysis of chalcedony-bearing high-grade veins reported from Hishikari, Japan, in which oxygen isotope results are indicative of extreme boiling and hydrogen isotopes indicate initial deposition of amorphous silica. The second is the finding of chalcedony within geothermal pipe work in the Rotokawa geothermal field in New Zealand. Rotokawa is a comparatively hot field (335¦C at depth); hence separation of the steam-water mixture produced by the wells is undertaken at a comparatively high temperature (220¦C) to minimise down-stream silica scaling. Even so, silica scale, some of which is chalcedony, does occur, under similar conditions to that in low-sulphidation epithermal deposits. Evidence of chalcedony forming under these conditions, reinforces the interpretation that decompressive boiling is the main deposition mechanism for gold in low-sulphidation epithermal deposits. It is possible that there is sufficient drop in temperature due to decompression that, at least initially, the silica deposits directly as chalcedony. Low-sulphidation epithermal gold deposits that do not contain chalcedony, such as those in the Philippines, may form at temperatures too high for chalcedony to directly form. The recognition of decompressive boiling as the main deposition mechanism in low-sulphidation epithermal deposits means that exploration can focus on zones where this has taken place by combining paleohydrological reconstruction and structural geology.

Jan 1, 2002

The integration of mining and mineral processing technologies into new advanced mining systems is considered to offer several benefits, including selective mining, reduction in waste, increased productivity, flexibility, and improved resource utilization. This paper focuses on underground hardrock mining and the integration of pre-concentration technologies into future mining systems as representing realistic, shorter-term integration options. Control of fragmentation to optimize grinding, pre-concentration of ores, in situ leaching, and modular mining/mineral processing systems are possible with existing technology. Current research is directed toward development of integrated underground systems that minimize surface activity and minimize or eliminate surface waste disposal. Results from a simulation model of an integrated underground pre-concentration system are presented.

Jan 1, 2002

The interaction between ore-bearing fluids and the siliciclastic rocks typically hosting orogenic gold deposits in Phanerozoic metamorphic terrains result in the development of a distinctive alteration halo. Along with petrological changes such as the replacement of chlorite by carbonate and the growth of sericite, characteristic geochemical modifications take place within this alteration envelope. These include variations in elemental abundances and more or less pronounced shifts in the H, C, N, O, and S isotopic signature of the ore system. æFingerprintingÆ these isotopic trends can provide exploration with additional vectors towards the ore zone, and yields valuable information regarding the source of the hydrothermal fluids and the solutes contained therein. Data from radiogenic isotope systems such as Sr-Rb, Ar-Ar, Xe-Ra, Pb-Pb, Re-Os, Sm-Nd, and U-Pb can constrain the kinematic history of ore-hosting structures, provide important clues concerning the absolute timing of gold emplacement, and enable the detailed characterisation of associated intrusives with respect to their magma source(s) and crystallisation age. Although high analytical costs, long turn-around times and the potential for misinterpretation prevent isotope systems from offering a æquick & dirtyÆ analytical method that would provide a significant advantage in exploration for orogenic gold mineralisation, the development of integrated four-dimensional ore genesis models depends heavily on constraints obtained from isotope mass spectrometry.

Jan 1, 2002

By M. H. Al-Dabbagh

In this paper, the authors outline the deficiencies of PERT/CPM as a method for scheduling complex projects such as mine development. In particular, PERT/CPM networks cannot accommodate logical nodes (events) or stochastic branches (activities). The Graphical Evaluation and Review Technique (GERT), developed by Pritsker and. co-workers, is introduced as an alternative to PERT/CPM that overcomes many of the deficiencies of the latter and enables a more realistic analysis of complex projects that are subject to significant uncertainties. A brief overview of GERT network structures and network analysis is given and a PC implementation of the method is described. The technique is illustrated by application to the development of an open-pit gold mine in Saudi Arabia.

Jan 1, 2002

By Paul Grisley

Air-supported belt conveyors-conveying systems that replace troughing idlers with a film of air-were a revolutionary concept when introduced in the 1970s. But high installation and operating costs limited their application. Now, system refinements have led to successful applications, even under the challenging conditions of mines and process plants. In this presentation the author will discuss the latest developments in the engineering of these systems, including the ability to retrofit existing transfer points with modular air conveyor components. Air conveyor applications and limitations in mineral-handling operations will also be examined.

Jan 1, 2002

A standard practice of auditing mill designs has developed in the mining industry. The purported aim of this task is to ensure that the mill being offered conforms to the design specification, thus reducing the purchaserÆs risk. However, careful examination of the auditing methods used in the past shows that this is not the case. In some cases, what auditors have been providing is effectively a quality assurance check of the input data, not a full independent audit of the vendorÆs design. It will be shown that these past auditing methods have contributed to the stagnation of mill specification development. This lack of specification improvement combined with the current trend towards increased allowable fatigue stress ranges can result in an increase in risk for the purchaser.

Jan 1, 2002

By H. B. Oblad

The WEMCO® SmartCell™ flotation machine is a continuously-stirred tank reactor in which solids are suspended in water and are contacted with air. The reaction is particle flotation resulting in the separation of valuable material from gangue. The effects of several operating variables on the flows of water and air and on motor power were measured. A miniature magnetic flowmeter was installed in the draft tube that allowed measurement of the water flows into the rotor. This work has led to a better understanding of machine function which will lead to improved performance and better operation. General equations for optimization, design, and scale-up were inferred.

Jan 1, 2002

Transformations of minerals to processed mineral products fundamentally involve wholesale chemical change, and therefore have a high potential for the release of chemicals and wastes. In this regard minerals processing contrasts with downstream production operations, which involve mainly physical changes. The contrast with mining, which must take place where the minerals are found, is that mineral processing allows choices as to location, processes, fuels and reductants. These choices provide a foundation for dealing with issues of resource stewardship. This paper locates the mineral processing industry in the global perspective by quantifying the masses of major material inputs and outputs, based on current processing choices. Estimates for recycling have also been collated, revealing figures that differ surprisingly from commonly held impressions. The paper draws on a variety of current sources, mainly those available through the Internet, to rank the major transformed virgin mineral products by production, price and value. The figures demonstrate the dominance of Portland cement and steel in the global environmental impacts of mineral processing. Aluminium comes a distant third in the list, and the metals particularly associated with localised environmental impacts have relatively small global effects compared with those of the staple materials of our built environment. This global macro input/output perspective, with materials flows expressed per unit of virgin product, provides a benchmark for grasping sustainability challenges within specific operating businesses. Because of the global scope and pervasive impact of the minerals processing industry, the issue of resource stewardship is rising as a matter for public concern. There appears to be a developing view that the mining and mineral processing sector should take responsibility for these products throughout their various life cycles. However, in a future of stabilising consumption, dematerialisation and intensive recycling, the mining industry would only need to provide the top-up to a stock of recirculating materials. The question of responsibility for stewardship over SocietyÆs stock of materials remains open.

Jan 1, 2002

Problems caused by water discharge from surface mine ventilation shafts can be significant and are usually unforseen. The discharged water is often hyper-saline or acidic and can cause environmental degradation over a wide radius. It can also lead to recurring power pole fires and primary fan breakdowns. A range of solutions to the water discharge problem has been implemented in many Australian mines. In most cases the solutions have been ad hoc, with the overall cost and effectiveness varying tremendously. This paper reviews and contrasts the practicality and effectiveness of the various available remedial options.

Jan 1, 2002

By Valentin Choquenaha Bombilla, Oscar Alvarez Muiloz

"Tintaya’s basic production line is copper concentrate, which has an important gold content. The process used is flotation; the objective of the metallurgical department is to obtain the best results in the copper recovery without neglecting the gold, using very specific reagents. Copper recoveries are considered high, nevertheless every day emphasis is placed upon increasing those recoveries. Regarding gold, optimum recoveries could not be achieved with flotation; and implementation of a gravity circuit was considered.According to microscopy studies, the coarse and very fine grains of gold in native form are lost to tails. The native gold due to its high specific gravity is concentrated at the underflow of the cyclone, remaining in the circulating load of the circuit. It reaches three times the concentration compared to the head grade entering the ball mills. This re-circulation generates very fine and laminated gold particles inside the ball mill, passing to the classification stage making a short circuit to the overflow of the cyclone.The very coarse gold particles as well as the thick flakes of gold do not react favorably to the conventional flotation process; thus studies that have included gravity separation have been conducted to increase the gold recovery. Part of the research included concentrating tables, jigs, and Knelson Concentrators. The Knelson Concentrator proved to be the best selection in terms of metallurgical performance and recoveries considering the throughput and operation conditions of the Tintaya Plant.The gravity concentration circuit with the Knelson Concentrator was commissioned in BHP Tintaya in October 1998, as per the flowsheet shown later on. Presently the global gold production surpasses any estimated expectations.Present efforts are directed towards showing the evaluation and optimization of the different parameters that govern the performance of the Knelson concentrator, as well as illustrating the difficulties and successes throughout the operating period.In the first year of operation 200 tons of gold concentrate have been produced with an average concentrate grade of 320 gramdton, having paid back in full the cost of the automated KC-XD- 48 Knelson Concentrator, the peripheral equipment, and the cost of the installation."

Jan 1, 2002

MIM Holdings Limited has acquired a reputation for the successful application of R&D to develop break-through technologies for the mining industry. The Isa Process tank-house technology has been licensed to copper refineries throughout the world, and almost 40 per cent of the worldÆs copper is refined using this technology. Isasmelt copper and lead smelting technology is either in use, or is currently being installed, by eight companies in eight countries around the world. Jameson Cell technology is widely used in the coal mining industry and increasingly in the base-metal industry. The IsaMills developed at Mount Isa and McArthur River made it possible to develop the McArthur River and George Fisher orebodies. This paper will address the need for innovation and then discuss the development of the IsaMill and Isasmelt technologies. It will conclude with some comments about why MIM has been so successful in developing such technologies.

Jan 1, 2002

By Narong Thasnanipan

Performance of diameter 1.5 m toe-grouted bored pile founded at depth 44 m in sand-gravel formation of Chiang Mai City is presented in this paper. Toe grouting was applied by using tube-a-manchette method. Effectiveness of toe grouting was observed from the standard penetration tests conducted immediately below pile toe through grouting pipes at two stages, prior to grouting and three weeks after completion of grouting. Improvement of pile end resistance by toe-grouting is demonstrated with a series of back analyses carried out by load-transfer method employing hyperbolic transfer function. Construction experience of large diameter deep-seated bored piles in multi-layered subsoil and practical aspects of toe-grouting are also briefly discussed.

Jan 1, 2002

By John Lemke

Current practice for monitoring static pile load tests commonly consists of measuring load and displacement at the top of a pile. This is typically accomplished by monitoring dial gauge movements, line pressure of a hydraulic jacking system, and electronic load cells on occasion. While this testing approach provides useful information for one boundary condition (the top of the pile), a system that measures movement and/or strain along the entire length of the pile can provide additional useful data that can be used to refine pile design. Automated data acquisition systems provide the essential ingredient that can integrate these types of sophisticated instrumentation devices into a standard pile load test program in a cost effective way. This paper provides a general overview of pile testing instrumentation and describes a newly developed chain of instrumentation modules that can be embedded in a pile to gather additional testing information. The new system can measure forces and movements within the test pile synchronously with measurements at the pile top, and the direct application of this system to axial and lateral pile testing is illustrated. This is particularly relevant to the design of ACIP and drilled displacement piles since determination of the reinforcement cage length is important from the standpoint of both seismic design and foundation cost.

Jan 1, 2002

The modern theory of sampling of particulate minerals essentially consists of a recent generalization of the procedures for applying and calibrating the formula usually known as ?Gy?s Formula? for sampling variance control, in which the central concept is a parameter called the liberation factor l. A model which can be experimentally adjusted was proposed by one of the authors several years ago, based on geostatistical considerations. This new model, which relates the liberation factor to the sizes of the fragments and mineral grains, solves the usual difficulties faced in the past, and permits predictions that are well verified in practice. Unfortunately, an older, arbitrary and less general formula is still widely used. The vast majority of today?s misapplications of Sampling Theory of Particulate Materials can be traced back to the use of this antiquated and generally incorrect model. Following a brief history of the models used for the liberation factor and a description of its main variable, the liberation size, and to illustrate the importance of proper modelling of l, this paper presents demonstrative calculations of the absurdity of the incorrect model using the particular case of gold mineralization as an example, followed by some more positive examples of application.

Jan 1, 2002

By Alain Bouchard, Germain Labonté, Jim Barrett

"Mill feed materials that are not run-of-mine ore are often a challenge for mineral processors and tend to accumulate in stockpiles, where they remain unprocessed for many years and become “slow moving inventories”. During a complete re-evaluation of the Clarabelle Mill operation (38,000 ton/day capacity) in 2000, it was concluded that there was an opportunity to assemble a 5,000 ton/day custom circuit to treat such stockpiles in the equipment that remained available during regularly scheduled maintenance shut-downs.This project was part of the larger Mill Redesign Project and involved testing the intended flowsheet under a number of operating scenarios for the first material to be treated: spent refractory bricks. The laboratory focus was on how to maximize returns using the available equipment and reagents.The circuit was successfully commissioned in the fall of 2000. As the brick stockpile was depleted, other potential feeds were evaluated at the laboratory, as well as in the new custom circuit itself. Processing of the spent refractory brick has yielded a significant contribution to the profitability of INCO. Significant opportunities lie ahead for generating more value from other slow moving inventories.INTRODUCTIONIntegrated mining operations tend to have slow moving inventories along the path from the mines to the finished products. Spent refractory bricks from furnaces and converters and furnace bottoms are materials that often end up in long-tern stockpiles. Such stockpiles are a challenge, although they represent small tonnages on an annual basis, because they are unique materials, which cannot be readily brought into the process at a rate anywhere near that at which they are produced, due to the high contents of deleterious components such as chromite or magnesia. Accumulation over years will eventually yield a metal inventory worthy of consideration given the right opportunity, such as availability of spare equipment or peak metal prices."

Jan 1, 2002