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By P. Oliveira, A. Peres, A. Silva

"The decrease in iron content and increase in contaminants grade, associated with greater participation of compact and semi-compact materials, has impacted the recovery of a mechanical cells flotation circuit in the Iron Quadrangle, Brazil. The recovery decrease in the flotation stage motivated the current conventional flotation circuit reevaluation seeking alternatives to restore the recovery, without affecting the final concentrate quality parameters, with low investment. Sampling, chemical characterization of samples, bench scale flotation experiments, and mass balances were conducted. Analysis of the results showed opportunities to improve the circuit performance. The stages prior to the flotation circuit changes were: rougher, cleaner, recleaner and scavenger. In the previous configuration, recleaner was operated as cleaner scavenger and the iron grade in the scavenger concentrate was 23%, representing 38% of the new feed. After the circuit change, the circulating load was reduced from 38% to 15% and the iron content was upgraded to 42%, resulting in increased residence time. The iron content in the global tailings of the concentrator was decreased from 10.9% (year of 2013 average) to 10.2%, representing gains in both mass and metallurgical recoveries.INTRODUCTIONRegarding plant practice, the year 1972 represents a landmark for the concentration of iron ores in Brazil. VALE started up 28 units of WHIMS (wet high intensity magnetic separators) at the Cauê plant in Itabira, each one producing 1x106 t/year of concentrate. Later 17 WHIMS machines were commissioned at Conceição. During the 80’s decade of last century, changes in the ROM required the addition of a cleaner flotation stage to decrease the silica content in the pellet feed.The first company to use reverse cationic flotation as the only concentration operation of iron ore was SAMARCO (start up in 1977). Since 2015 flotation has been utilized at VALE in Itabira as major concentration process, magnetic separation acting as scavenger stage.The Jones matrix type WHIMS were manufactured for decades under patent by KHD Humboldt Wedag. After the expiration of the Jones patent, Eriez Magnetics took the world leadership regarding WHIMS manufacturing. The Brazilian branch of Eriez is Inbras. Based on plant practice experience at the Fabrica concentrator, the Brazilian company Gaustec was established (RIBEIRO and RIBEIRO, 2010) and is now present in different countries. The mega sized WHIMS GHX-1400 (18.000 Gauss, gaps smaller than 1.5 mm) were developed to face the challenge of huge throughput required by iron ore processing (Ribeiro et al, 2017)."

Jan 1, 2018

By James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity ? up to 40 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonnes of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle ? particle contact. The small gap, high electric field, counter current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in the North America and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Sep 1, 2012

By Hao Zhang, Dezhou Wei, Qiang Zhao, Caie Zhang, Baoyu Cui, Xuetao Wang

"Nowadays, long periods of relatively low iron ore prices have made the steel industry get the greater pressure. To develop appropriate processing technology based on characteristics of the iron ore, so as to reduce the beneficiation costs, is crucial to the improvement of iron and steel enterprise competition. For a typical low-grade iron ore from northeast China, beneficiation process research was conducted based on the in-depth studies of ore characteristics. Results show that the iron grade of the ore was 31.56%, the content of FeO was 6.59%, the main iron minerals were hematite and magnetite with fine dissemination sizes and partly scattering in gangue; With the grinding fineness of 65% passing 0.074mm, and regrinding fineness of 90% passing 0.074mm, the concentrate with 66.80% iron and recovery of 82.90% was obtained via the combined flowsheet of stage grinding – classification – gravity concentration – low and high intensity magnetic separation – reverse flotation. Ratios of gravity concentration and low intensity magnetic separation were 70.21% and 7.57% respectively in 40.42% of total concentrate yield; The loss of micro-size fractions can be reduced by feeding spiral tailings into magnetic separation and flotation; It’s helpful in reducing the dosage of reagents and beneficiation costs by increasing the throughput of gravity concentration and outputting concentrate of low intensity magnetic separation.INTRODUCTION Iron and steel industries are facing the increasing pressures in the continued falling iron ore prices. In order to improve the competitiveness, it is extremely urgent for them to develop more appropriate separation process for the reduction in iron ore beneficiation cost. As a typical low-grade iron ore, Anshan-type iron ore is one of the most important iron ore resources in China [1-3]. The flowsheet of stage grinding and separation contained the classification of the coarse particles and the fine particles, the gravity concentration, the magnetic separation and the anionic reverse flotation has been widely applied for Anshan-type iron ore. With the appropriate separation progress as well as equipment, satisfactory separation results had been obtained, and mineral particles with different size were recovered separately [4-7]. However, the low recovery of fine mineral particles and the relatively high beneficiation costs still prevented the efficient application of the process [8]. For a Anshan-type low-grade iron ore, a typical process flowsheet, as mentioned earlier, with stage grading, classification of the coarse particles and the fine particles, gravity concentration, magnetic separation, anionic reverse flotation was adopted currently. And the concentrate with 67.10% iron and recovery of 75.50% was obtained and the gravity concentrate accounted for 39% of the total concentrate. However, a large amount of fine liberated iron ore particles were lost in the tailings."

Jan 1, 2018

By M. L. Liu

This work reports the results about the determination of mean activity coefficients and relative partial molar free energies for copper sulfide mineral bioleaching solutions by potentiometric method at 25ºC. The experimental potentiometric data were obtained by combining a solid state membrane-cupric ion selective electrode (Cu2+ ISE), containing a KNO3 filling solution, and an Ag/AgCl electrode. The measurements were performed in different series of copper sulfide mineral bioleaching solutions. The non-ideal behavior of the system was described on the base of the Pitzer ion-interaction model for mixed salts. Meanwhile, the relative partial molar free energies of bioleaching solution were investigated. The determination of the thermodynamic properties offers a basic data for the study of copper sulfide mineral bioleaching solutions.

Jan 1, 2014

By Ye Chen, Jianhua Chen, Meng Liu, Yuqiong Li, Xiao Mu, Cuihua Zhao

"Sulfidization-amine is the most effective method for the recovery of smithsonite (ZnCO3), however the interface interaction details remain unclear. The sulfidization-amine flotation mechanism of smithsonite has been studied by Density Functional based Tight Binding (DFTB+) method in this paper. The slab model of ZnCO3 (101) surface was built and the adsorptions of a monolayer of HS- and S2- ions were conducted to model the sulfidization effect on the ZnCO3 (101) surface adsorption. DDA hardly interacts with the hydrated ZnCO3 (101) surface. Under the low concentration of Na2S, HS- ions form a Zn-SH-SH structure on the ZnCO3 (101) surface, which hinders the interaction between DDA and surface Zn atoms. Under the high concentration of Na2S, a layer of ZnS is formed on ZnCO3 (101) surface, which is favorable for the adsorption of DDA on the surface. This is consistent with the flotation practice where smithsonite flotation requires a large amount of sodium sulfide. The results could provide a microscopic investigation into the sulfidization-amine flotation mechanism of smithsonite.INTRODUCTIONSmithsonite (ZnCO3) is an important and typical oxide mineral of zinc. It is a semi-soluble salt mineral with a solubility product constant of 1.46 × 10-10 (Weast, 1973). The most common and effective method to recover oxidized zinc ores is froth flotation (Caproni et al., 1979; Pereia and Peres, 2005; Kashani and Rashchi, 2008). It is well known that the flotation of oxidized zinc minerals is much more difficult than the flotation of zinc sulphide minerals (Hosseini and Forssberg, 2007).The recovery of zinc oxide ores with poor floatability attracts more and more attention due to the depletion of easy-recovered of zinc sulfide ores.Sulfidization-amine flotation, which using Na2S as sufidizing agent and amine as collector (Mckenna et al., 1949; Rey, 1954; Abramov, 1961; Rey, 1979; Hosseini and Forssberg, 2007). This method is the most successful technology used for zinc oxide minerals flotation in large-scale industrial applications since it was invented in the 1950s (Önal et al., 2005; Pereira and Peres, 2005). There have been numerous experimental researches on the sulfidization-amine flotation of smithsonite. Shi et al., (2013) studied solution chemistry of smithsonite flotation system. Feng and Wen (2017) studied the formation of zinc sulfide species on smithsonite surfaces and its response to flotation performance. Wu et al., (2017) investigated the sulfidization behavior of smithsonite with the use of zeta potential, inductively coupled plasma (ICP), scanning electron microscope (SEM), and X-ray photoelectron spectroscopic (XPS). Their measurement results confirms the chemisorption of sulfur ions and the formation of ZnS film on the smithsonite surface after Na2S treatment, however the influence of HS- ions on the surface and the influence of sulfidization on the amine adsorption have not been discussed."

Jan 1, 2018

By R. C. Dunne

A review of the current ?state of the art? of refractory gold treatment will be provided. This will include a global perspective of refractory processes past and present and the location of currently operating plants. Some discussion on the challenges that face the refractory gold industry will also be provided. Keywords: refractory gold treatment, flotation, roasting, pressure oxidation, bacterial oxidation, preg-robbing gold ores, fine grinding.

Sep 1, 2012

By Y. S. Sun, P. Gao, Y. F. Li, J. W. Yu

"Oolitic hematite ore is one of the most refractory iron ores in the world. It is not feasible to separate iron minerals from raw ore by conventional mineral processing methods. In recent years, a new technology called coal-based reduction followed by magnetic separation has been employed to produce metallic iron powder from oolitic hematite ore effectively. In order to find the nucleation mechanism, a thermodynamic analysis of the carbothermic reduction of oolitic hematite ore was conducted by the HSC 6.0 thermochemical software. The phase transition and microstructure changes during the coal-based reduction were also investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results showed that the iron oxides in the oolitic ore were reduced to metallic iron following the route of Fe2O3–Fe3O4–FeO–Fe in reduction process. The reduction reactions preferentially occur in the high activity regions to form a higher concentration of Fe elements, and then more supersaturated Fe separated out to form new phase nuclei. Under the action of homo-aggregation and principle of minimum free energy, the iron cores continuously absorbed migratory Fe around and grew into quasi-spherical iron particles embedded in slag phase. INTRODUCTION With the rapid increase of steel industry, premium grade iron ore in China has been gradually exhausted, and its supply has become bottleneck for the development of iron and steel industry (Guo et al., 2015). Therefore, it is urgent to exploit the refractory iron ores, such as oolitic hematite ore. Oolitic hematite ore is widely distributes in France, Germany, America, Canada, Pakistan, China, and among other countries (Maynard and Van Houten, 2004; Li et al., 2011). In China, the explored reserve of oolitic hematite ore is 3.72 billion tons, which accounts for approximately 1/9 of total iron ore resources of China (Gao et al, 2016). Oolitic hematite ore possesses complex composition,"

Jan 1, 2018

By Kwan Ho Kim

The beneficiation study of low quality pyrophyllite is conducted to enhance the value of it by selective grinding. In mining stage, the main gangue mineral is quartz, and the content of quartz in ore has an adverse effect on the quality of pyrophyllite. Using the huge difference in hardness between quartz and pyrophyllite, the selective grinding is accomplished using stirred ball mill. As a result, a finer pyrophyllite particle can be easily separated from coarser quartz particle by simple size classification, and the content of Al2O3 of fine particle smaller than 45um increased largely. It means that the pyrophyllite particle is ground selectively compared to the quartz particle, and the quality of pyrophyllite is enhanced.

Sep 1, 2012

By S. Z. Shafaei

An experimental investigation has been carried out using a laboratory scale Denver flotation cell. For evaluation of cokeable coal of Alborze Sharghi coal washing plant, the full factorial method was used to statistically design and analyse the experiments. The 2 factorial interaction model were developed for combustible recovery and ash content as response and diesel dosage, conditioning time, feed percent solids and rotor speed as factors. Model validation and residual analysis were con-ducted and results indicated that the fitness, predictability power and residual distributions of models were good. The effect of parameters and interactions were examined and it has been demonstrated that rotor speed, solid percent and interaction between diesel dosage and solid percent were more important terms of all responses. A product with approximately 78% combustible recovery and 10% ash content was obtained at 4000gr/ton diesel fuel oil (high level), 30 sec conditioning time (low level), feed percent solids of 15% (low level) and 800 rpm rotor speed in appropriate condition.

Jan 1, 2014

By D. Pirouzan

It is customary to use more than one stage of flotation to obtain an acceptable level of separation of valuables. Flotation circuit design is usually accomplished by applying empirical rules which usually results in operations not working at their optimum conditions. Given the capabilities of genetic algorithms (GA) in finding an optimum solution in a very disturbed search spaces, they can be used to obtain the desired flotation circuit configuration. In flotation circuit configuration and optimization problem, a combination of metallurgical parameters such as yield and concentrate ash content could be used as the fitness function for the genetic algorithm. The multi-objective nature of the problem justified to use Pareto method to arrive at a set of solutions. The appropriate configuration based on technical or economical considerations could then be chosen. To obtain the fitness function for any given configuration, it is necessary to model every flotation stage. The proposed method was used to find the optimum circuit configuration for a coal washing plant. The objective was to arrive at the highest yield while producing a concentrate with a certain ash content (< 11%). The feed to the flotation circuit was characterized based on the size fractions and their flotation rate constants. Results showed that with a 95% confidence, the absolute difference between the modeled and measured values were 2.9-5.5% for yield and 0.4-1.1% for concentrate ash content. When the proposed GA-based circuit configuration was implemented in the plant, the yield increased from the original value of 57.6% to 65.7% while producing concentrate ash content (10.9%) within acceptable limits. By adding one stage to the current three-stage circuit, it was predicted that the yield could further increase by 3.8% while keeping the quality of the concentrate within the appropriate level. Keywords: modeling, optimizing, flotation circuit configuration, genetic algorithms

Sep 1, 2012

By Li Tianxia, Zhou Jing, Zhu Yimin

"A typical low-grade of high sulfur bauxite fr contains 54.71% Al2O3, 11.35% SiO2 while the ratio of aluminum and silicon was 4.25, and harmful components such as Fe and S graded 7.3% and 1.33% respectively. The ore is characterized by complex mineral compositions, fine dissemination of particle size of pyrite and diaspore, low desulfurization efficiency, and difficult separation of aluminum and silicon. In order to improve the degree of concentration, recovery and desulfurization efficiency on the basis of process mineralogy studies, the floatation behavior of high sulfur bauxite in the process of desulfurization and desilication were studied through laboratory tests and pilot plant tests. KEYWORDS high-sulfur bauxite; low grade; flotation; desulfurization;desilicication INTRODUCTION In order to solve the selection problem of bauxite mine area, we carried out technological mineralogy, laboratory test, small-expansion Dalian test to solve the problem of the refractory ore. Main research contents and conclusions were presented as followings :(1)Process mineralogy research shows: the main mineral components include diaspore, kaolinite, chlorite, pyrite, limonite. (2)Batch flotation tests indicated that slime can be dispersed well during desulfurization floatation when Na2CO3 was used as modifying agent. (3)Poilot plant tests shows that Batch flotation tests results are correct. 2?PROCESS MINERALOGY 2.1 Chemical Composition of Ore 2.1.1 Spectral Analysis of Sample The results of the semi-quantitative analysis of X-Ray -fluorescence spectra of the original ore are shown in Table 2-1. The results of spectral analysis show that the main components of the sample are O, Al, Si, followed by Fe, Mg, Ti, S and so on, while the content of other elements is very small. The value is Al, and maybe Ti, for bauxite, while Fe and S are unfavorable elements, and Si and Mg and Ca are the main impurity elements."

Jan 1, 2018

By G. N. Jadhav

In India, bauxite deposits are concentrated in Central India, Western Ghats and Eastern Ghats. Bauxites from various regions in Gujarat were identified during the present investigations of geochemical mapping. Different types of Bauxites samples were collected from Kachchh, Jamnagar, Porbunder, Junagarh, Bhavnagar and Amreli areas of Gujarat state and were studied in detail for their geochemical signatures to plot the data on Geochemical map. Raw bauxites were characterized by using powder XRD, XRF, ICP and optical microscopy techniques (with the help of Model microscope having both transmitted and reflected light setups) and were later examined to grade their quality. Most of the bauxites from Kachchh region were of high-grade (gibbsitic) type; while those of Sourashtra region were of low-grade (lateritic / calcitic) types. Most of these bauxites were either of ferruginous/lateritic or of calcareous/calcitic types. Based on the mineralogical composition, such as gibbsite, hematite and/or goethite, Kaolinite and calcite minerals present in particular bauxites, the deposits were graded. Finally, the Geochemical mapping of Bauxites for Gujarat region was prepared and discussed.

Sep 1, 2012

By Liu Fan, Shang Yanbo, Wang Zhongming

"Besides valuable metals of Cu, Sn, WO3, Zn, there are S, Ag, CaF2, In and so on in a complex ore deposit in south China (which belongs to Hu Nan Shizhuyuan Non-ferrous Metal Limited Liability). Although it proved reserve amounts to 3.5×107 ton, its crystal character limits its utilization in large-scale. It features complex relationships between valuable minerals, finest crystallized particle size, low-graded valuable metals (Cu 0.30%, Zn 0.5-0.7%, Sn 0.2%, W<0.1%). If only tungsten minerals are considered, it means WO3 grade is too low (the cut-off grade of WO3 is 0.1% in China). Only Cu and Sn minerals are recovered from 2006 and Cu recovery is less than 70%, Sn 15-20%. Other valuable metals of W, Zn, S and CaF2 were lost in the tailings. To make good use of the ore, the technology of fully recovering Cu, Sn, W, Zn, CaF2 and rare metals are in urgent need. After systematic researches, the flow sheet of "bulk flotation of Cu-Zn minerals at first, then Cu-Zn separation, then recovering sulphide by flotation, then recovering iron minerals by magnetic separation, then bulk flotation of Sn-W minerals after desliming" is developed. Furthermore, specific Sn-W collectors of BK411 and BK412 are applied into the processes and better indexes are obtained. The industrial indexes are listed as followings: the content of Cu, Zn, Sn, WO3 of ROM ore is 0.31%, 0.65%, 0.13%, 0.03%; Cu and Zn recovery are 82.23% and 37.79% respectively; 63.76% of Sn and 34.34% of WO3 go into the Sn-W bulk concentrates. Economic benefits are remarkable."

Jan 1, 2014

By G. Mucsi, F. Kristály, Á. Rácz, É. Gregus, K. Bohács

"Stirred media mills are widely used in the industry for fine grinding. Most of the applications work in wet mode, however dry grinding in stirred media mill comes forward more frequently nowadays. The present paper deals with the differences and similarities of the wet and dry grinding in stirred media mill from energetic and mechanochemical point of view as well. Grinding experiments in batch stirred media mill were carried out with different materials. During the experiments zeolite and kaolin were used as feed material. The grinding experiments were carried out at different stress energy and stress number values; the grinding work was measured during milling. After grinding X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), particles size analyzes by laser scattering were carried out on the ground materials. As a result of the systematic grinding and analytical measurements a comprehensive comparison was carried out on the wet and dry grinding and their usefulness for mechanical activation in stirred media mill. INTRODUCTION The natural zeolites are crystalline hydrated aluminosilicates of alkali and alkaline earth characterized by the structure that contains frameworks responsible for the high cation exchange capacity (CEC) and absorption capacity. The frameworks are interconnected by cavities and resided by cations variable in size, coordinated by water molecules. Since zeolite comprises SiO4 and AlO4 tetrahedra interlocked by oxygen atoms that are situated in the structural nodes, their characteristics differ due to the varieties in the structure-directing agents and Si/Al ratio (Colella and Wise, 2014; Malekian et al., 2011; Terzic et al., 2017). The most common natural zeolite occurring in high amount, of industrial importance and involved in milling and MA is the clinoptilolite, in the literature equivalent to “natural zeolite” designated for high clinoptilolite bearing volcanic tuffs. Its amount in the host rock must reach ~ 40 % by weight to obtain the CEC and adsorption desired in its applications. In the highest quality rock might reach 80-90 % by weight (Favvas et al., 2016), but most often is the 40-60 % by weight content, associated with smectites, improving the CEC and adsorption of the tuffaceous rock. The application of such natural zeolites is problematic in many cases due to high silica (quartz, cristobalite and volcanic glass) content and beneficiation (concentration and extraction of pure zeolite) are not feasible. Thus, mechanical activation is a possible way to alter the other than clinoptilolite minerals generating high specific surface area and functionalized particle surfaces to enhance adsorption, reaction or particle adhesion. The zeolites easy availability and the utilization cost-effectiveness have prompted the research on their physicochemical and structural properties (e.g. adsorptive and molecular-sieve activity, heat resistance, and microporous cage structure) and finding new options for their application (Kusuma et al., 2013; Musyoka et al., 2014; Rida et al., 2013; Terzic et al., 2015b). Apart from the presence of exchangeable framework cations which are crucial for the adsorption ability, and a certain degree of pozzolanic reactivity. The thermal stability of dehydrated phases is another important characteristic for use of the zeolite in composite materials that are exposed to high temperature. Thereby, the zeolites found a wide application possibility in the design of the construction composites (Albayrak et al., 2007; Najimi et al., 2012; Vejmelková et al., 2015), as well as for resolving of the environmental protection issues like wastewater refining or heavy metal elimination (Gómez-Hortigüela et al., 2014) even from contaminated groundwater using passive methods like permeable reactive barriers (Gombköto et al, 2016). The grinding treatment of zeolite is a common and frequently applied procedure, both on laboratory (Bohács et al. 2017, Faitli and Czél, 2014)"

Jan 1, 2018

By M. M. Moghaddam

Charge motion is of prime importance in the efficiency of comminution in tumbling mills. Since direct observation of charge shape and its motion in industrial mill are not possible, a combination of analytical and physical studies was used to determine charge trajectory. Software packages, which predict charge motion such as the GMT (Grinding Media Trajectory) only consider the outermost layer of charge (single ball) and ignore the interactions of grinding elements. In this research, the measured charge trajectory in a 1m-diameter mill with the transparent end, called model mill, was compared with that of the GMT. Four types of polyurethane rings were accurately machined to scale down the liners arrangements at two industrial mills. To explore various charge shapes and trajectories, the model mill was operated at 55, 70 and 85% of critical speed for five levels of mill filling (10, 15, 20, 25 and 30% by volume). The angular displacement of the toe, toe departure, shoulder and charge impact point were determined from the photographs taken from the model mill. New relationships to predict charge shape and charge impact points were introduced to modify the GMT results. The relationships were validated by the model mill using the new liner of the Sarcheshmeh copper complex SAG mill. The relative error of prediction was found to be 1.1%. The results indicated that when the lifter face angle increased from 7 to 30º, the distance between the charge impact point and the toe decreased from 52 to 31º for 25% filling. This meant increasing the probability of charge impacting the toe not the liner which favoured more efficient comminution practice. After converting AG mills to SAG mills on account of liner profile change, 31% increase in throughput (from 419 to 548 t/h) in addition to 4% decrease in the product size (from 516 to 496 µm) were realized which was a significant contribution in the plant performance improvement.

Sep 1, 2012

By Kozlov Andrey, Matveeva Tamara

"The results of mineralogical and technological studies of platiniferous dunites from Svetloborsky zonal massif (Urals platinum belt) are presented and the basic typomorphic signs of productive mineral assemblages are substantiated. The characteristic features of platinum ore mineralization are revealed: a wide range of iron-platinum alloys, enrichment of ore-formed system by the elements Os, Ir, Rh and activity of the S and As in it, intrusion of Fe-Ni sulfides in platinum and its fusion with magnetite. More than 80% of PGM mineral grains has size less than 100 microns, that determines the possibility of significant losses of platinum in the process of gravity separation and the need for additional recovery processes for small and fine fractions of platinum tailings and sludge products. Summarized results of laboratory tests of small-volume sample processing of platiniferous dunites are presented and the processing flow sheet is developed and tested. The flow sheet incorporates several stages, including stage-wise grinding and gravity separation of ore using the centrifugal concentrator Knelson KS-MD for differently sized material and flotation treatment of tailing products using new classes of reagents for additional recovery of PGM fines."

Jan 1, 2014

By A. V. Kanarskay?

The research is aimed at involving in the processing of poor platinummetal natural and technogenic raw materials. The purpose of the research is the creation of a multifactorial complex of innovations in the system of ore preparation and separation cycles, which ensure a high efficiency of flotation enrichment of hard-to-treat raw materials. In the usual practice of enrichment, minerals of the platinum group (PGM) of less than 10 microns in size are the source of inevitable process losses. For poor raw materials, it is precisely thin PGMs that are characteristic, their proportion sometimes being almost 100%, and their opening leads to the formation of a large amount of slime, which adversely affects the efficiency of flotation. To reduce the yield of slimes and increase the selectivity degree of the opening of the PGM in the ore preparation cycle, a dry grinding scheme and pneumoclassification of the milling material has been developed to obtain fractions of different fineness, density and morphology of the particles. From 2 to 5-fold reduction in the yield of slurries for various ores has been achieved. The separation cycle successfully tested are: flotation of fractions in separate cycles with a differentiated choice of the reagent regime; preliminary selective flocculation of slime fraction material; use of a new generation of bioreagents for flocculation and flotation. A new approach to subsoil research is protected by a patent. The dependence of the efficiency of biocollectors on the composition of biomineral extract from the processed raw materials, which forms the basis of new reagents, is established. The possibility of obtaining the degree of extraction of PGM, native gold and sulphides from finely ground pre-fractionated poor ores with the use of biocollectors of at least 85% is proved. With conventional reagents, the extraction of PGM is 12-23% lower, with the use of traditional ore-preparation apparatuses, the PGM recovery rate was halved. Methods for the long-term storage and preparation in industrial conditions of biocollector reagents that do not require the purification of waste waters from them have been developed. The developed multifactorial system of intensification of flotation enrichment can be introduced to recovery PGM from tailings of enrichment of titanomagnetite, chromite and copper-nickel ores.

Jan 1, 2018

By A. J. Lynch, D. K. Tungpalan, Y. Reja, E. C. Avelar, G. Figueroa, S. Gómez, R. Alanis, M. A. Corona-Arroyo

"Have you been on a mine site? This question was posed by Emeritus Professor Alban Lynch to Higher Degree by Research (HDR) Students from the Sustainable Minerals Institute - Julius Kruttschnitt Mineral Research Centre (SMI-JKMRC) in the Student Technical Presentations in 2015. From that question, five HDR students from SMI-JKMRC organised a placement on mine sites in Mexico. The SMI-JKMRC is well known for its tradition to provide their students with opportunities to enhance and test their skills in mineral processing plants. The Student Venture became a short internship for HDR students which had the objective of establishing collaboration with mining companies in Australia and overseas, and of providing a unique experience for the HDR students in regard to their training, professional development, networking and cultural interchange. In return for the companies’ support, the students conducted plant audits to evaluate the process performance thereby providing valuable data to the host company. The 2016 Student Venture was held at the Grupo Peñoles & Grupo Fresnillo in Mexico, in which three mine sites received five HDR students from JKMRC and one young researcher from Universidad de Guanajuato (UG). This paper describes the positive outcomes for the mining company and the students for this experience. The Venture was considered very successful, as it provided valuable training for the students as well as in depth information about the operation of the comminution and flotation circuits of the host sites for the Grupo Peñoles & Grupo Fresnillo. The experience also provided an opportunity for an exchange of knowledge between the HDR students and the site personnel from the host operations. The indication of the success of the experience for all involved was the support of the host company in future student internships."

Jan 1, 2018

By P. Zarate, M. Peart, T. Bhambhani, D. R. Nagaraj

More than 50% of all the molybdenum produced in the world is a by-product of copper production. A bulk Cu-Mo concentrate is first produced, which is subsequently separated into Cu and Mo concentrates. The Cu-Mo separation circuits rely on the use of inorganic Cu sulfide depressants such as NaSH, Na2S, and Nokes, which are hazardous, and sometimes require very large dosages for effective depression. Synthetic polymeric depressants are safer and more efficient, and are now being used on the plant-scale. Data presented in this paper demonstrates that these polymeric depressants can replace 50-90% of all the NaSH in Cu-Mo separation at a fraction of the NaSH dosage. In this paper we provide an overview of the mechanistic and practical aspects of the Cu-Mo separation with inorganic depressants and polymeric depressants. Important practical aspects include depression dynamics (related to conditioning time and rate of depression), optimum pH for effective separation, the role of pH modifiers such as lime and NaOH, and the effect of flotation gas on the efficacy of the separation. Using nitrogen as flotation gas, the NaSH consumption can be reduced by up to 95% by using a small amount of polymeric depressant. The experiments with conditioning time demonstrate that there is a significant rate component to the depression mechanism with NaSH, which is absent for the polymeric depressant system. This has important implications in the effective use and application of the depressant. It is also demonstrated that the pH modifier type (NaOH or Ca(OH)2) has no significant effect on separation efficiency and Mo recovery (i.e. Ca2+ ions do not depress MoS2 in the Cu-Mo separation).

Jan 1, 2014

By Caroline Olsen

The objective of this study was to achieve Zn activation control in an industrial Cu flotation circuit treating a complex Cu-Pb-Zn-Au-Ag sulphide ore at the LaRonde Division of Agnico-Eagle Mines Limited (Québec, Canada). In order to provide process relevant results, a laboratory testing methodology was developed to duplicate plant operational parameters. The action mechanisms of ZnSO4, TETA (triethylenetetramine) and NaHSO3used as depressants in order to limit ZnS activation were examined. Laboratory flotation tests with and without Cu2+ions (the ions responsible for ZnSactivation)were performed. All depressants showed equal or better flotation performance relative to baseline tests. For example, in the presence of Cu2+, the Zn recovery reduced from 32.2% to 17.5% in the copper rougher concentrate after adding ZnSO4(with a dosage of 50 g/t). TOF-SIMS analyses confirmed the relative decrease in surface Cu in the samples treated with ZnSO4and TETA. For the case with TETA, this indirectlyindicates the formation of a copper TETA complex in solution, thereby reducing available Cu for transfer. The TOF-SIMS and XPS data indicate that the addition of ZnSO4and NaHSO3resulted in an increase in surface metal hydroxides and SO3 on ZnS grains inhibiting both Cu and collector attachment.ZnSO4 was subsequently tested with success in the LaRonde concentrator. The addition of 40 g/t ZnSO4 at the conditioning (or cleaning) stage led to a 2% reduction in Zn content in the Cu and PM concentrate. Recently, improvements towards the control of copper sulfate addition in the downstream Zn flotation circuit resulted in the reduction of Cu2+ in process water. As this ?cleaner? water is recycled for Cu and PM flotation, the addition of ZnSO4 is now used only as required.

Sep 1, 2012