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By Leena Vesa, Antti Remes

Design of thickeners is based on laboratory test work, characterizing the material and determining the optimal reagents, dosages and settling regimes. Several methods for dimensioning plant scale equipment exist. Kynch and Talmage-Fitch design procedures has been applied widely for a long time. Nowadays, besides them, a dynamic laboratory test work is applied for design of high rate thickeners. In that the laboratory unit is operated with known solids load per area, feed and flocculation conditions and with raking of the underflow. All these test methods afford useful data for setting up and calibrating a dynamic simulation model of a plant scale thickener. This paper presents a flocculation kinetics based dynamic thickener simulation model and a procedure to calibrate the model parameters. With the model, the underflow stream composition can be simulated over time as a function of the thickener operating parameters, which are: the feed rate and composition, underflow pumping rate, flocculant dosage and dilution of the feed. In addition, the model incorporates calculation of the slurry bed level, the cone pressure, the yield stress and the rake torque. Such a dynamic modeling scheme enables setting up simulation aided operator trainings and developing and testing of advanced control strategies, for example. The unit model can be integrated as a part of concentrator-wide flow sheet simulation model as well. Here, calibration of the kinetic flocculation model based on a laboratory test case data and further the operation of a simulated plant scale thickener are presented.

Jan 1, 2014

By Christopher Greet, Alfred Van den Bosch

"A range of media alloys with different chromium content has been developed for different milling applications. When selecting the grinding media alloy for a specific application, consideration must be given to the mineralogy of the ore as well as the water chemistry and mill operating conditions. The paper describes the influence of the microstructure of the alloy on the wear resistance and the influence of the chrome content on the pulp chemistry and downstream processing. It also provides information about the in-house tools which Magotteaux have developed to predict the media wear rate with different chromium content alloys and predict their flotation efficiencies that can be expected when the right alloy is selected for a particular application."

Jan 1, 2014

By Andrei Kolesnikov

"The results of CFD modelling of complex heat transfer and fluid flow in DC electric arc furnace are presented. The model includes energy and momentum conservation equations for gas phase (freeboard), liquid phase (molten bath) and solid phase (walls and graphite electrode). Simulation revealed the temperature distribution in all elements of the furnace. The influence of the arc and melt resistance on the temperature distribution is discussed.Computational Fluid Dynamics (CFD) becomes a powerful tool for better understanding of the heta and mass transfer processes in industrial equipment. In current work commercial CFD software STAR-CD was used to analyse complex heat transfer in DC EAF, including forced and natural convection, conduction and radiation. The finite volume solver using body-fitted grid was used. The grids are non-staggered hexahedral grids and all variables are evaluated at cell centers. Steady-state calculations were performed with PISO algorithm. For the convective terms in equations the hybrid differencing scheme was used. An upwind differencing scheme was used for other terms. Conjugative heat transfer was taken into account in heat transfer calculations on gas-liquid and gas-solid interfaces. Radiation from the arc and inner surfaces of the furnace was calculated by a “discrete beam” approach. Source term in energy conservation equation was used to represent heat release in the zone occupied by the DC electric arc. The volume of this zone was calculated from semi-empirical equations. The Joule heat and heat due to chemical reaction in the melt were calculated through the source term expression in the energy balance equations for the slag and metal in the molten bath. The gas acceleration in the electric arc zone and stirring of the slag due to gas bubbles motion were accounted for by momentum source terms in the momentum conservation equations.All simulations were carried out using axisymmetric two-dimensional grid. The grid resolution was 20 cm per cell in most part of the furnace, except the arc region, where resolution was 5 mm per cell."

Jan 1, 2003

By P. Saha, D. M. Chakrabarti, National Metallurgical Laboratory, P. Bhattacharyya, B. R. Sarkhel

The estimated reserve of the phosphatic soils at the Sukulu hills region of Uganda upto a depth of 60 meters is of the order of 200 million tonnes and analyses 10-12% P2O5. A 5-tonne sample of the phosphatic soil was received at the National Metallurgical Laboratory (NML), India for beneficiation studies. The ore occurred as a naturally degraded soil deposit and the slime contained earthy lateritic minerals which made it extremely sticky. Microscopic examination revealed the presence of limonite, magnetite (martitised), hematite and goethite as major minerals along with apatite and quartz. Presence of clay was indicated by earthy smell on moistening the sample. It was observed that getting rid of the slime was as important for adequate beneficiation of the ore, as it was difficult. Earlier studies on samples of the same ore at the NML and abroad established that it was necessary to pass the ore through a series of three stages of desliming, each consisting of a step of rigorous attrition scrubbing followed by hydrocycloning, for effective elimination of the sticky slimy coating which stubbornly adhered to mineral grains. Studies were carried out at the NML in two phases to develop a flowsheet for beneficiation of the phosphatic soil. In the first phase, reproducibility of the results obtained by employing a flowsheet developed abroad was confirmed along with suggesting some modifications of the flowsheet. Then 200 kg. of concentrate was produced following the recommended flowsheet for evaluation of its suitability for production of fertilisers. To remove the limonitic slimy coating, which stubbornly adheres to the other mineral grains, it was necessary to subject the ROM ore, after screening out the +840 micron size fraction which contained only 1.75% P2O5 , to three stages of hydrocycloning each preceded by attrition scrubbing. Then only conventional beneficiation techniques could be effectively employed to upgrade the ore.

Jan 1, 2003

By David Deglon, Martin Harris, Mehdi Safari

This paper investigates the effect of energy input on the flotation of galena in a novel oscillating grid flotation cell (OGC). Oscillating grids generate near ideal hydrodynamic environments, characterised by turbulence which is relatively homogeneous and isotropic. Previous work was limited to quartz (-100 µm). Galena (-150 µm) was floated in the OGC at power intensities from 0.5 to 3 W/kg using 0.13, 0.58 and 0.82 mm mean bubble sizes (d10) and at three collector dosages. Results show that the effect of power intensity on flotation kinetics is strongly dependent on both particle and bubble size. For fine particles (-19 µm), increasing energy input increases the flotation rate at a low collector dosage but leads to an optimum at both the moderate and high collector dosages. For intermediate particles (+19-38 µm), increasing energy input has no effect on the flotation rate at the low collector dosage but leads to an optimum at both moderate and high collector dosages. For coarse particles (+38-150 µm), increasing energy input has no effect on the flotation rate at the low collector dosage and leads to a general decrease at both moderate and high collector dosages. Optimum conditions for fine particles are using small bubbles at a moderate collector dosage and an energy input of around 2 W/kg. Optimum conditions for moderate particles are using small bubbles at a high collector dosage and energy inputs of around 1.0 W/kg. Coarse particles do not benefit from agitation.

Jan 1, 2014

By Anatoly N. Vinogradov, Vyacheslav A. Tsukerman

The North-West Russia for 70 years is one the main producers of Cu, Ni, Co, Al, P, REE, Zr, Ti, Ta, Nb, Fe ores and other minerals in the Europe. The largest mining companies locates in the Murmansk region, and they extracts about 100 mln. tons of ores and damps up to 250 mln. tons of waste annually. Nevertheless an environmental situation in the region is stable due to rational management and treatment of wastes on a base of the Noosphere Concept for Nature-using suggested by Vladimir Vernadsky. The Concept was performed practically in the Fersman’ scheme of “non-waste mining and metallurgical complex”, published in the monograph “Minerals of the Kola Peninsula: current status – analyses – prognoses” (1941) and served till now as a sort of “Bible” for industry managers lightening a strategy for an industrial “trophic chain”. The recent status of this scheme is shown on the picture below, and one can see that our concept is coincide with modern ideology known as the “Industrial Ecology”. Moving along this mainstream in the Kola Peninsula since 1929, when the first mining company “Apatit” was established, we provided the water close circuit in mineral dressing plants, hydrometallurgical treatment of slag and tailings, productions of building materials and adsorbents of wastes. The innovation set of technologies designed by the Kola Science Centre allow recently to involve tailing damps in re-exploitation as the technogenic deposits of valuable raw materials for fertilizers, tanning and cleaning agents, pigments, concretes and etc.

Jan 1, 2003

By P. A. Harvey

Previous studies have reported that inorganic electrolytes can enhance floatability of coal. The research has shown that the enhancement, if any, is highly dependent on changes in solution pH, type of electrolyte, and electrolyte concentration. The reasons for this are still not clear. In this study the floatability of coal particles in mono and divalent salt solutions was investigated. The zeta potential and hydrophobicity of the coal was measured experimentally, and a modified Hallimond tube was used to determine the floatability of coal particles by single bubbles, where the collision efficiency was equal to unity. The experimental information was used in conjunction with the Hogg-Healy-Fuerstenau equation to quantify the electrical double layer interaction. It was found that for low electrolyte concentration (less than 0.1 M) solutions the flotation recovery of coal particles was less than that for distilled water, and decreased with increase in concentration. Conversely, at electrolyte concentrations above 0.1 M, flotation recovery increased with increasing concentration (Figure 1). Both of these results are consistent with previous observations, but are inconsistent with expectations when considering the possible influence of electrical double layer interaction. Modelling of the system indicates that the electrical double layer is compressed with increasing electrolyte concentration, resulting in an increase in flotation recovery due to a diminishing of the (electrical double layer) repulsion between the bubble and the coal particles. Moreover, for electrolyte concentrations above about 0.1 M the electrical double layer is completely depressed and would have little further influence, if any, on the flotation process. Therefore, the electrical double layer interaction is not the principal determining factor for the flotation of coal in electrolyte solutions.

Jan 1, 2003

By Zhaohui Qiu, Yaguan Ji, Hong Zhong, Qingxia Liu, Yada Liu

"Water is a necessary process medium in mineral processing. For the operations where fresh water is not available, sea water could be used as an alternative processing medium to replace the fresh water if we would have built a solid understanding of the interfacial science and flotation chemistry of sulfide minerals in sea water. In this research, micro flotation of chalcopyrite and pyrite in deionized water and sea water were investigated. For chalcopyrite, the recovery starts to drop from pH 10 in deionized water and from pH 9 in sea water, and the flotation recovery close to 100% before it drops. We can found from the results that chalcopyrite flotation is depressed much at pH 11 in sea water when much white precipitate is found. For pyrite, the flotaion recovery changs a lot in deionized water with 1*10-5 M potasium amyl xanthate (PAX) as collector. It’s relatively high at pH 8~10 compared with that at pH<8 and pH>10. While in sea water, the trend is almost the same as that of chalcopyrite. Zeta potential measurements and chemical equilibrium calculation were used to find out that magnesium hydroxide species coats on the surfaces at high pH in sea water are the main reason for depressing the chalcopyrite and pyrite flotation. Through understanding the interfacial science and the solution chemistry of sea water and its impact on processing efficiency, this research will not only helps reduce the use of fresh water to minimize the disposal of spent water for environment protection, but also enhance the recovery of valuable minerals in froth flotation."

Jan 1, 2014

By J-P Franzidis, P. O. Gyebi

"Coal-water mixtures (CWM) of concentrated fine coal may be transported in pipelines but this is influenced by both CWM rheology and stability. Here, a low viscosity is required to reduce power requirements, as well as good stability for transport and storage. The objectives of this study are to investigate the importance of surface charge, solids concentration and dispersant addition on the rheology and stability of a fine Witbank coal-water mixture (<75 m). Zeta potential, rheology and stability were measured with a Malvern Zetasizer, a AR1500EA rheometer and a static rod penetration test, respectively. Sendep 30D, Sendep 30F and Norilose 8058, all supplied by Senmin International, were used as dispersants, at dosages of between 0.1 to 0.5% dry coal (w/w). Solids concentration was varied from 10 to 58% (w/w). The zeta potential was found to be positive at low pH and decreased sharply with increasing pH to a minimum of -50 mV at pH 10. The zeta potential decreased with increasing dispersant concentration for all dispersants. The lowest zeta potential of -63 mV was obtained for Norilose 8058 at a dosage of 0.3%. CWM rheology was Newtonian at lower solids concentrations but became non-Newtonian at solids concentrations over 40% (w/w), with an initial yield stress and pseudo plastic behavior. The yield stress decreased sharply with increasing dispersant concentration for all dispersants. The lowest yield stress was obtained for Norilose 8058. The addition of dispersants resulted in significant improvements in stability. A penetration ratio of over 70% was obtained for Norilose 8058 after 10 days. In summary, the addition of dispersants resulted in a decrease in the zeta potential which increased the electrostatic repulsive forces between particles, thus improving both CWM rheology and static stability.INTRODUCTION Coal Water Mixtures South Africa’s energy economy depends heavily on coal. It accounts for about 70% of primary energy consumption, 93% of electricity generation and 30% of liquid petroleum fuels (Eberhard, 2011). The transportation of coal to export markets and power generation stations is a problem in the South African coal industry due to ageing and inefficient rail infrastructure. This problem is intensified by the long distance of coal haulage, delays in the time required to load and unload wagons, and environmental challenges related to air pollution and water contamination. Fine coal may be transported more efficiently and economically in a pipeline as a highly concentrated coal water mixture (CWM). Typically a fine coal CWM will contain 60-75% coal, 25-40% water and nearly 1% of dispersing additives (Atesok et al., 2005; Dincer et al., 2003). However, the transport of CWMs in pipelines is strongly influenced by both CWM rheology and stability. Here, a low viscosity is required to reduce power requirements, as well as good stability for transport and storage. These quantities are affected by the coal composition/mineralogy, solids concentration, particle size and size distribution, particle shape, inter-particle forces and dispersant type and dosage (Laskowski, 2001)."

Jan 1, 2018

By Ashok M. Raichur, S. P. Vijayalakshmi

"Recent advances in technology and the growing environmental concern have laid emphasis on the usage of fine clean coal. Coal fines are also generated in large amounts during various coal processing operations and are difficult to be treated, handled and disposed. Since most of the operations use water as the carrying medium, the fines so generated contain lot of moisture. Conventional technique for processing coal fines includes flocculation by a polymeric reagent followed by moisture removal using a rotary drum or a pressure plate filter, which produce a product with more than 30% moisture. Polymeric flocculants though required in small amounts, need high shear mixing for good performance and operate only in a narrow pH range. Moreover they increase the viscosity of the solution by many folds. Hence it becomes imperative to emulate newer methods for efficient fine coal processing. One such method is the novel use of microorganisms in coal processing.The present investigation deals with the utilization of two gram-positive microorganisms, Mycobacterium phlei and Bacillus subtilis, as bio flocculants and dewatering aids in fine coal processing. Preliminary characterization done on J-coal and M.phlei showed that they are negatively charged over most of the pH range. B.subtilis was found to possess positive charge below pH 4.7. The adhesion studies proved the high potential of microorganisms for adsorption to surfaces. Adhesion tests were conducted at various experimental conditions by varying parameters like pH and ionic strength of the suspension. Results obtained showed that adhesion is always higher in the presence of an electrolyte like KNO3 and most of the adhesion takes place in 15 minutes. With change in pH the amount of B.subtilis adhering on to J-coal remained almost constant and for M.phlei it decreased at higher pH values. Increase in ionic strength did not increase the adhesion of bacteria. Flocculation experiments confirmed the ability of the bacteria to act as bio flocculants. It was seen that about 98% of the coal settled in about 2 minutes on the addition of bacteria along with the addition of the electrolyte. The electrolyte was found to be indispensable for efficient flocculation of the coal suspension and for the attainment of a clear supernatant after flocculation. Also the optical micrographs revealed the formation of large, tight flocs when the electrolyte is present along with the bacteria. Further, flocculation tests were done in the pH range of 2-10 and the flocculation efficiency was found to be independent of pH."

Jan 1, 2003

By Julian Dimitrov, Kremena Dedelyanova

"The paper presents research on hydrodynamic processes occurring at the elementary act of flotation. Discussed existing models to determine the effectiveness of conflict of bubbles with particles in vibration column flotation machine. The paper presents a disperser for a column flotation machine, in which the dispersion of the gas phase is carried out using vertical vibration with defined frequency and amplitude. The paper presents research of mechanism for the creation of air bubbles in vibratory column flotation machine. The factors influencing the increase in the duration of the bubble in the area of contact with the mineral particles are discussed. Research was carried out on the effect of frequency and amplitude of vibrations on speed of precipitation of mineral grains of different density. Formulas are derived for the parameter effect of vibrations, applicable to the design of flotation machine. The collision efficiency of the bubbles in vibratory column flotation machine is determined. The vibrations of the hydrated layer allow for cost-effective implementation of the elementary act of flotation by providing larger relative velocities at the contact point between the bubble and the solid phase. It is proposed to complement the model more accurate representation the mechanism of attachment of the particles to the bubble."

Jan 1, 2014

By A. J. Lynch, L. Ergun, M. Oner

"A research program on modelling cement grinding circuits has been in operation at Hacettepe University, Ankara, for four years. It has concentrated so far on tube mill and air separator grinding circuits for cement clinker, with emphasis on plant sampling surveys, including axial sampling inside the tube mills. The data used for model development have come from 33 surveys in 9 plants.The operating conditions have been:- mill sizes - 3.2 to 4.8 metres diameter and 8.5 to 15 metres long,- mill feed rates - 46 to 158 tonnes per hour,- air flow through mills - 25000 to 125000 cubic metres per hour,- cement clinker work indexes - 10.3 to 18,- separator sizes - 2. to 3.1 metres diameter,- separator feed rates - 132 to 689 tonnes per hour,- separator speeds - 12.3 to 21 metres per second.The ball mill model is Whiten’s perfect mixing model and the separator model is the Tromp curve with a fish-hook. This paper emphasises the importance of calculating the breakage rates and the discharge functions with three case studies at five different circuits which were selected for discussion because they show how particular features of circuit operation can be included in the general models. Size distribution graphs are used to illustrate every aspect of the discussion"

Jan 1, 2003

By Nicolás Caussade

"The IMPC 2014 slogan "Optimizing Water and Energy Usage for Sustainable Mining" refers to the ever decreasing availability of fresh water and energy, which has turned out to be a crucial aspect in assuring the competitiveness of the mining sector in Chile and the Andes region in general. The concern for sustainability and the supply of water and energy is nowadays part of the top priorities of mining countries and communities. This is also the case for Antofagasta Minerals. Several years ago its mining group implemented an energy policy based on intelligent, strategic and sustainable management, in order to successfully face the challenges imposed by the market. It is called an intelligent policy because it intends to provide energy through a diversified range of sources, which includes the development of in-house alternatives. It is also a policy focused on efficient energy consumption and one that is strategic. Because it is in line with the characteristics of the mining activity, it is developed for the long term. Finally, what makes the policy sustainable is that it gives priority to energy usage from renewable resources and as such, the required capacities have been developed to generate innovative solutions that respond to the restrictions that characterize the industry today."

Jan 1, 2014

By Stefan Mutz, Thomas Pretz, Jörg Julius, Frank Hilbk-Kortenbruck, Aachen, Hartmut Harbeck

"The annual global production of primary aluminium was about 22 million tons in the year 2000. This represents the second largest production rate in the world market after steel. Experts are predicting that the global demand for aluminium will rise in the near future.In contrast to other metals such as copper, the recycling of aluminium is considered relatively difficult. There are two main alloying groups, namely cast and wrought. In the case of aluminium it is important that the constituents within the scrap aluminium to be smelted are clearly identified. Within the secondary remelting process alloying does take place, but a removal of unwanted metal constituents is problematic. Therefore mixed aluminium scrap (not genuine in-house collected material) can only be used to produce cast aluminium. Thus, in other words a down-cycling of wrought (extrusions and rolled) products occurs. However, in spite of these difficulties there is an increasing trend to produce aluminium from secondary scrap (approx. 35% in Germany). Similar trends have been identified in the USA and other industrialised countries. This development is mainly caused by the high energy consumption for the production of aluminium from bauxite. Producing aluminium from scrap is saving about 95 % of the energy in comparison to the processing of primary raw materials.An improvement in sorting technology is necessary to separate wrought and cast alloys of aluminium as the absolute amount of recovery from old scrap is higher than the demand for cast.This contribution presents some alternative methods, utilizing automatic picking technologies, which will be used to separate secondary aluminium in the future. During the recent years, some major progresses have been made in automatic picking technologies for different applications in the processing of primary and secondary materials.For the sorting of aluminium scrap a special additional sensor will be necessary. The best detection will ultimately be based on online elemental analysis of single particles. First investigations in the field of laser based systems for these applications have already been performed several years ago. One of the laser based techniques is the laserinduced breakdown spectrometry (LIBS)."

Jan 1, 2003

By Victor Avdokhin, Valery Morozov, Valery Stolyarov

"The adaptation-determination method provides for keeping given relationship between concentrations of ionic and molecular components of a pulp liquid and correction of parameter of the model on the basis of analysis of ore composition, technological parameters of flotation, and cost of valuable components.• optimisation program “ADDEFLOT” and combined analyzer of pulp “RA-931”An adaptation-determination method provides for two-level control of bulk and selective flotation of polymetallic ores. The lower level provides for control of reagent dosing on the base of control of ionic composition parameters in the pulp liquid phase. The control goal is to keep the basis relationship among parameters of ionic composition (ions A, B, C) in pulp liquid phase given by equations of type:• alg[A] + blg[B] + clg[C] = K (1)Values of a,b,c coefficients are uniquely determined by a physico-chemical model used. Kind of the model depends on mineral composition of an ore and reagent regime applied. As parameter of ionic composition, also values of one or two parameters (or their combinations) can be used, for instance, pH, concentration of sulfide ions, ions of collector.The upper level of control is based on calculation and use of technological results of selective flotation. At the level, an adaptation of the model (1) is conducted. A principle of the adaptation is in determining (and including in pre-setting function of the lower level) such value of K parameter, at which maximal economic effectiveness of the process is reached. As a criterion of economic effectiveness of the process, a function of losses of several valuable components, taking into account cost of the metals lost, is used. For 2-component ore, in simplified form, the function is as follows:"

Jan 1, 2003

By Nirmal S. Weerasekara, Malcolm S. Powell, Mohsen Yahyaei

"An understanding of the fundamentals of different breakage mechanisms is critical for successfully modelling comminution processes. Due to the high frequency of low energy collisions in the grinding process, superficial breakage has a significant role in size reduction in mills. To develop a scaling up methodology for characterising low energy surface damage behaviour of ores, a series of surface damage tests have been conducted using three grinding mill sizes with diameters of 1.8, 1.2, and 0.8 m. Two types of gold-copper ore with different hardness were used: C-ore and T-ore. All tests were conducted using wet mode to remove the products during grinding. To ensure low energy surface damage was the dominant mechanism, in all tests the mill speed was reduced to 40% of critical speed. A surface damage index normalised with product mass and surface based specific energy is determined from the results enabling a study of the grinding performance regardless of mill size, energy level or charge mass. Incremental breakage tests using the JKRBT indicate that the A×b values of the T-ore were 60% higher than C-ore, suggesting the T-ore is considerably softer. The fractional mass loss rate for the T-ore in the 0.8 m and 1.8 m mills started from 16 and 7 (1/kWh/m2) while for the C-ore it was 4 and 2 (1/kWh/m2). After 6 minutes the surface damage index in all tests tends towards steady state a constant value, an indication of steady state surface damage condition. It has been demonstrated that this methodology can be a useful basis for characterising superficial breakage behaviour of ores."

Jan 1, 2014

By P. M. Solozhenkin, V. P. Nebera, V. D. Skorohodov

"Aqueous dispersions of air specifically prepared on the basis of flotation reagent solution acquire active properties in relation to the solid surface and may be imply as a medium for flotation ores. Such aerated solutions were defined as Activated Aqueous Dispersions of Air (AADA) with 5-6:1 ratio and the procedure of mineral separation was defined as a flotation process under non-equilibrium conditions. These procedures differ from conventional flotation mainly in reagent interaction with minerals through their adsorption films on gas bubbles simultaneously forming flotation complexes. Gas-liquid mixture is kept till an adsorption layer of reagents close to the limit value is formed on the surface of bubbles. The theoretical basis of AADA is considered.The results of two-phase gas- liquid mixture (AADA) were studied. Two versions of AADA were considered. Electrical surface potential of the air bubbles with the surfactant film, untreated minerals particles in Coulomb attraction and flotation complex formation were analyzed. Special flotation machines were constructed for separation of mineral suspension in air dispersion, whose effectiveness was confirmed in flotation of apatite waste of Kovdor ore. FK-9 machine introduced on Kovdor iron ore combine for the recovery of apatite from current departures of factory. The froth product contained 7.2 % P2O5, with recovery of 44 % apatite, which was processed for getting melted phosphoric-magnesium fertilizers."

Jan 1, 2003

By Andrzej Luszczkiewicz, Magdalena Duchnowska, Jan Drzymala

A selected flotation system of beneficiation of the copper ore at KGHM Polska Miedz S.A. has been analyzed in the article. It was found that a proper assessment of upgrading must be based on two elements, that is the upgrading process selectivity and working point of the considered flotation unit, both determined, preferentially by means of the Fuerstenau recovery-recovery upgrading curve. The Cu recovery - non-Cu components recovery upgrading curve was selected for calculations because its background lines (no separation and ideal separation) are insensitive to changes in the grade of feed of the processed material. This approach allows a comparison of upgrading results for feeds having different grade, being upgraded in various flotation machines and under different physicochemical conditions. It was shown in the paper that the main criterion for comparison of two working in parallel systems is selectivity of upgrading. However, when two flotation machines, despite of the same selectivity, produce concentrate and tailing of different grades, it is necessary to analyze their working points using upgrading curves. The proper position of the working point depends on the criterion imposed on the process and is a result of not only basic parameters of the upgrading process such as feed, concentrate and tailing grades but also on economic parameters such as costs associated with the production of concentrates and the time needed for their production.

Jan 1, 2014

By V. A. Masloboev, A. V. Svetlov, D. V. Makarov

"The methods of heap leaching are considered to be the most promising for the low-grade copper-nickel raw materials. The article presents intensification capabilities of the process. Objects of research: the low-grade copper-nickel ores of Moncheplutone deposits (Moroshkovoye Lake, Nyud Terrasa, Nittis-Kumuzh’ya-Travyanaya (NKT), as well as the copper-nickel ore dressing tailings of the “Kola MMC” JSC. The following directions for the intensification of the low-grade copper-nickel raw materials heap leaching have been considered: preliminary electric pulse destruction (EPD) of ore; ore crushing and further sulfuric acid agglomeration. The impact of sulfuric acid concentration (1-3%) on the extraction of non-ferrous metals kinetics from the copper-nickel ore dressing tailings under various conditions of the percolation leaching has been studied. INTRODUCTION The low-grade grade sulfide ores at the abandoned and producing deposits, overburden rocks, mill tailings and non-ferrous slag are thought to be one of the large-scale sources for non-ferrous metals, on the one hand. On the other hand, they are known to be the subjects of emergency environmental danger. For this reason, the use of mine dumps and tailings, as well as the remained ores left in the ground as raw products, and at the same time decreasing the load on environment, are considered to be the pressing ecological and economic issue (Chanturia et al., 2012). Methods of heap hydrometallurgical and bacterial leaching are sure to be potentially productive for processing such low-grade and technogenic raw materials (Petersen, 2016). The early studies of hydrometallurgical method possibility to process copper-nickel ores of the Murmansk region deposits were launched in the seventies of the previous century (Golovko et al., 1978). For referencing purposes, the main types of impregnated ores from the deposits Zhdanovskoye, Kaula, Sopchinsky Plast and Lovnoozerskoye were selected. The metal content varied, as %: 0.46-1.49 of nickel, 0.01-0.62 of copper. In the first experiments, the solution containing 150g/l of H2SO4 and 135g/l of NaCl, was used in the capacity of leaching reagent. The possibility of underground metals leaching from the ores of the Lovnoozerskoye deposit was justified due to the performed laboratory and further large-sized tests."

Jan 1, 2018

By Edgar Schach, Tom Leistner, Markus Buchmann, Urs A. Peuker, Martin Rudolph, Marius Kern

"In this study, the flotation characteristics of a cassiterite-bearing fine-grained and complex skarn ore from a deposit in the Ore Mountains is investigated. The tests are performed using an oil-assisted column flotation approach to process very fine ore fractions and avoid losses of cassiterite into the tailings. First, process parameters are obtained for a finely ground artificial mixture of quartz, magnetite and cassiterite, simulating the real ore. Thereby, magnetite is used, as iron oxides can have a detrimental effect on the flotation due to a similar flotation behavior. In addition, they can act as a source of multivalent ions, which are known to reduce the concentration of collector molecules, active for flotation. Based on the results, selected parameters are further tested for cassiterite skarn ore from the Hämmerlein deposit including a pre-conditioning and a water exchange step to remove ionic contaminants. The process response is analyzed in detail by XRF (X-ray fluorescence) and MLA (mineral liberation analysis) to get a better understanding of the behavior of the single ore components. Sulfosuccinamate type surfactant is utilized as the collector, emulsifier and to reduce the froth destabilization through nonpolar oil. Sodium hexafluorosilicate is added as the depressant.INTRODUCTION Complex skarn ore deposits containing considerable amounts of tin, indium and other metals are located in the Ore Mountains region (Germany). In this study, a skarn ore from the Hämmerlein deposit was investigated. Due to the finely disseminated nature of this ore, past beneficiation attempts failed, and the ore was considered economically unprocessable. However, increasing resource demands brings it back into focus (Schuppan and Hiller, 2012). Cassiterite is the main tin bearing mineral in this ore. Due to its high density (~7 g/cm³), the predominant beneficiation technique is gravity separation (Angadi et al., 2015). Tin ores from disseminated deposits have to be extensively comminuted to reach a sufficient degree of liberation of the cassiterite grains. As cassiterite has a brittle nature, it is preferable enriched in small size fractions, during comminution (Angadi et al., 2015). Gravity separation methods become more and more inefficient for particles smaller 40 µm (Falcon, 1982), causing tin losses of up to 30 to 40wt.-% (Angadi et al., 2015). Thus, froth flotation of cassiterite was first utilized in Altenberg in the Ore Mountains as an additional processing step to reduce the cassiterite losses into gravity separation tailings (Bulatovic, 2010; Gruner and Bilsing, 1992). Although the reported lower size limits for an effective cassiterite floatability are often smaller compared to other minerals, the flotation performance is in general decreasing for small particle sizes < 10 µm (Trahar and Warren, 1976). Therefore, different approaches have been already investigated for the flotation of such fine cassiterite fractions to overcome the limits in particle size. Bilgen et al. investigated the shear flocculation of cassiterite with a sulfosuccinamate collector (Bilgen et al., 1994). The agglomeration flotation of cassiterite has been tested by Schubert et al. (Schubert et al., 1966), in which the selective coagulation of fine hydrophobic particles and oil droplets leads to an increase of the effective particle size. Recently, Leistner at al. investigated an oil-assisted agglomeration flotation for ultra-fine cassiterite ore fractions (Leistner et al., 2016). However, a poor response due to an increased concentration of Fe and Ca ions, unselective oil/gangue coagulation and froth instability, that is caused by oil/frother interactions, has been observed."

Jan 1, 2018