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By N. Lock

"Despite the pre-eminence of the Jwaneng Diamond Mine as the world’s richest diamond mine, the discovery story has long been clouded in mystery. This is the 45-year old untold story of the Jwaneng discovery and contemporaneous Bechuanaland/Botswana political and socioeconomic history. Diamond exploration by De Beers in Bechuanaland began in 1955, with the first true kimberlite discovery near Letlhakane in 1967, before Clifford’s Rule was applied and before the use of indicator mineral chemistry. Surface deflation soil sampling and bioturbation by termites was the foundation for exploration into the Kalahari. The 1962 reconnaissance programme south of Jwaneng had failed to make any discoveries. Improved sampling methods were applied to the Kalaharicovered areas in 1969 and positive results were received by year-end. The Whateley’s Wish percussion drill-hole in December 1972 was confirmed as Jwaneng 2424D/K2 with drill core in early 1973. Jumper drills were required to penetrate the Kalahari sand cover. Diamond resources were demonstrated despite multiple technical problems. IntroductionThe Jwaneng Diamond Mine is, by value, the world’s richest diamond mine. Harry Oppenheimer is quoted as saying that Jwaneng is ‘the most important primary deposit found anywhere in the world since the discovery at Kimberley more than a century ago.’ (Taylor III, 1982) The mine opened in 1982 after some nine years of evaluation and construction since discovery in February 1973. Debswana (2017) states that 2015 production was 7.87 Mt of ore from which 10.408 million carats were recovered at a grade of 132 carats per 100 t (cpht). Although the value is not reported, it was noted that Jwaneng contributes 60–70% of Debswana’s total revenue from all mines, including Orapa, Damtshaa, and Letlhakane (Debswana, 2017)."

Feb 1, 2019

1. Mintek reports The folowing reports are available from Mintek, Private Bag X3015, Randburg, 2125 South Africa. They are available at R25 (plus R3,25 GST) per copy to South African addressees, and US$25 per copy (including airmail postage) to addressees elsewhere. Report M91D A mineralogical investigation of samples from the Renosterkop tin prospect near Upington, by M.J. Southwood. First issued Jul. 1983, reissued May 1989. 16 pp. Report M256D The upgrading of Mamatwan manganese ores heavy-medium separation, by P. W. Overbeek. First issued Apr. 1986, reissued May 1989. Report M299D A mineralogical investigation of samples from the Eenzaamheid cobalt-molybdenum deposit, by C.D. de Nooy. First issued Jan. 1987; reissued May 1989. Report M301D The evaluation of manganese metal powder by automatic image analysis, by E.J. Oosthuyzen. First issued Feb. 1987, reissued May 1989. 13 pp. Report M311D Mineralogical and beneficiation studies of ore from Lutzputz, by R.N. Guest and C.T. Logan. First issued Mar. 1987, reissued May 1989. 13 pp. Report M314D The beneficiation of a sample of magnesium ca/crete, by L. Jonker. First issued Apr. 1987, reissued May 1989. 13pp. Report M369 The determination, by flow-injection analysis, of thiocyanate, by E.A. Jones and M-J. Hennings. Jun. 1989. 7pp. Report M389 A spectrophotometric method for the determination of zinc by flow-injection analysis, by D.E. Barnes and RA. Jones. Jul. 1989. 15 pp.2. Recent publications Pumps-principles and practice. Available from K. Myles & Associates CC, P .0. Box 2212, Northclif 2115. :200pp. R99 including GST. Standard handbook of hazardous waste treatment and disposal, edited by H.M. Freeman. Bergano Book Co., P .0. Box 190, Fairfield, CT 06430, USA. 1120 pp. US$130.Quality control handbook, by J. Juran and F. Gryna Jr. Bergano Book Co. (address as above). 4th 00. 1536pp. US$125.Refractories in the manufacture and transport of pig iron. Verlag Schmid GMBH, P.O. Box 6609, 7800 Freiburg, West Germany. DM 100. The user-computer interface in process control, byW.E. Gilmore, D.I. Gertman, and H.S. Blackman. London, Harcourt Brace Jovanovich Ltd, 1989. " 312pp. $29.Aluminum alloys-contemporary research and applications, edited by A.K. Vasudevan and R.D. Doherty. London, Harcourt Brace Jovanovich Ltd, 1989. " 676 pp. " £90.3. TMS publications issued recently The folowing publications are available from The Minerals, Metals & Materials Society, 420 Commonwealth Drive, Warendale, PA 15086, USA (Telephone: (412) 776-9000, Telex: 9103809397, Fax: 4127763770). Advances in magnesium alloys and composites, by H. Paris and W.H. Hunt (eds.). 145 pp. $65. Arsenic metallurgy-fundamentals and applications, by R. Reddy (ed.). 515 pp. $104. Casting of near net shape products, by Y. Sahai (ed.). 7oopp. $155.Continuous casting of non-ferous metals and alloys, by H.D. Merchant, D.E. Tyler, and E.H. Chia (eds.). 360 pp. $90.Dislocations and interfaces in semiconductors, by K. Rajan, D. Ast, and J. Narayan (eds.). 210pp. $75.

Jan 1, 1989

By K. Woodward, Y. Potvin, B. McFadyen, M. Grenon

Open stoping has become a popular mining method in hard rock mines, not only due to the safety of the method as a non-entry approach, but also because of the high extraction rate and low costs. At mine sites, stope performance is evaluated by calculating stope overbreak using the stability chart. However, limitations of the stability chart regarding the precision of the predictions, nonconsideration of factors such as the influence of blasting, and the exclusion of underbreak have led to non-optimal designs. The capabilities of today's computers have increased the amount of data being collected and the power of models being built. This article presents a step towards a new stope design approach where stope overbreak and underbreak are measured and georeferenced using octrees at an approximately cubic metre resolution and predicted using multivariate statistical models (partial least square, linear discriminant analysis, and random forest). Results show that overbreak and underbreak location along the design surface and their magnitude are predicted with good precision using a random forest model. These predictions are used to build the expected geometry of the open stope. The resolution of the data and the use of multivariate analysis has enabled the prediction of variation in stope performance along the design surface, going well beyond the simple qualitative per stope face prediction provided by a traditional stability chart approach.

Jun 5, 2023

By M. Rhodes

The Sukari project, which is owned by Centamin Egypt Ltd, is located in southern Egypt, 770 km south of Cairo but close to the Red Sea. The project is the first new gold development in Egypt and was commissioned in the middle of 2009. In 2007, Centamin purchased the CIL plant from the Kori Kollo mine in Bolivia. This plant was originally designed to treat 6.5 Mtpa of oxide ore. The Sukari deposit contains an oxide zone close to surface with a thick zone of mixed oxide and sulphides below this. The sulphides contain relatively coarse pyrite and arsenopyrite with fine <10 µm gold inclusions. Eventually, the sulphide ore will be mined from underground. Metplant Engineering Pty Ltd, a subsidiary of Bateman Engineering Pty Ltd was contracted to design modifications and additions to the Kori Kollo plant to enable it to treat the Sukari ores. The plant was designed to treat the three ore types in stages. Throughput was set to 4 Mtpa, dueto Sukari ore being harder, at a head grade of 1.7 g/t to produce 200 000 oz of gold. The oxide circuit was based on the use of the Kori Kollo plant and the difference with mixed ore was that the oxide circuit would treat flotation tailings rather than ore. This circuit has a leach capacity of 26 000 m3 and residence time of 24 hrs The main feature of the upgraded mixed ore plant was the addition of a flotation circuit to produce a concentrate which would be reground and treated in a separate leach and elution circuit. Ore is crushed in a gyratory crusher and the comminution circuit uses a conventional SABC producing a product with a P80 of 150 microns. The throughput of 580 tph of oxide ore and 500tph of mixed ore was set to match the mills from Kori Kollo, with the addition of the pebble crusher to accommodate the more competent Sukari ore. The flotation circuit comprises a single rougher circuit to maximize recovery. The concentrate is thickened prior to regrinding which is carried out in a tower mill and two SMD mills operating in series. The final product, with a P80 of 12 microns, from the regrind circuit is leached in a CIL circuit with a total capacity of 2 550 m3. Gold is recovered through a conventional pressure Zadra circuit. Tailings from both circuits report to separate tailings thickeners and are pumped to a tailings storage facility. The circuit is designed to maximize the recovery of water. The project lies in one of the driest deserts in the world and a feature of the operation is the use of sea water from the Red Sea. This water is pumped 25 km from the coast.

Jan 1, 2009

By N. Hamlef

In this study, the effects of heat treatment on phase formation and surface morphology of the Cr-Pt coated system are investigated using X-ray diffraction and electron microscopy techniques. The CrPt andCr4Pt (Cr3Pt - A15 type) phases were formed after heat treatment of the coated samples. Heat treating at 1000°C renders a distinct island coating morphology that is non-continuous in nature. A diffusional model is proposed for this coated system with regards to the surface morphology formation after heat treatment.

Jan 1, 2014

Publications of the IMM These two titles have just been published as part of the popular series of Special Reference Lists being issued by the Institution of Mining and Metalurgy, 44 Portland Place, London WIN BR, England.

Jan 1, 1991

1. Book reviews Phosphate rock, a bibliography of world resources. London, Mining Journal Books Limited, 1984. £10 (surface mail), £12.25 (airmail). Reviewer: P.Le. Grubb Ok Tedi, by William S. Pintz. London, Mining Journal Books Limited, 1984. 206 pp. £19 (surface mail), £22.25 (airmail). Reviewer: R.P. Plewman 2. Publications of the Canadian Mineral Policy Sector Lime by D.H. Stonehouse. 5 pp. Phosphates by G.S. Barry. 9 pp. Statistical summary of the mineral industry in Canada. 77 tables. Talc by M. Prud&apos;homme. 6 pp. Zirconium by M.A. Boucher. 6 pp. Cement by D.H. Stonehouse. 13 pp. Gypsum and anhydrite by D.H. Stonehouse. 7 pp. Regional review by T.M. Buch. 12pp. SaltbyG.S. Barry. 7pp. Silicon, ferrosilicon and silicon carbide by D.G. Law-West. 6pp. SulphurbyB.W. Boyd. 9pp. Mineral Report 31. Canadian Minerals Yearbook 1981. Available from the above address at $40.75 per copy. 3. Mintek reports Report M18D The recovery of pyrite and gold from acid-leach residues from the Merriespruit Gold Mine. (First issued Feb. 1982; reissued Mar. 1984). Report M2OD The separation of ore from Cooke into high- and lowgrade fractions. (First issued Feb. 1982; reissued Mar. 1984). Report M33D Explanatory tests on the reduction of the sulphur content of sponge iron. (First issued Apr. 1982; reissued Mar. 1984). Report M43D Beneficiation tests on andalusite-bearing shales from a farm near Thabazimbi. (First issued Aug. 1982; reissuedMar. 1984). Report M129 The determination of tin, niobium, and tantalum in pegmatite by X-ray-fluorescence spectrometry. ReportM131 The determination of copper and nickel in iron- and chromium-bearing materials by a pressed-powder technique and X-ray-fluorescence spectrometry. Report M135 The installation of a 100 kV A plasma furnace at Mintek. The selection and installation of a 100 kV A a.c. plasma Report M136 The determination of gold in activated charcoal by use of a loose-powder technique and X-ray-fluorescence spectrometry. Report M140 The effect of physical and chemical factors on the corrosivity of a synthetic mine water.

Jan 1, 1984

By L. A. Jordan, D. van Vuuren

A two-dimensional finite difference model has been developed to describe the reduction of kilogram quantities of dehydrated phosphogypsum. The model’s scope has been limited to focus on the heat transfer and reactions that occur within a mass of material contained in a vessel inside a furnace rather than also including the effects of heat transfer to the vessel. Changes in the heat transfer properties (k, ρ, and Cp) are incorporated as the composition of the mass changes as the chemical reactions progress. The model is validated against experimental data, with samples heated to 1000°C at 3°C min−1 while purging with nitrogen gas. A sensitivity analysis of model predictions to the pre-exponential factor of the reaction rate constant of the main chemical reaction and the thermal conductivity of the powder bed indicated that, at the envisaged process conditions, the behaviour of the system depends much more on the rate of heat transfer than on the rate of the chemical reaction. The model demonstrated a significant increase in accuracy when the thermal conductivity was modelled to increase linearly with temperature compared to assuming a constant value.

Oct 1, 2022

By B. Friedrich, A. Birich

Gold has been a metal of special importance for mankind for several thousand years. Its outstanding chemical resistance is an important property of this noble metal, but becomes a disadvantage when it comes to gold recovery. The established processes are based on highly aggressive and toxic reagents. Different alternative leaching reagents with a significantly lower toxicity proved to be promising alternatives in the last decades. Major research activities in this field focused on gold ores, so that leaching of secondary resources were not described sufficiently. Based on literature research and extensive experimental investigations, a reagent assessment was conducted for hydrometallurgical gold recovery from electronic waste. It was found that besides thiourea and halides, thiosulfate in particular represents an alternative of major relevance. A variety of different electronic waste (e-waste) specimens were investigated to identify suitable leaching conditions. As a result, an almost complete and selective gold recovery in less than 48 hours from different electronic waste types and components was achieved by thiosulfate leaching. Within the experiments conducted, it was found that the leaching behaviour of cyanide alternative lixiviants differ strongly from leaching of primary ores. Keywords: Gold leaching, cyanide alternative, thiosulfate, electronic waste

Jan 1, 2020

By M. C. Bekker, T. Govindasamy

The potential benefits of implementing the Last Planner System (LPS) on mining infrastructure projects were explored through two case studies in the South African mining industry. The first part of the study involved measurement of the impact of LPS through earned value techniques on secondary project data. The second part sought to establish the lean construction success factors leading to improvements in construction performance. This was done by means of a research questionnaire distributed to the project owner’s teams, contracted parties, and the LPS facilitators. The results revealed a positive correlation between LPS application and planned percentage complete. However, the performance achieved during the LPS pilot was not sustained. The success factors and benefits considered most evident in the case study pilot differed among the three stakeholder groups. The findings are expected to guide construction stakeholders to better define performance measures and focus on factors required to make LPS implementation more effective in the South African mining sector.

Feb 12, 2024

By E. M. Sacris

The semi-autogenous grinding mill is the bottleneck whenever treating hard and finely fragmented ore at Benguet Corporation&apos;s Kaline Concentrator. Low milling rates result from very high and fluctuating mill power draw. Attempts to use a mill horsepower control loop to regulate feed rate were unsuccessful because of operational upsets caused by fluctuations in feed rate on downstream operations. The objective of the computer control was to maximize tonnage throughput by stabilizing the power draw at a high but safe level without upsetting subsequent operations. The semi-autogenous mill is operated in closed circuit with a stationary screen. Instrumentation consists of a feed weightometer, a power transmitter to measure mill load, a headwater flowmeter and an ultrasonic level sensor to measure the mill discharge sump level. A 64 k-byte FOX-3 Foxboro computer processes field data from various sensors and manipulates the input control variables. These variables are the fresh feed rate and the headwater flowrate. Feed rate is controlled through a supervisor-type computer program aimed at maximizing and stabilizing power draw. The control scheme was according to how the operators responded during an operator-directed automatic control mode. Mill dilution is similarly controlled. Results achieved reflect a 3% increase in tonnage milled because of the reduction in control variability that ensued.

Jan 1, 1987

By J. A. Theron

"This paper provides guidelines on performing mass and energy balance modelling involving coal and coal derivatives. Usually, the inputs to a pyrometallurgical process would be specified in terms of elements and compounds. Reliable thermochemical data is more widely available for species involving uniquely defined, relatively smaller molecules. However, in the case of coal, the molecules are extremely large and not uniquely defined. Consequently, modelling processes involving coal and its derivatives have several potential pitfalls. These are outlined in the present paper. The main findings are as follows:•,Coal proximate analysis should not be regarded as absolute; it could vary with several parameters, including heating rate •,For modelling, the use of ultimate analyses should be considered a preferable option to proximate analyses, where, ‘fixed carbon’ and ‘volatiles’ are not defined in terms of chemical composition •,Significant errors could be made if the larger molecules are neglected during calculation of the calorific value (CV) of coal gas (the gas liberated when coal is heated in the absence of oxygen) •,For elemental analyses, the oxygen content (which is calculated by balance) should be checked to ensure it is within the expected range •,For representation of sulphur in coal, double-counting due to SO3 in the ash analysis should be avoided •,Potentially, oxygen in coal could be represented as O2, H2O, CO, or CO2; however, use of some of these species without considering the experimentally determined gross CV results in significant errors in the energy balance. If coal enthalpy is calculated from elemental analyses without correction, representation of coal oxygen as H2O(l) gives reasonable accuracy (up to 6.9% error for a set of South African coals). Coal volatiles could be represented by a complex mixture of compounds, even using different oxygen-containing species than the abovementioned four, provided the enthalpy is corrected •,It is recommended that an ‘enthalpy correction value’ is incorporated in energy balances involving combustion, devolatilization, or conversion of coal and coal derivatives, e.g. coke, char, or tar. That would imply that proximate analysis, elemental analysis, as well as the gross CV would be required for all solid or liquid coal-derived substances being modelled. No other correction due to the form of carbon being different than graphite should be used, as that would imply doublecounting some effects."

Jan 1, 2014

By T. Szendrei and S. Tose

Historical approaches to the problem of flyrock based on correlation studies and regression analysis, including artificial neural networks and similar techniques, are inherently incapable of addressing two core issues – root causes of flyrock and projection velocity. A further shortcoming of correlation techniques is that they give no information on the influence of rock size and shape on the flight distance. The scaled depth of burial model for crater blasting in the collar zone and bench face does not specifically address the question of flyrock velocity. A third approach, based on flight trajectory calculations, often neglects the very significant effects of air resistance on the trajectory. Some trajectory models incorporate air resistance but use an implausible fragment velocity model that cannot propel sizeable rocks to distances much beyond 150 m. Nonetheless, trajectory calculation incorporating the effects of air drag affords the most promising approach to the prediction of flyrock range. A unique and insightful feature of the proposed realistic flight modelling is that it collapses all suspected causes of flyrock, many of which are not well understood, to just a single parameter – the launch velocity. This indicates that the root causes of flyrock lie in the mechanisms of momentum transfer to broken rock and suggests new avenues of study.

Dec 13, 2022

By I. Cerny, M. Vanek, J. Hubácek

"SWOT analyses and the closely related TOWS matrix are frequent starting points for an organization to develop its strategy. The paper deals with the evaluation of the TOWS matrix and presents three novel approaches to evaluate the different factors of the TOWS matrix, namely (1) approach to evaluate the factors with identical weights; (2) approach to evaluate factors with their weights determined within the different quadrants of the TOWS matrix; and (3) approach to evaluate factors with weights determined within the whole TOWS matrix. The third approach has two variants. The proposed approaches to evaluate the TOWS matrix were tested on a SWOT analysis of a significant mining company in the Czech Republic. The results imply that the strategy W-T (weaknesses-threats) is recommended in three cases, while the strategy S-T (strengths-threats) is recommended once. The paper may be valuable for managers responsible for strategic planning.IntroductionThe process of human needs gratification has been closely connected with raw material resources of the planet. In the contemporary socio-economic conditions, the task of the mining company managers, apart from extracting mineral resources, is to meet the owners' intents.The managerial work itself becomes very complex. In mining companies in particular, the complexity is augmented by the characteristics of the business. Undoubtedly, the key factor is that mineral resources cannot be renewed or relocated. Stojanovi (2013) characterizes mining projects as involving great investments in finance and time, as well as consecutive decisions and a 'complex mosaic of numerous unknown factors that affect the value of the project'. He adds that mining projects are typified by a 'number of geological, technological, technical, economic, environmental, social, and financial risks' (Stojanovi , 2013).Inter alia, the managerial work may also be intese due to the dynamic internal and external conditions for the existence of any company (Vane? k, 2014). This tallies with Peter Drucker’s prediction in 1969; that the times at the turn of the millennium could be expected to be turbulent (Drucker, 1969)."

Dec 1, 2018

By N. V. Moraka

In dealing with transformational aspects, the South African Constitution aspires for a balance between attempts to broadly represent the country’s demographics in the way in which organizations are structured and the need to maintain the necessary skills to ensure continual retention of skills for optimum and efficient organizational performance. Through the Mining Charter, government aimed to redress gender and racial imbalances in the mining industry as part of transforming the demographic representation of mining companies to include black people, women, and people living with disabilities in all job levels up to top management. While the Constitution calls for an appropriate balance between demographic representation and competency, this aspiration for mining poses challenges for companies due to the proficient and competent skills needed in this industry. To this end, the South African mining industry has been subjected to substantial criticism from government regarding the slow progress of transformation. The mining industry justifies its slow pace of transformation by pointing at inconsistent, varying legislation and definitions governing transformation, limited skills available from historically disadvantaged groups, and cautioning not to compromise the sustainability of mining companies by marginalizing white males and white youth with the objective of addressing racial imbalances. This lack of understanding between industry and the government has led to considerable confusion regarding the accountability of stakeholders in transforming the industry. This article presents the perspectives of ten mining executives on transformation in the South African mining industry. The theoretical description of transformation, as well as other mining stakeholders’ interpretations of transformation. is presented. Qualitative data from interviews with mining executives demonstrates their understanding of transformation through rich descriptions, interpretations, and implications in their contexts. The findings demonstrate that transformation in the mining industry is not simply about race and gender, but about cultural change, a change in mind-sets, embracing diversity, equalizing rights and opportunities, and attaining social justice. Moreover, transformation is clearly a gradual process. The article concludes with a recommendation for the definition of transformation to be corroborated with the views of mining executives and that of the Constitution of South Africa. This will create an overarching, simplified definition of transformation that can be accepted and interpreted by all stakeholders.

Jan 1, 2016

By M J. Daniel

The diamond industry is no newcomer to High Pressure Grinding Rolls (HPGR) as it has used the technology for more than 20 years, predominantly in secondary crushing and recrushing roles. In fact it could be argued that the diamond industry has led the way for the wider minerals industry to consider its application. In existing conventional secondary cone crushing applications, large valuable diamonds are" won" through meticulously managing the recovery process within defined particle size ranges. Conventional crushers operate with relatively large closed side settings, but have the potential to damage diamonds by making direct contact with the sides of the crusher. Cone crushers also result in steep product size distributions that run a high risk of losing many of the smaller, unliberated but more abundant diamonds from the rock. This current comminution paradigm of particle size reduction management results in recrushing processing applications or plants where HPGRs are often used.

Jan 1, 2010

The Skorpion process comprises three processing steps-atmospheric leaching in sulfuric acid, zinc solvent extraction and electrowinning to produce special high grade zinc. The major mode of impurity transfer was attributed to crud runs in the solvent extraction circuit. Crud may be described as a heterogeneous, partly inorganic, partly organic mass of material which accumulates predominantly at the interface between organic and aqueous solutions. The paper describes the root causes of the crud formation in the solvent extraction circuit and optimization strategies which are being followed to prevent impurity excursions in electrowinning. Keywords: zinc oxide, solvent extraction, crud formation, colloidal silica.

Jan 1, 2007

By P. O. Akinseye, F. T. Cawood

Mineral royalties are one of the oldest forms of mining taxation, and were initially introduced to extract economic rents from mining. Over time, the royalty regime has become more complex as it was identified as an important policy instrument that can achieve more multi-faceted outcomes. Such a multi-tiered approach in the use of the royalty instrument is also the case with South Africa. With South Africa’s new mineral royalty regime now in place for ten years, it is perhaps time to assess its impact and effectiveness. To carry out this assessment, an econometric evaluative study was undertaken using four major commodities in South Africa, namely gold, platinum, iron ore, and coal. The study explored five different policy options for government to consider and tested them to determine the most favourable one that will realize the regime’s policy objectives. After the assessment, two major options stood out. Hence, this paper seeks to highlight which of the two options is the most favourable for consideration by policymakers. Based on that study, we find that the current structure is effective, but also recommend that the factors in the formula for refined minerals be ‘modified’ to reduce the capped profitability ratio from the current 60% to 30% and the maximum royalty rate for refined minerals from 5% to 3%. The minimum rate of 0.5% during times of depressed mineral prices and no or low profitability will not be affected.

Dec 1, 2021

By N. F. Mashinini

Optimization of current control systems, proper maintenance and efficient training of personnel are recommendations made to control the amount of dust that underground employees are exposed to on a daily basis in the coal mining industry. This dissertation forms as part of Sasol Mining?s commitment to protect the health and safety of their employees by suppressing and controlling dust at their mines. This study aims to understand the relationship among mining processes, exposure to dust and dust suppression control measures. The research phase of the project was done at the Sasol Mining Secunda complex where underground visits were undertaken to investigate current control systems and also new systems that are being implemented by Sasol Mining. This work was important because it helped determine the sources of dust underground and also to identify the shortcomings of current control systems and to test the efficiencies of the new systems implemented at Sasol Mining. The most important result of the research work was the identification of which underground operators were exposed the most to dust as this assisted in designing a dust suppression system for the areas where these operators worked. The main conclusions of this study are that the current control systems are sufficient for controlling dust and ensuring dust compliance if they are used efficiently and maintained properly.

Jan 1, 2008

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluoridesl.2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02?SiO2) with the ammonium acid fluoride (NH4F?XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo-dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012