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By Joseph Bloch

The hydriding of bulk metals and alloys is a gas-solid reaction in which a hydride product layer is initially nucleated adjacent to the gas-solid interface and continues to grow until a complete transformation of the parent (a) phase into the hydride phase. The combination of measurements of the overall hydriding kinetics of samples having defined shapes and dimensions, together with examinations of partially hydrided samples, enables the presentation of the reaction rate in terms of an appropriate reaction model. A common and important type of topochemical development of the hydride in bulk metals and alloys involves a hydride layer formed on the metallic surface. The continuity of the layer can affect the reaction rate. The rate of hydrogen absorption in a sample, in the presence of a hydride layer, is usually analyzed using a model combining several sequential steps in which the hydrogen is transferred from the gas phase into the reaction site. Coupling the flux equations across the layer under proper steady state conditions, results in a complex rate equation in which the steady state rate of hydrogen absorption (proportional to the hydride layer velocity) is expressed in terms of the pressure, temperature, the rate constants of the sequential steps and the critical concentrations of hydrogen in the hydride. Generally, the rate constants of the individual microscopic processes are comparable in magnitude, so that the overall rate is not controlled by any of the specific sequential steps. However, there are two limit cases related to the first stage, the adsorption, for which the general rate equation is much simpler, namely, the fast and the slow adsorption approximations. Using this limit cases, equations are derived for the steady state hydriding rate of a given system. These equations provide means to anticipate the pressure dependence of the steady state absorption rate under low pressures, close to Peq and under very high pressures. At the low pressure regime both the fast and slow absorption cases yield linear pressure dependence. For the very high pressure range, it is found that the rate become independent of the applied pressure. The rate is given then by a combination of the individual rate constants of the system and the critical hydrogen concentrations. The model is shown to apply in several real cases, such as ZrCo, LaNi5 and titanium.

Jan 1, 2002

By Miie Shields, Ed Billington

Trail blasters for the National Park Service (NPS) live and work in remote mountain terrain throughout the western states, where any support or resupply may be sporadic and ditlicult and mountain weather affects every activity. Mechanical “aids” are the pick, shovel, rock-bar, wheelbarrow, and a Pionjar or Cobra dritl. The blaster is usually faced with an extraordinary range of work, t?om delay blasts in weathered rock using driiole depths of 18” (46cm) to as little as 4” (1 Ocm), through reducing boulders and talus fields to useable tread, blasting stumps, snags and log-jams, to the explosive disintegration and casting of animal czcasses. One day he/she might provide a 500cf (14 cu meter) anchor excavation for a suspension bridge, the next day directionally fall 60” (1.5m) diameter snags in a camp area, and the following day blast a 3-foot-wide (1 meter) tread bench across a steep bedrock slope. To be effective, the blaster must design each and every blast around desired end result, crew and public safety, maximizing effective use of limited quantities of explosive, and the minimnation of environmental effects. Since almost all drillhole blasting occurs in the weathered zone of the rock, blasting is more the art than the science of judging rock density, hardness, cohesion and prefracturing, and selecting explosives, drill and delay patterns, and loading techniques responsive to those conditions. For these reasons the NPS issues its own Blaster’s License, with a basic requirement of at least 40 hours of NPS blaster training and 3 years of supervised Blaster in-Training experience. The focus of this pre-license requirement is on safety and using explosives as a precision tool, versus just “blowing things up”.

Jan 1, 2002

By Cameron Rees

The University of New South Wales Mining Research Centre (UMRC) has a longstanding research reputation in mining research, with particular expertise in mining systems, mining geomechanics and excavation engineering. The UMRC is now focusing this expertise on the potential of mining Seafloor Massive Sulphides (SMS). The UMRC has initiated a three-year research project that will identify and examine the requirements to effectively and efficiently mine SMS deposits. The major aims of this project are: ? To develop an understanding of the geomechanical characteristics and local physical environmental conditions associated with a ?typical? SMS deposit. ? To develop and evaluate a range of both conventional and innovative excavation processes for mining SMS deposits, and define the engineering parameters required for each extraction option, and ? To identify the materials handling and lifting requirements of the ?mined? SMS material, and the possible integration of the lifting system with the excavation processes considered.

Jan 1, 2002

By Jacques Villeneuve, Stéphane Brochot, Jean-Claude Guillaneau, Marie-Véronique Durance

Since 1986, BRGM has been developing a powerful process simulation software package, USIM PAC. These last years have seen significant developments in mineral processing technologies, particularly in hydrometallurgy, bio-hydrometallurgy and mineral liberation. The new version of the simulator, USIM PAC 3.0, incorporates these modem-processing fields. Its structure and tools allow the user to take into account, at the same time, a wide range of technological, economical and environmental aspects. The improvement of the existing features and the introduction of new unit operation mathematical models and tools such as the supervisor, global optimization, workshop model or chemical reactions contribute to a global approach in mineral processing design.

Jan 1, 2002

By Johann van Wjk

Mandatory Codes of Practice to Combat Rock Fall Accidents came into force on South African Collieries in 1997. These were drawn up in accordance with guidelines issued by the Chief Inspector of Mines, The Codes of Practice (CoP's) are legal documents in terms of the South African Mine Health and Safety Act 1996. One of the main results Of the introduction of the COP'S from a practitioner's point of view is that they formalized much of what would have constituted a typical visit to an underground section previously. Other important requirements were as Billows: Support rules and Strata Control Standard Procedures were to be drawn tip. Identification of Special Areas (areas requiring a higher level of rock engineering input and with, typically, higher order of support and restrictions on mining geometries), Changing conditions underground to he identified timeously. Implementation of the CoP to he monitored. To comply with these requirements on Ingwe Collieries (a division of BHPO Billiton Energy Coal) it was decided to produce too separate forms to be used in conjunction with each other. The first of these, the "Underground Section Physical Risk Rating" measures the physical conditions in each section whereas the second form, the "Section Perfomance Rating" determines how well the section personnel are Coping with the conditions. This form also pleasures compliance with the Support Rules and Strata Control Standards. Both forms are essentially risk matrices but with various scenarios described, each with a certain weighting. The "Risk and Performance Form" system for bord and pillar operations has by now been used for five years in the Ingwe and Eyesizwe Mining Collieries and has achieved a great deal of acceptance. This system has enabled the quantification of previously subjective observations and has improved the strata control awareness and management of underground mining sections. Amongst other initiatives it has assisted ill reducing the severity and frequency of fall of-ground accidents.

Jan 1, 2002

By B. K. Mishra, R. K. Rajamani, A. D. Joshi

The liners are the most important part in the SAG mill operation. Hence, the liners and their design parameters are primarily studied to see its effect on SAG mill operations. Effective liner designs are directed to reduce downtimes, which is needed for the replacement of worn liners. There exists constant chance of improvement in the capacity of mill by studying the effect of liner design on the charge motion inside the mill. This need is satisfied by three-dimensional discrete element code "Millsoft", which uses Discrete Element Method (DEM) to analyze the motion of charge. This simulation of SAG mill keeps track of all the moving bodies like ball and rock and observes its interaction with liners and lifters. The recent work done on this software helps generating mill to more reality by putting conical wall at feed and discharge end, over the earlier flat walls. Millsoft is an effective tool to watch the change in the motion of the charge due to different types of lifter bars and different design parameters. It was concluded that by simply increasing chord length between the lifters and increasing the face angle of the lifters, capacity of the mill could be increased. On the other hand, this software can also be used to get power draft at the respective mill design.

Jan 1, 2002

By Saba Mohan

This study presents results based on the Pile Installation Demonstration Project (PIDP) that was conducted as a part of the East Span San Francisco-Oakland Bay Bridge Seismic Safety Project. For the three full-scale pile installations, two different high-energy hydraulic hammers were selected for the installation. However, these hammers may not have sufficient energy to drive these large diameter piles at their ultimate capacity following long-term set-up. Nevertheless, these hammers were selected because, soil plug behavior, the generation of excess pore pressures and remolding of soil during driving were expected to reduce the shaft and end bearing resistance, and therefore reduce the energy required to drive these piles to design penetration. Data collected during continuous installation driving and after a series of re-strikes at different set-up times ranging from 1 to 33 days were used as input data for CAPWAP. These results were used to estimate the soil resistance along the pile length and at the toe of the pile, and the soil pile set-up behavior. Validity of the procedures used to predict the soil resistance to driving and predicted blow counts were verified with the field observed blow counts and the energy that was delivered to the pile. Based on combined CAPWAP analyses, the soil pile set-up with time was estimated and compared with results of other methods currently available in the literature for predicting the soil pile set-up rate.

Jan 1, 2002

By G C. Kiel, G J. Nicholson

Corporate governance has never been more topical. A glance at any major newspaper or business publication will reveal a litany of corporate failures based upon the governance of the organisations involved (eg Byrne, 2002; Hayes, 2002; The Economist, 2002). The increased compliance requirements and speculative nature of our industry means that corporate governance systems are, if anything, more important than in the general business community (Arthur, 2001). Rather than focus exclusively on the contribution of governance to corporate failure within the mining industry, however, our objective in this paper is to examine how boards can add value to the corporations that they govern. In order to highlight how a board can add value to a company, we commence by outlining the role of the board in the modern corporation in general and the mining industry in particular. We then introduce the concept of shareholder value and identify the steps on which a board needs to focus to enhance shareholder value through value tracking processes. Our discussion pays particular attention to the importance of organisational culture to the companyÆs activities and utilises three case studies from the mining industry. We conclude with an overview of what mining boards can do to enhance their culture and drive performance changes for the benefit of the companies they govern.

Jan 1, 2002

By D. Cronan

Both the S.W. Pacific and Caribbean island arcs are host to submarine hydrothermal mineral deposits, the former more so than the latter. In the S.W. Pacific, the whole gamut of such deposits occurs on the sea floor, sulphides, silicates, Fe and Mn oxides, whereas during the limited studies to date in the Caribbean only hydrothermal Mn oxides have been found to occur on the sea floor there in any abundance. Comparisons between the respective Mn oxides are thus the most fruitful at the present limited stage of our knowledge of Caribbean submarine hydrothermalism. Southwest Pacific hydrothermal ferromanganese oxides and their possible relationships to underlying sulphide mineralisation or bedrock anomalies (the geochemical window concept) has been a fruitful field of research in recent years. Certain element enrichments in crusts may be indicative of underlying mineralisation (Rogers et al. 2001). However, more recent studies on buried hydrothermal crusts in the S.W. Pacific (Cronan et al. 2002) have shown there to have been postdepositional diagenetic uptake of elements in them, and thus these elements cannot be used with any confidence in geochemical exploration for buried sulphide deposits unless sediment involvement can be eliminated.

Jan 1, 2002

By Thomas R. Larson

"Many concentrators use re-circulating “plant” water for dilution in their flotation circuits. However, if crusher dust suppressants, ball mill grinding aids, or even agitator bearing grease are introduced into this water, and the water itself is not subject to cleaning steps, then sufficient quantities of these chemicals may appear in the flotation cells and begin to impact the flotation separation. A bench flotation procedure has been coupled with statistical analysis in order to estimate the impact of small quantities of non-flotation chemicals on flotation performance.INTRODUCTIONCleveland Cliffs produces iron oxide pellets for blast furnace feed, and is developing the capability to produce ferrous metallic products to supply a wider customer base. Cliffs manages five North American iron mines, including the Wabush mine sites in Labrador and Quebec. Based on various characteristics of the ore bodies, the flow sheets of the five mines are diverse. For example, Hibbing Taconite uses magnetic separation alone as their primary upgrading method, but Northshore and Empire use magnetic separation followed by flotation, and Tilden uses flotation alone. Last but not least, the Wabush concentrator upgrades primarily with gravity and electrostatic separation techniques.At Northshore, concentrate from the magnetic separator circuit is fed to a reverse flotation circuit. By design, the magnetic separators operate at the highest possible recovery of magnetite, as the separator tails are discarded, and relatively high silica content was acceptable to Northshore’s customers. As the steel-making industry moved toward lower and lower slag volumes, the silica content in the magnetic separator concentrate became a problem. The flotation step was added in the late 1980s in order to decrease the silica assay of the magnetic separator concentrate to meet the current customer requirements. In this setting, the flotation feed stream contains very little silica that occurs as liberated quartz particles. As the degree of liberation of the flotation feed stream is then a limiting factor for silica removal, the online grind control then was linked to flotation in the overall plant control system so that grind can be adjusted to achieve improved liberation if necessary for the flotation process."

Jan 1, 2002

By T Mizuta, D Ishiyama

The Vienna Wood hydrothermal is hosted by mid-oceanic ridge type basalt in graben morphology and is located in the Central Manus Basin. The hydrothermal field is about 300 metres in diameter and consist of a sulphide mounds and tall huge death and active chimneys. From the three distinct ore types collected from the Vienna Wood site, the dominant ore minerals recognised are pyrite, wurtzite, sphalerite, chalcopyrite, Fe-oxide and gangue minerals of anhydrite, gypsum, barite and silica. The consistencies in the paragenetic sequence and in the spatial distribution of the sulfides across the three ore types suggest that similar hydrothermal process exist across active and death chimneys. Fluid inclusion studies reveal a homogenisation temperature of 190-260¦C and an average salinity of 5.1-5.4 wt per cent NaCl equiv. The pH of the hydrothermal fluid ranges from 4.2 to 6.1. Bulk chemical analyses indicate that the mineralisation in the Vienna Wood can be classified into the Zn-(Cu-Pb) type of mineralisation. The tenors of the ore and mineral assemblage resemble those of the Mid-oceanic ridge system and ancient ophiolite hosted massive sulphide deposits of Cyprus and Oman.

Jan 1, 2002

By M. Alley, P. Schroeder, L. Zelazny, S. Nagle

The Old Hickory mineral sands ore body in Virginia (>2000 ha) currently supports a productive rowcrop agriculture. Reclamation experiments were implemented on pilot-scale mining pits from 1995 to 1998. Half of each mining pit was topsoiled (25 cm) while the remaining half was left as either (1) mixed tails/slimes or (2) re-graded subsoil over tails/slimes treated with 112 Mg/ha yardwaste compost. Post-mining productivity was estimated to be reduced by 23%, 3%, 27%, and 20% for each crop (wheat/soybeans/corn/ cotton) in sequence when compared to undisturbed soils. Variability in surface texture and compaction limit restoration of soil productivity.

Jan 1, 2002

By Flor De Cock

The paper reflects part of the work from the European Regional Technical Committee on Piles (ERTC3) during its mandate between 1994 and 1999, and, in particular, describes the find­ings from an International Seminar held in 1997 in Brussels on European practice for design­ing axially loaded piles. The seminar included contributions from 17 European countries, each of which provided a synopsis of their respective national design approaches. This paper pays particular attention to the design methods based on laboratory and in-situ test data for both bored and displacement piles.

Jan 1, 2002

By H. E. M. N. Moursy, Hassan El-Shall, M. N. Ahmad, Ponisseril Somasundaran, C. R. Holland, D. Chandler, G. Walker, Regis Stana, Patrick Zhang

The reaction kinetics of the acidulation of Moroccan phosphate rock (32% P?05) using 45% nitric acid were investigated using the Shrinking Core Model (SCM) , a newly developed Diffusion Model (DM) and a newly developed Combined Reaction and Diffusion Model (CRDM). This was achieved buy conducting a number of experiments in a controlled batch reactor system at different temperatures. The conversion and the reaction rate were calculated at different time intervals. The SCM based on reaction time and the CRDM characterize the acidulation process of phosphate rock. Diffusion of nitric acid and the products of acidulation at the early stages of reaction through the phosphate rock were found to be the rate-controlling step, resulting in a dif- fusion coefficient, which controls the mass transfer process. The reaction kinetics were found to fit first-order kinetics especially during early stages of reaction time. The deviation of the kinetics from first-order at later stages was due to the fact that the overall reaction was mass transfer controlled with respect to nitric acid and products diffusion.

Jan 1, 2002

By Steve Dillingham

PHYSICAL BLAST DATA Pattern Description All measurements related to the description of the physical blast pattern must be made with the mind-set that it has to tell a powerful factual story enabling a future accurate reconstruction of the event. A case has never been lost because too much factual information was available to assist investigators. An accurate physical description of the pattern must be provided based on the blaster’s observations of the pattern actually loaded. The blaster must measure the pattern size, depth, face heights, etc., recording only accurate results. All too often, a blaster records simple pattern sizes and information relayed to him or her from the driller, or from a phone call into the office the night before for powder pre-load inventory purposes. If a pattern was actually measured on the job site by the blaster to be 8.5 x 9.5’, it may, in fact, originally have been ordered at 9’x9’, 8’x9’, or 9’x l0’. In a claim situation, particularly flyrock, recording a “generalization” of what was loaded could result in an interpretation of a blaster’s negligence due to “not knowing or caring” what the actual pattern was, and not loading appropriately for conditions. It is important to remember that other documentation exists such as a drill log from a contract driller or mine records that may provide a different interpretation of the loaded pattern.

Jan 1, 2002

By Christian Besson

This article describes the implementation of a new jointing process for use between diaphragm wall panels. This process was initially introduced on the SOCATOP work site in uburban Paris (which involved the closing of the western section of the A86 bypass road), on a tunnel ventilation shaft. This brand new system upgrades the potential offered by other types of joints available and enables both ensuring the continuity of panels for structures over 40 m in depth under the strictest safety conditions and constructing shafts with diameters of less than 15 m. A patent for this process has recently been filed.

Jan 1, 2002

By E. Ulrich Klotz

It is difficult to predict accurately the capacity of driven piles in sand. In practice, this uncer­tainty either leads to conservative designs if the capacity is under-predicted, or worse, if the capacity is over-predicted, it can lead to severe foundation problems. One significant possible cause of the problem is that currently available semi-empirical design methods do not capture the fundamental mechanisms that govern the load capacity of driven piles in sands. As part of a recent research project at City University centrifuge tests on a driven model pile in sands have been undertaken. A fully instrumented model pile was constructed and pushed into samples of quartz and carbonate sand thus covering a wide range of mineralogies. Tri-axial tests were used to determine the fundamental patterns of behavior of the sands. This allowed a general framework to be established, in which the in situ stress:volume relationship is shown to govern the capacity of the pile. The paper sets out with a brief introduction of the experimental techniques used in the study. The results of the pile tests are discussed in detail with particular attention given to distribution of the radial stresses along the pile shaft. Existing design methods for piles in sand are then discussed in the light of the new understanding gained from the research, highlighting their deficiencies and suggesting an improved approach.

Jan 1, 2002

By Carl Ealy

Static and STATNAMIC (STN) rapid load test (RLT) was performed on 3-drilled shafts. The purpose of the RLT part of the study was to obtain data in support of FHWA research on innovative load testing methods. The research site is located at the National Experimentation Research Site (NGES) in Amherst Massachusetts and is underlain by Connecticut valley varved clay. Two of the tested shafts were constructed without planned defects and the third with manufactured defects to evaluate current non-destructive integrity testing (NDE) methods. Quick Load Test (QLT) and Constant Rate of Penetration (CRP) static axial load tests were performed on two shafts to plunging failure. Good agreement between static and RLT derived static failure loads was attained for a 5% failure criterion (load at a movement equal to 5% of shaft diameter).

Jan 1, 2002

By Walter E. Vanderpool

Type 1B micropiles (Bruce and Juran, 1997) can be installed rapidly and efficiently. During an 85-day period, 536 micropiles were installed to depths of 61 meters within a site 41 meters by 43 meters. Their performance, as measured by load test, varied even where the materials, construction procedure, and installation technique were closely monitored and controlled. The variation in displacement, as measured by the standard deviation, exceeded 50 percent of the mean test-load displacement for all loads up to the maximum load applied (2670 kN). This study provides a statistical basis to predict variability with respect to the construction method, micropile materials, and installation technique. The variability of displacement at all test loads is a fundamental characteristic of this type of drilled deep foundation system.

Jan 1, 2002

By P Lever, D Hainsworth, H Gurgenci

The ACARP Landmark initiative has created the opportunity to advance the level of automation in the coal industry by first focusing on the core production area of longwall mining. A Landmark Longwall Automation project was commenced in July 2001. The major outcome of automation using on-face observation has been divided into ten outcome areas that have been fully scoped for a three-year initial project life. A major facilitating technology has been the implementation inertial navigation system (INS) technology that can map the shearer position in 3D. A focus of the project is to deliver a system that is at least as productive as the current most productive manually controlled longwall face.

Jan 1, 2002