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By K. N. Han, H. C. Cho, R. Kim

"A comprehensive analysis of the effect of OH- on various cations in hydrometallurgical systems has been investigated. Cations chosen for this analysis included groups 1A and 2A, rare-earth elements and other common transition metal ions such as Cu2+, Fe2+, Fe3+, Mn2+, Ni2+, Co2+, Ag+, Cd2+, U4+, UO2 2+, Hg2+, Al3+ and Zn2+. The Newton-Raphson technique was used to calculate and plot various metal species over a wide range of pH. This study has clearly shown that by adjusting the concentration of OH-, the separation of Fe from Mn, U from V, Ce and Eu from other rare-earth elements, and In from Sn is possible. The effects of hydrated metal ions on the separation and removal of various metals from each other under various conditions is discussed.IntroductionThe primary purpose of hydrometallurgical processing is to extract, remove and purify various metals from diverse sources. Hydrometallurgists are frequently preoccupied by the extraction of cations in metallic form, but overlook the important role anions play in such processes. A proper choice of anions can determine the fate of successful extraction, removal and purification of metals (Esmaeili et al., 2005; Brbooti et al., 2011; Wei et al., 2005; Jeppesen et al., 2005; Al-Tarazi et al., 2004), and also separation (Farha et al., 2011; Sevenich and Fritz, 1983; Rashid, 1974) of cations from various solutions.In this study, the authors have examined some of the effects that anions play in various solutions. The anion considered in this study was the first hydroxide, OH-. Other anions, such as Cl-, Br-, I-, and CN-, will be dealt with in the second part of the series of two papers."

Jan 1, 2015

By G. D. MacDonald

The Grasberg porphyry copper-gold deposit of P.T. Freeport Indonesia, Co. is located in the Jayawijaya Mountains of Irian Jaya, Indonesia approximately six km west northwest of Puncak Jaya, the highest point on the island of New Guinea. Disseminated mineralization is confined to the Grasberg intrusive complex, a multiphase intrusion of dioritic to monzonitic composition which intruded tightly folded carbonate rocks of the Tertiary Faumai and Ainod formations. The high tonnage and grade of the deposit (1 X 109 tonnes at 1.4 % copper and 1. 8 ppm gold) appear to result from a succession of coincident intrusive and mineralizing events about three million years ago. This paper will focus on the history and character of these events.

Jan 1, 1993

By Brian H. Kaye

Efficient design of grinding circuits for efficient production of ultrafine material requires rapid feedback of information concerning the fineness of material leaving the grinding device. Generating this information requires efficient sampling and adequate rapid characterization of the material leaving the grinding machinery. Recent developments-in electrooptic inspection of dry end wet material leaving a grinding device are critically reviewed. New methods for characterizing ultrafines are discussed. A rapid operating automated cybernetic (intelligent) permeability device for automatic control of grinding circuits using Blaine index and other fineness indices is described.

Jan 1, 1983

By Douglas G. Brookins

Clay mineralogic studies of ore versus barren rocks in the Grants mineral belt show that some combination of chlorite (rosette form), illite, mixed layer illite-montmorillonite, (- Mg-montmorillonite) are penecontemporaneous with uranium minerals in trend ore; these same clay minerals plus kaolinite are related to the roll type ore near the main redox front of the Grants mineral belt. Clay minerals from barren rocks are characterized by a greater abundance of Na-montmorillonite, kaolinite, and face-to-edge form chlorite. Chlorites from ore zones contain much more vanadium than do chlorites from barren rocks. Trend ore probably formed from southeasterly flowing waters following paleochannels in the Late Jurassic. These deposits are found almost entirely in reduced rocks, and organic carbon may have been an important reductant to remove U-V-Se-Mo from solution as carbonate from ore zones contains some organic carbon based on stable iso¬tope studies. Uplift, remobilization and reprecipitation of some of the trend ore resulted in the formation of redistributed ore, some of which possesses a roll type geometry. Mineralization for the roll type ore was apparently controlled by sulfide-sulfate equilibria at or near the main redox front in the Grants mineral belt. Trend and roll type ore possess different assemblages of clay minerals and different trace element abundances. Laramide faults cut both trend and some roll type ore. Stack ore is found in Laramide fault zones. Limited oxygen isotopic data from clay minerals in two mines at Ambrosia Lake in reduced rocks indicate probable preservation of ancient, formational waters and no evidence for infiltration by young meteoric waters. This information, plus the pre-Laramide faults, suggest, but do not unequivocally prove, that the main redox front has been relatively stable since its formation, probably some time in the Cretaceous. Younger encroachment of the redox front in post-Laramide is proposed by others, however, and the problem is unresolved. Uranium for the deposits was most likely carried in solution as an oxyion, probably as (UO2(CO3)2.2H2O)2- or (UO2(HPO4)2)2-, although organic transport cannot be entirely ruled out. Oxyions of vanadium, selenium, molybdenum and possibly arsenic and antimony, are interpreted from Eh-pH diagrams to have been segregated and transported with U6+ soluble species and precipitated when a chemically reducing environment was reached. The rare earth elements are also enriched in ore zones, but it is not clear if they were transported with the U-V-Se-Mo-(As)-(Sb) suite or derived from a more local source.

Jan 1, 1980

By Neil H. Bostick

This research, sponsored at Stanford Research Institute by the Grand Junction Operations Office of the U.S, Atomic Energy Commission, was an outgrowth of the concern that presently-known ore reserves may be inadequate to meet the projected demands of nuclear power reactors. The original program at SRI was to design a comprehensive geological information system and use it to store and analyze the very great quantity of data needed to estimate uranium ore reserves. Study of the problem showed that it could be solved only by use of modern electronic data processing techniques, so such a comprehensive system was designed and tested. The system test was satisfactory, but input lead time and total expense were shown to be too great for the system to be practicable for the AEC under present circumstances. Thus, based on results of the earlier research, a specialized and simplified procedure for predicting approximate uranium ore reserves was devised. The prediction is based on general geology of specific area cells of the earth, in order to provide complete volume coverage; the strata in these ores are evaluated for uranium ore favorability on the basis of a few selected criteria in order to allow rapid data input. Since the bulk of U.S. reserves are in clastic host rocks only such strata are considered in this work. This paper describes the structure and some details of the resource system and how it was tested in rn area of the western United States.

Jan 1, 1969

By Cesar Carrasco, Heath Arvidson, Mark Forster

Block models built to represent the geology and rock characteristics of mineral deposits represent huge complex data sets, which form the basis of strategic and business planning, and public reporting of Mineral Resources and Mineral Reserves. Recent advances in cloud computing and database technology developed for the Internet of Things offer a different way of working with these critical data sets. Enabling a cloud based, open data structure with high performance data analytics capability presents a compelling improvement in governance and a democratization of ore body knowledge that can lead to automation use cases that support the digitalization of mining.

Jun 25, 2023

By Murat Erdemoğlu, Turan Uysal, Thierno Saidou Barry, Mustafa Birinci

The rapid development of the global alumina and aluminum industry is straight coupled with the demands and the needs of these materials. Nowadays, the only well-known accessible resources to produce alumina and aluminum are bauxite ores. But bauxite ores are limited, and the remaining exploitable reserves do not have high contents in alumina. In countries where there is little or no bauxite reserves or where the recovery of existing bauxite ores to produce alumina with the Bayer process are not economic, alternative resources for alumina have been explored. The most attractive resources for replacing bauxites are aluminosilicate clay minerals and coal fly ash. The important processes developed for the recovery of alumina from these sources are acid leaching and alkaline leaching processes. The acid leaching is known as the most efficient in which thermal and mechanical activation are included for improving the performance of the process. The objective of this review is to give a comprehensive insight on the production of the alumina from thermally or mechanically activated clays and coal fly ash by hydrochloric, sulfuric, and nitric acid leaching processes.

By Katarína Gáborová, Marcela Achimovičová, María Florencia Márquez‑Zavalía, Jaroslav Briančin, Oľga Šestinová, Pavel Škácha

In this paper, the structure, morphology, chemical composition and leaching of naumannite ( Ag2Se) were studied. Mechanical activation of Ag2Se in a planetary ball mill resulted in increasing its specific surface area. The influence of milling time on the particle size was studied by particle size distribution analysis and scanning electron microscopy. The leaching kinetics of non-activated and mechanically activated samples in 3.5–7.9 mol/L HNO3 solutions were examined. Subsequently, the effect of leaching temperature in the range of 25–50°C on the recovery of silver from mechanically activated naumannite was documented. The maximum yield of silver 94% was achieved after 120 min of leaching in 7.9 mol/L HNO3 at 50°C for the sample mechanically activated for 30 min. Based on calculated activation energy values from the Arrhenius equation, a mixed leaching mechanism consisting of diffusion and surface chemical reaction as the rate-controlling steps of the solidliquid reaction was assessed.

Mar 4, 2023

By John T. Atkins

Utah International's Shirley Basin Mine is located in the Southeastern High Plains of Wyoming at an elevation of about 7,100 feet. The Shirley Basin area is a gently rolling semi-arid land. The uranium ore zone occurs at depths ranging from 270 to 350 feet below the surface. Overburden consists of poorly consolidated sandstones, siltstones, and clays. Underground mining was begun in 1960. Conditions were made difficult by high rates of water inflow and ground support problems. The development of a solution mining I or in-situ leaching technique allowed underground operation to be abandoned in 1964. Solution mining provided limited production from 1963 to July 1970. In January, 1969, large scale development of open-pit mining was begun. A 1,200 ton per day mill went "on stream" in March, 1971.

Jan 1, 1973

By Harry Leslie Bullock

With silica making up more than 27% of the earth's crust, its oxides amounting to more than 59% of the igneous rocks and quartz the most prevalent of the main free oxides, it follows that the mining engineer' is in constant contact with quartz, mainly as a gangue material to be removed as completely and economically as possible and sometimes as a valuable mineral to be purified' for the chemical,, ceramic or glass industries. Water scarcity under desert or semi-arid conditions, dwindling water supplies and difficulties of wet waste disposal in many locations and trouble from freezing in arctic locations make dry benefication more and more desirable. Advances made during the last few years in apparatus and methods and a steadily increasing knowledge of solid state physics are widening the field open to the economical application of electrostatic separation.

Jan 1, 1967

By Gordon Kidd

Inflation and burgeoning costs are two among many factors which have generated a new surge of interest in "fringe benefits" (sometimes referred to as "supplementary remuneration" or "supplementary compensation"). Other specialized forms of compensation ("perks", in the vernacular) such as company cars, windowed offices, etc., which also are the subjects of current study, are outside the scope of this paper. For businesses, interest in fringe benefits is based on concern for employees? welfare, compliance with government requirements, and an increasingly burdensome impact on bottom lines. In 1980, according to Fred D. Lindsey in the October 1980 issue of Nation's Business, employee benefits will cost American employers an estimated $420 billion. To paraphrase Winston Churchill, "some fringes!" Indeed, few if any administrators consider employee benefits as fringes. Employee benefits impact other major areas of a company's operations as well. As listed by Beadle (1980), these areas include employee relations, collective bargaining, short-term costs, long-range funding, manpower planning, compliance with legislation, taxation for the company and for the employee, corporate image in the community, competitiveness for staff, communications, administration, claims cost containment, etc., etc.

Jan 1, 1980

By William W. Edgerton, Moussa Wone, David H. Corkum, Carlton M. Ray

"The DC Clean Rivers (DCCR) Project is a 25 year, $2.6 Billion court ordered project to reduce combined sewer overflows (CSOs) discharging into the Potomac and Anacostia Rivers and Rock Creek, and also reduce flooding in the northern areas of the District of Columbia. Like all massive infrastructure programs, DCCR faced technical challenges, management challenges, risks of cost and schedule overruns, procurement challenges, and financing challenges. While DC Water is no stranger to large capital improvement projects (CIP), this CSO Program represents a once in a lifetime event for the Owner requiring the assembly of a single purpose team to implement. Some of the DCCR Project team’s most successful accomplishments to date are attributable to its introduction of early contractor involvement (ECI) to thoroughly vet the work from the perspective of the future constructors, development of functional baselines to share risks that are difficult to price and reduce reliance on geotechnical baseline interpretation during tunnel excavation, and attainment of financing through Municipal Century Green Bonds based on using design criteria of a minimum of 100 year life for the structures to establish intergenerational equity and fairness. This paper will discuss these innovations in detail and provide some sets of recommendations for the underground industry on when and how to use different approaches to better manage projects of this magnitude. INTRODUCTION The District of Columbia Water and Sewer Authority (DC Water) is an independent multi-jurisdictional authority that was established in 1996. Its primary mission is to provide water distribution services to more than 640,000 residents in the District of Columbia (District), and sewer treatment and disposal to 1.6 million residents of the District, Montgomery and Prince George’s counties in Maryland and Fairfax and Loudoun counties in Virginia."

Jan 1, 2016

By D. K. DeForest

The olfactory system (sense of smell) is crucial to the ability of fish to avoid predators, recognize kin, and synchronize reproduction (Baldwin et al. 2003). Copper (Cu) has been shown to impair olfaction in juvenile freshwater life stages of salmonids (including Pacific salmon and trout) in some laboratory experiments; and in the United States, public concerns have been expressed that current regulatory criteria for Cu in fresh water are not adequately protective of olfactory function in salmonids (e.g., OSU 2007; Pearson 2007). These concerns have largely been raised because some Cu concentrations that have caused olfactory impairment in salmonids in the laboratory are less than Cu concentrations that have been shown to reduce salmonid survival, growth, or reproduction (the effects endpoints that are typically considered in deriving ambient water quality criteria). However, two important and interrelated points that must be considered: (1) freshwater Cu criteria are "driven" by the sensitivities of several invertebrate species that are more sensitive than the olfactory impairment threshold in salmonids when (2) the influence of water chemistry on Cu bioavailability is properly considered in deriving Cu criteria. Bioavailability refers to the ability of various chemical forms of Cu to interact with receptors on the surface(s) of organisms and thus directly cause toxicity or uptake by the organisms. The toxicity of Cu and other metals to aquatic organisms is a function of water chemistry. For example, acute Cu toxicity in fresh water generally decreases as pH, water hardness (Ca2+ and Mg2+), alkalinity, and dissolved organic carbon (DOC) concentrations increase (Meyer et al. 2007). The U.S. Environmental Protection Agency (USEPA) has recommended hardness-based freshwater aquatic life criteria for Cu and other metals since the 1980s (e.g., USEPA 1985); and hardness-based metals criteria decrease (i.e., become more restrictive) as water hardness decreases. More recently, the USEPA has recommended freshwater aquatic life criteria for Cu based on the biotic ligand model (BLM; USEPA 2007), which accounts for the influence of multiple water chemistry parameters, including DOC, pH, alkalinity, Ca2+, Mg2+, and several other cations and anions. The BLM-based Cu criteria generally decrease as DOC concentration, pH, alkalinity, and water hardness decrease. Because DOC has a stronger influence on Cu bioavailability than water hardness, hardness-based and BLM-based Cu criteria can differ considerably. For example, in water that has low DOC and high hardness, the hardness-based Cu criterion would be relatively high (because it is driven by the high hardness) but the BLM-based Cu criterion would be relatively low (because it is driven by the low DOC). Thus, any evaluation of the protectiveness of Cu criteria against a given effect, such as olfactory impairment, must properly account for the chemistry of the exposure water. Meyer et al. (2013) compiled data on Cu-induced olfactory impairment and olfactory-induced behavioral effects from tests in which BLM parameters were measured. They demonstrated that the USEPA's BLM-based freshwater life criteria for Cu are protective against olfactory impairment, because it adequately accounts for water chemistry (whereas the USEPA's hardness-based Cu criteria are not consistently protective). Olfactory impairment by Cu is now receiving increased attention in Canada and Europe (e.g., Wall 2013; Stang 2013). Accordingly, in this paper we have expanded the analysis of Meyer et al. (2013) to consider copper guidelines from various other countries and whether these guidelines are protective against olfactory impairment.

Feb 23, 2014

By Robin Burgess-Limerick

The introduction of automation to mining has great potential to reduce safety and health risks by removing people from hazardous situations. However, automation changes the tasks performed by people and may introduce new tasks. For the system to function optimally, these tasks must be designed taking human abilities and limitations into account. Humansystems integration refers to systems engineering processes that ensure that human-related issues are adequately considered during system planning, design, development, and evaluation. During procurement of automated systems, a human-systems integration program plan should be prepared that describes the human-systems integration activities that will be performed to address each of the six core domains of human-systems integration: staffing, personnel, training, human factors engineering, safety, and health.

Jun 16, 2020

By Gordon C. ‘Bud’ Presley

The pumice and pumicite review arrived too late for the June issue. Estimated domestic production of pumice and pumicite in 1992 was up compared with 1991, according to US Bureau of Mines statistics. The Bureau estimate of domestic production of 400 kt (440,000 st) for 1991 turned out to be 401 kt (442,000 st) of actual production, the lowest since 1989. In 1992, the estimated the value of pumice and pumicite sold or used in the United States was $11.6 million, up only $200,000 from the 1991 value. There was an increase in the mine, or mill, average price from the five-year low of $11.44/t ($10.37/st) in 1986 to $26.42/t ($23.96/st) in 1992. Estimated tonnage produced in 1992 was 439 kt (484,000 st). Apparent domestic consumption was 642 kt (707,000 st), up 135 kt (149,000 st) from 1991. Imports for consumption were estimated to be 215 kt (237,000 st) last year. Domestic production supplied 68% of the demand in 1992, with net imports supplying the remaining 32%. This compares with domestic production sup¬plying 53% and net imports supplying 47% of the apparent consumption in 1988. Exports were about 900 t/a (1000 stpy) for the period 1984 to 1988. In 1989, exports rose sevenfold to 7 kt (7700 st) and to 20 kt (22,000 st) in 1990. The Bureau of Mines reported that the amount of pumice and pumicite exported in 1992 was 12 kt (13,200 st). It is assumed that these exports were from the Pacific Coast because imports, mainly from Greece, continued to be a market factor on the East Coast and the Gulf Coast States in the United States.

Jan 1, 1993

By Paul Kents

The Canadian Javelin Limited Cerro Colorado copper-porphyry deposit in Panama, possibly the largest known copper-porphyry, contains between 1350 and 450 meter elevations, drill proven and probable ore in excess of 3.0 billion tons averaging 0.65% of copper equivalent. The deposit is located in the Central Cordillera Range, straddling the Continental Divide at 1500 meter elevation. Local topography is very steep. Accessibility is difficult, all logistics made by helicopter, and only recently a 52 km. road from the Pan-American highway was completed into the area. The deposit was discovered in 1969, and since then 75 shallow exploratory holes and 98 deep holes, the deepest 1340 meters, totalling 45,000 meters have been drilled. Deep holes were drilled at the corners of a regular rectangular 150 meter grid.

Jan 1, 1975

By R. Bryce, T. J. Doughty, K. Stoll

Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Ca6Al2(SO4)3(OH)12•26H2O Ettringite readily precipitates in high pH water and by doing so, removes sulfate from impacted waters. The SAVMIN process, piloted in South Africa, is one method to produce ettringite. In this process, aluminum hydroxide is the aluminum source. The Cost Effective Sulfate Removal (CESR) process is similar to SAVMIN, but uses a proprietary aluminum source instead of aluminum hydroxide. Outotec and Veolia also have their own versions of the process using their specialized process equipment. TWC patented a version of ettringite precipitation using metallic aluminum as the aluminum source for ettringite formation. The benefit of using aluminum metal is that no additional ions are added to the process. At high pH, the raw aluminum corrodes in water causing hydrogen gas generation as the water is chemically reduced. This reaction is shown below:

Jan 1, 2019

By S. C. Sun

A process was developed to recover coal, clays and pyrite from coal wastes. The process consists of fine grinding followed by coal flotation and pyrite flotation leaving the clays in the flotation pulp. A bituminous coal refuse, containing l0% S-30% C*, was treated by this method to yield a coal product containing 4% sulfur, 10% ash; a pyrite product containing 45% sulfur (84% FeS2), 1% carbonaceous material and a clay product containing 2% sulfur (3.5% FeS2). The coal yield was about 89%. The pyrite yield was about 77%. The process steps may be entirely flotation, or gravity separation (hydrocyclone) may be used to increase the pyrite: coal ratio in the flotation feed. Cost estimation shows a profit of $2.28 per ton of low pyrite grade refuse (Labor, maintenance, overhead and plant depreciation were not included). The development of this process consisted of three parts: 1) exploratory tests, 2) optimization tests and 3) confirmatory tests.

Jan 1, 1968

By R. E. Thill

An ultrasonic, pulse-immersion apparatus and method are described for determining the effects of moisture on the dynamic elastic properties of rock. The method provides an alternative approach for assessing the moisture sensitivity of rocks. Ultrasonic wave velocities are continuously monitored in immersed rock samples as a function of water absorption and time up to saturation. Moisture effects on compressional wave velocity vary as a function of the type of rock and the time and amount of water absorption. Regression analyses are used to curve-fit plots of the data and to derive empirical expressions for compressional wave velocity as a function of water content for different categories of rock. Results indicate that compressional wave velocity can be used to predict both the moisture content and its effect on strength and deformational properties of rock. These results have potential for detecting or monitoring bad roof conditions in situations where the mine rock exhibits strength degradation with moisture absorption.

Jan 1, 1986

By H. X. Li, A. Correa, M. M. Zhang, W. Xuan, M. Andrade

"With increasing demand for steel and depletion of high-grade iron ore deposits, more research efforts are being directed toward extending the life of existing ore reserves and developing technology to treat low-grade iron ore resources. Among all the reported technologies, biotechnologies in mineral processing – specifically bioleaching and microbially induced flotation – have emerged to be considered as low-cost, environmentally friendly potential alternatives to many of the current mineral processing techniques. This paper provides a comprehensive review of current research on the use of microorganisms for iron ore beneficiation and, further, discusses the applicability of bioleaching, bioflotation and bioflocculation for the beneficiation of low-grade iron ores.IntroductionIncreasing global demand for raw materials has led to diminishing resources of high-grade iron ore. As a result, the mining and utilization of low-grade hematite, limonite, specularite, siderite and goethite ores have attracted more and more attention. However, these types of iron ores are of complex paragenesis and fine disseminated grain size, and often contaminated by phosphorus in the form of solid solution. The distribution of phosphorus throughout the iron mineral crystals prevents the effective use of physical separation techniques, and these complex ores are at present largely untapped due to a lack of cost-effective and efficient processing methods. Chemical leaching and roasting-magnetic separation approaches have been mainly tested only on the laboratory scale and are all either cost prohibitive or ineffective when used on low-grade complex iron ores."

Jan 1, 2015