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By Robert B. Fulton, Gill Montgomery

Fluorspar is the commercial name for fluorite, a mineral that is calcium fluoride, CaF2. The name, derived from the Latin word fluere (to flow), refers to its low melting point and its early use in metallurgy as a flux. It is the principal industrial source of the element fluorine. Two other minerals, cryolite and fluorapatite, have significant fluorine content. Cryolite, sodium aluminum fluoride, Na3AlF,, is a rare mineral that has been found in commercial quantities only in Greenland. The natural material has been supplanted by synthetic cryolite for its principal industrial use in the manufacture of aluminum. Fluorapatite, Ca5F(PO3)2, is a source of phosphate for fertilizer manufacture, containing a small percentage of fluorine. Commercially mined deposits of apatite have varying amounts of fluorine, chlorine, hydroxyl, and carbonate. HISTORY Fluorspar was used by the early Greeks and Romans for ornamental purposes as vases, drinking cups, and table tops. Various peoples, including the Chinese and the American Indians, carved ornaments and figurines from large crystals. Its usefulness as a flux was known to Agricola in 16th century Europe. Fluorspar mining began in England about 1775 and at various places in the United States between 1820 and 1840. Production grew substantially following the development of basic open hearth steelmaking, wherein it is used as a flux. Use was stimulated by growth of the steel, aluminum, chemical, and ceramic industries, particularly during World Wars I and 11. Fluorocarbons entered the picture in 1931. The use of anhydrous hydrogen fluoride (HF) as a catalyst in the manufacture of alkylate for high octane fuel began in 1942. Differential flotation for separating fluorspar from galena, sphalerite, and common gangue minerals in the 1930s and the application of heavy media concentrating methods to the treatment of low grade ores in the 1940s were outstanding technological advances that facilitated increased production. Pelletizing and briquetting of flotation concentrates for use in steel furnaces and the development of flotation schemes for beneficiating ores containing abundant dolomite and barite have been major improvements in the industry. USES OF FLUORITE Fluorspar is used to make hydrogen fluoride (HF), also called hydrofluoric acid, an intermediate for fluorocarbons, aluminum fluoride, and synthetic cryolite. It is used as a flux in the steel and ceramic industries, in iron foundry and ferroalloy practice, and has many minor specialized uses. Hydrogen fluoride is produced by reacting acid grade (97% CaF,) fluorspar with sulfuric acid in a heated kiln or retort to produce HF gas and calcium sulfate. After purification by scrubbing, condensing, and distillation; the HF is marketed as anhydrous HF, a colorless fuming liquid, or it may be absorbed in water to form the aqueous acid, usually 70% HF. Synthetic cryolite, organic and inorganic fluoride chemicals, and elemental fluorine are made from hydrofluoric acid. The acid itself is important in catalysis in the manufacture of alkylate, an ingredient in high-octane fuel for aircraft and automobiles; in steel pickling, enamel stripping, and glass etching and polishing; and in various electroplating operations. The manufacture of one ton of virgin aluminum requires about 12 to 29 kg of fluorine content in synthetic cryolite and aluminum fluoride. This quantity, through improved technology and recovery practices, is being lowered significantly in countries with the most advanced technology (i.e., Australia and Sweden), while others (i.e., Surinam and South Africa), remain at the high end. Elemental fluorine is prepared from anhydrous hydrofluoric acid by electrolysis. Gaseous at room temperature and pressure, fluorine is compressed to a liquid for shipment in cylinders or in tank trucks. Elemental fluorine is used to make uranium hexafluoride, sulfur hexafluoride, and halogen fluorides. Gaseous uranium hexafluoride is used in separating U235 from U233 by the diffusion process. Sulfur hexafluoride is a stable high dielectric gas used in coaxial cables, transformers, and radar wave guides. Halogen fluorides have important applications, mostly as substitutes for elemental fluorine, which is more difficult to handle. Emulsified perfluorochemicals, organic compounds in which all hydrogen atoms have been replaced by fluorine, are undergoing investigation as promising blood substitutes. They transport oxygen and, in conjunction with a simulated blood serum, perform many functions of whole blood. With further development, these organic compounds may ultimately, in emergencies, be useful in saving lives of animals and humans during periods of acute shortages of natural blood. Inorganic fluorides are used as insecticides, preservatives, antiseptics, ceramic additives, and fluxes and in electroplating solutions, antioxidants, and many other products. Boron trifluoride is an important catalyst. Organic fluorides are volume leaders in the fluorine chemical industry. Fluorinated chlorocarbons and fluorocarbons are prepared by the interaction of anhydrous HF with chloroform, perchlorethylene and carbon tetrachloride, and are characterized by low toxicity and notable chemical stability. They perform outstandingly as refrigerants, aerosol propellants, solvents, and cleaning agents and as intermediates for polymers such as fluorocarbon resins and elastomers. Fluorocarbon resins are inert compounds that have unusually low coefficients of friction and have found a number of applications as lubricants for parts that cannot be oiled, e.g., bearings for window raising equipment located inside of automobile doors, in small electronic equipment, for the manufacture of chem-

Jan 1, 1994

By G. Van Weert

Oxygen transfer from dispersed air in agitated slurries represents an important unit operation in the minerals processing industry. Gold leaching, iron precipitation and especially bio-oxidation come readily to mind. However, little engineering information is available on the variations between impeller types on such O2 transfer. Engineering literature on the subject, i.e. information which relates slurry density and energy input to O2 transfer, is reviewed and compared to current experimental work. The latter was carried out with minus 50 micron sand/water slurries in a 64 I laboratory tank of standard proportions, equipped with a variable speed drive with torque meter. A standard Rushton turbine and a specifically sized A315 were compared. Results confirm an increasing impairment of O2 transfer with increasing slurry density for both impellers. The volumetric mass transfer coefficient, k,a, in a 10 vol. % slurry shows a decrease of 30% compared to the k,a in water. At 20 vol. % sand this decrease is near 50 %, depending somewhat on superficial gas velocities. Power efficiency, i.e. the kg O2/kWh, decreases about 25 % more rapidly for the Rushton turbine than for the A315 with the addition of sand. However, for equivalent O2 transfer the Rushton turbine was more efficient in this work. Experimental results are presented and their significance for slurry bio-oxidation discussed.

Jan 1, 1996

By K. W. Harris, K. A. Perry

Underground coal mines beneath Black Mountain in the Harlan County district of the Central Appalachian coalfields have an extensive history of bump events, which yields an elevated probability for significant injury or fatality to underground miners. According to Mark (2009), Harlan County has had the greatest concentration of deep-cover retreat mining in the United States. Combined with the extensive multiple seam mining history, room-and-pillar coal bumps have had a disproportionate impact on coal operations in this region. The Harlan seam, one of the principal, economically recoverable coalbeds exploited beneath Black Mountain, has a significant burst history that extends into modern times. A numerical investigation using the LaModel software of 17 bumps that occurred at the same mine in the Harlan seam was conducted and used to create a calibration methodology which serves as the quantitative basis for current and future numerical efforts in an adjacent mine exploiting the same reserve. In addition to this numerical study, a qualitative assessment of the geologic factors that are believed to contribute to the bump potential was completed. Combined with stability prediction using the numerical basis, these geologic factors will be used for recognition of high bump potential areas with the goal of reducing the potential for future bumps, helping to ensure the highest level of safety and productivity for underground personnel.

Jan 1, 2016

By J. Killian, S. Cox

Many questions exist within the geotechnical industry as to the applicability of Strength Reduction Factor (SRF) values to the design acceptance criteria (DAC) of mining operations. There are many factors that contribute to changes in the SRF estimate, some of which are numerical (e.g. dilation angle) and some of which are geometric (e.g. model grid size)[1]. Numerous studies have confirmed equivalent values of SRF and FOS are found for soil slopes of limited height as presented in, [2] and [3]. However, significant deviation of the SRF value was observed for highly cohesive materials (rock slopes) of heights typically encountered in mining, [4]. This paper builds on the work presented in [4], providing a more rigorous examination of the modeling parameters that control the SRF estimate. The failure mechanism assumed for this study was a simple circular shear surface in a uniform material. Both LEM and numerical methods are suited well for analysis of this failure mechanism. A parametric study was completed to evaluate and test the relationships of key numerical variables that affect the estimated value of the SRF using Itasca’s Fast Lagrangian Analysis of Continua (FLACTM) software. The effect of groundwater has been tested and may be significant but is not presented as part of this body of work for brevity and simplicity of presentation.

Mar 2, 2022

By Eric Jones, Leslie C. Thompson

Biological processes for cyanide detoxification in mine waste are receiving attention as an alternative to conventional chemical treatment options. Some of the advantages of biological treatment include: Low comparative treatment cost * Shorter treatment time * In Situ Treatment * Complete Detoxification - Ends long-term liability - Eliminates in-perpetuity monitoring - Natural Re-Vegetation potential Natural and non-toxic nutrients, by-products and process end-products Hecla Mining chose a bio-neutralization process developed by Pintail Systems, Inc. for cyanide detox in spent are and process solutions from heap leach operations at the Yellow Pine Unit. The Yellow Pine operation is located 50 air miles east of McCall, Idaho, in the Stibnite Mining District. This district is a historic mining district dating back to the early 1900's. During World War II, this district produced a majority of the antimony and tungsten the United States using for the war effort. More recently, the Stibnite district has been known for its gold production. Hecla Mining Company is based in Coeur d'Alene, Idaho, and is a leading domestic producer of precious metals and a major supplier of specialty aggregate and industrial minerals. Pintail Systems, Inc. is a company specializing in the development of biological treatment processes for mine waste remediation. PSI has offices in three states and a laboratory, pilot plant and field office in Aurora, Colorado

Jan 1, 1993

By Harleigh V. S. Tingley

Investment in the mining industry has increased substantially throughout the world in recent years. So have acquisitions, divestitures, and financial restructurings. The return of outside investors to the industry is welcomed. The trend toward stockholder litigation is not so welcomed. Both have provided the impetus for commissioning outside professional due diligence studies of potential minerals transactions. For a number of reasons, some unique to the industry, evaluation of mining investments is a challenging task for the investor. Investments in exploration prospects and undeveloped properties have a high speculative content. Buyers pay for uncertain future prospects. Alternatively, most developed mining investments are large and long-lived and cannot easily be modified during that life. Even so, to be successful, they must compete in an environment in which their reserves - the source of their profits - are often imperfectly known. And markets, competition, technology, and politics are among the many continually changing factors that affect investment performance. Minerals investment evaluation is further complicated because each minerals investment has its own singular combination of risks and opportunities. Each ore type and each ore body presents different problems in reserve evaluation, mining, and extraction. Each minesite has its own often unique combination of mine, infrastructure, political, environmental, and other risks. And the key requirements for commercial success differ substantially among various minerals.

Jan 1, 1990

By W. Ter-Minassian

Besides the question of the stability of the roof and walls, one of the main problems encountered with tunnelling and shaft-sinking through the soft ground of alluvial origin forming the sub-grade of most large towns is settlement. Public transport and road tunnels in town centres are particularly affected, as they cannot generally be designed at any great depth for several reasons, such as the fact that ventilation shafts and access to the surface by means of stairs, escalators, lifts, ramps and so on must be fitted into the limited space available and are therefore costly, and because of the difficulties of driving below the water table. It is for this reason, coupled with the need for wide radius curves, that tunnels now so often pass close under buildings and monuments which must not be exposed to any risk of damage from subsidence during excavation. Grouting is the usual method used for consolidating soils, improving their strength and making them less compressible, but it is itself liable to cause heaving and cracks in the buildings above and has many other attendant dangers, including continually revised estimates which are the reason for the often inordinately high costs met with in urban tunnelling to-day. The mechanics of the problem have been studied and it has been found that a fraction of the total settlement is

Jan 1, 1997

By Gary S. Brierley, Tracy J. Lyman

INTRODUCTION Geotechnical engineers play a major role in tunnel design primarily because tunnels are constructed entirely within the ground. In general, this role can be divided into two major tasks: subsurface investigations and project design. Under subsurface investigations, it is necessary for the geotechnical engineer to accurately describe the ground in which the project will be built. Under project design, it is necessary for the geotechnical engineer to work together with other members of the design team to make certain that the tunnel fulfills its intended purpose at least cost. Given in the paper are the authors' opinions about what constitutes an adequate scope of services for these two tasks on a tunneling project. SUBSURFACE INVESTIGATIONS o Background Study All subsurface exploration programs for tunnels begin with a thorough investigation of background information about the proposed site. Such background information includes geologic, reports topographic maps, aerial photography, and case history reports of other nearby tunnels. Once completed, it is necessary to study the background information so that the proper scope and magnitude of subsurface exploration work is performed in a manner that provides maximum input to a knowledge of those intact and rock mass properties that are important for an understanding of the entire ground mass. The blind application of field and laboratory techniques, no matter how sophisticated, is wasteful and potentially

Jan 1, 1989

By N. Colvin, J. W. Gulyas

HISTORY The Surigao Nickel Refinery of Marinduque Mining and Industrial Corporation is located on Nonoc Island off the northwestern coast of Mindanao in the Philippines. Nonoc Island is part of the Surigao Mineral Reservation which had been identified as early as 1912. Initial interest in these deposits was due to their iron content, and their value as a nickel deposit was not seriously entertained until the late 1950's. The Philippine government undertook extensive test pitting and sampling programmes at that time and in the early sixties Marinduque became involved in helping to establish firmer ore reserves. Evaluations of the test pitting programme indicated reserves of 75,000,000 tonnes of ore averaging 1.22% Ni, 0.1% Co and 38.5% Fe. The Philippine government called for bids on the reservation in 1962 and Marinduque and Sherritt Gordon carried out some feasibility studies for the recovery of nickel from the deposit. However, it was not until 1968 that Marinduque was granted proper authority to exploit the Surigao deposits. Marinduque and Sherritt then entered into an agreement which allowed Marinduque to utilize a process developed by Sherritt for treating lateritic ores. During 1968, a 25 st/d pilot plant was erected in Fort Saskatchewan, Alberta for the purpose of modelling all process steps. A 10,000 tonne ore sample was sent from Nonoc as feed stock for the pilot plant.

Jan 1, 1979

By Jeffrey M. Listak, Gregory J. Chekan

The U.S. Bureau of Mines, in an effort to improve coal conservation and utilization is currently investigating longwall panel layouts to maximize coal recovery and minimize interactive problems in multiple-seam operations. When longwalling coalbeds in descending order, the transfer of stress from overlying gate roads is a major design constraint affecting pillar stability in the lower mine. The lower mine gate road pillars must be properly designed to withstand the additional load transfer if gate roads are superpositioned in successive seams. The Bureau's MULSIM/NL model was used to analyze load transfer mechanics for superpositioned gate road pillars. Analysis of Longwall Pillar Stability (ALPS), which is an empirically based design method for longwall gate road pillars, was used to calibrate model input parameters. The attributes of both the MULSIM/NL model and ALPS were combined to develop a modified method for estimating pillar stress for multiple-seam cases. The modified method uses a multiple-seam (MS) factor to estimate the stress on the lower mine gate road pillars when superpositioning is practiced. Numerical analysis shows that the MS factor is dependent upon the interburden thickness and pillar width and is presented in a series of graphs relating these two parameters. Several examples are included to illustrate the use of the MS factor for estimating lower mine pillar stress and resulting stability factors.

Jan 1, 1992

By Kostas Fytas

A computer package has been developed which is capable of evaluating alternative production schedules (long and short range) of an open pit mine once the ultimate pit limits have been defined. The model user can choose the best alternative according to cash flow considerations and the particular mining conditions. The package involves a combination of simulation for long range production scheduling and linear programming for short range scheduling. The simulation model based on an iterative technique, maximizes the profits within each long scheduling period (eg. year or sixth month period), and at the same time defers stripping as long as possible. A minimum exposed ore quantity is kept at the beginning of each mining period. The final long range schedule satisfies a set of constraints for each period, mainly ore quality and quantity constraints for ore and waste. An interactive smoothing procedure at the end of each period results in a schedule that is feasible in terms of mining practice. Finally a cash flow analysis model carries out cash flow calculations so that the user can select the best alternative. The linear programming model, based on a certain number of shovel regions, defined interactively by the model user, calculates the optimum production schedule for each short period under consideration, so that a set of constraints is satisfied.

Jan 1, 1986

By Stéphane Servant, Jacques Ouellet, Ferri Hassani

This paper presents essentially the logistic and practical aspects involved for in situ testing of mine paste backfill with a self-boring pressuremeter. The investigation discussed in this paper is part of an extensive and ongoing research project to identify and validate an in situ testing technique for cemented mine backfill such as hydraulic or paste backfill as well as Insitu behavior of backfilled stopes. After a literature review on field testing of soils and past experiments on mine backfill in situ testing, the self-boring pressuremeter was selected as the most appropriate instrument for this task. The authors presents in this paper the technical aspect involved in a field trials that was conducted in a Canadian underground mine using paste backfill. The results of this first successful trials show that self-boring pressuremeter test can provide high quality and reliable backfill characteristics results, using analytical techniques developed for soils (Ouellet et al., 1998). The parameters obtained were: estimation of the lateral stress in the ground, the soil stress-strain response and the soil strength. The logistic and equipment required to conduct such testing underground is fully described. Performance achieved in the field and technical difficulties encountered are highlighted. Recommendations for future experiments with such instruments are given. Some potential technical improvements to better adapt this in situ testing technique to mine backfill are proposed.

Jan 1, 2001

By J. L. Fuller

This paper contains a brief summary of design descriptions and generally accepted designations for longwall ventilation systems. Various ventilation systems for longwalls developed using single-entry and multiple-entry systems are discussed. Design considerations specific to longwall mining are included.

Jan 1, 1989

By J. L. Fuller, N. A. Abdel-Khalek

This paper contains a brief summary of design descriptions and generally accepted designations for longwall ventilation systems. Various ventilation systems for longwalls developed using single-entry and multiple- entry systems are discussed. Design considerations specific to longwall mining are included.

Jan 1, 1991

By J. Mattern

Performance monitoring, operational practices and ongoing collection of geologic data in open pit slopes all provide valuable information for quantifying potential steepening of subsequent slopes. Mining at the Goldstrike open pit has been ongoing since the early 1980’s, with its share of slope instabilities. In areas where slopes have remained stable, consideration has been made for potential slope steepening of final walls. With the proper available equipment, steepening of bench face angles via pre-split blasting is not an uncommon method for steepening of inter-ramp slope angles. As an alternative at Goldstrike, the commonly used Modified Ritchie Criteria for empirical catch bench width has been adjusted resulting in quantified, rock specific formulas for bench width and rock fall berm placement. The result is an inter-ramp slope angle increase of 2 degrees on a 300m high slope, without the necessary purchases and procedural changes that would be required for pre-split drilling and blasting. The result has shown significant net benefits through reduction in mined waste tons and an increase in gold reserves. Location The Goldstrike open pit is located on the Carlin Trend gold belt in northeastern Nevada USA (Figure 1). The mine has produced over 43 million ounces (1.2M kg) of gold during the past 30 years. Engineering Geology Stratigraphy Figure 2 is a stratigraphic section of the rocks in the Goldstrike open pit. Quaternary alluvium and Miocene materials typically are poorly indurated stiff soils and are not present in all locations. Bedrock units consist of siltstones, mudstones, sandstones and cherts. From top down the major units exposed in the open pit are the Vinini Formation, the Rodeo Creek Unit, and the Popovich Formation. In general, rock mass strength increases with depth.

Jan 1, 2019

By Nora M. Hutt, Kevin A. Morin

Geochemical static tests are a basic component of geochemical assessments and predictions for acidic drainage, and include acid-base accounting and total-metal contents. A key database for such information is the International Static Database (ISD), which currently contains more than 45,000 static-test analyses from over 200 minesites. Such large databases are useful in identifying general trends and, just as important, the percentage of exceptions. General trends and significant exceptions can be seen in the ISD by comparing one parameter against another. This paper shows that bulk neutralization potential (bulk NP) obtained from acid titration is often a good indicator of neutralizing capacity above values of 10 t CaCO3/1000 t. Other types of calculated neutralizing capacity are then compared to bulk NP to determine if they, in fact, reliably represent actual neutralizing capacity and if they can substitute for the more time-consuming and expensive bulk NP. For example, bulk NP correlates better with Carbonate NP (from carbonate analyses) and Total-carbon NP (from total-carbon analyses) than with (Ca+Mg) CaNP (from solid-phase analyses of calcium and magnesium). This means that, in general, (Ca+Mg) CaNP is a less accurate substitute for bulk NP than the other types, and thus requires intensive site-specific justification if a substitution is attempted. This also means that measurement of the frequently less-expensive parameters of total carbon and carbonate can often substitute, within site-specific error bars, for the bulk-NP titration. However, the ISD also shows that non-carbonate minerals make the primary contribution to neutralization in up to 20% of samples, so Carbonate CaNP and Total-carbon CaNP do not always reveal the full neutralizing capacity of a sample.

Jan 1, 2000

By J. Wagner, P. Eger, G. Melchert

In 1991, LTV Steel Mining decided to close an open-pit taconite mine in northeastern Minnesota using a passive-treatment approach consisting of limiting infiltration into the stockpiles and wetland treatment to remove metals. More than 50 Aft (55 million st) of sulfide-containing waste had been stockpiled adjacent to the mine during its 30 years of operation. Drainage from the stockpiles contained elevated levels of copper, nickel, cobalt and zinc. Nickel is the major trace metal in the drainages. Before the closure, the annual median concentrations ranged from 1.5 to 50 mg/L. Copper, cobalt and zinc are also present but they are generally less than 5% of the nickel values. Median pH levels range from 5 to 7.5, but most of the stockpile drainages have pH levels greater than 6.5. Based on the chemical composition of each stockpile, a cover material was selected. The higher the potential that a stockpile had to produce acid drainage, the lower the permeability of the capping material required Covers ranged from overburden soil removed at the mine to a flexible plastic liner. Predictions of the reduction in infiltration ranged from 40% for the native soil to more than 90% for the plastic liner. Five constructed wetlands have been installed since 1992. They have removed 60% to 90% of the nickel in the drainages. Total capital costs for all the infiltration reduction and wetlands exceeded $6.5 million, but maintenance costs are less than 1 % of those for an active treatment plant. Because mine-drainage problems can continue for more than 100 years, the lower annual operating costs should pay for the construction of the wetland-treatment systems within seven years.

Jan 1, 2000

By Richard L. Bullock

Drilling of small diameter blast holes in the conventional tunnel driving system or mining operation still consumes a significant part of the time and money required to extend an opening in rock. The use of pneumatic drills for most small hole applications has been the dominant tool used by miners and tunnel men alike throughout the world. But now, a, trend has been started that is showing major inroads into the traditional areas of pneumatics drilling for all types of rocks. Operators dealing in very soft materials, such as coal, salt or potash, traditionally had the option to use hydraulic power for their drilling tools. Twelve to fifteen years ago, drillers in medium hard, but nonabrasive rock extended their drill machine option by helping to develop a drill that still used air to power the hammers, but relied on hydraulic power for the rotational torque and feed thrust. (1) This was a significant step forward, particularly for those who drilled in rocks that were compatible to rotary-percussion bits. However, this application was in fact somewhat limited to the limestone and dolomite formation of mid-United States and the softer sediments in Europe. Now high performance rock drills have been developed, using all-hydraulics for both the hammer and rotation, that have many advantages over the conventional pneumatic systems. In two previous papers on this subject, (2)(3) this author reviewed in detail: 1) the characteristics of each of the manufacturer's products that were on the market; 2) The specific advantages of the all-hydraulic drilling systems; 3) Data from the applications of these drilling systems that was in use; 4) What was needed to further develop this drilling system and utilize its potential in the mining or tunnelling cycle. This paper will attempt to update previous papers, without reiterating many details of drill descriptions or

Jan 1, 1976

By Dennis C. Drehmel

Because of their relatively low cost, carbonate rocks are desirable in abatement of air pollution by acid gases. Although many processes and types of equipment have been proposed to control or prevent the emission of acid gases, this paper considers only three: dry-limestone injection, wet-limestone scrubbing, and chemically active fluid beds. For the dry-limestone-injection process, surface area-especially from pores in the 0. 2- to 0.3-micron range-is one of the important parameters which will discriminate between less and more reactive carbonate rocks. Marls, chalks, oolitic calcites, and other fine- grained limestones show larger-than-average surface areas and better- than-average removal efficiencies. Inert chemical impurities such as silica detract from reactivity. A dolomite is not necessarily less re- active than a calcite. For the wet-limestone-scrubbing process, dissolution rate of the carbonate rock controls the differences in stone reactivity. In this process the dolomites are less reactive than the calcites. In addition, more than 90 percent of the dolomitic impurity in Fredonia white lime- stone is inert during limestone scrubbing. Dissolution rate is also a function of particle size for large-grained carbonate rocks. Fine grinding of such rocks will increase the dissolution rate to that of a fine-grained rock. Hence the requirement of high dissolution rates may be met by some grinding of fine-grained material (e. g., marl, chalk, or other limestone) or by fine grinding of coarser grained material. For chemically active fluid beds, chalks have the best capacity to absorb both SO2 and H2S. However, most chalks are probably unsuitable for fluid beds because of high attrition rates. Because dolomites are generally more reactive than calcites with both SO2 and H2S, a dolomite would be the feed material of choice for a chemically active fluid bed.

Jan 1, 1974

By M. Christou

The LIFE-Environment Demonstration Project ?Treating Waste for Restoring Land Sustainability?(www.bangor.ac.uk/ies/TWIRLS/TWIRLS_home.htm), a project initiated by the University of Wales, Bangor, UK in which NAGREF is a partner, aims to demonstrate the effective use of industrial and municipal wastes for the remediation of post-industrial and degraded sites in urban and rural sites. Within the framework of this project, a schist quarry, which is located in a mountainous area near Athens and which has been exploited in the past for cement production, was chosen for bioremediation experiments in collaboration with the quarry owners, TITAN Cement Co. Three different areas within the quarry were selected representing 3 different topographies. These were a compacted, flat area with seasonal water logging (untreated control), a gently sloping, land formed area; and artificially created mounds of overburden rock material formed on the flat area. Compost produced from mixing municipal waste, green waste and digested sewage sludge at the recycling plant of the Association of Communities and Municipalities in the Attica Region (ACMAR), near Athens was used for nutrient amendment. Six replicates of three treatments were applied with varying compost application rates in order to examine the effect of the addition of organic matter in the establishment of suitable vegetation on the infertile schist material. Pine trees (Pinus halepensis Mill.), 4 per replicate, were pocket planted in a volume of 3 liters of schist or schist-compost mixture (1:2 and 2:1). Tree height, main stem diameter and branching were measured following planting and these measurements will be repeated annually to test hypotheses that compaction and water logging reduce Pine establishment by natural regeneration and that nutrient addition improves establishment of pine on schist waste. The availability of nutrients and variation in other soil physico-chemical parameters will also be studied in each treatment and related to plant growth. As a demonstration project, open days are planned on the site for the public and official bodies involved in municipal waste handling and other relevant areas. The aim of these will be to illustrate the effective re-use of waste for the sustainable restoration of post-industrial and degraded land.

Jan 1, 2006