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By B. Das

The separation of iron values from a typical Indian iron ore slimes containing 57.2% Fe, 5.81% SiO2 and 7.05% Al2O3 by wet magnetic separation and selective magnetic coating is investigated. The iron phases, which are mostly paramagnetic in nature, have been coated with magnetite or colloidal magnetite in presence of surfactant by manipulating the surface properties of the minerals. The studies have indicated that an iron concentrate containing 62.32% Fe with 66.5% iron recovery can be obtained at medium magnetic intensity of 7.8 kG which is much less compared to normal magnetic intensity of 13 kG to14 kG required for hematite-goethite separation. The performance of this technique with respect to both grade and recovery is superior to conventional magnetic separation or flotation of iron ore slimes.

Jan 1, 2014

By Herman Mendoza, Luisa Ciriaco

An investigation of the seeding mechanism using heterocoagulation and the Derjaguin - Landau - Verwey - Overbeek (DLVO) theory of two pure minerals is the objective of this study. The seed was silica with modal diameters of 4.529 µm (fine particles) and 5.216 µm (coarse particles) and the test powder was hematite with a modal diameter of 0.883 µm. Parameters included variations in the concentration and particle size of silica. Both particles were first subjected to size determination and settling tests via Stoke’s Law. The silica-hematite system was then suspended in 0.001 M KNO3 electrolyte solutions where pH was adjusted. Afterward, the suspension was agitated and was allowed to settle at different time intervals while obtaining turbidity readings. Results through settling time and turbidity vs. pH graphs indicate that maximum heterocoagulation occurs from pH 2 to 5 while minimum heterocoagulation occurs from pH 6 to 7. At these pH levels the zeta potentials of silica and hematite are negative and positive, respectively. On the contrary, repulsive forces dominate the system from pH 8 to 11 due to the particles’ negative zeta potentials. Furthermore, the attachment of hematite to silica increases when the parameters become larger thereby increasing the effectivity of heterocoagulation at acidic to neutral pH levels.

Jan 1, 2014

By N. Naudé

The theory on particles displacement subjected to upwards and settling movements in water, using a water pulse, is described in literature, but very little experimental data is available to verify these theoretical ideas. The aim of this research work was to visualize the displacement of solid particles in a mixture of water and solid particles created with the aid of water pulses in the Mineral Density Separator. From the literature it is known that lighter particles are subjected to higher levels of displacement than heavier particles, and when the particles then settled down, layers of material are formed ac-cording to the densities of the material. By removing the individual material layers, the materials can then be separated according to their densities. During this study the individual material layers were investigated regarding the density and size distribution in that specific density layer. It is important for this project to have a statistical prediction of the ?real? flow of the particles with different density and size distribution, inside the Mineral Density Separator. The information gathered during this study will be used to show the correlation between a two dimensional model of the particle flow and that of the real three dimensional flow inside the Mineral Density Separator.

Jan 1, 2014

Flinders Power, formerly NRG Flinders, is considering the possible use of low rank coal from Lake Phillipson, South Australia (SA) in its power stations at Port Augusta, SA. Typically, this coal contains about 35% moisture and 10% ash. Unfortunately, it also contains high levels of sodium (1% Na) and chloride (0.95% Cl) with a Na2O level in ash of 18.9%. Such levels cause serious problems during coal combustion, making the use of as-mined coal impractical for power generation. This paper describes the development of an aqueous leaching technique to remove 90% of the sodium and chloride and to yield a product with a Na2 O level in ash of less than 3%. Small-scale agitation leaching tests with good quality tap water at ambient temperatures showed that the coal needed to be crushed to minus 5.6 mm to obtain maximum removal of water-soluble sodium and chloride in 30 min. Leaching kinetics, but not the ultimate removal of salt, were enhanced by the use of higher temperatures (up to 150°C), but this was deemed uneconomic. Varying the pulp density between 20% and 50% had little effect on extractions and there was no benefit in multiple stage water washing. The best results by water leaching were 69%~74% extraction for sodium and 95%~97% for chloride, meaning that the sodium removal was well below the target level. From SEM examinations of the leached product it was concluded that the remaining sodium was organically bound to the carbon atoms in the coal. Further tests using aqueous solutions containing cation exchange additives such as calcium chloride (CaCl2) or ammonium chloride (NH4Cl) or sulphuric acid (H2SO4) showed that significantly enhanced sodium extractions were possible and target specifications were met. Two options, namely a single-stage and a two-stage leach, were then investigated. In a single-stage leach with additive, minus 5.6 mm coal was leached at 33%~50% solids for 30 min at ambient temperature and then filtered and washed with fresh water. This gave a sodium removal level of about 81% and a Na2O level in ash of about 5%. These levels do not quite meet tar-get specifications. In a two-stage leach, the coal was first leached with water alone without an additive as in the single stage leach, and the washed residue re-leached under similar conditions for about 5 min with an additive (CaCl2), and then filtered and washed. This gave a cumulative sodium removal of 96% and a Na2O level in ash of 1.4%~2.4%. These levels are well within target specifications.

Jan 1, 2014

By E. Vahidi

In this study, a hydrometallurgical treatment involving solvent extraction of zinc using D2EHPA (di-2-ethylhexyl phosphoric acid) has been investigated to recover zinc from an industrial zinc leach residue. The residue was leached with sulfuric acid producing leach liquor which was subjected to solvent extraction for enrichment of zinc and removal of impurities. Operating variables for the zinc extraction process, such as pH of the mixed solution (0.5~5.0), concentration of D2EHPA (5%~40%, w/w), temperature (25~60°?C), A/O volumetric phase ratio (1/2~4/1), concentration of tri-butyl phosphate (TBP) as modifier (3%~7%, w/w), concentration of NaR2RSOR4R in aqueous phase (0.05M, 0.1M, 0.2M) were also studied. Practically all zinc was extracted from the aqueous solution at pH 2.5 with 20% w/w D2EHPA in kerosene. At this operating condition, zinc could be extracted at one theoretical stage at A/O phase ratio of 1/1, as calculated by the McCabe-Thiele method.

Jan 1, 2014

By G. Y. Zhou

During Zijinshan copper heap bioleaching, pyrite was leached in plenty resulting in high ferric concentration in solution. It has affected bioleaching and extraction processing greatly. It results much acid and iron in solution and bad effect to extraction processing. The paper studied the influence factors in the course of pyrite leaching and ferric ion chemical oxidation, especially studied the redox potential for copper bioleaching so as to find key factors affecting the dissolution difference between chalcocite and pyrite. The results show that the redox potential is important factor. Copper and pyrite leaching rates are 95% and 11% respectively and there is great dissolution difference between them at redox potential 700 mV (SHE). During pyrite bioleaching, the indirect action of bacteria gives priority to bioleaching cooperating with the direct attack of microbial cells attached to the mineral surface. Redox potential is determined by ratio of ferric and ferrous, ferric in solution was supplied by the way of oxidation of T. f bacteria, sufficient bacteria concentration and active character were two vial factors of controlling redox potential. It is indicated that copper can be selectively bioleached during copper bioleaching by controlling redox potential of bioleaching. The conclusion will provide theoretic foundation on balance of acid and iron during bioleaching for copper of higher S/Cu ratio. The experinment proved that bacteria activation was decreased on condition of both low pH value and intermittent aeratation during bioleaching. It resulted that the oxidation velocity of ferrous ion was decreased and redox potential was controlled. The dissolution of pyrite was depressed. It would be possible to actualize selective leaching of secondary sulfide copper ore during bioleaching process.

Jan 1, 2014

By Jihoe Kwon, Daeyang Lee, Mario Fujimura-Kashiwagui, Heechan Cho

"Calcium carbonate is one of the most widely used mineral in today's industries such as plastic, paper and pigment. There are many essential physicochemical properties required by each industry field but the most common requisite is size. One way to achieve appropriate size is grinding. Grinding is typically an energy intensive process, consuming about 40% of total energy cost in mineral process. Due to that reason, optimization of grinding process is a critical element to achieve price competitiveness. Two different type of grinding apparatus were hired to find out optimum condition in terms of energy efficiency. Utilizing samples containing 10, 20, 30 and 40% solids concentrations, a 1l batch type attrition mill was operated as the first grinding step at various operating speed with 1? to 5? grinding media in order to study the optimum operating conditions to reach submicron particles. Next, a 0.15l vertical beads mill was tested as next step with 100? to 500? grinding media to study the optimum conditions in the submicron range. Net energy and the specific energy input was measured to reach stated size ranges. Also, using a back-calculation based on the population balance model further operating conditions were studied. There were several competitive combinations which showed significant energy efficiency improvement when compared with the single step grinding."

Jan 1, 2014

By C. Çelik

Nowadays the optical sorting of industrial minerals is one of the most important processing methods which has cost efficient production possibilities. This method is used for industrial and raw materials that have different colour and brightness features. Initially this technology is used for sorting of foodstuffs and recovered glass, but for a long time also as physical mineral processing method for both industrial minerals like: limestone, marble, talc, basalt, flint, quartz and secondary raw materials like: building rubble, refractory materials, glass, plastic and household waste. In this study via optical sorting the separation of quartz out of a flint mix, which consists of the particles with different colors and brightness, is aimed. Experiments are performed on an optical sorting machine named CombiSense® 1200 at the institute of ?Aufbereitung mineralischer Rohs-toffe? RWTH Aachen. This automatic picking device was developed by the company ?Separation Systems Engineering (SSE), Wedel?. Hand picking method is used for product analysis and the efficiency tables are prepared on every step accordingly. This process enables to reach quartz products with purity up to 100%.

Jan 1, 2014

By I. Kairyakov

The present paper is about the restoration of the molybdenum production in the floatation plant of Ellatzite-Med AD in Bulgaria. The process, based on a working design, includes the construction of a new floatation molybdenum section in the existing molybdenum department of the Floatation Plant using the so called Vemco inert-gas floatation machines, made especially for the molybdenum floatation. While in the ordinary floatation machines, block impellers create suspension of the air, sucked from the atmosphere with the slime particles of the concentrate, which creates conditions for oxidizing the reagent, Vemco inert-gas floatation machines are covered with hermetic lids and the air inside the chamber is used. The technology, suggested by Geotechkoper Ltd. for making the working project, employs special machines from Dor Olliver Aimco, suitable specifically for molybdenum floatation in order to reduce the oxidizing of the reagent sodium hydrosulphate. Also the transport of the chamber product is done in hermetic conditions as the molybdenum flotation is done in two floatation rows and refining operations 3 to 8 are placed in the second row. Thus in the basic molybdenum floatation together with the first and second refining operations, which are hermetically closed, an ambient condition with low content of oxygen is created, that is about 8% for oxygen and about 92% of nitrogen, in which the oxidizing process is extremely reduced. This in turn results in reducing the consumption of the reagent depressor ? sodium hydrosulphate. In that way there is an improvement of the economical indices of the molybdenum production.

Jan 1, 2014

The value creation with kaolin clays depends on removing the colored impurities which manifests in to higher brightnessone of the most sought after properties on applications such as paper coating, paint and others. The processes for removing impurities include magnetic separation, froth flotation and selective flocculation. While the flotation and selective flocculation processes exploit the physico-chemical differences between the surface properties, the magnetic separation uses the bulk magnetic susceptibility differences between the diamagnetic clay and ferro- and para-magnetic nature of the impurities. The major advantage with magnetic separation remains high yield and no or low reagent usage. However, the magnetic separation technology suffers from low separation efficacy when finer colored impurities (<1 µm) are encountered in the feed. Use of stronger magnetic intensities during magnetic separation showed limited success; nonetheless the adverse effect due to finer size range remains a dominant effect even at 5 Tesla magnetic field. Furthermore, the presence of diamagnetic colored impurities irrespective of their sizes can not be removed. Cytec Industries has recently developed a ?bolt-on? chemical enhancement technology for magnetic separation that essentially embraces the best product performance attributes of flotation and selective flocculation while keeping the chemical usage to a minimum level and using the readily available magnetic separation equipment. The paper will outline the technology and illustrate optimization work at pilot plant magnet on a wide variety of crude accommodating the process needs and plant limitations. The major advantages of chemical enhancement technology to magnetic separation include: 1) simple extension to existing magnetic separation technology, 2) ability to produce comparable product in quality with cost effectiveness compared to flotation and selective flocculation, 3) removal of impurity minerals over wide size range, 4) removing non-magnetic impurities, 5) providing robust process with high process yield and 6) operation-friendly nature. Furthermore, chemical enhancement technology for magnetic separation has also emerged as a platform for re-moving impurities at low levels in other mineral systems as well.

Jan 1, 2014

By J. Zou

With the increasing applications of the Chinese metal magnetic liners, the requirement for their technical specifications has become stricter and stricter. It is necessary to deeply analyse the metal magnetic liners in order to improve their reliability and economics. The key issue of metal magnetic liners is magnetic forces: their attractions to mill shell and protection layer. Mathematical models were developed using finite-element analysis software and systematic simulation analyses of the two most critical indexes of magnetic liners were performed to find out the most important parameters and their effect on the liner?s characteristics. The relationships between magnetic forces and installation gaps, thickness of permanent magnets and thickness of protection layer may be used to guide the design of metal magnetic liners for ball mills in order to achieve good economic indexes.

Jan 1, 2014

The Arctic is a region of special economic, geopolitical, research, socio-ethnic, and defense interests of both Russia and other countries of the Arctic zone. Introduction of innovation technologies at ore-processing factories is a direct responsibility of the state and this problem should be solved on the basis of coordination of interests of different stakeholders. The task of elaboration of scientific principles of rational state regulation in the North is very topical. Innovations require considerable investments first of all from private capital. However as an investment object innovations are not attractive for investors as they require large expenditures for long-term projects, and they are connected to high risks because market incentives form striving to get quick profits of private companies and result in a certain behaviour strategy while innovations need ?long money?. Under such conditions without state regulation of investment and innovation activities development of the mining sector in the Arctic practically has no prospects. At innovation development of mining enterprises economic growth is provided at the expense of active state innovation activities. The elaborated strategy of ore-processing enterprises should correspond to the modern paradigm of the ore-processing industry development which is not only for extraction of minerals but also for multi-profile structure having comprehensive use of the resources on the rational basis intended for rational complex utilization of mineral resources of the AZR which by the definition includes maximally full use of the whole aggregate of resources on the economically rational basis with obligatory environmental with resource reproductive and socio-economic functions and deterrents. The main principle of creation of innovation technologies is to obtain more products of higher quality with minimal costs. This allows increasing ?productivity of the resources? several times. This principle makes increasing productivity of the resources the most important and in this case efficiency of use of the resources brings extra profits at the expense of lack of new costs such as payment for protection and utilization of wastes. According to the economic theory only ratio between demand and supply is able to fix optimal proportions in economy and to give necessary signals for investment activities of mining enterprises. In this context market for minerals and increase of mineral resources productivity do not create incentives for investment activities without which neither sustainable economic growth nor solution of macroeconomic tasks are possible. Nevertheless countries should not reject this idea in spite of economic efficiency of the enterprises. Extraction degree of useful components and especially oil in the Arctic zone is one of the lowest in the world. This can lead to crisis of oil industry and other mining sectors. The reason for that is lack of a state policy of realization of innovation technologies in the mining sector in the Arctic.

Jan 1, 2014

By M. Q. Xu

During the flowsheet development for a potential commercial Cu/Ni separation plant at the In-co?s Sudbury operation, extensive laboratory and miniplant studies were carried out. There are two potential feed streams for Cu/Ni separation at the existing operation. It is shown that Cu/Ni separation from the rougher concentrate is relatively simple without need of regrind. However, Cu/Ni separation can be difficult from the bulk concentrate because of the presence of excess flotation reagents in the bulk concentrate slurry and locked particles. Excess flotation reagents created excess froth increasing entrainment. By replacing the slurry water with tap water and with addition of some hydrogen peroxide, entrainment is minimized and good Cu/Ni separation is achieved on the bulk concentrate. Fine regrind is required to increase liberation of the locked particles for ultimately high copper recovery at the minimal nickel content.

Jan 1, 2014

By David Newton, Christian O’Keefe, Robert Maron, Jerin Russell, Paul Rothman, Dylan Cirulis

"The presence of unwanted coarse material in flotation feed streams negatively impacts both recovery and throughput of concentrator plants. The detection of this coarse material is a long-standing problem in mineral processing that has been poorly addressed by existing instrumentation systems. This problem has been overcome by the development of two new systems that detect in real-time the presence of coarse material in the overflow stream of individual hydrocyclones. They both use sensors mounted to the overflow pipe of the hydrocyclone and provide a robust and maintenance-free system measurement that enables corrective actions through operator intervention or automatic control strategies. One system is non-invasive and detects very coarse material 6mm or greater in size. The other system uses a wetted sensor and detects coarse material down to a lower size limit of approximately 100 um. Both systems have been commercially deployed. The systems will be described in detail. Validation data and typical plant data will be shown"

Jan 1, 2014

By Z. H. Wang

The internal parameters of ball mill are very important in the grinding process and have significant impact on the grinding results. Accurate measurement of the internal parameters of ball mill is crucial and indispensable for optimization and control of grinding process. In this paper, a novel tri-sensor measurement method was used to measure the external signals (i.e., bearing pressure, sound intensity and power consumption) of ball mill. Mathematical models, which link the external signals of ball mill with its internal parameters, were established to predict the internal parameters of ball mill. Experimental results showed that the mathematical models could directly predict the internal parameters of ball mill once the external signals were obtained. The tri-sensor measurement method and the mathematical models proposed in this paper provided a new way and solid basis for optimization and control of ball milling.

Jan 1, 2014

By P. Raghavan1

Reverse froth flotation experiments were carried out in the laboratory using two different types of kaolins for the separation and removal of coloring titanoferrous impurities from cryo-filtered clay after subjecting to high shear pre-treatment. This high shear pre-treatment consists of high shear agitation of a high solids clay slurry with the dispersant (high shear dispersion, HSD) followed by high shear agitation with the collector (high shear conditioning, HSC). After this pretreatment, the slurry is diluted and reverse flotation is carried out. One sample is from, Gujarat, India (Mamuara clay, ?MC?) while the 2nd sample is from Amberg, Germany (AKW clay, ?AC?). While MC consisted of 89% particles below 2µm and analyzed 1.06% of TiO2 and 0.29% Fe2O3 and measured a brightness of 83.4 %ISO, the corresponding values for AC are 67% below 2µm, 0.3% of TiO2? 0.49% Fe2O3 and 83.4 %ISO. The flotation performance is found to be greatly influenced by the conditions of high shear treatment. Important variables are HSD intensity (rpm), HSD time, HSC intensity (rpm), HSC time, HSD/HSC time ratio, ?HSD+HSC? total time etc. Higher shear intensities favor both the impurity liberation and collection. For both clays, it could be shown that impurity removal increases as total pretreatment time (?HSD +HSC? total time) increases up to a certain limit. For MC, the HSD time was only half or less than that of HSC time, while for AC, HSD time is at least twice (or more) than HSC time which is just an opposite manifestation. This is believed to be due to the striking differences between these two clays. Most importantly, the shear frequency is found more influential than the shear rate for the overall flotation performance for both clays. Interestingly, at high shear frequencies, i.e., when a stirrer with more number of teeth on the rotor is used, the ?HSD+HSC? total time is greatly reduced. Again, increased shear frequency helps to reduce flotation time and significantly improves flotation performance. At optimum conditions, product titania reduced to 0.35% for MC whereas the same reduced to 0.13% for AC. The product of flotation of MC measured 85%ISO brightness while that of AC measured84.6%ISO thus enhancing the value of the final product. It could also be established that the high shear pre-treatment shows better flotation performance than that due to collector dosage. Keywords: high shear dispersion, high shear conditioning, titanoferrous impurities, shear rate, shear frequency, brightness, clay recovery, Mamuara clay, AKW clay

Sep 1, 2012

By Saeed Farrokhpay

It is known that the grinding condition has a major effect on the beneficiation characteristics of the minerals in subsequent processing, in particular, flotation. In the flotation process, particles surface and their condition can significantly influence collector adsorption and flotation performance. For example, particle shape and its surface roughness occurred during grinding may influence flotation characteristics of a specific ore. In fact, adsorption of different cationic and anionic species on mineral surfaces can be varied depending on the selected comminution procedure. The flotation performance of sulphide minerals can be detrimentally affected by the surface oxidation. The amount of surface oxidation may reduce the hydrophobicity of the mineral and makes adsorption of collectors less selective. Improved liberation may generally result in improved flotation recovery. However, this may result in finer grinding and slimes, and consequently, reduce the overall flotation recovery. This paper discusses the effect of wet and dry grinding on copper flotation of a complex Cu-Pb-Zn ore. Industrially, wet grinding is preferred due to its higher energy efficiency and owing to downstream processing requirements. In this study, series of flotation tests were conducted,and surface analysis (XPS and ToFSIMS) were performed after wet or dry grinding at two different P80 values. Mineralogical study was also conducted to investigate the liberation of valuable minerals after grinding. A higher copper flotation recovery was found for wet grinding. However, the copper recovery was increased by further grinding in both conditions (wet and dry). The results showed a higher collector adsorption on copper mineral surfaces after wet grinding. The surface analysis also revealed that the ore is slightly more oxidized after dry grinding probably due to higher temperature during dry grinding.

Sep 1, 2012

By N. I. Um

The coal bottom ash generated from coal-fired power plant accounted for approximately 5 mil-lion tons in Korea. Almost all of coal bottom ash was treated as reclamation of the landfill because of the content of unburned carbon. For recycling of coal bottom ash, effective removal of that is required. So, in this study, the removal of unburned carbon by flotation was studied with respect to adsorption ability in surface of a bubble in order to consider its application to recycle the coal bottom ash. The sample A, B and C were that the coal bottom ash contained 2.73%, 7.01% and 10.49% of the unburned carbon (UC) respectively. The column flotation was carried out for each time as the artificial injection of air at 10.0L/min flow rate and the reagents of 500g/ton kerosene and 80g/ton MIBC were used. The samples per water of 1.3 liters were from 0.5% to 4% (w/w.%). In the result of this study, the kinetic curves of unburned carbon adsorption from injected air bubbles were in-creased rapidly as equilibrium was approached; only 5 sec was needed from the sample A and B and 10 sec was from sample C. And the equilibrium isotherms of unburned carbon adsorbed by the infected air bubble from the sample B and C could appear the BET adsorption isotherm; MT = KMEEO/(EO-E)[EO+(K-1)E](K: adsorption affinity), but not the sample A that was not enough to express the adsorption curve.

Jan 1, 2014

By E. Emelyanenko, P. Solozhenkin, J. Yagudina, O. Ibragimova

To recover tetrahedrite-tennantite series minerals from porphyry copper-pyrite ores by the froth flotation method, further research on thiol collectors is launched to promote the utilization efficiency of copper ores. In the present paper the adsorption mechanism of the collectors on tennantite surface has been investigated by computational modeling and FTIR-spectroscopic analysis, which have revealed that the decrease in prognosis of collector activity evaluation (PCAE) for tennantite is in the following order: BX (-0.34318), AEROPHINE 3418A (- 0.61756), AERO 5100 (-14.18857). The lower PCAE the stronger the ability of the collector to interact with the mineral surface of tennantite and form the stable complex. More kinetic reliable conditions to form suitable adsorption layer and rupture of the liquid interlayer with AERO 5100 have been observed by FTIR spectra due to decrease of the intensity and stretching and bending vibrations of water (less than 20 and 65%, respectively). In order to verify the feasibility of AERO 5100 as a collector the industrial flotation tests have been conducted. Flotation performance has improved significantly with the stadially grinding and preflotation of tennantite in intercycle copper flotation that allows to avoid desliming of the fragile mineral and minimize loss of Cu and As in tailings. The recovery of copper in copper concentrate increases by 3.9% with the grade maintained.

Jan 1, 2018

By Y. M. Zhu, G. C. Gong

"The influences of citric acid (CA) on the flotation behavior of cassiterite using styrene phosphonic acid (SPA) as the collector were studied via single mineral flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations in this paper. The results of single mineral flotation tests revealed under the conditions that pH=4 and the dosage of SPA 100 mg/L, the recovery of cassiterite reached 76.78%. The addition of 20 mg/L AC decreased the recovery by 12.42% at pH=4. Contact angle measurements demonstrated the adsorption of CA prior to SPA made the cassiterite more hydrophilic. The results of zeta potential determinations and solution chemistry calculations indicated the chemisorption of C6H7O7- and C6H6O72- filled parts of the Sn site on cassiterite surface and prevented the SPA from getting adsorbed. The hydrophilic effect of AC was stronger than the hydrophobic effect of SPA and the flotation of cassiterite was crippled. INTRODUCTION Tin is an important metal which is widely used in medical instruments, marine engineering materials, electronic and electrical devices, welding, weapon manufacturing and organotin compounds industries (Angadi et al., 2015). Cassiterite is the only mineral from which the tin can be extracted, thus it is of great importance to efficiently exploit the cassiterite mineral. Flotation is an indispensable method for the recovery of cassiterite (Li et al., 2015). However, cassiterite is usually in association with many other gangue minerals which are of similar floatability, such as quartz, calcite, fluorite, iron oxide, wolframite, scheelite and tourmaline (Sreevinas, 1997). So some modifiers are necessary in the cassiterite flotation process. The amounts of the modifiers used in the flotation must be judicious and the overmuch modifiers may cripple the recovery of cassiterite (Parsonage et al., 1987). Nevertheless, the research about the effects of the modifiers on the flotation behavior of cassiterite has been rarely reported. In this paper, the influences of citric acid (CA) on the flotation of cassiterite using styrene phosphonic acid (SPA) as the collector were investigated by flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations."

Jan 1, 2018