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By Adam Powell

A Cahn-Hilliard phase field model is formulated to describe transport-limited electrochemical reactions coupled with fluid flow in a metal reduction cell. When the reaction is limited by mass transfer of metal ions from the electrolyte to the cathode, the metal-electrolyte interface at the cathode exhibits a Mullins-Sekerka instability, leading to the growth of dendrite-like "streamers" of liquid metal into the electrolyte, which in turn significantly enhance the apparent mass transfer coefficient there. Model results for iron reduction from ferrous oxide in slag show formation of these streamers. Although the double-layer is not included in this model, the related phenomenon of electrocapillarity can be represented by a gradient penalty term which includes the electric potential gradient, such that interfacial energy is a function of the electric field normal to the interface.

Jan 1, 2003

By M. Shahabi, M. Kashfi

This paper briefly describes the excavation procedure of a powerhouse, comprising of its incremental excavation, reinforcement measures, and the installed monitoring system. During the first phase of excavation, the data obtained from monitoring of the behavior of Mudstone layers were used to recommend extra support measures. These data are also used to design the support of the powerhouse during its extension phase. In diesen bericht wird die bohrmcthode von kraftwerk ecavation in stupenweise dargestelt, und in die richtung d.sicherung, Mit hilfe von monitoring systeme. Die monitoring in (mudstone) schichten ist an schutz in bohrung entworfen und montiert in diese methode in K.W. fase 1 schutzung das K.W. in erweiterung der K.W. das berte auserwelt worden ist Cet article décrit brièvement le procédé d'excavation d'une centrale électrique, comportant de son excavation incrémental, de mesures de renfort, et du système de surveillance installé. Pendant la première phase de l'excavation, les données obtenues à partir de la surveillance du comportement des couches de schiste ont été utilisées pour recommander des mesures supplémentaires de soutien. Ces données sont également utilisées pour la conception de la soutènement de la centrale électrique pendant sa phase d’extension.

Jan 1, 2003

By Ed Clah, Catherine Aimone-Martin

The vibration response of a 30 in. diameter high-pressure (845 psi) natural gas pipeline to 11 coal mine blasts was measured. The X-52 steel pipeline was buried 7 ft. below the ground surface. Ground and pipeline motions in terms of velocities were recorded on the pipeline, in the ground adjacent to the pipeline, and near the ground surface directly above the pipeline. These data were used to estimate the maximum stresses and strains in the pipeline occurring during the blasts. Pipeline standoff distances varied from 264 ft. to 3720 ft. Two blast hole layouts and timing schemes were used. One represented highly confined blasts to limit movement of the shot overburden that generated high ground motions at the pipeline. The second represented patterns that provided greater relief and lower the ground velocities at the pipeline.

Jan 1, 2003

By Ken Baxter

The Sepon Copper Project is located in Laos and has a mineable reserve of approximately 16Mt of ore grading 5% copper with minor gold and silver values. The deposit is a clay-hosted secondary copper mineral suite, predominantly chalcocitic in nature with associated pyrite. The current project design is based on the production of 60,000t/a of LME Grade A cathode by an acid leaching process followed by solvent extraction and electrowinning. Significant metallurgical testwork was conducted as part of the Definitive Feasibility Study (DFS) with process challenges identified and overcome at each phase of testing. Flowsheet configuration is geared to autogenously generating sufficient acid and ferric iron to meet gangue acid consumption and to leach the copper. The ability to maintain acid and ferric levels in the process liquors is strongly influenced by the proportion of pyrite in the ore presented to the autoclave. This paper will outline flowsheet development from preliminary variability testing to pilot plant and DFS design. The Sepon process solution seeks a balance between operability and capital/operating costs, and provides insights into the basic mechanisms influencing flowsheet selection for these ore types.

Jan 1, 2003

By H. Sekimoto, T. Matsuoka, K. Yasuhara, M. Ota, S. Akutagawa

A magnetic anisotropy sensor is used for nondestructive measurement of stress on surfaces of a ferromagnetic material, such as steel. The sensor is built on the principle of the magneto-strictive effect in which changes in magnetic permeability due to deformation of the material is measured in a nondestructive manner, which then can be translated into the absolute values of stresses existing on the surface. This technique was applied to measure stresses of H-beams used in tunnels. The results show that this method could be one of the promising technologies for non-destructive stress measurement for safe construction of underground structures. Une sonde magnétique anisotropique est utilisée pour des mesures non-destructives de stress sur la surface d' unmétal ferromagnétique, comme l'acier. La sonde est construite sur le principe de l'effet magnéto-strictif dans lequel les changements dans la perméabilité magnétique due à la déformation du metal est mesurée avec une manière non-destructive, qui peut être alors traduite en valeurs absolues des stress existants à la surface. Cette technique a été appliquée pour la mesure de stress des poutres en H utilisées dans les tunnels. Les résultats montrent que cette méthode peut être l'une des technologies promet tantes concernant les mesures non-destructives de stress pour des constructions sûres de strcutures souterraines. Ein magnetischer Anisotropie-Sensor wird für die zerstörungsfreie Messung von Spannungen an Oberflächenvon ferromagnetischen Materialien wie z.B. Stahl verwendet. Der Sensor kann Änderungen in der magnetischen Durchlässigkeit auf Grund von Verformungen des Materials erkennen, die dann in Absolutwerte der Spannungen an der Oberfläche umgerechnet werden können. Die Methode wurde auf Messung von Spannungenvon H-Balken in Tunnels angewendet. Ergebnisse zeigen, dass dies eine vielversprechende Methode für diezerstörungefreie Messung im Tiefbau ist.

Jan 1, 2003

By L. Sh. Tsemekhman

The results of laboratory, large-scale laboratory and commercial scale investigations regarding the process of slag melts cleaning by oxidizing-reduction gas mixtures with a wide range of Po2 and the use of matte of various compositions as an extracting phase are presented. The copper, nickel and cobalt behavior during the cleaning process has been studied based on SEM and x-ray Microprobe of the quenched slag melts. The general cleaning mechanisms have been found. On the basis of the obtained data the most efficient cleaning methods have been proposed.

Jan 1, 2003

By Dale Ramsey

During Phase IV of our Landfill Mine Stabilization project at a coal burning power generating station, it was determined that a coal barrier pillar separating two abandoned areas of the deep mine had to be breached prior to expansion of the ash disposal area. The proposed plan by the landfill design engineers involved using a high pressure jet cutting tool to cut a slot to allow water flow to an existing industrial waste water treatment facility. Our plan proposed using explosives to breach the pillar from the surface reducing earth disturbance in a high quality watershed while reducing the project cost and accelerating the project time schedule. Many issues surfaced with the proposed change of using explosives. There were a number of lessons learned from this case history and is the primary basis of this paper.

Jan 1, 2003

By O. M. G. Newman

Research into potential applications of spouted bed electrowinning (SBE) in the zinc industry was conducted, in a collaboration between our two organizations. The main system investigated was zinc from acidic sulfate electrolytes. However, SBE can be extended to other electrolytes, or recovery of other elements. Electrolytic tests were carried out at the 0.01 to 0.1 m2 scale. Spouting behaviour has been studied at a larger scale, approaching a size suitable for an industrial unit cell. Much of our work was carried out using a micro-porous separator (Daramic®). However, we have also shown that ion exchange properties can have a controlling effect on the process chemistry, electrochemical efficiency, and plant flowsheet. In initial 0.1 m2 scale electrolytic tests, design and engineering issues for scale-up were identified. We review the major achievements, promising areas for application in the zinc industry, current status, and remaining barriers to development of SBE technology.

Jan 1, 2003

By S Ramsay, D Povey

This paper presents recent case study data collected by field portable x-ray fluorescence spectrum analysers (FPXRF) as part of grade control activities at three separate (nickel, copper and copper/gold) mining operations. FPXRF has been under utilised for grade control in recent years, largely because the success of early versions of FPXRF was limited to a few metals (eg tin). Efforts to utilise these early versions for other metals was largely unsuccessful and created a perception that FPXRF could not be utilised more broadly within the mining sector and specifically the area of grade control. The structural setting of the analytical function within mining operations has also contributed to the under utilisation of more recent FPXRF instrumentation. The concept of FPXRF as a grade control tool straddles the boundaries of the geology and laboratory departments. As such, this option is often not considered as part of an assessment of grade control procedures for new and existing mining operations. This paper assesses data collected by Australian and New Caledonian miners using FPXRF technology as part of the grade control function and concludes that FPXRF can provide operational and cost benefits to certain mining operations.

Jan 1, 2003

By Steve Signer

Researchers at the National Institute for Occupational Safety and Health (NIOSH) have developed several new tools for evaluating roof support performance. A miniature data acquisition system (MIDAS) was developed that can collect readings from up to 16 strain gauges at regular time intervals and store the readings for later retrieval. Three LED lights change from green to yellow, then red, based on the reading levels and/or rates of change of rock movement. This feature can be used to warn miners of rock instabilities. The system can be used with any strain-gauged support (resin bolt, friction bolt, cable bolt) or with a newly developed rock strain strip (ROSS) developed by NIOSH to measure rock strain. A ROSS is grouted in a hole drilled adjacent to the rock support to be evaluated; the deformed shape of the ROSS provides anchorage on either side of the strain gauges. Data from both laboratory tests and field evaluations are presented that describe the capabilities of both the MIDAS and ROSS instruments.

Jan 1, 2003

By K. A. Natarajan, Abha Kumari

In this paper, electroleaching and electrobioleaching of ocean manganese nodules are discussed along with the role of galvanic interactions in bioleaching. Polarization studies using a manganese nodule slurry electrode system indicated that the maximum dissolution of iron and manganese due to electrochemical reduction occurred at negative DC potentials of -600 and -1,400 mV(SCE). Electroleaching and electrobioleaching of ocean manganese nodules in the presence of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans at the above negative applied DC potentials resulted insignificant dissolution of copper, nickel and cobalt in IMH2S04 and in sulfuric acid solution at pH 0.5 and 2.0. Mechanisms involved in electrobioleaching of ocean manganese nodules are discussed. Galvanic leaching of ocean manganese nodules in the presence of externally added pyrite and pyrolusite for enhancement of dissolution was also studied. Various electrochemical and biochemical parameters were optimized, and the electroleaching and galvanic processes thus developed are shown to yield almost complete dissolution of all metal values. This electrobioleaching process developed in the laboratory may be cost effective, energy efficient and environmentally friendly. Keywords: Ocean manganese nodules, Electroleaching, Electrobioleaching, Galvanic interactions

Jan 1, 2003

By Guido Venturini, Giorgio Martinotti, Luca Delle Piane, Paolo Perello

This paper presents a critical review of geo-structural mapping methodologies applied to deep tunneling projects in complex mountain chains such as the Alps. Geological forecastings are often a crucial part of tunneling projects, which should allow contractees or contractors to assume their own risks. Despite this, often adequate methodological criteria are not applied in the realization of these studies, with consequent increase of costs and delays. A discussion should hopefully start in the world of tunneling in order to define a correct approach.

Jan 1, 2003

By Jian Zhang, Yongfu Yu, Fuguang Zhang, Liping Che

There is one large-scaled iron ore deposit in Inner Mongolia of China, but it is very complex which includes about 170 types of minerals and 71 elements. The hematite, magnetite are mainly iron ores. It is difficult that the iron mineral can be separated efficiently by common dressing methods due to the complexity, and the iron concentrates in the mineral processing factory contains many foreign substance such as K, Na and Si so that the process in iron mill is influenced because of the foreign substance, so it is vital reducing the foreign substance.

Jan 1, 2003

By B. Haimson

A new loading apparatus was fabricated and used to conduct true-triaxial compression tests on KTB amphibolite, a crystalline basement rock. Tests in dry jacketed samples reveal that the intermediate principal stress has a significant effect on the onset of dilatancy and on rock strength, contrary to the implicit assumption made by Mohr-type failure criteria. Failure is induced through a shear fracture that dips steeply in the direction of the least principal stress. Experimental results lead to a new generalized strength criterion in terms of all three principal stresses. Unjacketed KTB amphibolite specimens, exposed to confining fluid, are considerably weaker than the jacketed ones, despite the negligible porosity and permeability. Failure is facilitated by several closely spaced subparallel tensile cracks normal to the least stress direction. SEM analysis suggests that microcracks developed upon dilatancy onset are penetrated and extended by the confining fluid, bringing about the unexpected rock failure mechanism at reduced stress levels. Un nouveau dispositif à chargement fut fabriqué et utilisé afin de réaliser un vrai essai de compression tri-axial sur KTB amphibolite, une roche cristalline du sous-sol. Les essais effectués sur échantillons enveloppés et secs révèlent que les contraintes principales intermédiaires affectent considérablement le début de la dilatance et la résistance de la roche, contrairement à la supposition fondée sur le critère de rupture de Mohr. La rupture est produite grâce à une cassure de cisaillement très incliner en direction où la contrainte principale est moindre. Ces résultats expérimentaux indiquent un nouveau critère de rupture général en fonction des trois contraintes principales. Les échantillons de KTB amphibolites sans enveloppe, exposés à un liquide confiné, sont considérablement plus faibles que ceux enveloppés, malgré la porosité et la perméabilité négligeable. La rupture est facilitée par plusieurs fissures de traction adjacentes et sub-parallèles, normales à la plus petite contrainte principale. L’analyse SEM suggère que les micro-fissures développent suivant le début de la dilatance, elles sont pénétrées et agrandies par le liquide confiné, produisant un mécanisme de rupture de roche inattendu, ceci à un niveau de contrainte réduit. Ein neuer Ladungsapparat wurde hergestellt um real - triaxiale Druckfestigkeitsversuche in KTB Amphibolit, einem kristallinen Grundgebirgsgestein, durchzuführen. Messungen in trockenen, bedeckten Proben zeigen that die mittlere Hauptspannung eine bedeutende Wirkung auf das Einsetzen von Dilatanz und auf die Stärke des Gesteins hat, im Gegensatz zu der impliciten Annahme auf Grund von Mohr-ähnlichen Versagungskriterien. Versagen ist induziert durch eine Scherfraktur die sich steil in die Richtung der geringsten Haupspannung nach unten senkt. Messergebnisse führen zu einem neuen, verallgemeinerten Stärke Kriterium dass auf alle drei Hauptspannungen basiert ist. Unbedeckte KTB Amphibolit Proben, die unmittelbar den umgebenden Fluiden ausgesetzt sind, sind wesentlich schwächer als bedeckte, trotz geringfügiger Permeabilität und Porosität. Versagen wird gefördert durch mehrere, nebeneinander liegende, sub-parallele Spannungsbrüche, normal zu der geringsten Spannungsrichtung. SEM Analyse lässt vermuten dass Mikrobrüche, die sich beim Überschreiten der Dilatanzschwelle entwickeln, durch die umgebenden Fluiden fortgepflanzt und weiter verbreitet werden, und unerwartet, auf Grund der reduzierten Spannungswerte, den Versagungsmechanismus des Gesteins einleiten

Jan 1, 2003

By Knut L. Sandvik, Erik Larsen

"Estimated global solar energy demand in 2001 required approximately 5,500 tons of silicon feedstock. This required 65,000 tons of quartz. If the trend continues, the solar energy demand in 2010 would require approximately 30,000 tons of silicon feedstock and 350,000 tons of quartz, although the need for quartz probably will be lower than this due to higher solar cell efficiencies, larger and thinner wafers, more extensive recycling of waste material and new routes for the production of silicon feedstock. The raw material requirements for the production of metallurgical-grade silicon are most likely to change. This may favour increased beneficiation of primary raw materials in the future solar cell production chain.SOLAR CELL PRODUCTION CHAIN SCENARIOSThe major problem concerning solar cells is the production costs. Electricity produced from fossil fuels and hydropower plants are currently much cheaper than the electricity produced from solar cells. Also, limited availability of silicon feedstock for the production of crystalline silicon solar cells is considered a major threat to the further growth of the PV industry. The present route for solar silicon feedstock goes from quartz, through metallurgical-grade silicon (MG-Si) and to electronic-grade silicon (EG-Si). The reject from the EG-Si production are further processed into wafers and solar cells. This situation is not satisfying, however, because it has created a silicon feedstock shortage and a PV energy price that is not competitive in a large scale.Crystalline silicon solar cells are the most important solar cells manufactured today. This will most probably remain the situation the next decade. Also, the future silicon ""feedstock"" is most likely not reject from the production of electronic-grade silicon, as it is today. There will probably be a more direct solargrade silicon route, excluding the very expensive electronic-grade silicon ""detour"". Quartzite has been regarded as the most suitable primary raw material used in the silicon solar cell production chain. This may change as the raw material requirements for the production of metallurgical-grade silicon are most likely to change. In addition, quartz or other silica-containing minerals from other rocks may be of a higher purity or contain lesser amounts of the most harmful elements. This favours increased beneficiation of primary raw materials in the future solar silicon feedstock production chain"

Jan 1, 2003

By J. Riss, S. Gentier, A. Marache

The study of the hydromechanical behaviour of fractured rock masses requires a detailed knowledge of the isolated fractures. The aim of the paper is the simulation of the evolution of the void space, located between both walls of a fracture, during a shear test under constant normal stress. Results of the mechanical simulation model are first validated then analyzed in detail. We observe that, during the shear process, there is an opening of the fracture with the creation of preferential channels. These channels are determined at the early phase of the shear process (pre-peak phase), and we observe during the post-peak phase that void areas increase in size rather than the creation of new apertures. Die Untersuchung des hydromechanischen Verhaltens eines zerlegten Felsmassivs erfordert genaue Kenntnisse der einzelnen Spalten. Ziel dieses Artikels ist die Simulation der Evolution des Hohlraumes zwischen den beiden Wänden eines Spaltes während eines Abscherungsexperimentes unter konstantem senkrechtem Druck. Die Ergebnisse der Modellierung werden zunächst mit dem Abscherungsexperiment verglichen und dann im Einzelnen ausführlich analysiert. Während des Abscherungsprozesses tritt eine Öffnung des Spaltes auf, die die Bildung von bevorzugten Fliesswegen fördert. Diese Kanäle werden bereits in einer frühen Phase des Abscherungsprozesses (pre-peak Phase) festgelegt. In der post-peak Phase tritt dann eher eine Vergrößerung dieser Kanäle, als die Bildung neuer Hohlräume auf. L’étude du comportement hydromécanique d’un massif rocheux fracturé ne peut se faire sans une connaissance approfondie des fractures le constituant. L’étude présentée dans cet article concerne la simulation de l’évolution de l’espace des vides présent entre les deux épontes d’une fracture au cours d’un essai de cisaillement à contrainte normale constante. Les résultats du modèle sont tout d’abord validés puis analysés en détail. On constate que, au cours du cisaillement, il apparaît une ouverture de la fracture permettant la création de chenaux préférentiels. Ces derniers sont déterminés très tôt dans le cisaillement (phase pré-pic), et on observe dans la phase post-pic davantage un accroissement de la taille des chenaux plutôt que la formation de nouvelles zones de vides.

Jan 1, 2003

By A Havenga, F, J Hough, R Grobbelaar

After the closure of mines they naturally start to fill up with water. As a result, hydraulic gradients develop between adjacent mines and different hydraulic water pressures are exerted onto peripheral areas or compartments within mines. This results in water flow between mines, or onto the surface. This flow is referred to as intermine flow. The geometry of the collieries in the central Witbank Coalfield make intermine flow possible in several areas. Since the Department of Water Affairs and Forestry declared intermine flow as one of its greatest concerns for granting closure to South African mines, much research into this phenomenon has been undertaken. The importance of the quantification lies in the DepartmentÆs goal of sustainable water management, and the possible long-term financial implications these flows could have for individual mines. The challenges of determining intermine flow are numerous, and attention is focused on the identification of areas where these flows can take place. Detailed mining plans on a regional scale are required, and detailed coal-seam floor data are combined to provide targets for possible interaction between these mines. The quantification of these flows is problematic due to the uncertainties regarding geometrical configurations and the variation in site-specific hydraulic characteristics of the coal and overlying lithilogical layers. To this end, use has been made of several analytic solutions and numerical flow modelling. Stage curves (volume versus elevation curves) for the opencast and underground workings have been calculated and first-order estimates for intermine flow or decant from these areas have been determined. The numerical modelling methodology entailed a down-scaling approach, starting with a broad regional model covering the entire area, followed by modelling the interactions between interconnected mines and finally looking in detail at the major areas of interaction. By considering different scenarios within the context of these flows, possible management options for intermine flow can be evaluated in terms of volumes and qualities that might emanate in the post-closure phases. Challenges for the future include obtaining site-specific information on the groundwater hydraulics and acceptable ranges for model parameters, and verifying model results over time.

Jan 1, 2003

By Leon J. Jacobs, Kyle R. Ott

This paper discusses design and construction aspects of the tunnel, shaft and station for the Weehawken Tunnel and Bergen line Avenue Station. The project consists of a 1,269 m (4,156 ft) long existing railroad tunnel, which will be enlarged and equipped with a two-track light rail system. The project also includes construction of a deep underground station, with a large shaft connecting the surface station to the below ground station for access and ventilation purposes. Vibration and noise from blasting is a critical community issue and blasting adjacent to two 230-kV duct banks located in the tunnel invert required special blasting procedures.

Jan 1, 2003

By H. Z. Kuyumcu

In order to ensure a sustainable development in the mineral industries it is very important to reduce the process water consumption in mineral processing. Based on a systems analytical approach this paper deals with the most important parameters of process water management during plant operation and indicates strategies for reducing the water consumption in mineral processing.

Jan 1, 2003

By T. Saito, S. Murata

An original concept of JRC-diagram that can evaluate JRC and its size-effect by using a fractal model was proposed. In order to confirm the applicability of the JRC-diagram, first, JRC of the tensile fracture surfaces of a granite and a sandstone were evaluated by both the JRC-diagram and Barton's JRC-profiles, and then, it was compared with the JRC inversely calculated from the peak shear strength that is obtained from the shear test for each fracture using Barton's empirical equation. As a result, JRC evaluated by the JRC-profiles was much smaller than the inversely calculated JRC. On the other hand, it became clear that JRC evaluated by the JRC-diagram is almost the same with the inversely calculated JRC, if the size of interlocking is evaluated correctly. Therefore, for the JRC evaluation, it is thought that the JRC-diagram is more applicable than the JRC-profiles. Als ein neues Verfahren zur Bewertung des Rauheitsindexes JRC für die Bruchfläche von Felsenschichten anhand eines fraktalen Modells, wobei auch der Maßeffekt berücksichtigt wird, wird ein JRC-Diagramm vorgeschlagen. Um die Angemessenheit der Bewertung vom JRC mit diesem JRC-Diagramm festzustellen, wurden die JRC-Werte an einer Bruchfläche zwischen Granit und Sandstein sowohl mit dem JRC-Diagramm als auch mit dem herkömmlichen JRC-Profilverfahren bewertet. Anschließend wurden die durch die beiden Verfahren ermittelten Werten mit den JRC-Werten verglichen, die von den Schertestergebnissen mit Hilfe von Bartonschen Erfahrungsformel zurückgerechnet werden können. Daraus ergab sich, daß das JRC-Profilverfahren ziemlich kleinere JRC-Werte gibt als bei der Zurückrechnung, während die JRC-Werte durch das JRC-Diagramm unter entsprechender Bewertung des Ineinandergreifungsmaßes an der Bruchfläche beinahe gleich sind wie die zurückgerechneten Werte. Diese Tatsache weist darauf hin, daß das JRC-Diagramm eine bessere JRC-Bewertungsmethode als das JRC-Profilverfahren darstellt. Nous avons proposé le diagramme JRC, nouvelle méthode d'évaluer JRC qui est un indice de rugosité superficielle d'une fracture de roche à l'aide du modèle de fracturation, compte tenu de son effet d'échelle. Pour vérifier la validité de JRC évalué au moyen de ce diagramme, nous avons évalué JRC d'une fracture de roche, granite et grès, par le diagramme JRC et le profil JRC, méthode conventionnelle, et les résultats ainsi obtenus ont été comparés avec la valeur de JRC calculée en sens inverse à l'aide de la formule empirique Barton sur la base des résultats de l'essai de cisaillement des fractures. Il en résulte que la valeur de JRC obtenue par le profil JRC était assez faible en comparaison avec la valeur calculée en sens inverse alors que celle de JRC obtenue par le diagramme JRC correspondait approximativement à la valeur calculée en sens inverse à condition d'évaluer l'échelle d'endentement d'une fracture. Par conséquent, nous considérons que le diagramme JRC est une meilleure méthode d'évaluation de JRC par rapport au profil JRC.

Jan 1, 2003