Search Documents

By Ruixiang Wang, Jinhui Li, Youjun Xiao, Daoling Xiong, Hao Chen

"Leaching solution prepared from spent battery materials contains large quantities of valuable metals, such as Cu, Ni, Co, Mn and Fe. Therefore, recovery of valuable metals from acidic polymetallic aqueous solutions is of great importance for every plant. In this work, a method is introduced of recovery of Ni, Co and Mn from polymetallic solution prepared by leaching spent battery material. The basic concept includes copper was removed through replacement by iron powder followed by iron precipitation in goethite method. The experimental results show that Cu can be removed 99% at least through replacement by Fe powder, and the removal of Fe can achieve 99% by goethite method. At the same time, the loss of Ni, Co and Mn are about 2%, 3 % and 2%, respectively. The process of differential removal of metals can be selected as the treatment alternative that combines simplicity, efficiency and reliability with low capital and maintenance costs. The purified solution which only contains Ni, Co and Mn can be used to prepare NixCoyMnz ternary system precursor.1 IntroductionNickel and Cobalt are very important metals which are applied in many fields, such as energy material and support material for some new material field. The world demands for such metals is progressively increasing, while raw resources are being depleted and with the constraints raised by the Law and related legislation assigned to protect the environment from hazardous wastes in the world. Nowadays study on reutilization of waste materials has great significance for achieving secondary resources recycling and preventing environmental pollution. There are many hydrometallurgy methods applied for dealing with these wastes, while they usually contain large quantities of valuable metals, such as Cu, Co, Mn and Ni, as well as impurities, such as Fe, Zn, and etc. Therefore, proper treatment of these leaching solutions prior to their discharge is of great importance, so that the contained valuable metals can be recovered.Separation and extraction of metals from leaching solution can use some methods through solvent extraction[l,2], ion exchange[3,4], precipitation with sulfide[ 5] or alkali[ 6] and electrolytic recovery[?]. Among the appropriate treatment alternatives, replacement and differential precipitation is the most attractive treatment that combines simplicity, efficiency and reliability with low capital and maintenance costs."

Jan 1, 2011

By C. Demir, M. S. Celik, I. Gülgonul

Na-feldspar (albite) and K-feldspar (microcline or orthoclase) are major feldspar minerals with identical crystal structures and physicochemical properties. Flotation appears to be a unique method of separating these minerals. Fundamental studies on amine/feldspar system in the presence of monovalent salts showed that separation of these feldspar minerals by flotation is possible at certain concentration of monovalent salts in HF medium and natural pH. A comparison between natural pH and HF medium indicates that the latter provides a better selectivity at the expense of higher collector requirement. A general mechanism for both systems involving an ion exchange between the uncommon ions and adsorption of the common ions is proposed to be responsible for creating differences in the charge of albite and microcline unto which amine adsorbs.

Jan 1, 2002

By William I. Watson

Problems encountered in beneficiating mineral raw materials become increasingly difficult as there is a shift to lower grade and more complex raw materials, and because of the economic need to strive for ever higher recoveries, higher grade products, and lower processing costs. Methods of attacking the many problems should include not only the familiar chemical and physical tests and equipment, but such techniques as X-ray analysis, infra-red analysis, differential thermal analysis, and the use of electron and X-ray microscopes. Many people in the mineral-treating field are unfamiliar with these newer methods and techniques. The differential thermal analysis method, in particular, does not seem to be very well known, even though it offers interesting possibilities in the study of many ore treatment problems.

Jan 7, 1959

By A. J. MacRae

Metallurgical furnaces are made up of complex multi-component systems that must function either together or in parallel for safe, and reliable operation. Thermal expansion of single material components experience induced stresses during heating and cooling, which can lead to cracking or failure. Multi component elements and systems can experience significant thermally induced stresses during both steady state and transient temperature conditions. Examples pertaining to temperature effects on refractory, copper cooling blocks, furnace shells, and complete systems will be discussed. The purpose of the paper is to highlight how stresses and strains are developed due to differential thermal expansion.

Jan 1, 2015

By D T. Froedge

A new system for acquiring blast vibration data and a method for presenting that data in such a way that there can be an extraordinarily enhanced insight into the understanding of vibrations produced by blasting is described in this paper.

Jan 1, 1989

By Waldemar Lindgren

THE purpose of this paper is to present certain facts relating to Cordilleran differentiation and metallization. Theoretical discussions concerning the exact modus operandi of differentiation, the causes that led up to it, and the original distribution of the magmas have been omitted because the author feels that his knowledge is deficient. These subjects have been adequately treated in the admirable works of Iddings, Daly, Harker, Tyrrell, Shand, and Wolff. The facts here set forth seem to indicate that differentiation and metallization form one continuous process during the eastward movement of the magmas, culminating in the alkaline province of the eastern border of the Cordilleran Ranges.

Jan 1, 1933

By Moore R. F, Macias L. F

The Filbara region of northwestern Western Australia contains several known occurrences of mafic/ultramafic rock assemblages which may host platinum group element (POE) mineralisation. This paper deals with occurrences at Munni Munni and Andover. The Munni Munni complex is of particular interest because it is known to contain PGE mineralisation and is currently undergoing active exploration. The US/Australia Joint Scanner Project of October 1985 collected airborne scanner data for the BMR over Munni Munni. Such an ultramafic-mafic complex had not been previously researched with advanced remote sensing instrumentation. Extensive investigation of data from the NSOO1 (Thematic Mapper Simulator) scanner resulted in successful differentiation of gabbroic and ultramafic rocks, and also subdivision within the ultramafies. Similar differentiation could not be achieved using conventional Landsat MSS imagery and aerial photography. Encouraged by those results and in support of BMR field research into the mafic-ultramafic suites of the region, data from the Landsat Thematic Mapper (TM) instrument were investigated to attempt differentiation of the ultramafic and mafic rocks in the Andover complex some 50 km to the northeast of Munni Munni.

Jan 1, 1988

By James J. Tansey

A Deep Foundations Institute meeting with the University of Michigan at Ann Arbor in March of 1984 featured legal rights under Differing Site Conditions. A workshop conducted by the authors and Gerard Ittig, Esq. added to the value of the symposium. This paper will be of interest to your attorneys in any subsurface disputes.

Jan 1, 1985

By Jürg Künzle

Underground construction is a matter of dealing with the inherent uncertainty of subsurface geology. If the encountered conditions are less favorable than the expected ones, the execution of excavation, support, ground treatment or lining works is likely to require more or different efforts than anticipated, thereby delaying the works and increasing the costs. The 2019 first edition of the FIDIC Emerald Book model contract (FEB) addresses many of the issues to which underground works give rise, including those related to differing site conditions (DSC). This paper examines how under the FEB disputes arising from or in connection with DSC could or should be avoided.

Jun 13, 2021

By Peter J. Tarkoy

The use of personal computers (PCs) is increasing in underground construction applications, specifically, for estimating, record keeping, construction performance analysis, project cost reporting, and the effective application of construction experience for estimating and aggressive bidding. Applications particularly suited to the PC are analyses of construction performance and differing site condition claims. The advantages of using a PC in the analysis of differing site conditions claims is that the PC: requires quantitative and factual data, allows vast data manipulations, calculations, and sorting, and provides a simple graphic representation of complex data and issues. The restrictions imposed by a PC are conducive to the focus on essential facts, issues, quantitative analyses, and inherently, the truth. As computer thinking is established, a clearer, more precise and accurate focus on the elements of a differing site condition is essential for successful evaluation and presentation.

Jan 1, 1987

By J. Ling, L. Racine, P. Cousin, A. R. Laplante

"The problem of gold recovery by gravity from high density gangues is first discussed from a fundamental perspective. Three potential difficulties are presented: poor liberation and fine gold particle size, concentrate bed erosion by coarse dense particles, and slow percolation of gold particle through the high density gangue bed. Two case studies are presented to illustrate the impact of these three problems on circuit performance and the feasibility of gravity recovery. It is concluded that careful testing can determine the scope of the first problem and feed preparation can limit the extent of the second. The third problem is clearly the most serious and results in lower gravity recoverable gold recoveries than would be achieved with the same recovery effort on a low density gangue application.IntroductionSince the commercialisation of the Knelson Concentrator in 1980, gold gravity recovery has experienced a surge in interest, in Canada and the United States first, then Australia, Zimbabwe and Russia, and finally worldwide. Table I details number of units sold in various countries, which corresponds approximately to their importance as gold producers 1. Exceptions. such as the low rank of South Africa or the importance of Zimbabwe, despite the much higher gold throughput of the former, are generally the result of differences in the effectiveness of the local marketing strategies, as well as a reflection of the ""philosophy of recovery"" prevalent in the country.The impact of the Knelson has not been felt equally in all plants. Typically, a highly successful application falls into the following categories: (a) alluvial or hard rock recovery for which gravity is the sole recovery method, (b) hard-rock free gold milling with ores which have a very high gravity-recoverable gold (GRG) content, (c) low grade sulphide copper-gold ores which include flotation ahead of cyanidation and (d) free-milling gold ores ahead of Other applications can be successful, but are not as common. The ""explosion"" of centrifuge concentration, of which the Knelson is the most successful but by no means the sole model, has created a certain euphoria which can be summarized as ""gravity recovery will improve the profitability of gold milling, no matter what."" This presentation is about applications that are not so successful, or even downright unsuccessful. The rationale is not to down-play gold gravity recovery, but to set it in its rightful position: metallurgically, it is not appropriate all of the times; it can become inappropriate if poorly designed; and it can be metallurgically possible but economically unjustifiable. In this paper, this will be illustrated and explained rather than demonstrated, with the use of both industrial plant surveys and laboratory test work. Alternate gravity approaches will be suggested."

Jan 1, 1997

By J. Ling, J. Xiao, A. R. Laplante

"The most challenging gold gravity separations occur when gangue has a high s.g., gold is fine, or a combination thereof This paper examines such separations, and evaluates the performance of a 3-in Knelson Concentrator at various rotation speeds, a 4-in SuperBowl, and a laboratory Mozley Multi-Gravity Separator (MGS). Synthetic feeds, primary cyclone underflows and flash flotation concentrates are tested.It is concluded that higher rotation speed are mostly useful for very fine (< 3 7 µm) gold recovery, with potential loss of recovery in the 37-212 µm range. This problem is traced to the collapse of the flowing film at higher Gs, which hinders the percolation of particles of intermediate size. Increasing fluidization water flow can alleviate this problem, but the recovery of very fine particle then drops. The MGS does not operate with the same principles, and can achieve good to very good recoveries of very fine to fine gold particles, but the unit has a high cost to capacity ratio, and there is no evidence yet that it can yield smeltable concentrate grade or a concentrate that can be upgraded with a shaking table.IntroductionThis presentation is a sequel to similar CMP presentations of the past eight years; all focused on practical aspects of gold recovery. The first hard rock application of the Knelson Concentrator (Laplante et al, 1990), studies of the grinding and classification behaviour of gold and other malleable metals (Banisi et al, 1991; Laplante et al, 1995), the development of a 3-in Knelson based methodology to study gold gravity circuits (Laplante and Shu, 1992), a comparison of the Knelson and Falcon (Laplante, Laplante et al, 1993), the presentation of a test to determine the amount of gravity recoverable gold, or GRG (Laplante et al, 1996), and the use of synthetic materials, in particular tungsten, to mimic gold (Laplante et al, 1995) were presented. A summary of many practical implication of the McGill research was presented in 1994 (Laplante). Whereas gold gravity recovery was less popular and largely jig-based (in North America) at the beginning of the eighties, many gold plants now incorporate a gravity circuit, and the Knelson Concentrator is the most commonly used unit."

Jan 1, 1998

Vale Inco?s Coleman Mine 153 Orebody is a narrow vein deposit with a dip that varies from 30 to 70 degrees. It has a strike length of 1200-feet and the current mining extends from the 4250 level to 5100 level. The primary mining method is mechanized cut-and-fill although drift-and-fill is also used in wider sections of the ore zone. The ore body is divided into six main mining horizons with an average of three mining blocks on each cut. There are some interesting rock mechanics challenges related to mining upward from the 4550 level and these challenges are increasing as the mining front progresses toward the 4400 level. The mining of the 4550 block is currently at cut 13 whereby the crown pillar thickness is approximately 60-feet. Significant factors including increased stress levels in the crown pillar, the change in the orebody dip at this level and a recently indentified geological structure in the footwall, have all combined to introduce seismic activity in the footwall of 4550 level. Closer studies revealed a consistent trend of seismicity that was further examined with core logging and Acoustic TeleViewer technology. The data from these assessment tools disclosed a geological structure that is influencing the mining environment. This paper reviews the seismic analysis for the 4550 level mining zone and the subsequent procedures used to locate the new geological structure. The paper also discusses the key mining practices used to successfully mine cut 13 of 4550 level and briefly reviews the studies that are underway to up-date the mine design for continued extraction of high-grade ore in a safe and productive manner.

May 1, 2009

By AIME AIME

AT a recent meeting of the Utah Section. A.I.M.E., P. D. Nielson, general plant superintendent of the new Geneva steel plant at Provo, Utah, spoke on "General Operations of the Geneva Plant." Mr. Nielson explained that the plant was located at Provo, Utah, on account of railroad facilities, the proximity of coal, iron, and limestone, and the nearness of water for operating the plant. Water probably was the most important item in making the decision.

Jan 1, 1944

Because of the work of the pioneers of sampling theory, we know the principles, test work and equations to use to design sampling systems to meet targets for precision and accuracy. However, we do not see such æproperÆ systems deployed everywhere a sample is obtained around mineral processing plants. In many cases, we do not have solutions that satisfy all of the theoretical, economic and practical considerations. There are some well-known problems, such as high-volume streams with wide size distributions combined with a sparse valuable component that is heterogeneously distributed (such as gold ore SAG mill feeds). However, other difficult sampling issues are common, such as streams which vary widely over a day in flow rate and slurry density (many flotation concentrates), and loaded CIP carbon on transfer to elution. Inventory measurement issues abound, especially for leaching operations where daily inventory change is significant for metallurgical accounting. The result is that operators realise that although they issue reports daily, they do not know what is actually going on in their plant on a daily basis with sufficient confidence to quickly diagnose problems or confidently predict the benefits of potential enhancements. The industry needs practical and economic solutions that can be awarded the ætheoretically correct samplerÆ tick in order to better understand and optimise their processes.

Jan 1, 2008

By Cary Moffat, John Kita, Rick Walker

The Lac des Iles Mine, in an isolated area of NorthwesternOntario is a relatively new open pit platinum and palladium mine. They were encountering problems with the equipment and production scheduling when ramping down to begin production on the subsequent benches. A co-operative effort between Lac des Iles Mine operation people, ICI Explosives, and the mines drilling and blasting contractor - Consbec Inc., resulted in a decision being made to use full depth sinking cuts to provide access to the next bench.

Jan 1, 1996

By William Gleason

"Ed Rapp is among those who believe in the saying that necessity is the mother of all invention. Rapp is the president of Caterpillar’s mining group. As such, he is tasked with leading the world’s largest mining equipment maker, and its customers, through this time of lower commodity prices, while also positioning his company to be prepared for better days that lie ahead.The decade-long mining boom fueled by growth in emerging markets and demand for commodities that led to record prices for some metals paused in 2008 with the global financial crisis. However, according to Rapp, thanks to stimulus packages around the world, and in particular the stimulus from China that was focused on infrastructure, the mining sector recovered fairly quickly, and from 2010 to 2012, mining was strong.And then the stimulus stopped. Credit dried up and global growth began to slow down and, in the three years since, commodity prices have declined by an average of 60 percent. Caterpillar expanded during the boom, acquiring Bucyrus, and investing billions into the mining sector. It has felt the pinch of the slowdown as much as any mining company in the world. These pages, and those of other mining publications as well as mainstream media, have been filled with stories of doom and gloom about the industry. But Rapp, while acknowledging that the difficult times have been painful, also said Caterpillar sees opportunity in the slow down and reaffirmed his company’s commitment to the mining industry as absolute."

Jan 1, 2014

By Orlando Oliveros

The Los Bronces Mine and Concentrator, one of the three operating units of Compania Minera Disputada de Las Condes S.A. (an Exxon Minerals Co. affiliate), is located in the high Andes of East-Central Chile approximately 70 kilometers northeast of Santiago at an elevation of 3,650 meters above sea level. (Figure 1). Santiago, the capital city of Chile, is located at an elevation of about 500 meters above sea level and enjoys a very mild climate, similar to some areas of California. At the mine site, however, extremely heavy winter conditions prevail occasionally, with very heavy snow and the resulting snow avalanches endangering installations and people. At the same time, ideal skiing conditions are found at the nearby ski resort of Portillo and Farellones. Mount Aconcagua, the highest mountain in the western hemisphere is only about 55 kilometers further to the northeast of the Los Bronces mine.

Jan 1, 1983

By James T. Ludwiczak

Drilling and blasting in a Karst (sinkholes and mud seams) environment has long been a problem for blasters, miners, quarry operators, contractors, and developers. While one cannot change the geological conditions, one can take some measures during the bidding process and the initial preparation of the blasting program to help reduce some of the problems. During the geotechnical investigation and developing the test/core drilling grid, the owner/developer needs to take some additional measures that will provide important data to the blaster to help reduce the problems associated with blasting this type of geology. The owner/developer must also understand that, due to the geologic conditions, the results of the blasting will not be ideal and there may be additional blast-related costs. If provided the proper geologic data, the blaster can develop drilling patterns and blast designs that will help reduce some of the more problematic areas.

Jan 1, 2005

Minerals similar to the indicator minerals used in kimberlite exploration are widespread in the Cainozoic alkali basalts of north Queensland. Magnesian ilmenite, pyrope garnet, chrome diopside, chrome spinel, phlogopite and zircon were recovered from most of the localities examined. The occurrence of these minerals creates significant problems when indicator minerals are used for diamond exploration. Basaltic ilmenite is visually similar to kimberlitic ilmenite. Untransported grains are rounded and have pitted surfaces. Basaltic ilmenite grains often have exsolution lamellae and reaction rims of titanomagnetite. Although kimberlitic and basaltic ilmenite are chemically similar, basaltic ilmenite grains are usually less magnesian than their kimberlitic counterparts. Basaltic ilmenite contains very little Cr203. Pyrope garnet occurs as megacrysts and in a variety of xenolith lithologies in north Queensland basalts. Most basaltic garnet is Cr-poor and comparable with kimberlitic garnet from Groups 3 and 5 of Dawson and Stephens (1975). Wine-purple, chrome-bearing garnet is common in kimberlite but rare in basalt.

Jan 1, 1984