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By H. O. McDonald

The Bureau of Mines has demonstrated a hydrometallurgical method to separate chromium from other metals in a variety of surface-finishing wastes by precipitation with benzoate ion. The resulting chromium salt may then be converted to the hydroxide, and the benzoate may be recycled. Chromium recoveries of 92 to 100 pct are obtained.

Jan 1, 1983

By P. Coleman, J. C. Kerkering, S. Iverson

Fault tree analysis is a systematic safety analysis tool that proceeds deductively from the occurrence of an undesired event (accident) to the identification of the root causes of that event. One recurring mine safety problem—a dozer falling into a void over a drawpoint on a coal surge pile—was analyzed using available, inexpensive fault tree programs on a personal computer. The analysis identified basic and intermediate events that led to the burial of the dozer and graphically depicted the interrelationship between these various subordinate events as well as the various chain of events leading up to the primary event. A sensitivity analysis on these probabilities showed which events had the greatest influence on dozer burial in a coal surge pile.

By Russell C. Frith, David C. Oyler, Dolinar Dennis R., Christopher Mark

Unusual circumstances may require that a longwall retreat into or through a previously driven room. The operation can be completed successfully, but there have been a number of spectacular failures. To help determine what factors contribute to such failures, a comprehensive international database of 131 case histories has been compiled. The cases include six failures where major rock falls occurred in front of the shields, and seven even more serious failures involving major overburden weighting. The case studies suggest two types of room failure mechanism. The first is a roof fall type failure caused by loading of the immediate roof at the face as the fender or remnant longwall panel narrows. The second is an overburden weighting type failure caused by the inability of the roof to bridge the recovery room and face area, and affecting rockwell above the immediate roof. The data indicate that the roof fall type of failure is less likely when intensive roof reinforcement (bolts, cables and trusses) is employed together with higher-capacity shields. The overburden weighting failures, in contrast, occurred when the roof was weak and little standing support was used. Weighting failures were not greatly affected by the density of roof reinforcement. In one of the overburden weighting cases, in a Pittsburgh coal bed mine, stress cell, convergence, bolt load and extensometer data have been used to analyze the failure in detail. Key words: coal mining, ground control, longwall, recovery room.

By K. O. Bennington

The thermodynamic properties of synthetic acmite, NaFe3+Si206, were determined by the Bureau of Mines. The enthalpy of formation was determined by hydrofluoric acid solution calorimetry. The values of the standard enthalpy of formation at 298.15 K, ?Hf°298.15, from the elements and from the oxides, ?H°298.15, are ?Hf°298.15 = -615.87 ±0.71 kcal/mole, ?H°298.15 (from oxides) = -32.08 ±0.53 kcal/mole. Various experimental data were combined with other data from the literature to calculate all the related thermodynamic properties in the range of 298 to 1,263 K. The standard Gibbs energy of formation is ?Gf°298.15 = -575.8 kcal/mole.

Jan 1, 1981

By T. Kessler

Spark-source mass spectrometry has been used to determine the amounts of minor and trace elements in coal particles of various sizes, including the respirable range (<5 microns). Fifty-six elements ranging in concentration from 0.1 ppm wt to 5,000 ppm wt have been determined. The investigation of coal and coal ash has shown that the organic material in coal does not interfere with the spark-source determination of the various elements.

Jan 1, 1971

By J. E. Chilton

Underground miners may be exposed to hazardous quantities of toxic gases, such as carbon monoxide (CO), generated from mine fires or explosions. Every underground miner is required to carry a filter self-rescuer (FSR), which when operated will remove CO from the miner&apos;s breathing air. In addition, every underground miner must have a self-contained self-rescuer (SCSR) near the worksite that will supply breathing oxygen. In many situations, miners do not know when to don either rescuer since they do not know if there is a fire in the mine, nor do they carry instrumentation necessary for the detection of the toxic, colorless, and odorless fire product CO. If each miner carried a personal CO alarm, which would respond to high concentrations of CO, the miner would then be alerted when to don either the FSR or SCSR and exit the mine. A prototype personal miner&apos;s CO alarm called PEMCOAL was developed by the U.S. Bureau of Mines. The PEMCOAL unit is small enough to be carried on a miner&apos;s belt, has a flash lamp visual alarm, requires no calibration for use, and uses a chemical sensor that changes color by reaction with trace quantities of CO. The chemical sensor was tested at concentrations of CO from 10 to 1,000 ppm, at temperatures from 5° to 40° C, and with several potential mine gas interferents. The PEMCOAL alarm times were sufficiently fast to warn miners before they are exposed to hazardous quantities of CO.

Jan 1, 1989

By Fred N. Kissell

Methane concentration peaks were measured by the Bureau of Mines at coal mine working faces during entry development. The statistical distribution of peaks was found to be normal or log normal depending on how well the methane was being mixed into the ventilation airstream. A normal distribution indicated good mixing, whereas a log-normal distribution indicated that mixing was poor. In addition, the "highest" peaks over selected intervals were found to fit a type I extreme-value distribution, a result similar to that obtained while mining longwall faces.

Jan 1, 1974

By L. J. Douglas, A. G. Kim

Methane and other hydrocarbon gases, byproducts of coalification, are emitted from coal at widely varying rates and often present ventilation problems during mining. The air in some coal mines apparently contains no methane. To determine if coals from mines which had no history of detectable gas emission contained adsorbed methane, samples of coal at the shaft bottom and at an active face were obtained and placed in sealed metal cylinders. The atmosphere around the coal was sampled and analysed by gas chromatography. Methane, ethane, ethylene, propane, propylene, and butane were found to have been desorbed from these coals. Hydrogen and helium were also detected. An estimate of the amount of residual gas per ton of coal indicated that coal samples from the active face generally contained more adsorbed gas than coal samples obtained from the shaft bottom, although in both instances the total amount of gas was relatively small.

Jan 1, 1973

By Cecil E. Lester

Since the advent of coal mining, the minimal lighting in the under¬ground working place has been an obstacle to the safe and efficient performance of the miner&apos;s many tasks. Compounding this problem is the fact that the machines being operated in the working place are so large that the vertical and horizontal clearances around the machinery are severely limited. Consequently, in these poorly lighted and congested working places, the machine operator is unable to utilize his peripheral vision. He cannot see hazards as they develop and, too often, cannot react in time to avoid serious injury or death to himself or his fellow miners. The greatest hazard to miners inby the last open crosscut is from falls of roof which are often preceded by warning signs such as falling rock fragments, roof supports taking weight, or a sudden reduction in the height of the working place. These warning signs often go undectected because the machine operator&apos;s attention is focused on the small circle of light emitted from his cap lamp. Congress recognized the illumination deficiencies, and, in the Federal Coal Mine Health and Safety Act of 1969, charged the Secretary of the Interior with the authority and responsibility for development and promulgation of minimum standards for illuminating working places in coal mines. These standards have been developed and, as stated in the April 1, 1976 Notice, Federal Register, Volume 41, No. 64, will be promulgated on October 1, 1976, as mandatory regulations under Section 75.1719, Title 30, Code of Federal Regulations. The regulations require that the designated surfaces within the miner&apos;s normal field of vision be illuminated to 0.06 foot-lamberts while self¬propelled mining equipment is being operated in the working places. The term "working place" is defined in the Act as "the area of a coal mine inby the last open crosscut".

Jan 1, 1976

By E. G. Davis

The flash reduction of fine iron ore in a dilute-phase system was investigated at 500° to 900° C within a heated stainless steel tubular coil. Alabama brown iron ore and Mesabi semitaconite ore were fed into the coil concurrently with reducing gases of hydrogen and reformed natural gas, so that the velocity of the gas at the reaction temperature was sufficient to entrain and pneumatically transport the solids through the coil. Reduction is very rapid with retention time of the ore in the coil varying from 4 to 15 seconds. Variables affecting reduction are temperature, ore feed rate, and gas flow or velocity. Results of the studies show that a partially reduced product (10-to 25-percent reduction) can be made which, on subsequent magnetic concentration, yields a concentrate containing 64 to 70 percent iron with a 90-to 94-percent iron recovery. Maximum reduction of 77 percent was obtained when hydrogen was used in a four-stage reduction test to yield a product containing 61 percent metallic iron.

Jan 1, 1972

By Thomas M. Barczak

Longwall roof behavior is characterized by strata displacements in both the face-to-waste (horizontal) and roof-to-f1oor (vertical) direc-tions. The roof support structure provides resistance to this motion by translation of these displacements into vertical and horizontal support loading. Observations indicate that the shield reacts with both a vertical and horizontal force to uniaxial convergence (displacement). However, there are different magnitudes depending on whether the displacement is vertical or horizontal. This makes it possible to use supports as monitors of strata activity and loading. The Bureau of Mines examined this behavior using a linear elastic model of the support structure with two degrees of freedom. Vertical and horizontal load reactions were related to associated displacement actions of the strata. This was done by determining the stiffness of the shield under controlled vertical and horizontal displacement motions in the Bureau&apos;s mine roof simulator. This report provides example predictions of strata convergence and isolation of horizontal support loading due to vertical roof convergence using the linear elastic shield model. The report also examines efforts to determine strata behavior by direct measurement of support displacement.

Jan 1, 1987

By Maria I. De Rosa

Table 10 and figure 4 show the number of fires and fire injuries occurring at the surface of underground coal mines by state during 199&1999. Table 10 also shows by state the risk rate, employees&apos; working hours, and lost workdays. A total of 65 fires occurred in 10 states. Thirteen of those fires caused 12 injuries and 1 fatality (the yearly average was 6.5 fires and 1.2 injuries). Four fues and one fire injury involved con- tractors. The Ewhr value was 97 x l O6 hr (Irr = 0.025); the LWD value was 6,206. Pennsylvania had the most fues (20 fues and 5 injuries), followed by West Virginia (1 6 fires and 1 fatality) and Kentucky (1 5 fires and 3 injuries). Among these states, Pennsylvania had the highest injury risk rate value (Irr - 0.095). Table 1 1, partly illustrated in figure 5, shows by time period the number of fires, fire injuries, and fire fatalities; risk rates; employees&apos; working hours; and lost workdays. The number of fires and fire injuries show a decrease followed by an increase during the five time periods, accompanied by a decline in employees&apos; working hours throughout the periods (see table 11 and figure 5). The Irr values follow patterns similar to those shown by the injury values. Tables 12- 17 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 6 shows the major variables during 199&1999. Table 18 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By C. J. Walker

The ever-increasing use off natural underground formations for storing natural gas has focused attention on the behavior of such storage formations under varying operating conditions. The need for a means of evaluating in¬dividual wells and groups of wells has become manifest. It is essential that industry and others be able to determine the rates of flow that can be ex¬pected from a given well or group of wells under different conditions and to ascertain whether certain wells are deteriorating. Such questions need more exact answers now than ever before because of the vital role underground gas storage plays in the industrial and domestic consumption of natural gas. The Bureau of Mines--in cooperation with the American Gas Association--has main¬tained an active interest in gas-well testing because of the implications of such test procedures on the consumption and efficient production of natural gas. A basis for testing gas wells was provided by the back-pressure method of Rawlins and Schellhardt (12).4/ They showed that for normal gas wells there is a consistent relationship between rates of delivery of gas and corresponding pressures when the formation pressures are used as the basis of interpretation, The equation for this relationship is as follows: Q = C (Pf2 - Ps2)n where; Q = rate of flow, generally expressed in cubic feet per 24 hours. C = a coefficient.

Jan 1, 1960

By D. B. Dow

"Natural gas-gasoline is made by collecting in the liquid state the condensable hydrocarbon vapors that exist in different natural gases in varying amounts. In the richer type of natural gas the gasoline is generally recovered by compression and cooling. If exceedingly high pressure or low temperature is used, there is dissolved in the gasoline a large amount of very volatile material, which evaporates rapidly at atmospheric temperature and pressure.In the leaner type of natural gas, the gasoline vapors are selectively absorbed from the permanent gases by passing the natural gas through an absorbing oil. The gasoline is recovered by distilling the saturated oil, and as compared with ""compression"" gasoline is of high Baume' gravity and low vapor pressure. Before a volatile gasoline can be transported in tank cars, it is necessary to decrease its volatility in order to lessen the risk of fire or explosion, as well as to prevent excessive evaporation in transit. This can be accomplished either by weathering the gasoline, or by blending it with a more stable material, naphtha being commonly used in the weathering process the more volatile portions of the gasoline are allowed to evaporate and the losses in volume are very large, therefore, blending is preferable, wherever possible.It is very difficult, however, to produce by blending, in gasoline plants, a motor fuel which is equal to straight-run refinery gasoline. In order to make a blended motor fuel of a grade equal to straight-run gasoline, only a small percentage of natural gas-gasoline can be blended with the naphtha, consequently it is customary to blend the gasoline with only enough naphtha to enable It to be shipped to an oil refinery when the material is again blended to form a finished motor fuel."

Sep 1, 1921

By William M. Nabors

As a part of a program to promote conservation and efficient utilization of petroleum resources, Bureau of Mines engineers are studying secondary oil-recovery projects in the United States. Published reports that set forth the pertinent facts of these operations help others to profit by the experience gained. This report presents the results of a study of secondary-recovery methods used in Kentucky by the Cumberland Petroleum Co. on its L. C. Bailey lease, Oil Springs pool, Magoffin County, Ky. This is believed to be the first water-flooding project in eastern Kentucky (fig. 1).

Jan 1, 1958

By Paul B. Harder

Round Mountain Gold (RMG) in central Nevada, reports that over a nine-year period and a million operating hours, its fleet of 150-ton and 190-ton haul trucks has averaged better than 93% availability, with some of the trucks approaching 70,000 operating hours. Repair costs have been far below industry averages. Mine operations manager Pete Kesl credits the high availability and low repair costs to a succession of Product Support Agreements between RMG and Caterpillar dealer Cashman Equipment. He adds that good equipment and a high level of trust and co­operation between all parties to these agreements have been essential to their success at Round Mountain.

Jan 1, 1998

By R. E. Lindstrom, D. J. Bauer

Studies were conducted to assess the potential of naphthenic acid as a fractional extractant for rare- earth mixtures and yttrium in sulfate solution . Naphthenic acid was an effective extractant , and separation factors were favorable in the presence of aqueous phase chelating agents . Addition of EDTA to the naphthenic acid extraction system resulted in average separation factors of 2.2 between adjacent yttrium- group elements , whereas DTPA resulted in average separation factors of 3.5 between adjacent cerium- group elements . EDTA was of value in separating yttrium from the rare- earth elements . Thorium and uranium were preferentially extracted over the trivalent rare- earth elements by naphthenic acid .

Jan 1, 1964

By E. D. Eastman

The recent determination by Eckman and Rossini of the heat of formation of sulphur dioxide appears to be of much greater accuracy than any previous measurement . The value obtained by them , 70,940 cal . , is in good agreement with that of Thomsen ( 71,080 ) , but differs by about 1,700 calories from Berthelot's result ( 69,260 ) , and by 1,940 calories from the provisional figure ( 69,000 ) adopted by Lewis and Randall in their studies of the free energies of the sulphur compounds . This large discrepancy suggested the desirability of a recalculation of the free energy of sulphur dioxide . In addition it is now possiblt to fix the specific heat of S₂ gas with greater certainty than at the time of the original calculations . These two changes are incorporated in the recalculations described below , and directly affect the values of AH , and the Ar terms in the free energy equation . In the determination of the integration constant of the latter equation , the free energies and specific heats of water vapor and the oxides of carbon are required as auxiliary data . In this work these are based , with certain exceptions , upon the equations previously deduced , which differ appreciably from the corresponding equations of Lewis and Randall . 56 · The principal equilibria employed below , and the plan of calculation , remain the same as in the calculations of Lewis and Randall . Before beginning this revision a search of the literature was made , extending to August , 1930 , for studies of additional equilibria . Only one reaction was found that gives promise of increased accuracy . This is the equilibrium of sulphur dioxide with copper , cuprous oxide , and cuprous sulphide . In this case , however , certain of the subsidiary data are lacking , and until they become available , the existing studies of the equilibrium in this system can not be successfully utilized . The changes in the numerical data mentioned above , especially in the thermochemical constants , are therefore solely responsible for the rather significant differences of the revised from the original values of the free energy .

Apr 1, 1931

By Edward L. McHugh, Charles Sabine, Louis J. Denes, Jami M. Girard, Peter Metes

The Spokane Research Laboratory, National Institute for Occupational Safety and Health, is investigating various remote sensing technologies as possible tools to detect, monitor, and mitigate hazardous situations in surface mines that could lead to catastrophic slope failure. Promising technologies include a field-portable spectro-polarimetric imager and a stationary interferometric radar device. Field tests were conducted of a prototype visible and near-infrared spectro-polarimetric imager (SPI) built at the Carnegie Mellon Research Institute. The SPI employs anacousto-optical tunable filter (AOTF) to control wavelength, a phase retarder to measure polarization signatures, and a digital camera and computer to capture data. Images obtained at the Mountain Pass and Castle Mountain mines in southeastern California showed that the instrument is capable of obtaining hyperspectral images of highwalls, outcrops, hand samples and drill core in the field. We have retrieved spectra from Mountain Pass images that closely match those of bastnaesite and have had some success in classifying images. Although radio frequency noise in the data limited spectral classification of imagery, we project that careful alignment of the AOTF should minimize the noise and greatly improve classification.

By Paul T. Allsman

THIS CHAPTER reviews the highlights of developments in mining technology during 1956 and presents a special report on the design of mine openings in stable ground. This special report is presented each year in an endeavor to stimulate use of the scientific approach to the solution of problems related to mining technology. Assuming that the literature on mining technology reflects trends in mining, it appears that two areas of activity were given most attention in 1956. One was research on mining technology,4 and the other was improvement of transportation, particularly trackless transportation, both at surface and underground mines.

Jan 1, 1958