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By R. L. Castro

Currently, in several caving operations, the spacing between the drawpoints is determined by consulting Laubscher's design guide (Laubscher 1994, 2000), a methodology based on the gravity flow characteristics of the caved rock. Laubscher's methodology is based upon the height of interaction between adjacent flow zones, but does not allow calculation of primary recovery for a given layout. In this paper the authors present a technical and economic methodology based on the flow that occurs near the drawpoint and the associated development costs to estimate the optimal spacing. The flow model at the drawpoint was validated at the El Teniente mine, which extracts coarse caved rock. To validate the flow model, small-scale simulations using drawpoint clusters were conducted and results compared to extracted grades, marker recovery, and drill holes to determine ore remnants that are part of the production control programme at the mine. The results indicate that primary recovery depends on the height of interaction, which varies with the friction angle of the caved rock and the spacing between adjacent drawpoints. Primary recovery estimations indicate values from 85 per cent to 97 per cent depending on the drawpoint spacing used. Extrapolations were then conducted to estimate the primary recovery for different drawpoint configurations planned to be used in the New Mine Level of the mine. The results indicate that the optimal drawpoint spacing is 32 m x 20 m with a through length of 18 m. The methodology developed may be used to estimate optimal drawpoint spacing for block caving mines under different metal prices and mine cost conditions.

Jan 1, 2012

By E. Hakami

The objective of the study was to estimate the largest shear displacement that could be expected on a pre-existing fracture located in the repository area, due to the heat release from deposited waste. Two-dimensional numerical analyses using UDEC have been performed. The maximum shear displacement, at the fracture centre, amounts to 0.2 – 13.8 cm depending on fracture parameters. The fracture extension, friction angle and shear stiffness are found to be the most important. Le but de cette étude est de déterminer le déplacement maximal en cisaillement qui puisse se développer le long d'une fracture préexistante en réaction à la chaleur dégagée par les déchets radioactifs enfouis dans la roche. Les analyses numériques ont été réalisées à l'aide du code 2D UDEC. Le déplacement maximal en cisaillement enregistré au centre de la fracture varie entre 0.2 et 13.8 cm en fonction des propriétés de la fracture. L'ouverture, l'angle de friction et la rigidité au cisaillement semblent avoir une influence dominante sur les résultats. Zielsetzung der Studie war die Abschätzung der maximalen Scherverschiebung, die auf einer innerhalb des Endlagergebietes existierenden Rissfläche infolge der Wärmeabstrahlung des eingelagerten Materials zu erwarten war. Es wurden zwei-dimensionale numerische Berechnungen mit UDEC durchgeführt. Die maximale Scherverschiebung im Zentrum der Rissfläche beträgt 0.2-13.8 cm, abhängig von den Risseigenschaften. Dabei hat sich herausgestellt, dass Rissgrösse,Reibungswinkel und Schersteifigkeit den grössten Einfluss haben.

Jan 1, 2003

By M. H. Lampen

The SILAG Material Tracking System MTS monitors and controls the complete material flow throughout the plant - and even companywide. The customized system developed by Siemens especially for bulk material handling applications enables companies to track bulk material from the mine to the harbor, to the steel mill or to the power plant. All relevant material data is available at every single step of the material’s journey. SILAG is an open, scalable system based on Windows NT / 2000. Using standard interfaces of Windows NT, like API, ODBC, SQL and socket technology, the system is very flexible and can easily be tailored to meet different requirements. SILAG can be used as a stand-alone solution or - if complete plant control and visualization is required - as a component of a fully integrated automation system with the Win CC HMI system and the PCS7 process control. In contrast to conventional material tracking systems, SILAG offers many advantages. - The Material Tracking System is an object oriented, online to the process, linked system. All changes in the plant during operation e.g. selecting another conveyor route, start and stop etc. will be automatically detected and will influence the calculation. - The systems is able to split and blend material (quantity and quality).Measurements of tonnage, volume or quality analysis can be linked online to the system. Each movement of material is monitored by the system and leads to online recalculations of the images and databases. - All material data is based on 3D-stockpile images, which are calculated by an internal mathematical model based on quantity and quality information. - If a laser scanner is available on a stockyard machine it can be taken to update the profile directly from the piles. - Efficient control and report functions are available on each, free selectable point of the total plant.

Sep 1, 2001

By G. J. C. Young

The new metallurgical plant has a simple, compact layout, being designed for a small team of operators. The reasons for building the new plant are given, and its various sections are briefly described. These include the conveyor plant, milling plant (for run-of-mine milling), thickener plant, agitator plant, filtration, clarification, smelthouse, and central core joining the mill and filtration sections.

Jan 1, 1978

By C G. Robinson, B. K. Loveday, J. C. Paynter

"A method of optimizing the design of a processing plant has been developed which minimizes capital and operating costs for average stripping ratios and ore characteristics. Models were developed to describe the operating characteristics and costs involved in various operations such as up-grading, leaching and solid-liquid separation.The options available in up-grading policy and the relation between the cut-off grade and the costs incurred subsequently in the treatment of the ore formed the basis of the optimization. To arrive at an optimum plant configuration and a set of operating parameters, the interrelation between grinding size, leaching temperature, leaching time, and various plant recycle options was investigated."

Jan 1, 2014

By L. Zhou, J. Qiu, M. Tang, J. Wang, G. Dai

Coal spontaneous combustion in longwall gobs is a major concern in coal mines. In comparison to other hazards, this phenomenon is difficult to detect. Fifteen factors influencing coal spontaneous combustion in longwall gobs were identified from the literature. The logical relationships between these factors were evaluated and quantified by decision-making trial and evaluation laboratory (DEMATEL) and interpretive structural modelling (ISM) methods. A four-level hierarchical structure model was established. The research shows that combining DEMATEL and ISM can reveal the key factors that influence coal spontaneous combustion in longwall gobs and establishthe interactions and relationships among these factors. The results can provide the basis for preventing and controlling coal spontaneous combustion in longwall gobs.

Jun 10, 2024

By M. M. Hajdasinski

The internal rate of return (IRR) is one of the most popular project evaluation criteria in the mineral industry, as well as in other industrial sectors. Analysis of its assumptions reveals, however, that this criterion does not function in the way it is supposed to. The search for a new criterion that would reflect the true rate of return (TRR) of an investment project or the true borrowing rate (TBR) of a borrowing project has led to the development of several approaches, yielding, for the same project, generally different values of the interest rate in question. Two of those approaches have been selected as the most representative and practical. Each has been presented in two variants, and subsequently analysed. As a result, it is shown that the various approaches to the TRR/TBR are all consistent with the net present value (NPV) criterion, and that each can serve as an independent project evaluation instrument, provided its assumptions can be regarded in a given situation as realistic enough.

Jan 1, 1987

By F. R. Deist, R. P. Plewman

Discussion: A. Hazell (Associate Member) and T. J. Kotze (Graduate Member): The authors must be congratulated on the development of a versatile computer programme for determining the stresses and displacements resulting from mining operations. As a design tool it will no doubt take its rightful place together with the analogue computer. Union Corporation made use of this digital computer programme whilst still in its development stage to determine the stress distributions which were causing the unexpected failure of the Marievale sub-incline shaft. Two features arising from this investigation may be of interest to members, namely: A. The solution to the problem of stabilizing a rectangular inclined shaft, which turned out to be contrary to accepted mining practice, and B. A comparison between the results obtained with the pure digital system and the analogue computer. A. The shaft is nine ft high and 20 ft wide, dipping at 9° to the horizontal and crossing the bedding planes. Fig. 1 is a plan and Fig. 2 is a section of the sub-incline shaft pillar area showing the relative positions of the shaft and reef as well as their respective dips. The deepest point in the shaft is 3 300 ft below surface and the requirement of a stress free ground surface may not be satisfied. It also means that the original gravitational stresses are low. A 900 ft wide pillar was left to protect the bottom section of the shaft, the top section being understoped years ago. Extraction of the pillar was started at the beginning of last year, mining operations being carried out in the accepted manner, starting beneath the shaft and mining outwards. The approach did, however, turn out to be the wrong one, because failure of the shaft was noticed soon afterwards. Even small movements were serious in this case due to the low clearance between the skips and the shaft supports. During October, 1968, failure between benchmarks 8 and 10 (see Fig. 1) became so excessive that hoisting speeds had to be reduced. Failure continued to occur and, by the end of March, 1969, failure had propagated up the shaft as far as benchmark 7, and down as far as benchmark 12. As this shaft had a tight hoisting schedule it was imperative that a quick solution be found to arrest the failure.

YEAR 1943-1944 Vol. 44 Page A major change-over in the ventilation of a deep level mine, by F. G. Hill and E. C. Ranson, 27; Discussion 56, 62, 67, 71, 72, 79, 123, 129 131 A note on the quarrying of surface limestone in the Sinai Desert, by V. L. Bosazza.. .. 59 Mining with diamond drills at the Nkana Mine of the Rhokana Corporation, Limited, Northern Rhodesia, by W. A. Odgers and A. G. Stirling, 95; Discussion 117, 121, 122 123 On silicates and dusts from the Witwatersrand gold mines (some preliminary notes), by J. J. Frankel, 169; Discussion .. 178 Presidential Address-Review of the rock pressure problem, by C. Biccard Jeppe, 3; Discussion 11,15 17 The chemistry, production and application of plastics, by P. N. Lategan, 138; Discussion 151 153 YEAR 1944-1945 Vol. 45 Page A microtechnique for the size-grading of mine dust, by S. R. Rabson, 34; Discussion 49, 50, 52 55 Activated carbon for regenerating used lubricating oil, by F. J. Tromp and J. J. Matthee 90 A contribution to the study of the production of zeolites, by C. C. le Grange and A. J. Petrick 235 A laboratory method for the determination of the suitability of South African coal and coal blends for the manufacture of metallurgical coke, by R. F. J. Teichmann .. .. 202 Copper containing cements for self-sanitising surfaces, by R. S. Young and H. L. Talbot 156 Notes on some sulphide minerals from the Far East Rand, by E. Mendelssohn, 84; Discussion, 88 89 Presidential Address-A review of underground support on the Witwatersrand with its Bearing on the Problem of ultradeep mining, by P. J. Louis Bok, 3; Discussion, 24, 25 27 Scientific management with particular application to a Witwatersrand gold mine, by J. S. Ford, 63; Discussion, 77, 80, 82 83 Some aspects of rock-drilling practice (the Witwatersrand gold field), by C. J. Irving, 163; Discussion, 185, 190 *197 Temperature measurements in a mine on the Witwatersrand with an electrical resistance thermometer, by O. Weiss, 127; Discussion, 136 137 The measurement of the geo-thermic gradient by means of the clinical thermometer, by R. A. H. Flugge-de Smidt, 105; Discussion, 136 137 The micro-chemical determination of free and combined silica in mine dust, by S. R. Rabson, 43; Discussion, 49, 50, 52 55 The oxidation of pyrites associated with South African coals, by R. F. J. Teichmann 141 YEAR 1945-1946 Vol. 46 Page Air cooling plant, No. 4 Shaft, City Deep, Limited. A review of layout and results achieved, by H. W. Unwin, A. Malcolm and R. E. Campbell Pitt, 66; Discussion, 100, 102, 103, 106, 110 115 A preliminary note on the Waterberg coal field as a possible source of coking coal, by P. E. Hall 124

By J. J. Taute, N. B. du Preez

"A well-performing solvent-extraction circuit is a key part of producing good quality copper cathode. To ensure consistent operation, a good understanding of the circuit’s operation and an ability to rapidly troubleshoot key parameters is required. This paper briefly discusses the modeling of solventextraction circuits. The paper then goes on to discuss the determination of key performance parameters from plant data and comparing these with the circuit models to quantify circuit performance. The identification and troubleshooting of circuit issues is presented with a worked example. INTRODUCTIONA well-performing solvent-extraction (SX) circuit is a key part of producing good quality copper cathode. To ensure a consistent, high-quality operation, a good understanding of the circuit performance is required. Evaluating the performance of an SX circuit is an extensive topic. The objective of this paper is to focus on the evaluation that the metallurgist should be performing on a regular basis using flow and concentration data. This paper does not cover important topics, such as crud management, phase continuity, or organic management. Some basic SX modeling concepts are first be presented. The calculation of the parameters is then presented with a brief discussion and recommended ranges (where applicable). A worked example is used to provide a basis for further discussion on the evaluation of the calculated parameters and use of data collected.BASIC SOLVENT-EXTRACTION MODELING CONCEPTSThis section presents the basic modeling concepts used in SX simulation packages currently available. SX reagent suppliers have invested significant time and effort into collecting data on the performance of their reagents under different conditions. Based on these data, suppliers have developed packages which they normally make available to their clients for free. These are typically used for process design and plant optimization studies. For example, BASF developed ISOCALCTM and CYTEC Industries developed MINCHEM® and MEUMTM.Chemistry of Copper Solvent ExtractionLiquid–liquid extraction involves the selective transfer of a substance between two immiscible liquid phases by controlling the relative solubility in each phase. In the case of copper SX, the exchange is typically achieved by an oxime-based chelating mechanism. In particular, mixtures of aldoxime and ketoxime are normally used in conjunction with modifiers. More detail on this extensive topic can be found in Schlesinger et al. (2011)."

Jan 1, 2015

By M. E. C. Snyman, N. Naudé

"Coal fines produced during processing are difficult to dewater and result in a lower quality product and consequent lower value. A South African coal mine experiences severe difficulties with belt filter dewatering operations due to the presence of fines reporting from the thickener underflows. Plant 2 currently handles super-fine particles of size -34 µm and has low belt filter efficiency: excessive moisture retention lowers the product quality and strains downstream processing. It was necessary to determine an alternative method for dewatering these fines. Blending of fine material with coarser material was proposed as a solution. The effect of coal particle size and layering during ultrafines belt filter dewatering was evaluated using various blends of the fine Plant 2 material with coarser Plant 1 material. The best layering arrangement of the two materials and its optimum blend required to achieve reduced filter cake moisture content was determined in practise using a vacuum filter to simulate belt filtration. A blend of the two materials gave improved dewatering efficiency for the belt filters compared with that of the Plant 2 material alone. The best layering configuration was with Plant 2 material at the bottom and Plant 1 material on top. The optimum blend for industrial applications comprised 48% fines from Plant 2. IntroductionFines are produced during the processing of coal. It is estimated that 2 to 3% of run-ofmine coal reports to the ultrafine portion (-100 µm) (le Roux, 2005). The particle size of coal is inversely proportional to the amount of water adsorption, so smaller particles adsorb more moisture. Moisture removal requires either mechanical processes or thermal drying: mechanical processes are less expensive, but the fines still have high moisture retention. Discarding of fines leads to economic losses, so it is essential that they be dewatered so that they can then be sold as a product: fines need to be treated for both resource management and conservation reasons (Kenney, 1994). Removal of free surface moisture from ultrafine coal particles using a belt filter therefore remains a process that needs to be continuously improved. Ultrafine coal originating from a thickener underflow is known to be difficult to dewater owing to factors such as filter cloth blockage and moisture retention due to clogging. Mixing of finer and coarser materials has been proposed to deliver better dewatering efficiency and improved the quality of the recycled water (Kenney, 1994)."

Mar 1, 2019

By S. C. Essack

"Tenova Pyromet has designed a slag flow control valve that throttles the flow of slag in order to control the tapping rate. In addition, the valve has proved to be a reliable tool for closing the furnace during normal operation as well as emergency conditions. The valve makes use of a water-cooled copper element that is hydraulically operated and attached directly to the slag tap-hole. The equipment is compact, simple to maintain, and cost-effective to purchase and install. It can be retrofitted to most existing slag tapholes with minimal modifications.During the development phase, finite element method (FEM) and computational fluid dynamics (CFD) software was extensively used to model predicted operating conditions and to optimize the design. By using CFD, it was possible to understand the flow patterns inside the copper and to optimize these to improve overall performance.The slag valve was installed and commissioned in 2011/2012 on a 12 MW furnace as part of a new mineral wool plant in the USA. It has performed well since its installation despite operating under conditions in excess of the original design criteria. During the first 6 months of operation it quickly became the preferred method of closing the furnace, although the design intent was for occasional use during emergency shutdown conditions only. Since replacing the mudgun as the main method of closing the tap-hole, a few minor changes have been made to the installation in order to cope with the increased heat load and much higher frequency of use."

Jan 1, 2014

By S. C. Everett, I. S. Schache, P. A. Bannister, G. F. Balderson

The Pooncarie Project is located in the Murray Basin region of Australia. This region is a potential new mineral sands province. Due to the geological environment and the lithology of the deposit, these deposits have some technical challenges that need to be addressed prior to their successful development. Within the Pooncarie Project the Ginkgo deposit will be developed first. The technical challenges it presents include its geographical isolation, the requirement to remove substantial quantities of overburden as well as the processing issues raised by the highly weathered nature of the ilmenite family of minerals. Ore characterization bench scale testwork and bulk sample pilot plant programmes have been carried out and the data obtained used to design flowsheets for both the wet plant and mineral separation plant circuits with the flexibility to enable these plants to handle the variable heavy mineral assemblage. In addition to the solving of the processing challenges, technical issues such as removal of overburden for the minimum unit cost, the use of hyper saline water in the dredge pond and the provision of infrastructure, have had to be addressed. None the less, the orebodies making up the Pooncarie Project have many positive features including low slimes content, good rutile and zircon grades and the ability to recover most of the ilmenite family of minerals into acceptable TiO2pigment feedstocks. The development of the project is set to proceed with the establishment of mining operations on the Ginkgo orebody feeding a mineral separation plant at Broken Hill. The initial shipment of products is expected to occur in early 2005.

Jan 1, 2003

By B. Genc, C. Gous

Spontaneous combustion during coal mining operations is a major problem that affects the health and safety of workers and causes environmental problems. The phenomenon is associated with the presence of coal, coal shale, and pyrite. In 2020, a premature detonation incident occurred at an iron ore mine where the waste material contains black carbonaceous shale units known to be associated with pyrite. The spontaneous combustion propensity and properties of samples of the black carbonaceous shales from the mine were examined and compared with samples from the Witbank Coalfield. The spontaneous combustion liability indexes of these samples were correlated with X-ray fluorescence (XRF) and proximate and ultimate analyses using linear regression. The Wits-Ehac Index classification results show that the samples were between medium and high risk. The linear regression analysis showed very poor correlations between the Wits-Ehac Index results and the XRF and proximate and ultimate results. The most valuable relationship found is between the presence of relatively high sulphur (greater than 3%) and ground reactivity with nitrate-bearing explosive emulsion.

Jun 5, 2023

By S. M. Graham, G. Mellis

"The determination of the oxidation state(s) of an element present in a solid sample may be required for a number of reasons, including the assessment of the degree of reduction which has taken place during a multi-step production of a metal. In addition, possible flaws in a metal may result from small amounts of oxides included in the solid. The analyte of interest may be present as a major component of a sample of interest, or as a minor impurity - beneficial or requiring removal - in another matrix.Numerous methods have been established for the analysis of species in solution samples - for example, Fe2+ and Fe3+ by titration, Cr6+ by colourimetric means, etc. With appropriate knowledge of the solution being analysed, many of these methods are fairly straightforward, extremely reproducible and accurate. In those instances where the analyte in a solution is known to be in only one form, the analysis is even more straightforward, since it can be achieved instrumentally (by AAS, rCP-OES or rCP-MS, for example).However, the situation with respect to the analysis of solids is not as simple. Various techniques - such as X-ray diffraction - are routinely used by our mineralogists to obtain information about the various minerals present in solid samples, and thus about the oxidation states of the analyte elements present. However, these techniques usually give results that are qualitative, or semi-quantitative at best. They are also usually time-consuming and expensive. One of our colleagues at Mintek, Deshenthree Chetty, has done extensive work in developing a method for the quantification of manganese species in solids using mineralogical methods, and this is no small achievement."

Jan 1, 2014

By P. R. Jochens, D. D. Howat, R. B. Atmore

INTRODUCTION The Miller chlorination process has assumed a preeminent position in the refining of gold bullion, a position it has maintained for over half a century. In the early sixties considerable interest was aroused by the idea of producing a consistently high grade bullion at the mine smelthouses themselves. However, as the use of chlorine in industrial plants is associated with considerable hazards, oxygen was considered a natural alternative, apart from bing less expensive than chlorine. Partial refining at the mine smelthouses would considerably decrease the requirements made on Rand Refinery Limited as well as indicating the possibility of reducing final refining costs. An added factor would be the purer silver chloride obtainable, after prior removal of the base metals by oxygen injection, which would facilitate the production of high-purity silver. The free energies of formation of the oxides of the metals;- silver, copper, lead, zinc, iron and bismuth indicate that, with the exception of silver, these metals should be capable of removal as oxides by oxygen injection. Rose1 had shown that during injection of gold bullion, considerable loss of silver to the boraxsilver slag occurred and, furthermore, that copper removal was not efficient and oxide attack on the refractories was severe. Plant test work2 had confirmed the difficulty of copper removal, but had shown that zinc and lead were almost completely removed. The difficulty of copper removal by oxygen injection warranted further investigation. Also, the high decomposition pressure of silver oxide suggested that by suitable control of the slag composition it might be possible to reduce to very small proportions the silver carried into the slag as oxide. The oxidation of copper by oxygen injection and subsequent dissolution of the oxide in a slag may occur according to the following reactions; Reactions 4 and 5 were considered because of the relatively high solubility of oxygen in molten silver and silver alloys. Thermodynamic data indicate that there is little possibility of any reaction involving the formation of CuO occurring at temperatures above 1 000 °C. To ensure that the operative reactions 1 and 4 take place to the maximum extent, the following factors He significant. (a) an increase in the activity of the copper in the bullion, (b) an increase in the partial pressure of oxygen in the system, (c) an increase in the activity of the oxygen in solution in the metal, (d) a decrease in the activity of cuprous oxide in the slag. From practical considerations, the operative variable most easily susceptible to control is the composition of the slag. SOLUBILITY OF COPPER OXIDES IN BOROSILICATE SLAGS Very scanty information exists on systems containing copper oxides but the indications are that slags containing considerable amounts of boric oxide would possibly prove to be the best solvents for cuprous and cupric oxides. This is attributed to the fact that the activities of copper oxides are much lower in boric oxide slags than in slags in which silica is the main network former. The number of possible slags containing boric oxide was limited by consideration of liquidus temperature, viscosity, corrosive action on refractories, volatilization, and ultimately cost (for industrial application). Slags in the systems soda-boric oxide-silica and lime-boric oxide-silica were selected paying due attention to the above limitations. Additions of 5, 10 and 15 per cent cupric oxide were made to the finely ground, premelted slags. These mixtures were then reground and 2g quantities held in re crystallized alumina crucibles at temperatures of 1150°C and 1 250°C respectively for 30 minutes. The crucibles were removed from the furnace, rapidly cooled, cut in half longitudinally, and a thin section taken from one half was subjected to microscopic examination.

By S. Swanepoel, A. V. Cherkaev, Q. G. Reynolds, M. Erwee

Ferrochrome (FeCr) is a vital ingredient in stainless steel production and is commonly produced by smelting chromite ores in submerged arc furnaces. Silicon (Si) is a componrnt of the FeCr alloy from the smelting process. Being both a contaminant and an indicator of the state of the process, its content needs to be kept within a narrow range. The complex chemistry of the smelting process and interactions between various factors make Si prediction by fundamental models infeasible. A data-driven approach offers an alternative by formulating the model based on historical data. This paper presents a systematic development of a data-driven model for predicting Si content. The model includes dimensionality reduction, regularized linear regression, and a boosting method to reduce the variability of the linear model residuals. It shows a good performance on testing data (R2 = 0.63). The most significant predictors, as determined by linear model analysis and permutation testing, are previous Si content, carbon and titanium in the alloy, calcium oxide in the slag, resistance between electrodes, and electrode slips. Further analysis using thermodynamic data and models, links these predictors to electrode control and slag chemistry. This analysis lays the foundation for implementing Si content control on a ferrochrome smelter.

Mar 14, 2024

Papers and Contributions Since the Institute's inception, it had been our practice until some years ago to meet regularly for discussion of new developments, using as a basis a paper read by one of the members. Usually, the Journal issue containing the paper would have been circulated well before the meeting, giving members plenty of time to absorb it and perhaps to prepare contributions. Discussion was generally lively, often controversial. The author always had an opportunity to reply.

Jan 1, 1991

By T. Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques and controlled bulk leaching studies. The anodic dissolution process has been established to be a sevenelectron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions, which suggests that the sulphur is oxidized to thiosulphate and the copper and iron released as Cu+ and Fe2+ in these systems. The deportment of Fe2+ and S2O3 2- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, supporting formation of different sulphur species as proposed for the sulphate and carbonate salts. Scanning electron microscopy and energydispersive spectroscopic analysis of the mineral surface after leaching indicate presence of an iron–sulphur surface layer completely free of copper in the sulphate system, an iron-rich surface layer in the perchlorate solutions, and absence of surface layer build-up in carbonate solutions. XRD analysis of a bulk leach residue from leaching in ammoniaammonium sulphate solutions showed the surface layer to be mostly amorphous (90%). The crystalline content (10%) is composed of 95% polymorphs of anhydrous iron oxide hydroxide FeO(OH). Choice of ammonium salt and the hydrodynamic environment of leaching have been shown to influence the presence or absence of the surface product, as well as its nature. IntroductionHydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different routes for hydrometallurgical treatment of chalcopyrite can be followed. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilization of copper (I) and copper(II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation [1] (Beckstead and Miller., 1977a):"

Jan 1, 2016

By B. Mulcahy, M. Valenta

"The purpose of executing a project in a stagewise fashion is to evaluate all potential options in a cost-effective manner and develop an understanding of the project drivers, thereby minimizing overall project risk to the client. Among the more valuable tools for this exercise are production and financial models that can be used to quantify the sensitivity of the project to the critical parameters.The mine and concentrator used in this case study are located on the Kalahari Copper Belt, which extends from Zambia through northern Botswana into Namibia. This area of Africa has seen very little industrial development and the project will create much-needed employment and development in the region.The success of this project thus far can be attributed to the close cooperation between the geological, mining, and metallurgical disciplines. Regular updates of projected capital and operating cost estimates coupled with project outputs guided the teams in optimizing their various discipline models, ultimately delivering a compelling argument for the execution of the project. Key to the success was the development of a geometallurgical model for the prediction of concentrate tonnage, grade, and recovery for the life of the mine from the mining plan.This paper summarizes the metallurgical findings and the outcome of the various project stages. The development of the model is discussed, as are the challenges faced in developing a suitable metallurgical process route. IntroductionThe Kalahari Copper BeltThe Kalahari Copperbelt, which extends from Zambia across northwest Botswana into Namibia, is considered to be a broad time equivalent of the Central African Copperbelt, with a similar style of mineralization. However, at shallower depths (<25 m), chrysocolla and malachite exist in significant proportions in certain geological areas. As illustrated in Figure 1, the project is located in the Ghanzi-Chobe Fold Belt which forms part of the Kalahari Copper Belt. The Ghanzi Group, which overlies the lowest stratigraphic unit (the Kwebe Formation), consists of three formations, namely the Ngwako Pan, the D’Kar, and the Mamuno Formation (Hall, 2012)."

Jan 1, 2016