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By A. Dunnett, N. J. Turner, J. Koyanagi, M. Ji

The analysis of rare earth element (REE) samples is a necessary part of the metallurgical process for rare-earth bearing ores, providing invaluable information during testing procedures. This requires a fast, multi-element technique, capable of analyzing a variety of matrices for all rare earth elements. X-ray Fluorescence spectrometry and Instrumental Neutron Activation Analysis are typically used for high concentrations of REE, but they have limitations for some process work applications due to an inability to measure all elements, longer analysis times, significant interferences and elevated detection levels. The work reported here uses new approaches with Inductively Coupled Plasma Mass Spectrometry (ICP-MS) in order to achieve high precision and accuracy within acceptable timeframes. A combination of aerosol dilution and Kinetic Energy Discrimination (KED) produce a process solution assay method that is robust enough to deal with changing sample matrices and concentrations, whilst maintaining low reporting limits and precisions of less than 5% Relative Standard Deviation (RSD). For high concentration metallurgical and geological samples, a sodium peroxide fusion digestion procedure was used, followed by ICP-MS analysis using extended dynamic range (EDR) and KED. Using these technologies, it has been demonstrated that the necessary support can be given to metallurgical process work for REE extraction.

Jan 1, 2014

By M. J. MONEA

Canada's only economic high-swelling bentonite deposit is mined in Wilcox, Saskatchewan, by A vonlea Mineral Industries Limited. The bentonite resulted from devitrified and altered volcanic ash released during the Laramide Orogeny. Volcanic ash was deposited in a pre-Cretaceous basin that was formed by salt solution collapse structures. Sedimentary rocks in the Wilcox area belong to the Snakebite Member of the Upper Cretaceous Bearpaw Formation. Bentonite beds are 61 cm, 46 cm and 30 cm thick; these are separated by 365 cm and 182 cm of shale respectively. Saskatchewan bentonite is used primarily in the oil well industry.

Jan 1, 1984

By C. L. Reichardt

Pressure exerted on gold producers by regulators, project financiers and civil society in the wake of the Baia Mare tailings spill in Romania during 2000 prompted most responsible gold companies to sign up to the International Cyanide Management Code for the Manufacture, Transport and Use of Cyanide in the Production of Gold (the Code). The Code stipulates a ?cradle to grave? approach more comprehensive than that applied to any other mining reagent and poses particular challenges for operators who use cyanide-bearing tailings for backfill. This paper examine some of the challenges for Code compliance facing deep underground gold mines that employ backfill technology, most particularly the requirement to demonstrate that the potential migration of cyanide (and its degradation products) from emplaced backfill will not have an unacceptable impact on worker health and safety or the receiving environment, either during mine life or after closure. Although the Code only contains a single reference to backfill, more careful consideration confirms that most sections of the Code that deal with tailings management are potentially applicable to mines where tailings material is used for backfill, as are certain principles pertaining to aspects of operations, worker safety, emergency response, training and dialogue with stakeholders. For gold mines of the Far West Rand, the most significant cyanide-related risks associated with backfill operations relate to worker exposure to cyanide-bearing seepage and HCN gas. There is potential for seepage of cyanide-bearing water from backfill to compromise the beneficial use of surface and groundwater, and thus impact on downstream users and ecosystems. However, the extreme depth of mining and the specific geological and hydrological controls on the Far West Rand suggest that the potential environmental risks associated with backfill are likely to be considerably less significant than the cyanide-related risks to the workforce.

May 1, 2007

By U. Dillon, G. Blackwell

"Geographic information systems (GIS) provide an efficient means for the recording, manipulation, revision, display and analysis of spatially referenced data. GIS are widely used at the exploration stage of mine development, and are increasingly used for reclamation planning. The ability of a GIS to perform spatial searches and query spatially referenced data make it a powerful tool for use at all stages of mine development. As the amount of data available for analysis increases, so does the power and flexibility of GIS as a planning tool.Starting from the exploration database, this paper describes how a GIS can be used for the development of mining plans based on topography, geology and mineralization information stored in a relational database. Planning decisions approaching the optimal can then be made for a wide range of parameters, including stockpile and waste dump locations, the location of potentially acid generating and neutralizing material for dump design, profitable and risk-controlled mine extraction sequencing, and haul road locations. This is made possible by the overlay and buffer analysis capabilities of a GIS which are explored and exploited to produce a continuous mine production planning program, as well as site remediation and reclamation using a successful case study. The Ore and ProductsThe mines in the Saskatoon area — Agrium, PCS-Cory, PCS-Allan, PCS-Patience Lake, PCS-Lanigan and IMC-Colonsay — extract the ore from the Patience Lake member. The mines in the southeast corner of Saskatchewan — IMC-K1 and K2, PCSRocanville — extract from the Esterhazy member, while IMC-Belle Plaine, near Regina, solution mines potassium chloride from both potash-bearing members.Ore from the Patience Lake member is a medium-grained mixture of sylvite and halite, with a KCl content of 36%, insolubles averaging up to 5.5%, and little or no carnallite.The ore from the Esterhazy member is a coarse-grained mixture of sylvite (KCl) and halite (NaCl) with a small amount of water insolubles, and some carnallite (a K-Mg chloride). Average run-of-mine grades are about 30% KCl."

Jan 1, 2003

By A. Vasebi, É. Poulin, A. Desbiens, D. Hodouin

Maximizing benefits generated by separation plants in the mineral processing industry is of prime importance. To achieve this goal, observers and controllers are both key tools playing a crucial role for economic optimization. Although these methods have been widely discussed in the literature and that numerous applications have been reported, coupling the different algorithms raises practical challenges. The economic function definition, the selection of the real-time optimization structure, the elaboration of observer and controller models, the controller development, and the tuning of stochastic and deterministic parameters strongly influence economic performances. The objective of the paper is to discuss the major difficulties related to the implementation of a real-time optimization system and highlight the benefits of linking data reconciliation and model predictive control for a simulated flotation plant. A systematic topdown approach is used to go through the main design phases and to comment on the different options available for the development of the optimization structure. An internal model predictive controller coupled with a stationary observer is applied for the direct optimization of a three-stage flotation plant simulator based on a phenomenological model. The results show performance improvements in terms of increased revenues brought by reduced grade variability and collector consumption. The discussion also proposes alternative avenues that could be taken to achieve comparable improvements. Finally, since the limited simulated case-study cannot provide a complete understanding of the benefits brought by a data reconciliation observer, recommendations for industrial applications, which are more complex, are provided to promote effective implementations.

Jan 1, 2016

By J. E. Danoczi, J. A. Herbst

"Shore Gold Inc. (Shore) is presently designing a diamond processing plant for the Star and the Orion South kimberlite deposits in the Fort à la Corne (FalC) area in central Saskatchewan. The first step in the plant is diamond liberation and occurs in the comminution section. Diamond liberation is the process of breaking up the kimberlite rock, as gently as possible so as not to damage the diamonds.Autogenous grinding mills (AG mills) use a combination of impact crushing, abrasion and attrition to break up the kimberlite. The forces that occur during the actions of abrasion and attrition cause the kimberlites to break up preferentially along lines of weaknesses which offers a “diamond friendly” method of comminution.Hard competent kimberlite is commonly found in the diatreme zone as well as the root zone of the volcanic pipe and is the source of kimberlite for most of the Southern African diamond mines. Softer kimberlite is typically found in and around the crater area of a volcanic pipe and it is this kimberlite that makes up the majority of kimberlite for both the Star and Orion South deposits. These softer kimberlites can be readily broken up using abrasion and attrition imparted by AG mills. In order for Shore to benefit from the softer kimberlite found in the Star - Orion South diamond project, two large (10.97 m diameter x 7.10 m long) AG mills were designed for the comminution section based on extensive test work and simulations by Metso Minerals (Metso)."

Jan 1, 2012

By A. K. Debnath

Mining being a site specific activity, land becomes the prime requirement for starting, successful execution and closure of any mining project. Many important mining projects are not progressing satisfactorily just because land is not easily available or environmental/social issues are not addressed properly. This is especially true in the case of open-pit mining, which requires large areas for mining, dumping of waste and additional land for other mine facilities. Mine closure & post mining land use exercises, though funded generously, may not achieve their objectives owing to uneven land profile after mineral extraction is over. One of the prominent solutions to these issues is application of steep angle conveyors in large open pit mines that will result in more space for internal waste dumping and enhanced slope stability of the dump. Additionally, such applications will result in economic extraction of mineral in deep open pits. Land reclamation exercise may start concurrently during early years of mine development as mineral evacuation is limited to a specific part of the mine. Surface mining facilities can also be advanced along with the pit by using modular/portable structures. The paper presented here attempts to address specific land related issues by developing suitable schemes and plans that can be practically implemented in open pit mines using advanced technology i.e. steep angle conveyors.

Aug 1, 2013

By Denis Landry

"RÉSUMÉAu cours de dix dernières années, la compagnie Maghemite a développé, expérimenté et breveté un nouveau precédé de concentration du minerai de fer à partir de la récupération d'hématite présente au bassin de sédimentation de la Compagnie Minière Québec Cartier.A partir de cette nouvelle technologie de concentration par induction, la compagnie Maghemite produit une poudre d'hématite qui est mélangée avec du strontium carbonate à un ratio de l à 6 en poids. Le mélange homogène est achemine sur un disque d'agglomération, et ensuite incorpore dans la fournaise de la Compagnie Minière Québec Cartier. Le temps de cuisson et la température (l200°C) correspondent exactement aux critères nécessaires pour la fabrication d'aimants de céramique, Grade 5, à partir de la poudre de ferrite.IntroductionMeghemite a débuté sa production de poudre de ferrite au printemps 1986et prévoit une production de 20 000 tonnes par année dans cette nouvelle usine. A très court terrne, une usine sera construite pour la production de cinq à dix millions de Iivres d'aimants permanents par annee et à long terme qu'une usine de fabrication par robotique de moteurs à aimants permanents, utilises dans I'industrie automobile. La poudre de ferrite à base de strontium est une compose ferro-magnétique forme d'une molécule d'oxide de strontium et de six molécules d'hernatite. Ce compose d'hexa fluorite de strontium a une force tres puissante et fournit la source d'énergie magnétique la moins dispendieuse comparée aux autres aimants permanents. L'utilisation des aimants de céramique formes d'hexa fluorite de strontium a connu un croissance phenornenale depuis 1970 pour atteindre un marché de 500 millions de livres par année en 1985.II n'y a aucune autre usine de production commerciale de poudre de ferrite à base de strontium au Canada. Le facteur determinant qui a favorise l'etabilissement a Port Cartier est base sur la réduction de 30% du cout des aimants de cerarnique provenant de notre poudre. Notre debouche majeur se situe aux États-Unis et vise la production des aimants de cerarnique pour les moteurs utilises dans les automobiles, les ordinateurs et les appareils ménagers, L'objectif de cette compagnie est de réduire le prix futur des aimants de cerarnique à environ 30% du prix actuel.L'usine commerciale de production de poudre de ferrite est maintenant opérationnelle. Le financement et la construction de cette usine sont Ie résultat de l'opération d'une usine pilote sur une période de 5 ans afin de récupérer l'hematite d'un haut niveau de pureté provenant de résidus de I'usine de bouletage de la Compagnie Minière Québec Cartier (CMQC) à Port Cartier. La fournaise de CMQC est utilisee pour chauffer les boulettes cornposees d'un mélange de carbonate de strontium et d'hematite d'un haut niveau de pureté en étalant environ 5 tonnes à l'heure de ces boulettes au-dessus du tablier de boulettes de fer dans une des fournaises fonctionnant à environ 450 tonnes à l'heure."

Jan 1, 1987

By Audrey Wagenaar

Introduction ?? Rising public pressures are being placed on companies worldwide to protect the environment and the health and safety of their workers and local communities. ?? International bodies and shareholders want to make sure developments and companies can meet internationally acceptable standards for EHS. In 2005, Golder Associates was asked by the IFC to conduct a comprehensive review and update for their Environmental Health & Safety Guidelines including the mining sector.

May 1, 2008

By Harold N. Miller

Lost time and services caused by electrical equipment breakdown or cable faults can often be substantially reduced by the use of direct-current high-voltage testing as a maintenance tool. This paper discusses the relative merits of alternating-current versus direct-current testing, pointing out the advantages in size and cost of equipment and more definitive results achieved through the use of D.C. General principles of direct-current high-volt-age testing, types of testing, methods of performing the actual test and interpreting the results are explained. ?The value of insulation resistance measurements and their relationship to high-voltage testing is discussed. Pinpointing the physical location of a cable defect using a fault locator or thumper is described. Reference is made to several organizations that have effected considerable savings with high-voltage test programs. Introduction T HE past decades have seen great advances in the field of electrical power distribution and application. Motor generators, power-operated equipment, cables, etc., have all gone through various stages of improvement both in efficiency and reliability. Un-fortunately, however, power failures and equipment breakdown still occur -frequently with disastrous effects in loss of time,

Jan 1, 1965

The NorthMet deposit of PolyMet Mining is located in northern Minnesota, adjacent to the Iron Range. The deposit is polymetallic with values of Cu, Ni, Co, Zn, Pt, Pd and Au. The processing route selected for extraction of these values utilizes bulk sulfide flotation followed by hydrometallurgical treatment. The hydrometallurgical process has been thoroughly tested on the bench and pilot plant scale at SGS Lakefield Research. The major steps in the process are; ? Chloride-assisted total pressure oxidation for extraction of base and precious metals ?Thickening/filtration/washing of the barren residue from total oxidation ? Reduction and precipitation of Au, Pt, Pd from the oxidation solution ? Partial neutralization of autoclave acid using limestone ? Copper SXlEW for production of copper cathode ? Treatment of a portion of the raffinate from Cu SX to recover NilCo/Zn as either a mixed Ni-Co-Zn hydroxide or as separate Ni hydroxide, Co hydroxide and a Zn sulfate solution. ? Recycling of the remaining raffinate to the autoclave as coolant The process flowsheet, chemistry and bench/pilot plant test results will be reported in this paper.

Jan 1, 2007

By Walter Valery, Lauren Hafla, Megan Tibbals, Adrian Dance, Jeff Snyder

"Newmont Mining Corporation’s Carlin (“Carlin”) operation processes roaster feed through a double rotator, dry grinding mill following secondary crushing. Metso Process Technology & Innovation (“PTI”) was involved in a review of crushing and dry grinding circuit operations in August 2009. A number of opportunities for increased throughput were identified in the PTI study.Extended plant trials were conducted in July 2010 to provide justification for possible circuit modifications and if needed, additional equipment. The trials confirmed that a finer crusher product would reduce the build-up of material ahead of the coarse grinding chamber in the double-rotator. Also revealed were material transport and airflow restrictions in the dry grinding circuit that resulted in a high circulating load.The secondary crushing plant demonstrated it was capable of reducing the amount of +¾” material in the mill feed thus increasing dry grinding throughput. However, wet and sticky feed affected screening efficiency resulting in low utilisation of the existing crusher capacity. The open circuit configuration also made it difficult to control crushing circuit product size.For the dry grinding circuit, changes in grinding media size, transfer grate design and increased airflow were recommended to reduce circulating load issues and increase circuit capacity. This paper summarises the crushing and grinding circuit review, the extended site trials performed by PTI and the improvements in dry grinding operation that resulted from this study."

Jan 1, 2012

By S. Timbillah, R. LaDouceur, C. A. Young

A low carbon-chain trithiocarbonate ((NaOOC)CH2SCSSNa), known as Orfom® D8, was tested as an organic depressant in the differential flotation separation of chalcopyrite and molybdenite in the presence of sodium isopropyl xanthate (SIPX) or potassium ethyl xanthate (KEX). Flotation studies show that Orfom® D8 depressed chalcopyrite while molybdenite remained floatable. A study of the mechanism of adsorption indicated that Orfom® D8 adsorbs on chalcopyrite through its trithiol (CS -) functional group via both chemisorption and Orfom® D8-metal complexation. The Orfom® D8 depressant is selective and does not form any Orfom® D8-molybdenite bonds. Thus, the combination of the depressant in the presence of either collectors depressed the chalcopyrite and floated the molybdenite. Fundamental parameters of the Orfom® D8 including pKa determination as well as possible decomposition products of the depressant are reported. This study includes an economic case illustrating why using Orfom® D8 can be beneficial. INTRODUCTION Depressants are incorporated in mineral flotation units in the minerals processing industry to make or keep certain minerals selectively hydrophilic. Most reagents used are inorganic and include, for instance, sodium hydrosulphide (NaHS) which is the major reagent used for depressing sulphide minerals, particularly those containing copper, iron and lead. However, the issues with its use include high toxicity, tendency to explode, strong odour, and high consumption due to required high dosages as well as its tendency to oxidise in air. The latter can be overcome by conducting flotation in inert atmosphere such as nitrogen and recycling of the flotation process water. The use of more novel depressants that are essentially organic including homopolar reagents with hydrophilic functional groups on both ends of its structure adsorb onto a target mineral surface with one polar end, the other polar end orients into the bulk solution making the surface hydrophilic and thus, ensuring that the desired mineral does not float. The stringent environmental and safety regulations being implemented in recent times mean that the search for more environmentally friendly chemical reagents is a must have. The use of organic depressants for flotation systems such as Cu-Mo sulfide bulk concentrates has become increasingly important because of the health, safety and environmental issues surrounding the use of inorganic depressants. Nagaraj et al. (1983) investigated the Cu-Mo sulphide flotation system using a structure-activity study of depressants. They found that a major advantage of organic depressants is the ability to tailor-make organic molecules to suit many requirements and thus, eliminate the guess work approach that was predominant in the industry.

Jan 1, 2019

"In the UK, Ireland, and Western Europe, the mineral resource and reserve reporting standard is the PERC Code, developed and maintained by the Pan-European Reserves and Resources Reporting Committee, which is a standing committee set up under the auspices of a number of professional organisations which include the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI) to develop a Pan-European reporting code. The PERC Code supercedes the old IMMM Reporting Code 2001 and is recognised by the UK securities regulators and stock exchanges.""FOREWORD1 The Pan European Reserves and Resources Reporting Committee (PERC) Code for Reporting of Exploration Results, Mineral Resources and Mineral Reserves (further referred to as 'the Code') sets out minimum standards, recommendations and guidelines for Public Reporting of Exploration Results, Mineral Resources and Mineral Reserves in the United Kingdom, Ireland and Europe. The history of development of this code is summarised in Appendix 4.This 2008 edition supersedes all previous editions of The Reporting Code and the IMM Reporting Code.INTRODUCTION2 In this edition of the PERC Code, important terms and their definitions are highlighted in bold text. The guidelines are placed after the respective Code clauses using indented italics. They are intended to provide assistance and guidance to users in interpreting the application of the clauses in the Code. The same indented italics typeface formatting has been applied to Table 1, and to Appendices 1 and 2 which form part of the Guidelines.3 The Code has been adopted by the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI), and is therefore binding on their individual members.Appendix 1 contains a table of generic terms and their equivalents, designed to avoid unnecessary duplication or ambiguity in the textAppendix 2 provides Rules of Conduct for Mineral Resource and Mineral Reserve estimators that should be considered in addition to the Codes of Ethics normally applying to members of professional institutions."

Jan 1, 2003

By Guohong Yin

Oxidized sulfidic tailings contain significant amounts of accumulated acidity in the form of water-soluble secondary sulfate minerals and thus constitute long-term sources of acid drainage at many metal mining sites. As part of site remediation activities, alkaline amendments are often added to the oxidized tailings to increase the pH and immobilize the metals. This study assessed the advantages and limitations of using lime mud, a byproduct of Kraft pulp mills rich in calcium carbonate (> 90 wt. %), as alkaline amendment. The inorganic and organic constituents of lime mud samples were quantified. Leachable impurities were determined by the TCLP method. The performance of lime mud was compared to that of reagent grade quicklime (CaO) and calcite (CaCO3). Tailings treated with lime mud or calcite have strong buffering capacities and remain at neutral pH conditions (pH ~ 6.7) for long times. In contrast, tailings treated with quicklime have a very low buffering capacity, and their pH decreases with time. Furthermore, lime mud has finer particle sizes and thus a greater specific surface area than most forms of commercially available calcite, which results in enhanced reactivity. Dissolved metal concentrations are similar in tailings slurries treated with lime mud or calcite. This study suggests that lime mud is an environmentally and economically attractive alkaline amendment for oxidized mine tailings.

Nov 1, 2002

By A. McLean, J. Hou

Waste slag is a major environmental concern within the metallurgical industry. In the steel industry, about 100 kg of slag is produced in making one tonne of liquid steel from iron in addition to that produced during ironmaking. The amount of slag from the steelmaking converter can be significantly reduced when charging hot metal with low phosphorus and sulphur contents. In this context, hot metal pretreatment is known as an effective means of preparing high quality charge material for the converter thus limiting the generation of residual slag during the steelmaking process. In the aluminum industry, about 2-4 tonnes of slag, including red mud from alumina production and dross from aluminum electrolysis and casting, are generated during the production of one tonne of aluminum. In recent years, reuse of waste slag from the aluminum industry is a topic that is receiving increasing attention. In this paper, the possibilities of using waste slag and by-products from the aluminum industry as a refining flux in the steel industry are discussed. Several successful processes to convert waste materials from the aluminum industry to steel refining fluxes are described. Some theoretical aspects of using calcium aluminate based flux for desulphurization are outlined together with results obtained from laboratory experiments on sulphur removal from hot metal. By intelligent use of waste materials, the disposal of solid waste from the metallurgical industries can be reduced.

Jan 1, 2004

By S. Harvey

The McArthur River deposit is a structurally-controlled unconformity-related uranium deposit. The mineralization is situated at the intersection of a pronounced fault zone, referred to as the P2 fault zone, and the unconformity between Paleoproterozoic Wollaston Group metasedimentary rock and Paleoproterozoic to Mesoproterozoic Athabasca Group. Mineralization is variably hosted within the Athabasca Group fault wedge and the faulted basement, consisting of twelve zones covering a strike length of 2,700 m. The main P2 fault zone consists of several reactivated foliation-parallel faults containing narrow seams of graphitic clay gouge that are separated by highly cleaved, graphitic wall rock. The mine grid east-dipping P2 fault zone is characterized by reverse offset of the unconformity surface. It varies from a single discrete fault to splay offsets consisting of two to three individual splays. The combined vertical offset along the P2 fault zone is a maximum of about 80 m. The fault has emplaced a wedge-shaped sequence of Wollaston Group metasedimentary rocks into the Athabasca Group. Foliation-oblique faults occur throughout the McArthur deposit trend. Steep east-northeast trending faults generally exhibit apparent oblique dextral sense of shear. Less common, and possibly conjugate, are steep faults trending east-southeast with an apparent sinistral sense of shear. Offsets are generally less than 10 m on these structures. South-trending and shallow west-dipping brittle faults with offsets less than 1 m are also observed while rare steep, north-trending faults are also noted locally and played a critical role in development of the Zone 2 basement-hosted mineralization.

Jan 1, 2020

By P. W. Waggitt

ABSTRACT From approximately 1986 until 2000, uranium production was at a historic low. In 2003, uranium mineral exploration surged, despite the global financial crisis; however, the shortage and aging of qualified and experienced operators and regulators might soon become a constraint to this upsurge. This is true for all types of engineers, geologists, other scientists, tradespeople, and technicians. The situation raises questions about how the global mining industry in general and the uranium sector in particular will cope with future staffing needs. In this paper, the author examines the current situation and describes how some organizations are seeking possible solutions.

Jan 1, 2014

By M. Tanaka, Y. Sato, H. Narita, S. Alam, T. Ogata

To ensure a stable supply of rare earth elements (REEs), it is highly necessary to establish the corresponding recycling technologies for RE magnets and phosphors in inplant wastes and endoflife products. Solvent extraction using 2ethylhexylphosphonic acid mono2ethylhexyl ester (EHPNA) is often applied in the separation and purification of REEs. In this study, the equilibrium distribution ratios of neodymium and dysprosium between 1 mol/L nitrate solution and the EHPNA in an alkane diluent were measured at 298K. The experimental data were analyzed by correcting the nonideal behavior of the organic phase using the Alstad empirical equation under the assumption that a complex with a molar ratio of 1:6 (REE:extractant monomer) was formed. The model correlated well with the experimental data and the extraction equilibrium constants were obtained. The extractant equilibrium constants obtained by this methodology would be useful in the design of REE recycling processes using solvent extraction.

Jan 1, 2014

By N. A. P. Kiran Kumar

The Zr-Nb alloys are reported to be showing superior resistance to corrosion and substantially lower hydrogen pickup when compared with zircaloys. In the present study zircaloy-4 and Zr-1Nb (E110) alloys were hydride using high pressure hydrogen gas furnace at a pressure of 20 MPa. Thermal cycling was done on the samples at a temperature of 3500C for 10 cycles with 5h soaking time at 3500C per each cycle. The Microstructural observations on zircaloy-4 samples show long and interlinked hydride like chain, oriented along the circumferential direction. Whereas in Zr-1Nb, short hydrides were observed with hydride platelets not showing interlinked chain like structure. The hydrides in Zr-1Nb were observed to be not showing particularly orientation along the circumferential directions. Electron backscatter diffraction was use to understand the hydride precipitation and their orientation in Zircaloy-4 and E110 alloy.

Aug 1, 2010