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By G. B. Harris

In recent years, increasing attention has been focused on the hydrometallurgical treatment of base metals feeds, especially nickel laterites and polymetallic sulphides. One approach that has received some attention is the use of high?concentration chloride solutions (brines), which are now showing some promise after initial setbacks. Iron is usually the major component in the base metal feed to such processes, and if physical means cannot be used to remove it, then the iron concentration in the pregnant leach solution is always significant. This paper presents some of the background theory on the hydrolysis of iron in high-strength (>3M) chloride brines, and discusses the roles of temperature, solution concentration and free acidity. It is shown that the system is complex, but that crystalline and readily-filterable hematite can be generated, and that the system has a low energy requirement.

Jan 1, 2006

By D. P. Ziegler

Formulas relating economic optimum busbar cross sectional areas to busbar cost, electric price and financial parameters are reviewed and revised. Application of the formulas is illustrated with discussion of the appropriate choice of parameter values and the sensitivity of the optimum to the parameters. The extension of the single busbar concept to optimization of more complicated arrangements of bus for smelting pots is complicated by the constraint of obtaining a specified current distribution. An example problem illustrates the optimization of a section of a bus network containing a fork, with the imposed limitation of achieving a specified uniformity in the current. In cases where the current in the individual conductors may vary, Kelvin's law does not apply. Further extension of the technique to a full pot set of conductors poses additional problems which are discussed, but whose solution has not yet been accomplished. Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by

Jan 1, 2006

This paper attempts to draw together the experience of over 30 years of research and practice in the United Kingdom on the rehabilitation of abandoned metalliferous mining wastes. The reliance on water when the mines were operating has implications for water quality and the techniques used to restore sites to alleviate the principal impacts of the mines. Drivers of reclamation included concerns about human health from wind blown dust and pollution of watercourses as well as perceptions of dereliction. Techniques of reclamation used involved removal of spoil from near to surface watercourses, capping of spoil, diversion of watercourses, use of impermeable membranes, prevention of surface sinks into underground workings and the use of constructed wetlands. The issues to be dealt with in mine reclamation have become more complex and sometimes diverge. The schemes in the 1990s described have been effective in dealing with pollution from spoil heaps and small but significant adit discharges; however, significant issues, particularly those of large flows of polluted water from mine sites, still need to be dealt with. Although the paper describes the legacy of mining, which largely finished in the late 19th/early 20th century, similar issues but on a larger scale are to be found in more recent mining, for example Eastern Europe. In many of these areas minerals still remain to be won and dealing with this legacy may fall on new mining developments.

Jan 1, 2006

As a bubble travels through the pulp region of a flotation cell, it will collect the most hydrophobic particles of an intermediate particle size range, this being the primary source of true flotation selectivity. Despite its role on bubble-particle attachment, however, particle hydrophobicity is still missing a mathematical definition that can be used for plant simulation. In this paper, particle hydrophobicity is defined in terms of the induction time necessary for attachment and then linked to the mass of collector adsorbed per particle. This allows particle hydrophobicity to be written as a function of density of collector adsorption as well as particle size and mineralogy. The model is calibrated from the experimental measurement of the flotation rate constant. Liberation data from an industrial flotation rougher is used for model validation. It is demonstrated that the model can describe a broad experimental dataset by means of a minimal number of parameters. Main industrial application is in simulating the effect of the chemical environment upon plant metallurgical performance.

Jan 1, 2006

By Varadarajan Seshadri

Geometallurgical characterization of iron ore which is a raw material for Iron making as in the case of charcoal blast furnaces operating in Brazil or for production of agglomerates such as iron ore sinter which serves as burden material for blast furnces of high productivity or pellets extensively used in the direct reduction processes all over the world in the iron and steel industry. Selection of proper raw material after due characterization should lead to an improvement of the productivity of the respective processes The usual classification of quality of iron ore is uniquely based on chemical analysis, granulometric and physical parameters. However not much emphasis has been given to the structural characteristics which also are important in the processes. Different typological categories of Brazilian iron ores have been used in the characterization . For instance, several kinds of hematite crystals like specularite, martite and microgranular hematite, etc with variable crystal sizes are found in the different ore types. They are also composed of different of fabrics and types of accessorial mineralogical constituents and have different porosities, pore diameters, etc which influence the cold and the hot agglomeration stages of the ore fines, and also chracteristics such as reducibility, decrepitation etc, important for assessment of quality of iron ores. . The first step for attaining a good characterization of ores is to know in detail about the structure of the deposit, shape of the body, types of iron ores and their distribution. This requires a geological-structural study and the mapping of the bodies using mineralogical criteria for typological classification of ores. followed by structural characterization of materials in stages of mining, comminution, screening and concentration processes. In this contribution a geometallurgical approach for quality control of Brazilian iron ores for sintering and pelletizing processes is highligted.

Jan 1, 2006

By Hee Dong Jang

Crystalline metal oxide nanoparticles such as lithium cobalt oxide (LiCoO2) and indium tin oxide (ITO) were synthesized from sprayed droplets of aqueous precursor solution by flame spray pyrolysis. Complete thermal decomposition of the aerosol precursors was obtained at high flame temperature. Molar concentrations of the precursor solution, and the flow rate of combustion gas such as hydrogen, oxygen and air were varied to control particle size, size distribution and crystal structure. The crystalline nanoparticles synthesized were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm for LiCoO2 and from 8 to 15 nm for ITO.

Jan 1, 2006

By Manolete Mena

WC-Co nanocomposite powder is among the first group of materials with a promising potential for nanocrystalline-materials application. A chemical vapor synthesis (CVS) process that has previously been used for preparing the aluminides of titanium and nickel, and other metallic and intermetallic powders has been applied to the preparation of WC-Co nanocomposite powder. This CVS system was designed so that a tungsten precursor (WCl6 powder) and a cobalt precursor (CoCl2 powder) were separately fed into each evaporator in a reactor by means of specially designed powder feeders. The reduction and carburization of the vaporized chlorides by methane-hydrogen mixtures produced nanosized WC and Co composite powder. The product is a very uniform mixture of the constituent powders, which is important to ensure a high quality of the bulk cemented tungsten carbide product after consolidation. In the present work, the effects of reaction temperature, CH4 to WCl6 ratio, CH4 to H2 ratio, residence time, and Co content on the powder composition and particle size were determined. The products were characterized using XRD, carbon analyzer, and TEM.

Jan 1, 2006

By N. K. Jaber

The "Pidgeon Process" for the extraction of magnesium from dolomite ore utilizing ferrosilicon as the reducing agent has been studied extensively by active metallurgists such Mr L,M, Pidgeon the father of this process, Most of the work sited so far has focused on heating the (FeSi/MgO,CaO) briquette mix under vacuum in stainless steel retorts by external fuel hydrocarbon heating, In this work Electrical Induction Heating was employed as the heating method whereby the briquette mix was placed in a steel crucible around which an Induction Heating copper coil was wound and placed inside in a stainless steel vacuum tank, It was observed that by virtue of the fast Induction Heating method utilized in the silicothermic extraction process higher reduction temperatures were reached in shorter periods of time due to fast heat transport into the ore charge mix, This facilitated shorter metal reduction times as compared to the conventional fuel heating methods.

Jan 1, 2006

By Benoit Virollet

Over the last 10 years the diameter of unbraced, unlined and unanchored circular shafts has grown dramatically in many parts of the world. This progress has taken place through improvements in: construction methods; concrete rheology; and design capabilities. Excavation equipment has become more precise in terms of operator control and ability to correct alignment of digging elements leading to better alignment tolerances. Also contributing to the increases in shaft diameters is the evolution of design models. A better understanding of soil structure interaction is being incorporated into the analyses in terms of radial soil stresses and imposed loads on the shaft. This paper provides an overview of the recent progress made in circular shaft construction, the primary design considerations, and some innovative uses of efficient arc elements to develop unsupported structures of other shapes. In addition, a summary of recent circular shafts constructed worldwide is provided.

Jan 1, 2006

By Sutham Niyomwas

Synthesis of alumina-mullite-silicon carbide composite (Al2O3-Al6Si2O13-SiCw) was obtained in situ by carbothermal reduction of a mixture of kaolin and two different silica sources. The carbothermal reduction was carried out in a horizontal tube furnace under flow of argon gas. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The synthesized products were mixtures of alumina, mullite and silicon carbide in the form of whiskers. The effects of adding two different silica sources of rice husk ash and silica powder to the mixture of kaolin and activated carbon were investigated. XRD and SEM analyses indicate complete reaction of precursors to yield Al2O3- Al6Si2O13-SiC as product powders, with the SiC having whisker morphology.

Jan 1, 2006

Public perceptions about coal remain neutral to negative But gains are slowly being made as the public becomes more aware of coal as ?abundant, affordable, and increasingly clean?

Jan 1, 2006

By Patrick R. Atkins

Energy issues will have increasing impacts on decision making in all facets of society over the next few decades. Industrial users of energy and producers of products that affect energy use must be fully aware of the implications of their processes and products on the energy situation. This paper describes a model that has been developed for the aluminum industry that allows scenarios to be evaluated to gain improved understanding of possible implications for our businesses. A brief overview of the model is provided.

Jan 1, 2006

By Patrick R. Atkins

Energy issues will have increasing impacts on decision making in all facets of society over the next few decades. Industrial users of energy and producers of products that affect energy use must be fully aware of the implications of their processes and products on the energy situation. This paper describes a model that has been developed for the aluminum industry that allows scenarios to be evaluated to gain improved understanding of possible implications for our businesses. A brief overview of the model is provided.

Jan 1, 2006

By G. E. Bandelis

In this paper, solid bed erosion processes and the mechanisms involved when a two-phase liquid-solid mixture flows over a bed of solids in a horizontal annulus are analyzed. There are few such studies available with some authors arguing that the flow rate for erosion is always less than the flow rate for the suspension of solid particles thus necessitating further study and analysis of such phenomena. Tests were run to determine the mechanism of erosion and the erosion velocities of the solid bed formed in a concentric annulus for three flu-ids, water, a low concentration water solution of Carboxyl-methyl-cellulose (CMC), which behaved as a Newtonian fluid and a higher concentration CMC water solution which behaved as a power law fluid. Glass spheres of 2 mm nominal diameter were used as solids. The flow rate at which erosion occurred together with the mechanism of bed erosion were determined visually, while the whole process was video recorded. Our tests indicated different erosion mechanisms and different erosion velocities for the three tested liquids, with the liquid viscosity playing a major role. The first mechanism, observed for water flow, gives erosion from the front of the bed while the second mechanism, observed for the flow of the two viscous fluids, gives erosion from the top of the bed. The role of each of the parameters to erosion is investigated, whether it is turbulent flow with the turbulent fluctuations being more capable to remove the solids from the formed bed or whether it is liquid viscosity, which results in the hydrodynamic shearing force. The results demonstrate that liquid viscosity plays a role in the erosion mechanism and yields different erosion velocities of the solid bed hence, it should be taken into account when modeling flow pattern transitions for solid-liquid flows. Prior studies have not identified this and it could be the reason of the disagreement between theoretical models and experimental and field data.

Jan 1, 2006

By C. Sima, M. Legoabe

Keywords: Pyrometallurgy, furnace, platinum Mortimer Smelter is one of the three smelting operations in the Anglo Platinum Group. It is located in the Limpopo Province, approximately 100 km north of Rustenburg, and approximately 15 km west of Northam. The smelter operation is the smallest of the three smelting operations in the group, with a smelting capacity of 170 kt/annum. The operation consists of a Larox filtration plant, a Drytech flash drying plant, a modified Elkem / Hatch 19.5 MVA furnace, and a 60 t/h matte crushing plant. The operation does not convert its furnace matte, and hence the final sulphide rich matte is transported to and processed further at the Anglo Platinum Converting Process (ACP) within the Waterval Smelter Complex in Rustenburg. Furnace slag is granulated, and processed through a slag mill, or transported to a slag dump.

Jan 1, 2006

By M. Andrews, B. J. Göhre, G. Strong, C. Terblanche

Mechanized mining can be experienced as a symphony by substituting the instruments for the different machines that each perform their own function and thus have different sounds. The drill-rig is the soloist around which all the other machines must play their part in harmony. Each machine can function on its own, but productivity is achieved only when all of the machines function in a holistic manner, as the different sounds of instruments form a symphony when playing together. To produce a symphony is to have the ability to put together all the pieces. It is the capacity to synthesize rather than to analyse. Today?s managers have to apply this harmonic way of thinking to make the system of mechanized mining work. In other words each of these people must have the ability of a conductor, whose job involves corralling a diverse group of notes, instruments and performers, and producing a unified and pleasing sound. At Modikwa Mine the introduction of the MAPS (Mine Activity Performance System) has allowed management to obtain a clear view of all the activities associated with the equipment. Through synthesis the issues that hampered productivity were identified and addressed to improve production and reduce costs.

Jan 1, 2006

By J. Loredo

Asturias, in northern Spain, emits 18 Mt CO2/year to the atmosphere, which supposes the biggest industrial CO2 emissions in the country. In order to avoid CO2 emissions to the atmosphere, keeping the availability of energy from fossil fuels, background studies focussed to the selection of favourable sites for CO2 geological storage are necessary. In Asturias, the options for CO2 geological storage are sequestration in deep saline aquifers or sequestration in unexploted coal beds. In the area, there is the biggest coal basin of the country and a great Palaeozoic sedimentary basin with appropriate silicoclastic or carbonated reservoirs and impermeable caprock for CO2 geological storage, located in proximity to thermoelectric power plants and other sources of CO2 emissions. All evidences suggest that CO2 storage in deep aquifers is the most interesting option but a legal planning and a technical regulation are still to be done. The possibility for CO2 sequestration in coal beds is modest and associated to the CBM commercial exploitation. It is necessary to have in mind that the feasibility of CO2 geological storage in Asturias apart of technical factors will depend on price of CO2 ton, legal conditioning and possibility to apply emission rights to projects.

Jan 1, 2006

By Chai Li-yuan

Anodizing behaviors of magnesium alloys AZ31 at constant applied current, based on the electrolyte solution free of chromate or fluoride, were investigated. The anodizing process was influenced by constituents of electrolyte greatly. Therein, the oxylate salts, which led to the occurrence of the two totally different processes, played a determinant role in anodizing. They were stable and sparking process respectively. The morphology of anodizing film was observed by SEM and the structure of film was analyzed by XRD. During the stable process, a brown thin film was formed, however the sparking process led to the formation of white hard thick film. The functions of some kinds of additives, such as ammonia, glyceryl alcohol and PVP etc were also studied. Some of them had great effect on surface morphology of anodic film and some of them affected stability of anodizing process significantly.

Jan 1, 2006

By Hiroyuki Matsuura

Treatment of electric arc furnace (EAF) dusts has become an important issue from the viewpoint of the environmental protection and recycling of variable resources because these dusts contain considerable amount of zinc and lead. A new recovery process of these metals has been proposed, in which the metals in the dusts react with waste polyvinyl chloride to form metal chlorides. Therefore, it is important to clarify the physicochemical properties and behaviors of zinc, lead and those chlorides and oxychlorides. In the present study, the kinetics of chlorination of ZnO, PbO and ZnFe2O4 mainly contained in the EAF dusts were investigated at 1023 K to 1273 K with Ar-O2-Cl2 gas. Based on these results, the selective chlorination and evaporation process of zinc and lead from the mixture of Fe2O3-ZnFe2O4-ZnO-PbO was examined and the high efficiency of selectivity has been demonstrated.

Jan 1, 2006

By M. Sahoo, P. Burke, Y. Fasoyinu, J. P. Thomson

The effects of grain refinement, mold temperature and chemical composition on the hot tearing resistance of aluminum alloys 535.0 and 206.0 has been studied by pouring constrained rod castings in metal molds. In addition, two prototype components that could be used in automotive applications were also poured from both alloys by gravity tilt-pour and low pressure permanent mold casting processes. This paper summarizes the results and issues encountered during the casting trials. It was shown that grain refinement and mold temperature ::::: 400°C reduced, and sometimes eliminated hot tear cracks in both alloys. The two prototype engineering components could be cast successfully from both alloys in metal molds. The metallurgical issues related to molten metal treatment and processing temperatures were well controlled. However, issues related to the control of hot tearing, casting and mold design must be addressed in future studies to guarantee the production of defect free castings.

Jan 1, 2006