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By P. L. Woolf, J. P. Morris, E. Foerster, G. R. Zellars

Measurements of vapor pressure can be used to determine the thermodynamic activities of the components of metallic solutions . The determination of activity by this method requires accurate values for the vapor pressure of the pure component and for its partial pressure above the alloy solution . This investigation was conducted to measure the vapor pressure of liquid manganese for use in future studies of the activity of manganese in various liquid alloys . In related investigations in the Bureau's Pyrometallurgy Laboratory , vapor pressures of copper , iron and nickel have been measured and activit 4 5 6 have been determined in the iron- copper and iron- nickel systems . Difficulties were experienced with manganese which were not encountered in the previous investigations . Manganese oxidizes readily and greater care was needed to maintain an oxygen- and moisture - free atmosphere in the furnace . In addition , liquid manganese wet the refractories and there was a tendency to foam and splash on introduction of the carrier gas . Because of these difficulties several variations in the experimental procedure were studied . These were first tested with silver which has a vapor pressure of the same order of magnitude as manganese but is relatively inert at high temperatures . Although no significant changes in the original procedure resulted from this work, considerable data were obtained for silver and have been included in this report . Bauer and BBrruunnnneerr7/ have reported the only extensive investigation of the vapor pressure of liquid manganese . However , their results are not consistent with the data obtained by McCabe and Hudson for solid manganese . Measurements of the vapor pressure of silver have been reported by McCabe and Birchenal1,2/ Schadel and Birchenall , 10/ Harteck , 11 / Fischer , 12/ and von Wartenberg.13 / Generally , these investigators conducted their measurements at lower temperatures than were used in this study .

Jul 1, 1960

By A. J. Forney

This report summarizes the findings of methods of treating caking coals in a fluid bed to destroy their caking properties. In batch tests it was found that several coals, including those with a free-swelling index greater than 8, could be decaed at temperatures from 400° to 425° C with a fluidizing gas composed of inert gas or steam containing 0.2 percent oxygen and a minimum residence LS,-;,' of 5 minutes. When treatment decreased the free-swelling index from about 8 to 1-1/2 or lower, the resulting treated coal was noncaking. In a continuous unit with continuous feed and discharge of coal, slightly more severe conditions were required to decake the coal. For 18- to 100-mesh coal a temperature of 430° to 440° C and an oxygen-to coal ratio of 0.4 cubic foot of oxygen per pound of coal feed was necessary. Finer mesh sizes required lower oxygen-to-coal ratios. In tests using air only as the fluidizing medium and treatment temperatures well below the softening range, the caking properties of 150- to 200-mesh coal were destroyed in 30 to 40 minutes of residence time at 200° C. Coarser sizes of 18 to 48, 48 to 100, and 100 to 150 mesh required longer residence time.

Jan 1, 1966

By Grace N. Broderick

U.S. supply and demand data for coal, by States and regions, were tabulated for the years 1960 and 1965. Estimates are provided of State-by-State quantitative data for the coal industry that can be integrated into State and regional energy balances by source, form, and consumer sectors, and used for estimates of interstate and interregional energy flows. The tables give an estimated total supply of coal available for consumption, and also report the distribution of the supply among the major consuming sectors (household and, commercial, industrial, transportation, and electricity generation). To enable comparison of coal data with those for other energy forms, tonnages were converted to British thermal units (Btu). Future energy analysis studies could be facilitated by changes in the categorization of information collected on the coal industry. The data shown are based primarily on Bureau of Mines source material.

Jan 1, 1969

By John B. Gayle

The suitability of fluid petroleum coke as a blending agent for producing metallurgical coke has been investigated using the Tuscaloosa and sole-heated experimental ovens. From the results of tests with three representative blends, it has been fond that additions of fluid petroleum coke effect the following changes: (1) Increase in size, resistance to shatter, and apparent specific gravity of cokes produced; (2) little or no change in coke hardness and stability or in the amount of breeze formed; (3) increased charge density; (4) modification of expansion characteristics of blends charged; and (5) decreased ash and increased sulfur contents of blends charged and cokes produced. Substitution of a calcined sample of fluid coke of greatly reduced sulfur content resulted in a coke of inferior physical properties. This effect indicates that additions of the calcined product should probably be limited and that other methods for producing a low sulfur fluid coke should be considered.

Jan 1, 1956

By G. S. Scott

[In the course of the investigation the Bureau of Mines is carrying on to determine the causes, behavior, and control of mine fires, the detection of incipient heating underground in the mines and above ground in refuse banks has received consideration. A report has been published5/ describing apparatus and tests made on anthracite to determine the amount and composition of the a oxidation products when normal dry air was passed through it at temperatures varrying from 100° to 350° C. These tests showed that the amount of evolved gases and their relative proportions varied with the temperature. From these results, graphs were prepared by which the temperature at which the coal was oxidized could be estimated thus giving a possible means of detecting incipient heating.]

Jan 1, 1938

By D. Harrington

Ventilation of underground workings consists of establishment of such control of air currents that the underground workers may work in safety, with maximum comfort and efficiency, mad without impairment of health; and that the mine openings may be made subject to such control of air flow as to remove from the workings at ordinary times harmful gases and dusts, and at time of emergency, such as fire or explosion, there may be maintained as much or as little air flow as may be desired covering portions of the mine or the mine in its entirety. Control of air flow is the keystone of any ventilating structure, and this very essential feature is obtainable only by the installation of mechanically operated fans, to ether with other ventilating devices such as doors, overcasts, regulators, etc. Every mine, large or shall, coal or metal, should from the outset be equipped with a fan. While much has been written about natural ventilation and many claims have been made that in specific mines there is sufficient natural al" flow, there are few if any mines, coal or metal, where natural ventilation supplies anything like adequately safe or healthful conditions for underground workers even at ordinary times; and at a time of mine fire or explosion the mines depending upon natural ventilation are practically helpless, and certainly are decidedly dangerous to those unfortunates forced to be in them.

Jan 1, 1933

By Michael D. Dunn

The Bureau of Mines evaluated a quartz schist formation within the Blue Joint Wilderness Study Area which was identified as having a "high potential" for copper-silver-cobalt-barium resources. Stratiform and remobilized copper occurs near, and bedded barite within, the study area. In addition, the black to gray Proterozoic quartz schist may correlate with the Yellowjacket Formation which contains cobalt-copper-gold-silver deposits at Blackbird, ID, about 30 miles to the south. Eighty soil and 43 rock samples collected across the quartz schist formation were analyzed for gold, silver, copper, cobalt, and barium. During the reconnaissance and sampling, particular attention was given to looking for malachite (copper carbonate) and erythrite (cobalt arsenate, also known as "cobalt bloom"). The sample analyses and geology in this localized area do not provide enough evidence to support the "high potential" designation for copper-silver-cobalt resources. Barium potential still appears high, however.

Jan 1, 1987

This Bureau of Mines report on underground mine communications addresses methods and equipment to meet the communication requirements of working sections and places of coal and metal-nonmetal mines. A review of the status of trapped miner detection is also presented.

Jan 1, 1977

By F. W. Brown, F. C. Gibson

"INTRODUCTION There is urgent need for a satisfactory permissible multiple-shot blasting unit capable of firing 10 detonators in series and safe for use in underground mining where a. gas-ignition hazard may exist.. As there is at present no entirely satisfactory permissible unit of either the battery or generator type, tile described capacitor-battery type has been developed. Consideration of the Bureau of Nines approval schedule pertaining to the generator and magne to-type units and of the electrical characteristics of the unit described in this report indicate that this unit should meet Bureau of Mines permissible requirements.This report gives a detailed description of the design and operation and results of tests to determine safety of operation in gassy atmospheres.DESIGN AND OPERATION OF UNITOperation of the vibrator-type multiple-shot blasting unit is based upon utilization of the discharge energy from a capacitor charged to a given. voltage and having capacitance adequate to store enough energy to initiate 10 detonators in series. The primary source of energy is a 4-volt cap lamp battery such as is carried for illumination on the person of underground workers in nearly all mines. As this battery is already available and is recharged daily it is considered to be a reliable and convenient source of energy for a blasting unit. Figure 1 is a schematic diagram of the circuit for an improved unit, and figures 2 and 3 are views of the experimental unit. The battery potential is applied through a radio-type synchronous vibrator (8) to an 8-volt center-tapped primary of a small transformer (9) having a high-voltage center-tapped secondary. The vibrator introduces an alternating low-voltage potential into the primary and mechanically produces full-wave, rectified, pulsating, direct current from the secondary. A buffing condenser (11) across the secondary gives the proper wave form for long vibrator life: a resistor (12) its in series with this condenser across the total secondary to protect the transformer in case of• failure .of this capacitor. A voltage divider (10) with an adjustable slider permits accurate adjustment of the potential applied to the high-capacity firing condenser (5)."

Oct 1, 1947

By S. M. Dar

The U.S. Bureau of Mines constructed a full-scale model of a 15-ft-wide coal mine entry to use in combination with finite-element analyses to investigate roof support systems and various types of roof bolts. The objective was to enhance understanding of the fundamental mechanics of the interaction between rock and supports and the relative integrity of bolted mine roof as a function of roof bolt type, length, spacing, and tension, and the basic characteristics of the roof strata. The laboratory test results, when correlated with computer simulations using fmite-element analysis and underground verification tests, should provide a basis for desigillng safer, more cost-effective roof control systems and help to establish guidelines for employing fully grouted resin and mechanically anchored bolting systems. The background for this research, the research approach, the methods and equipment employed, and the results are described in this report.

Jan 1, 1989

By Jr. Gabler

World resources of platinum-group metals appear ample for the foreseeable future; however, political and economic events in the last two decades have caused concern over the availability and reliability of an uninterrupted supply. Because of this concern, the U.S. Congress requested that the U.S. Bureau of Mines initiate a study of the flow of platinum-group metals in the economy that would delineate and quantify the production areas in which metal values are lost. As a result, the Bureau has developed a computerized commodity flow model for strategic and critical materials. Major attributes of this flow model are as follows: (1) it is generic and applicable to most commodities and (2) it can be updated as supply, demand, and/or production data change. The original model developed for cobalt, with slight modifications, was used to track the flow of platinum-group metals. This report follows the flow of platinum-group metals through their metallurgical, catalytic, and chemical applications and highlights areas in which significant losses occur because of downgrading, export, or disposal. The study indicates that materials containing about 63,426 kg of platinum-group metals were lost or could not be traced in 1989, representing about 63 pct of U.S. domestic consumption.

Jan 1, 1991

By L. H. Kalenowski

The metal lithium, its alloys, and its salts are becoming Increasingly important as industrial materials. Lithium metal, because of its great affinity for elements, such as nitrogen, hydrogen, oxygen, sulfur, phosphorus, carbon, and silicon, has become important for a wide variety of uses, ranging from purifying helium gas by removing the nitrogen to scavenging molten metals of undesirable impurities. The excellent fluxing properties of lithium salts have found increasing use in such applications as fluxes for welding aluminum and in lower melting ceramic glazes and coatings. Lithium chloride is one of the most hygroscopic salts known and is widely used as a dehumidifying agent. .About 17 lithium minerals are known. Four of these have commercial importance: Amblygonite, lepidolite, zinnwaldite, and spodumene. Spodumene is the most important source of lithium and lithium salts at present, but sizable deposits of amblygonite occur in the pegmatite area of the Black Hills of South Dakota. The size and nature of these deposits preclude the, possibility of, any assurance of an adequate supply of amblygonite for an operation processing only this mineral. Frequently spodumene and amblygonite occur associated in pegmatite minerals. Preliminary investigations indicate that a simultaneous recovery of spodumene and amblygonite can be made by froth flotation. A single process for treating spodumene and amblygonite or mixtures of thorn, would make possible more use of amblygonite as a source of lithium and obviate the separation of spodumene and amblygonite when they occur together.

Jan 1, 1952

By T. Estelle Gardner, A. R. Taylor

Heat capacity measurements were made on sodium bromide ( NaBr ) and sodium iodide ( NaI) in the temperature ranges of 7 ° to 300 ° K and 56 ° to 300 ° K using an adiabatic calorimeter . Smooth values of heat capacity, entropy , enthalpy function , and free- energy function were calculated from the heat capacity data at 10° K intervals and at 273.15° and 298.15° K. Entropy and free energy of formation values at 298.15° K also were calculated for the two compounds using entropy values determined in this study and other data reported in the literature . The entropy values calculated at 298.15 ° K were 20.75 ± 0.06 entropy units (eu ) for sodium bromide and 23.55 ± 0.07 eu for sodium iodide .

Jan 1, 1964

By J. F. Barkley

Field tests were made on the rate of corrosion of 30 materials used in air preheaters under regular operating conditions, and the buildup of deposits was observed. Twenty-three materials were tested with coal as the fuel on an underfeed stoker and seven with oil, including a short period with pulverized coal as fuel, The plant equipment is described, and pertinent plant operating data are tabulated. Figures 17 and 19 (pp. 24 and 27) give the results of corrosion tests on the uncoated metal test specimens. The information obtained from these tests follows the general pattern described in Bureau of Mines Report of Investigations 4996, Corrosion and Deposits in Regenerative Air Preheaters. The deposits were similar, and the corrosion rates of Cor-Ten and Mayari-R steel (previously found to be essentially the same at the Harding Street Station using coal) continued to show little difference at the Marion Generating Station using principally oil. The one high-alloy steel tested, type 321, showed a much higher corrosion rate than the low-alloy steel, Cor-Ten.

Jan 1, 1959

By N. S. Dalal, B. Jafari, X. Shi, M. M. Suryan

"It is well known that prevalence and severity of coal worker's pneumoconiosis (CWP) differ markedly in different regions and mines despite comparable exposures. These variations in the pathogenicity of different coal mine dusts can only partially be explained by the mineral composition of the coal mine dust and the rank of coal. Laboratory studies also do not correlate with the human experience. One major difference between human exposure and laboratory studies is that the coal miner breathes dust from freshly broken coal, while the animals or cells are exposed to stale dust. In an effort to find biochemical clues for resolving this apparent paradox, we have carried experiments to detect differences in chemical reactivities of fresh versus stale coal dust from several U.S. coal mines. Electron spin resonance (ESR) was used as a technique for the direct detection of the concentration and reactivity of free radicals. ESR measurements of freshly ground coal dusts of different ranks and composition showed significant differences in the amount and reactivities of the organic free radicals produced. The half-lives and reactivity patterns of these newly formed species of free radicals seem to correlate with the expected toxicity and pathogenicity of the dust, thereby, providing new clues to the biochemical mechanisms and pathogenesis of CWP. Similar detection of free radicals in freshly crushed quartz suggest that free radicals might play a significant role in the pathogenicity of quartz in causing fibrosis and eventually silicosis.IntroductionThe pathogenesis of coal workers' pneumoconiosis (CWP) has been an important topic of concern for decades, but the mechanism of CWP is still not understood. It is well known, for example, that the prevalence and severity of CWP differ markedly in different regions and mines despite com¬parable exposure'(1,2) but these observations can only par¬tially be explained by differences in mineral composition and rank of coal (3-5) Specifically, while epidemiological studies of coal miners indicate (1,2) that the effectiveness of coal in producing CWP correlates roughly with the rank (i.e. %,carbon content) of coal, such correlation has not been established via biological studies.(4-6)"

Mar 1, 1989

By J. C. Edwards

The Bureau of Mines developed a mathematical model for analysis of the impact of scrubber bed length, porosity, and gas flow rate on the absorption of C02 in a breathing apparatus. The model accounts for the decrease in available absorbent through chemical conversion. The pre-dicted efflux of C02 from a canister containing LiOR compared favorably with measured values reported elsewhere. It was determined from a com-putational study that the time for breakthrough of C02 at a prescribed level is nearly directly proportional to bed length and inversely pro-portional to gas flow and porosity.

Jan 1, 1987

By Frank B. Fulkerson

Three of the five primary aluminum producers in the Pacific Northwest have facilities in the region to make aluminum mill products. Only one of the three, however, produces a variety of shapes and forms. The principal reason for the lag in development of an aluminum mill products industry was found to be transportation cost. The long range outlook is for expansion, based mainly on growth of the western market for aluminum used in construction, containers and packaging, electrical applications, diesel trucks, mobile homes, and irregation pipe. Consumption of western aluminum mill products in 1985 is projected at 1.1 million tons, compared with estimated consumption of 250,000 tons in 1961.

Jan 1, 1965

By Arthur L. Murray

"During recent months much criticism as to the efficiency of mine labor has been heard from various, sections of the country. No doubt much of this criticism has been well founded. The present lack of efficiency and of stability is due primarily to a spirit of restlessness and partial irresponsibility engendered during the transition from war conditions to peace time conditions. This spirit or unrest not only among the laboring classes but in every branch of the human family following a period of intense nervous tension in a nation appears to be a natural sequence of war and beyond the control of man. This condition will gradually disappear, and the majority of our people will again assume their natural order of living, but labor will for a considerable period be sensitive to these influences, whether they be exerted for good or for evil. Employers of labor should take cognizance of this fact and bend every effort towards the development of measures that promote efficiency and permanence of the working force.Labor efficiency depends upon many and varied factors. Some of these factors as applied to mine labor are briefly enumerated in the following paragraph:Selection and Placement of Manpower:In the selection of men the two main considerations are physical ability and adaptability. The laws of mechanics should be applied in the selection of men as in the selection of machinery. If a machine is required for a certain class of work, the type of machine known to be mechanically fit for such work is selected. Likewise, men should be selected with regard to their physical and temperamental fitness for the kind of work expected of them."

Apr 1, 1920

By H. E. Powell

Magnetic susceptibilities were determined by the Bureau of Mines fur 19 cobalt- and nickel-bearing minerals and for a suite for synthetic cobalt-nickel diarsenides analogous to the rammelsbergite and safflorite series. Relations between susceptibility and composition were found to be nonlinear for both impure natural minerals and pure synthetics.

Jan 1, 1967

By A. Aly Selim

This report describes the feasibility of predicting percussive drilling rates by equations derived from statistical regression analysis. The least squares statistical method was used and the analysis was performed both by direct and by stepwise linear regression analysis. The predicted penetration rate is a function of the drill power and the physical properties of the rocks penetrated. The results show promise that the technique may be of value in providing a mathematical model by which percussive drill manufacturers and users can predict the performance of a given drill. Experimental work involved two mining type percussive drills. Penetration data for these drills were determined from nine rocks drilled in the laboratory. Drill work rates (power) were determined in a separate series of experiments. Rock physical properties were measured from diamond-drill core samples taken from the same blocks used for percussive drilling.

Jan 1, 1970