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By M. J. Gula, S. S. Xue, E. P. Horwitz, J. T. Harvey

A study was conducted to control iron in copper electrolyte streams using Eichrom Industries' new monophosphonic/sulphonic acid resin. The resin strongly and selectively extracts ferric ion over copper and cobalt from highly acidic copper electrolytes. The resin has a loading capacity of 27-g/L iron and can be readily regenerated. In addition, the new resin can easily be synthesized using commercially available starting materials. This paper presents the experimental results for iron control in copper electrolyte streams using the new resin and discusses its potential applications to other hydrometallurgical streams.

Jan 1, 2002

By M. Li, J. D. Miller

Recently water insoluble alcoholic solutions of alkyl hydroxamic acid collectors have been shown to be particularly effective in the flotation of coarse feed material sampled from phosphate operations in Florida, North Carolina and Utah (Miller et al., 2000). The experimental results indicate that high separation efficiencies can be achieved in single stage flotation with these new collectors. In some cases the concentrate grade reached 34% P2O5 with 93% recovery from single stage bench scale flotation experiments. Critical aspects of the composition and structure of these new collectors are discussed with respect to their effectiveness in phosphate flotation. The wetting characteristics at fluorapatite, francolite, dolomite and quartz surfaces are being investigated with the new collector. Finally, other surface chemistry considerations in the development of these new collectors for phosphate flotation are discussed.

Jan 1, 2002

By William H. Mount

INTRODUCTION Effective mine ventilation is required to maintain a healthy underground environment for humans. Without effective ventilation, the environment can become unhealthy or hazardous as a result of the depletion of oxygen, contamination with toxic gases, or the buildup of an excessive amount of particulate matter (dust). Each contaminant has an upper limit of concentration that should not be exceeded within an 8-hr period. This is known as the threshold limit value (TLV). The TLV represents an acceptable level of exposure that should produce no ill effects. Unfortunately, more than one contaminant may be present at any one time and the effects of the individual contaminants may be additive, i.e., the effects of each contaminant must be considered simultaneously to determine the potential danger to miners. Possibly the greatest threat to mine-air quality is the uncontrolled underground use of the diesel engine. The diesel engine was invented in 1892 by Rudolf Diesel. His intention was to develop a power source that could burn coal dust as a fuel, but he was unsuccessful in that attempt and had to resort to liquid petroleum fuels (Johnson, 1975). In 1898, the diesel engine was intro¬duced into the United States by Adolphus Busch, who anticipated using it as a prime mover in factories and generating plants. At that time, the diesel engine was a very large and very heavy engine, designed for fixed installations. By 1919, lighter engines were being developed, and by 1931, Caterpillar was marketing a diesel-powered, track-type tractor (Henderson, 1975). Since 1931, the diesel engine has evolved into an extremely popular prime mover in medium and heavy-duty applications. Efficiencies now are on the order of 40% and improvements such as turbocharging and aftercooling have produced engines capable of generating power at a ratio of 0.3 kW/kg (1.0 hp per 5.0 lb) of engine weight. Although the diesel engine is relatively efficient as a mobile power plant, it is far from efficient in terms of the energy produced from the energy potential of the fuel. About 60% of the heat value of the fuel leaves the engine as wasted heat, with about 50% of that heat being emitted through the exhaust pipe and the other 50% being emitted through the radiator or cooling fins. Perfect combustion in an engine would produce only water vapor (H_0), carbon dioxide (CO_), and nitro¬gen (N2) as the byproducts. Since the diesel is not a perfect engine, each pound of fuel burned generates 5.6 m° (200 cu ft) of exhaust gas, containing about 0.009 m3 (0.33 cu ft) of carbon monoxide (CO), 0.009 m' (0.33 cu ft) of nitrogen oxides (NO, NO2, and NOD), and 0.57 m3 (20 cu ft) of carbon dioxide. The balance of the exhaust emission consists of free nitrogen and water vapor (Hurn, 1975). Contrary to popular belief, the diesel is not inherently dirty. Under normal operating conditions, a well-maintained engine neither smokes nor smells. However, the same well-maintained engine can and does produce toxic emissions. A diesel engine is not inherently safe and constitutes a distinct hazard to personnel. This chapter is devoted to a description of the various toxic substances that may be generated by a diesel engine. Although some of these substances may also be produced by blasting or natural causes, the focus of this chapter is on the relationship between the internal- combustion compression-ignition engine (the diesel) and the quality of the mine air. CARBON MONOXIDE Combustion Process During the combustion process (burning) of organic fuels, each atom of carbon combines with two atoms of oxygen, provided that a surplus of oxygen atoms is available. Thus, the carbon is oxidized to carbon dioxide. Most open flames, such as trash fires, camp fires, gas ranges, etc., produce carbon dioxide. However, with insufficient oxygen, incomplete combustion results as the carbon atoms each combine with one atom of oxygen to produce toxic carbon monoxide. Burning charcoal briquettes produce carbon monoxide because the combustion takes place inside the briquettes where sufficient oxygen is not available to the combustion process. Internal-combustion engines, whether burning gasoline or diesel fuel, also produce carbon monoxide. The only oxygen available to the combustion process is that trapped within the cylinder. If the amount of fuel delivered to the cylinder is excessive, there is insufficient oxygen for complete combustion and carbon monoxide production results. In a normally aspirated (nonturbocharged) diesel engine, the amount of air "sucked" into a cylinder is the same on every intake stroke, resulting in complete combustion only at low levels of engine loading, when small amounts of fuel are injected. Higher levels of engine loading cause larger amounts of fuel to be injected into the same volume of air in the cylinder. Unless the volume of air is increased, the combustion process becomes progressively less complete as the amount of fuel increases. Turbocharged engines are able to compensate some¬what for increased loading and increased fuel consumption. The turbocharger acts as a compressor for the intake air, forcing a larger volume of air into the cylinders as the engine speed increases. Hence the turbocharged engine burns cleaner than a naturally aspirated engine and produces slightly less carbon monoxide (Marshall and Fleming, 1971). Much of the underground equipment used today is powered by turbocharged indirect-injection diesel engines. Although these engines emit fewer toxic contaminants than naturally aspirated engines, they do not eliminate the problem. Since the turbocharger is driven by the exhaust gases, rapid accelerations can cause temporary overfueling of the engine until the turbocharger attains a speed sufficient to restore the correct air-to-fuel ratio. During this "turbocharger lag," the combustion cylinders contain insufficient oxygen, causing severe smoking and an increased output of carbon monoxide.

Jan 1, 1982

By Kal V. S. Sastry, Stephen N. Little

Computer simulation of comminution systems is found to provide significant cost savings by enabling efficient circuit design and development of control systems. These simulation systems are based on sound mathematical models and numerical methods. Nevertheless, they are found to be hard-to-use and hard-to-modify to carry out more elaborate process analysis. This paper discusses the fundamental principles and practical aspects of an advanced, highly functional, and user-friendly SIMulator for COMminution, SIMCOM, that is being developed at Berkeley by incorporating state-of-the-art software engineering principles.

Jan 1, 1992

By K. P. Madhusudhanan, R. K. Bhatia, K. S. Narasimhan, R. N. Singh

A typical case study of a coal washery of capacity 500 t/h raw coal input has been presented and discussed with particular reference to the techno-economics for flotation column vis-a-vis the conventional flotation cells, keeping parameters like input capacity and product ash same. The results presented indicate that substitution of flotation cells by columns in a coal washery results in advantages of increased fine coal recovery, better quality of concentrates, lower capital and production costs etc.,. The effect of increasing the specific capacity of the column by design modifications on the cost benefit is also analysed.

Jan 1, 1988

By Wei Bin, Liu Zhe, Liping Xiao, Jichi Bai

The Acid Mine Drainage has characteristics of low pH, high concentrations of heavy metal ions, such as Fe2+, Mn2+, Cu2+ and Zn2+. In this paper, the composite particles that consisted of bentonite and steel slags were used to dispose the Acid Mine Drainage. Bentonite is the mineral materials and can adsorb heavy metal ions excellently. The steel slags are alkaline and industrial solid waste for the treatment of the Acid Mine Drainage. The main influencing factors, such as adsorbent dosages, shaking rates, concentrations of heavy metal ions, temperatures, adsorption time and pH value were studied by the static experiment. Increasing the adsorbent dosages and the concentrations of the heavy metal ions, speeding up the shaking rates, raising the temperatures, extending the adsorption time and improving pH would improve the removal efficiencies of heavy metal ions. Through considering the removal efficiencies and the treatment costs, the optimum reaction conditions for the four kinds of heavy metal ions were obtained. The adsorbent dosage 21 mg/L, the rotational speed 120 r / min, the temperature 25?, adsorption time 100 min and the initial wastewater pH 7. The four kinds of heavy metal ions existed independently in the simulated mine wastewater. The highest initial concentrations of Fe2+, Mn2+, Cu2+ and Zn2+ were 150 mg/L, 100 mg/L, 170 mg/L and 140 mg/L respectively. The removal rates were 93.42%, 92.64%, 93.86% and 95.17% respectively. The determination of the particles’ SEM-EDS Microscopic characterization showed the composite particles could play a part in neutralizing, absorbing and the chemical precipitation. The acidity decreased notably and the heavy metal ions of Fe2+, Mn2+, Cu2+ and Zn2+were adsorbed and precipitated effectively. The research results can extend the practical engineering application of the composite particles.

Jan 1, 2017

By L. J. Laughlin

The majority of non-drive conveyor pulleys use rotating shafts, and typical idler rolls use non-rotating shafts, even though both products are used to support and guide the conveyor belt and its load. This paper will explore and compare the requirements for rotating and non-rotating shaft designs and the impact of that design on the product. Additionally, it will explore how the “roller” bearing types (deep groove ball, tapered, or spherical) affect these designs.

Jan 1, 2003

By J. Trimble, B. M. Davis, D. McClure

During initial mining operations at the Colosseum gold mine, discrepancies between the average blasthole grades and mill-head grades were quite large. In December 1987, mill-head grades averaged 39% lower than corre¬sponding estimates from the blastholes. The correlation between average blasthole grade and mill-head grade had an r-value of 0.015. The magnitude of the discrepancy and the lack of correspondence between estimated and actual grades led to a series of investigations of the sampling system, the effect of blast movement of the ore, and the estimation methodology. The discrepancy between blasthole grades and mill-head grades had been reduced by about half on a percentage basis at the conclusion of these studies. Ongoing studies have produced changes that reduced this discrepancy to its present level of less than 10%. Geology The Colosseum mine is within the Clark Mountain mining district about 68 km (42 miles) southwest of Las Vegas, NV in San Bernardino County, CA. Gold mineralization at the deposit is hosted in two 152 m x 213 m (500 ft x 700 ft) interconnected, rhyolitic intrusive breccia pipes that intruded Pre¬cambrian crystalline basement rocks and overlying Paleozoic marine sedimentary rocks. Subsequent erosion (deroofing) of all of the Paleozoic section and a portion of the Precambrian section has exposed the pipes to the present level (probably a significant depth in the original breccia pipe system). Lithologies exhibited within the breccia pipe complexes include rhyolitic felsite, and breccias of felsite and wall/ country rock. Breccia types grade from felsite plus Precambrian granite-gneiss fragments in an aphanitic felsite matrix to crosscutting breccias of felsite, Precambrian granite-gneiss, and Paleozoic sedimentary rocks in a matrix of finely comminuted material of the same composition. All the lithologies in and around the breccia pipes exhibit moderate to intense quartz-sericite-pyrite alteration, with sericite and pyrite the dominant visual alteration minerals. Gold at the Colosseum mine is generally submicroscopic and associated with sulfide mineralization, chiefly pyrite. It occurs as free gold, with minor alloyed silver. It is primarily in contact with pyrite in fractures or along pyrite grain edges. Secondarily, it appears as isolated particles in quartz and other gangue minerals but spatially always close to pyrite, and rarely as particles encased in euhedral pyrite. The pyrite mineralization and minor base metal sulfides occur in three distinct styles: as disseminations, as open space or vein/fracture filling, and in breccia clasts replacing dolomite. The pyrite megascopically ranges from absent to 30% of rock volume within the breccia pipes. Although the gold at Colosseum is apparently spatially and geochemically associated with pyrite, there is only a general proportional relationship between pyrite content and gold content. Sometimes, a high volume percentage of pyrite has only geochemically anomalous gold. This makes visual pyrite only a general grade control tool and not a specific tool. This further makes the ore control process at Colosseum all the more difficult. Initial grade control procedure Initial grade control was based on blasthole samples collected in two stages by an "automatic" sample collection device (rocket sampler). A sample was collected for the top 3 m (10 ft) in a hole. The bag was then changed so that a sample was collected for the lower 3 m (10 ft). Each sample was prepared and fire assayed to determine the grade. Large discrepancies were sometimes noted in the assays of top and bottom samples. The samples were averaged together and a plot was made showing the blasthole locations and their associated grades. Discrimination between ore and waste was based on as-

Jan 1, 1989

By D. L. Jones, S. Knoerr, J. Mansanti

The Buckhorn Mine in Nevada currently treats oxide ore using heap leach methods, but exploration has identified sulphide reserves which are refractory in nature. Preliminary testwork was conducted on the sulphide material to screen potential pre-cyanidation treatment methods. Processes evaluated included pressure oxidation, biological oxidation, nitric acid oxidation and roasting. An initial economic and process analysis of the results concluded that roasting was the only viable process, and only if the roaster off-gases were converted to soleable sulphuric acid. Further economic analysis indicated that roasting of the whole ore was more attractive than pre-concentrating by flotation, followed by roasting of the concentrate. These results were generalized to show that for high sulphur ore a roaster/acid plant combination is more attractive that either of the other options, ie. pressure leaching or bioleaching, provided the by-product acid is soleable.

Jan 1, 1990

By R. M. Campoy

In this review of the copper, lead, zinc, and molybdenum industries in Mexico, the author describes how the country's position in the world base metals market and the climate for foreign investment in Mexico have been affected by the nationalization of the banking industry in that country and by recent mining legislation and the current national debt crisis.

Jan 1, 1988

By Cong Shi, Cuiping Li, Enji Sun

"Tailings dam is a subsidiary facility of mining production. In order to decrease tailings dam accidents caused by the failure of flood drainage system, this paper proposed a framework of potential failure detection system of tailings dam flood drainage facility based on three dimensional panorama technology. A collection device of three dimensional panorama is designed to capture the onsite images of flood drainage system of tailings dam. The spatial information of flood drainage facility of tailings dam is recovered through projecting the image information to spherical surface by using three dimensional panorama technology. Two dimensional images are transformed into three dimensional images in three stages of panorama images process, which are pretreatment, registration and splicing. Combined with the framework of HTML5, panorama images are embedded into webpage. These web pages have the functions of user interface that the images could be displayed, moved and zoomed. With the function of interaction with panoramic display, 3D panorama scenes can be changed and scaled. Browsing the webpage is helpful to find potential risks such as possible holes, fractures and leakages of flood drainage system of tailings dam. The realization of this system can detect the potential safety risks of flood drainage system of tailings dam. The application of this system would improve the safety and provide the ability of accident pre-warning. It is useful to maintain the healthy and sustainable operation of tailings dam.Introduction It is reported by Xie et al (2009) that tailings dam are necessary facilities for mine production and places which constructed by damming troughs or encirclement used to store tailings that eliminated after ore selection in Metal and non-metallic mines. It is reported by Mei (2012) that tailings dam is a dangerous source of high-energy man-made debris flow, the collapse of the tailings dam takes devastating damage, which seriously threatens the safety of life and property of the enterprises and the downstream residents. It is reported by Dong (2011) that the collapse of the tailings dam causes secondary disasters such as environmental pollution at the same time. It’s a serious impact on regional economic development and social stability. The phenomenon of collapse of destruction is general excessively of tailings dams in China. It is reported by Zhang et al (2011) that most of these phenomena are caused by flood over the top of dams. The main reason is the lack of capacity or the failure of the drainage system. There are also accidents caused by the failure of drainage system in foreign countries in recent years. For example, November 5th 2015, the tailing dams collapsed because of the insufficient drainage capacity of the Germano mining area in Germano Mariana area in central Minas Gerais state in Brazil. After a small post-earthquake, the liquefied tailings fill sand submerge downstream cities and towns. It finally destroyed 158 houses, killed at least 17 people, polluted 663km river and destroyed 15 square kilometres of land along the river. It is reported by Rico et al (2008) that it’s necessary to continuous monitor and control the tailings drainage system in order to reduce the occurrence of tailings accidents and guarantee the sustainable production of the mine. The traditional artificial detection methods of flood drainage system of tailings dam exist many problems such as heavy workload, low efficiency, and susceptible to meteorological conditions. And it is reported by Luo (2013) that the tailings dam wastewater is corrosive which result a certain disease in flood discharge facilities such as tailings drainage culvert, etc. In order to realize the effective monitoring, management and maintenance of flood drainage system of tailings dam, advanced technologies need to be used to acquire the information of collection and management of flood drainage facilities of tailings dam."

Jan 1, 2017

By Edward S. Plotkin, Joseph D. Guertin

In a continuing effort to upgrade tunnel design and construction practice, the New York City Transit Authority sponsored a geotechnical monitoring program on a recently completed section of the E. 63rd Street line in mid-town Manhattan. The purpose of the program was to document rock behavior as well as temporary and final rock support systems to provide a possible basis for either confirmation or modificification to design methods and construction specifications. This paper describes those portions of the study associated with rock behavior and temporary support systems. The entire study included monitoring of rock movements above the tunnel as well as adjacent to a 36.6m (120 ft) shaft, monitoring of stresses in steel ribs, monitoring of loads in rock bolts in two test sections and monitoring of stresses in the final concrete lining. PROJECT DESCRIPTION Route 131-A, Section 4 is located in mid-town Manhattan extending from under the Central-Park Zoo on Fifth Avenue eastward under 63rd Street to the end of contract between Madison and Park Avenue. Figure 1 is a Project Locus Map. The contract included approximately 355m (1165 l.f.) of 4 track tunnel(13.4m (44 ft) wide by 13.7m (45 ft) high excavated dimensions) plus a 22.9m (75 ft) by 19.8m (65 ft) by 36.6m (120 ft) deep ventilation shaft. The entire tunnel and most of the excavation shaft was excavated in metamorphic rock, known locally as the Manhattan Schist. The depth to tunnel invert varied from approximately 27.4m (90 ft) at the west end of the contract to 35.Om (115 ft) at the east end. Rock cover above the excavated crown varied from approximately 6.7m (22 ft) at the approximate mid-point of the contract to 18.9m (62 ft) at the western end. A plan view and interpreted geologic profile are illus-

Jan 1, 1979

By R. Pazhianur

Many investigators conducted surface force measurements between hydrophobic surfaces in water, and observed attractive force that was substantially stronger than the van der Waals attractive force. The excess force was appropriately referred to as “hydrophobic force”, for which many different theories have been put forth by numerous investigators. In an earlier publication (Yoon and Ravishankar, 1996), it was suggested that the hydrophobic force maybe due to the interaction between the large dipoles created by the surfactants adsorbing on solid surfaces in patches (or domains). In the present work, a mathematical model has been developed to further elaborate the theory.

Jan 1, 2003

Humic acids adsorb on coal and depress coal floatability in the acidic pH range. In alkaline solutions, their effect is not pronounced. In the neutral pH range, a second small addition of kerosene plus MIBC leads to a significant increase in coal yield and better selectivity. Humic acids present on oxidized coal surface were found to be responsible for the inhibited floatability of the? coal. As expected, the flotation of such oxidized coal also strongly depends on the method of pH adjustment.

Jan 1, 1988

By S. A. Matthews, M. L. Nave

AC variable frequency motor drives are emerging technology for belt conveyors. The success of the application in mining depends on adequate and timely consideration of drive, motor, and conveyor features. The purpose of this paper is to familiarize and inform possible mining users of AC variable frequency drive attributes.

Jan 1, 1998

By Andrew J. Regis

The methods of evaluation of industrial minerals occurring on Federal lands have different meanings if the evaluations are done by a company rather than a government agency. For example, when the Bureau of Land Management (BLM) conducts an examination of mining claims, this is commonly referred to as a "validity examination," whereas it is an "economic evaluation" when performed by a company. Not only is there a difference in nomenclature in these evaluations, but there is a general lack of expertise in the Federal government on industrial minerals in general. A metallic mentality still prevails in the U.S. Forest Service (USFS) and the BLM. Because of this, many validity exams on industrial-mineral deposits commonly just skim the surface concerning economics and marketability. The BLM and USFS place a high amount of emphasis on past administrative case law pertaining to the validity of industrial minerals under the 1872 Mining Law and, rightly so, on marketability, which also is heavily addressed in case law. When the BLM considers marketability, only the marketability of a particular industrial mineral for only the primary use for which it was located is considered and any value-added markets cannot be included. The BLM defines marketability based only on the value of the mineral material in its in situ or raw state, rather than value-added through processing. Another difference in the evaluation of industrial minerals by government and industry is the question of by-products. When a company evaluates a mineral material it looks at all the markets. The BLM looks only at that market for that locatable mineral for which the claim was located. In other words, sales from non-locatable by-products cannot be used to support marketability or the prudent-man rule (i.e., oversize silica sand from a glass-sand claim being sold for construction sand, road base, fill, etc.). The question of reserves also can present conflicts. An industrial-mineral company will often try to identify all the reserves available for a possible future development. They must do this for financial backing and support from upper management. The BLM, however, will limit their validity examination only to those reserves that meet the prudent-man rule and marketability tests. The BLM will validate reserves sufficient to last 25-30 years, based on available market. The development of industrial minerals on Federal lands is a difficult process, and, if the 1872 Mining Law is changed, it could become not only more challenging but also more costly. The industry must become more tolerant of the mineral specialists in the BLM and the USFS. On the other hand, the government mineral examiners must become more aware of the importance of industrial minerals in everyday living, and the economic evaluation of these materials.

Jan 1, 1999

By Richard L. Wedertz

Although the physical appearance of excavating equipment doesn't seem to have radically changed over the past decade, important changes within the products and an innovative attitude on the part of the engineer in his design approach is becoming increasingly evident. The new philosophy is to go beyond simple refinements of existing designs that simply produce a machine which further reduces overall cost per ton or per cubic yard of material moved and to do it more efficiently than ever before. Standard ideas and preconceived notions have been discarded and have given way to providing a design and a machine that is best suited to get the job done. Understanding that the application will not always fit the machine, but, in most cases, the machine should fit or suit the application is a foremost consideration in the engineers' design criteria.

Jan 1, 1973

By B. K. Cantrell, D. H. Carlson, W. F. Watts, K. L. Rubow

The use of diesel equipment in underground coal mines is controversial because the National Institute for Occupational Safety and Health (NIOSH) regards "whole diesel exhaust" as "a potential occupational carcinogen." Threshold limit values (TLVs) are recommended for the gaseous pollutants CO, CO2, NO, N02, SO2 and some hydrocarbons emitted in diesel exhaust. There is, however, no TLV recommended for diesel exhaust aerosols (DEA) nor is there a standard method for sampling these aerosols. The University of Minnesota and the USBM have collaborated to develop a personal diesel exhaust aerosol sampler (PDEAS) that utilizes size selective, inertial impaction and gravimetric analysis. During the field tests of this sampler, numerous air quality measurements were conducted in underground coal mines that used diesel equipment. The objective of this report is to present these data and to assess the impact of diesel face haulage equipment on mine air quality. Air quality data were collected in four underground coal mines. The mines used continuous miners and diesel haulage equipment. Daily samples were collected at the section intake, haulageway and on haulage vehicles. Both full-and partial-shift samples were collected using a variety of aerosol instruments. These included the PDEAS and the micro-orifice uniform deposit impactor (MOUDI) that sample the mine aerosol diesel exhaust fraction. Two of the mines were also monitored for the major gaseous constituents found in diesel exhaust CO, CO2, NO, NO2 and SO2. These measurements were made by either collecting bag samples for subsequent gas analysis or by Palmes dosimeters. Concentrations of CO, C02, NO, NO2 and SO2 were well below regulated levels. The mine average DEA concentration determined by the PDEAS in the haulageway for the three mines surveyed was 0.79 mg/m3, with a standard deviation of 0.19 mg/m3. DEA contributed 65% of the respirable aerosol, at this location. These results were the same as the mean DEA concentrations calculated from size distribution measurements obtained using the MOUDI. This was 0.78 mg/m3, with a standard deviation of 0.22 mg/m3.

Jan 1, 1992

By C. R. Peterson

A cutter vibration monitoring system is described which would map seam strata non-uniformities to permit guidance within the seam. An extremely simple and rugged transducer is used which is compatible with conventional cutters and cutter replacement practices, and believed to be suited to the mining environment. Laboratory tests show that the system can detect bedding planes in otherwise homogeneous material. A data display system which would employ the human operator's natural pattern recognition skill and judgement will be developed, Intended for remote control applications in general, the system is of direct interest for today's continuous excavators in coal or in any other machine excavated bedded deposit.

Jan 1, 1985

By E. J. Beckman, R. M. Enick, C. Powell

Liquid carbon dioxide can be used as a replacement for organic solvents in the extraction of anionic platinum group metal complexes from an aqueous phase. However, because conventional extractant-metal complexes are not soluble in liquid carbon dioxide, this can be achieved only if highly carbon dioxide-soluble extractants are developed. For example, trioctylamine-gold chloride is not soluble in liquid carbon dioxide, although trioctylamine is CO2 soluble. The novel CO2-soluble extractants presented in this paper have a CO2-philic fluorinated tail to enhance solubility and a conventional amine head group for extraction of metals. Both the extractant and the extractant-metal complex are soluble at ambient temperature at pressures from 7 to 35 MPa. Efficiency factors as high as 2.23 have been measured using 1,1,2-trichlorotrifluoroethane (TCTFE), a low pressure screening liquid for carbon dioxide, indicating that these compounds will strongly bind the metal chloride. For example, 84% of Pt-chloride was extracted into TCTFE using a 3.5:1 ratio of a double¬tailed fluoroalkyl amine extractant: metal chloride. An 88% recovery of Pt-chloride into high-pressure liquid carbon dioxide was achieved using the same extractant at a 3.5:1 ratio. Therefore, it appears possible to replace organic solvents with liquid carbon dioxide during the extraction of platinum chlorides if highly carbon dioxide-soluble extractants agents are employed.

Jan 1, 2002