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By Pingchao Ke, Zhihong Liu

Fe(III)-As(V) precipitates were synthesized from the Fe(II)-As(V)-SO42--H2O system at 90°C in initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The synthesis were carried out by introducing oxygen gas into the system to oxidize Fe(II) ions into Fe (III) ions, and at the same time, adding aqueous sodium carbonate solution into the system to neutralize the acid released by the hydrolysis reactions, with the purpose of keeping the pH constant at 1.5±0.05. The precipitates obtained were characterized by XRD, chemical composition analysis, SEM, XPS, and Raman spectrum. The results indicated that the particles in the precipitates were in the morphology of irregular aggregation with their sizes in the range of about 1–4 µm. The precipitates consisted of scorodite, ferric arsenate and amorphous hydrated ferric oxide, of which amorphous hydrated ferric oxide formulated as Fe(OH)x(SO42-)y. The characteristic XPS peaks of Fe-AsO43- and Fe-O in the precipitates located at 711.8 and 713.3 eV, separately, and the existence of amorphous hydrated ferric oxide led to two series of shake off lines developed over the end of high binding energy of Fe2p XPS. The precipitates were stable in TCLP tests at pH 4.93 for 60 hours with the arsenic concentrations in the leaching solutions being 0.27 mg/L and 0.59 mg/L for the precipitates prepared in the initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The tests for the long-term stability of the precipitates were carried out by leaching them for 40 days at 25°C under various media in the pH range from 9.50 to 10.57, and the results showed that the precipitates synthesized in this study were much more stable than those by previous researchers.

Jan 1, 2017

By Larry B. Smith

"Feasibility studies are the means by which mineral reserves are established prior to financing a project. However, guidelines are generally lacking for the content, data quality and accuracy of these studies. Regulators take a principle-based rather than prescriptive approach to the content of studies and look to the industry to define study content. Professional organizations, engineering firms and mining companies must eventually establish guidelines and best practices for this work. Most likely these will draw on standards or “stage gates” that have been developed by major mining houses and engineering firms. Engineering studies must: 1.,Define optimal mining and processing methods, production rates, infrastructure, product sales, environmental management and risk mitigation. 2.,Increase confidence in resources, reserves, production plans, processing performance, infrastructure design, environmental management, permitting, capital and operating costs, and financial performance to support financing. 3.,Provide engineering designs suitable for accurate cost estimates. 4.,Develop project execution plans with sufficient confidence that project delays and cost overruns will not occur. Conceptual (scoping, preliminary assessment) Establish the principal characteristics of the project from the geology, resources, metallurgy and development constraints. Assess different approaches to mining and processing. Identify project execution requirements. Test project viability with economic analyses. Recommend additional work to increase the confidence in geology, resources, metallurgical performance, infrastructure, operating and capital costs, environmental conditions and permitting to allow selection of the best development options."

Jan 1, 2003

By Victor F. Hollister

Although none of the deposits discovered to date are of commercial interest, significant Frasch or sedimentary sulphur deposits occur in Nova Scotia in Upper Mississippian Windsor Group evaporites. The evaporite sequence contains anyhdrite and is overlain by impervious shales. It also is •mderlain by locally petrolijerous formations that are potential hydrocarbon sources for reaction with anhydrite to produce sulphur. As well, stratigraphic and structural traps are known to exist in the Mississippian beds. Thus, all requisites for sedimentary sulphur genesis are present. Available hydrocarbon sources are numerous but small; resultant sulphur deposits therefore are probably also small. Evidence suggests, however, that sulphur deposition is not yet complete.

Jan 1, 1984

By Jian-bin Xie, Lin-fang Shen, Zhi-liang Wang

"In order to research temperature field for construction of connecting passage in Metro using artificial freezing method, the finite difference software FLAC3D is employed to numerically simulate construction process of connecting passage. During construction, the overall distribution of temperature field around connecting passage, the relationship between soil temperature and freezing time, the distribution and variation for the thickness of freezing wall are studied from the perspective of numerical analysis. The results show as follows: after 55 days’ freezing, the soil temperature surrounding connecting passage is about -24 oC ~ -28 oC, and the minimum thickness of freezing wall is about 4.0m, which is larger than the design value 3.1m. So construction conditions have satisfied to the excavation of connecting passage and pumping station. During the excavation of connecting passage, soil temperature has almost no obvious change and the thickness of freezing wall remains constant mainly. After 45 days’ normal thawing, the temperature of freezing wall rises 12 oC approximately. And the soil temperature rises faster at the beginning of the normal thawing stage. In the whole process of construction, the frozen area is about 5m outside the edge of connecting passage, and the cooling area is about 10m outside the edge of connecting passage. INTRODUCTIONThe first recorded application of the artificial freezing method is on a mineshaft project in 1862, and it has been widely used in foundation pit engineering, subway tunnels, mine shaft engineering and so on (Wang Zhiliang, 2010; Zhang Juanxia, 2012; Qiu Fan, 2007; Zhou Xiaomin, 1999). This method has many advantages of enhancing soil strength; decreasing permeability and adopting various unstable soils (silt clay, sand, gravel, etc.). It has been applied successfully in metro engineering construction in Beijing, Shanghai and Nanjing. According to incomplete statistics, the construction of connecting passage using artificial freezing method accounted for 98% in Shanghai metro (Qiu Fan, 2007)."

Jan 1, 2015

By Ed Labelle, Terry Overton, Gary Bell

"LocationThe Miller Minerals lime and limestone production facility is located in the Temiskaming district of Ontario at Hailey bury on the west shore of Lake Temiskaming. Located less than 300 km from Sudbury, Timmins, Rouyn-Noranda and Val d'Or, the plant is very well situated to market products to the mining, pulp and paper, and environmental industries. Being located a few kilometres from the Trans-Canada Highway and the Ontario Northland Railway adds to transportation efficiencies.ProductsAt Miller Minerals, two principal products in various sizes are produced, which are limestone (CaC03) and quicklime (CaO).HistoryProduction of limestone products began in 1979 at this quarry site. During the 1980s, limestone products were marketed to a variety of applications for mining, forestry, environmental and agriculture applications. In 1990, the production of quicklime products began, following the commissioning of an Italian-designed vertical shaft calcining plant. During the 1990s, both quicklime and limestone products were produced to meet the customers' demands.From the quarry's conception until 1992, the operation was owned and operated by Dymond Clay Products. In 1992, it was purchased by Miller Paving Ltd. of Markham, Ontario, and became a key part of the company's industrial minerals sector of business. Other Miller interests include dolomite, cement, paving materials and waste management."

Jan 1, 2000

By L. Voisin, K. Mühlenbrock

A new pyrometallurgical process is proposed for cleaning complex copper matte and for recovering copper from copper scrap containing lead. In the process, a given amount of pig iron is added to the complex material under a reducing condition to produce two or three liquid phases at the equilibrium, depending on the content of sulfur in system, of copper-rich and iron-rich alloys, and matte, respectively. The novel process is proposed based on the experimental results obtained by performing laboratory scale tests in an electrical furnace at 1473 K followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Atomic Absorption Spectroscopy (AAS), Inductively Couple Plasma (ICP) and Carbon Infrared Spectrometry (CIS) techniques. The results were discussed on the basis of the distribution of lead as impurity in the miscibility gap where equilibrated phases coexist. According to the mass balance calculations, the elimination of lead into the iron-rich alloy phase as a harmless and smaller deposit might be feasible and the process proposed for cleaning the complex matte would be promising.

Jan 1, 2014

By Maria D. Mastalerz, Wei Wang, Maria E. Holuszko, Amit Kumar

In this study, the micro-FTIR analysis was used to investigate in-situ surface properties of coal and its components (macerals) and these were directly correlated to the coal hydrophobicity as measured by the contact angle before and after reagent addition to understand the suitability of the reagent for flotation. The micro-FTIR technique can provide a semi-quantitative analysis of the chemical functional groups on coal surface, exactly where the contact angle is being measured. Selected functional groups and their ratios that provide information about aromaticity, the contribution of oxygenated groups, and aliphaticity are used to evaluate the reactivity between reagents and various coal components. The observations made in relation to the susceptibility of some reagents towards certain coal components should lead the way to a smarter way of using process design in terms of reagents selection for coal flotation.

Jan 1, 2017

By C. G. McLachlan

Professor H.E.T. Haultain: To me from time to time the urge comes to say the agreeable thing as well as the disagreeable in commenting on the work of others. It is a prerogative of age. I don't apologize. To myself I justify my action as based on a long experience of the matters with which I deal, and I like to tell myself that I have a certain responsibility in such matters on account of my detached position. This Noranda article is a very fine contribution concerning Canadian milling, and I am surprised that no word of commendation or thanks has appeared concerning it in the BULLETIN. There is altogether too much written in these days by men rushing into print, concerning laboratory work, that has not been tied into, nor has resulted in application in the field. The authors of this paper have not rushed into print. The preparation of this paper was evidently an uncongenial task. If the authors had been that way inclined, it could have spread over several lengthy papers. It is an important article because it represents an enormous amount of work in the laboratory and the mill, extending over a period of sixteen years, and resulting in fine metallurgical and economic results with a very difficult and involved problem. It is a fine article because it is so well prepared and presented. It deals with an unusual ore condition, but there is much in it of use to every cyanide millman. It leaves very little room for criticism, though there may be differences of opinion in regard to some of the chemistry phases with which I am not conversant. I am struck by the enormous amount of persistent, painstaking, conscientious research work involved, and in the careful, sincere way in which the methods and difficulties have been described. Persistence and sincerity are the key note of the effort. It should have a good educational effect on the rising generation of millmen, and it should continue for long as a work of reference, and a spur to others. There has been an important by-product, the training and development of the young men engaged in the work. Three of them became superintendents of important mills. One was sought for important work in Africa, another has joined a large research organization in the United States.

Jan 1, 1946

By Joey R. Kish, Shooka Mahboubi, Hatem S. Zurob, Gianluigi A. Botton

The kinetics of the Cr2O3-based scale oxidation and volatilization were studied in the presence of water vapour (H2O). A commercial Cr2O3-based scale forming Type 310S stainless steel was examined at the ambient pressure (0.1 MPa) and 550ºC in relatively low and high H2O containing environments of air- 10% H2O and air- 70% H2O, respectively. The increase in the partial pressure of H2O (pH2O) from 10% to 70% resulted in transition of the oxidation and volatilization kinetics from the parabolic rate law for air-10% H2O to the paralinear rate law for air-70% H2O. The kinetics transition was attributed to the increase in the Cr loss rate from the base scale after coupons exposure in air- 70% H2O. The significant role of the Mn alloying element in the base scale protectiveness was also discussed in the context of the Cr2O3-based scale stability.

Jan 1, 2017

By S. E. Wolfe

AKNOWLEDGE of the density of a pulp or suspension is frequently required by the millman, to whom fluctuations in density, which occur in all mill circuits, are of importance and interest. There ,are many w.ays currently in use to determine density and probably the most common method is to take samples of the pulp. The proper sampling of the material is no easy matter, particularly when the pulp contains a sand fraction which settles rapidly. For example, when filling a liter container from the overflow of a classifier, it is al-most impossible to fill the can completely and yet prevent overflow. If there is an overflow, the pulp remaining in the can invariably has an excess of sand and the indicated density will be too high. To surmount such difficulties, and to obtain a continuous indication of the density of a pulp at any desired depth, the simple indicator shown diagrammatically in Figure l was designed by the writer in 1951. Its component parts, numbered as in Figure 1, are as follows.

Jan 1, 1958

By Yuki Koshino, Kenji Kaneko, Yasuhiro Aruga, Takuya Maeda

"In general, there is a strong correlation between dislocation characteristics and mechanical properties of aluminum alloys. In this study, dislocation characteristics of tensile deformed Al-Mg alloys were examined by transmission electron microscopy. An Increase in the solute concentration, ranging between 0.3 and 1.1%, Mg leads to increase in strength and decrease in uniform elongation. The accumulation of dislocations during the tensile deformation is observed in lower strain as the concentration of solute Mg in the alloy is higher. It is believed that the solute Mg in Al-Mg alloy promotes the accumulation of dislocation during the tensile deformation resulting in the decrease in elongation.INTRODUCTION The influences of the amount of Mg concentration on the tensile properties of Al-Mg alloys has been investigated by many researchers. It has been understood that the tensile ductility of Al-Mg alloy is higher for the Al-Mg alloys with higher Mg concentration beyond 2 mass% (Mukai, Higashi, Hirano & Tanimura, 1993). Uchida and Yoshida (1995) reported the formation of microbands during the tensile deformation due to the localization of dislocations, and the amount of microbands were reduced when the Mg concentration of the Al-Mg alloy was increased from 3 to 9 mass%. Their study suggested that the dynamic recovery of dislocation was retarded due to the increase of the Mg concentration during the tensile deformation, which resulted the increase in ductility. On the other hand, in the case of Al-Mg alloys with the Mg concentration less than 3 mass%, the reason why the ductility of Al-Mg alloys decreases with increasing Mg concentration has not been sufficiently investigated. In general, the Mg concentration used for automotive usage is less than 1 mass%, in the case of Al-Mg-Si alloys (Aoki, 2013). Therefore, to clarify the roles of Mg in the low concentration range on ductility of aluminum alloys and to elucidate its mechanism contribute to alloy design of Al-Mg-Si alloys having good formability."

Jan 1, 2018

By Abhilash

Uranium is conventionally extracted using a process that employs strong acid (H2SO4) and an oxidant (MnO2) as leaching agents. This method often creates environmental problems, requires large amounts of energy, and involves a complex operational plant. It is not, however, economically attractive to extract uranium from low-grade ores by chemical leaching. Because the content of U3O8 in the Indian ore is usually below 0.1% by weight, it is necessary to develop an alternative process to enable the efficient and economic recovery of uranium. Uranium ore from the Narwapahar mines, UCIL is a type of vein deposit found in India, which accounts for ~54% in India. The ore (0.047% U3O8), though of Singhbhum area, possess exceptionally different mineralogy due to presence of some refractory minerals and richness of apatite (5%) resulting in a maximum 78% recovery through conventional processing at UCIL, with a very high consumption of sulfuric acid and pyrolusite, besides possible loss of uranium as uranium phosphate. To avoid usage of environmentally non-benign oxidants, remediation of influence of phosphates, and improve the overall process output of uranium; an alternate extraction technology using microbial isolate(s) is worthwhile exploring and the same is presented in the paper. The microbial isolate enriched with Acidithiobacillus ferrooxidans grown from source mine water was employed for bio-leaching of uranium while varying pH, pulp density (PD), particle size, etc. On varying pH at 35oC using 20%(w/v) PD and <75µm particle size, 83.5% and 78% uranium bio-recovery were observed at 1.7 and 2.0 pH in 40 days against maximum recovery of 46% and 41% metal in control experiments respectively. Whereas, it was observed that grinding of ore to finer size actually helped dissolution of uranium. Finer size particles (<45µm) gave a maximum biorecovery of 93% in 40days at 10%(w/v) PD, 1.7 pH and 35oC. The bio-recovery of uranium fell down from 93% to 82.73% and 60% on increasing the pulp density from 10% to 20% and 30% respectively for particles of <45µm size. The higher uranium dissolution during bioleaching at 1.7pH can be correlated with increase in redox potential from 433 mV to 664mV in 40 days.

Aug 1, 2010

"The Society for Mining, Metallurgy, and Exploration (SME) Inc. developed a guide of minimum standards for reporting exploration results, mineral resources, and mineral reserves for the purpose of informing the general public. The SME Guide has been adopted by the Society.History1. In 1988, at the request of members of the Society for Mining, Metallurgy, and Exploration (SME), Inc., the President of SME formed Working Party #79, Ore Reserve Definition, with the mission to develop guidelines for the public reporting of exploration results, resources, and reserves. A Subcommittee was appointed by the Working Party to draft these guidelines and submit recommendations to SME. The Subcommittee's recommendations were published by SME in the April 1991 issue of ""Mining Engineering"", and as a document entitled ""A Guide for Reporting Exploration Information, Resources, and Reserves"" (the SME Guide) in January 1992. Work continued on an ad-hoc basis until 1996, when Working Party #79 was renamed the SME Resources and Reserves Committee and became a standing committee.In 1994, the Council of Mining and Metallurgical Institutions (CMMI) started a concerted international effort to create a set of international definitions for reporting mineral resources and mineral reserves. An ad-hoc International Definitions Group was formed, with representatives from mining and metallurgical institutions from the United States (SME), Australia (AusIMM), Canada (CIM), the United Kingdom (IMM) and South Africa (SAIMM). A major breakthrough came on October 18, 1997 when the CMMI International Definitions Group met in Denver, Colorado and reached a provisional agreement (the Denver Accord) on definitions of mineral resources and mineral reserves. Concurrently, and since 1992, the United Nations Economic Commission for Europe (UN-ECE) was developing an international framework classification for mineral resources and mineral reserves. Starting in October 1998, joint meetings were held in Geneva between the CMMI International Definitions Group and the UN-ECE Task Force, resulting in agreement to incorporate the CMMI definitions into the UN framework classification."

Jan 1, 2003

By Ernest Becker

Golder Associates provided overall radiological direction and assistance to the client in their interactions with the Canadian Nuclear Safety Commission and operational radiation protection services for the remediation of a calciner that had been used to process uranium. The project was somewhat unusual in that the radioactivity from within the calciner room was removed from the site and the cleaned steel recycled. The presence of yellowcake within the process equipment required stringent radiation protection measures. This project was completed successfully with minimal radiation exposures to the workers and the effective protection of the environment.

Aug 1, 2010

By Olav Mejia

The rising energy costs and environmental considerations in mining necessitate the development of energy-efficient copper and gold processing plants. This paper presents an analysis of technical strategies aimed at reducing energy consumption in these plants. Key approaches include the integration of advanced ore sorting technologies, High Pressure Grinding Rolls (HPGR), Coarse Particle Flotation (CPF), and high-intensity flotation. Ore sorting enables early-stage waste removal, reducing the downstream processing load and associated energy use. HPGR technology, recognized for its energy efficiency, contributes to significant energy savings in comminution circuits by reducing reliance on traditional grinding methods. CPF technology further optimizes flotation performance by enabling the recovery of larger particles, thereby decreasing the need for fine grinding and reducing overall power demand. High-intensity flotation units enhance separation efficiency and mineral recovery in a compact footprint, offering further reductions in energy consumption. Together, these technologies provide energy saving opportunities to achieve a more sustainable and economically viable processing operation. This paper evaluates the effectiveness of each method, highlighting their potential impacts on energy consumption, operational efficiency, and cost-effectiveness in copper and gold processing

May 4, 2025

By P. M. Chapman

Risks to aquatic receiving environments from uranium mining and milling fall into three categories: physical (habitat change), chemical (e.g., uranium, selenium, total dissolved solids [TDS], metals including vanadium), and radiological. Although all categories of risk need to be managed, chemical risks are the most significant and are typically chronic rather than acute. For instance, selenium toxicity is primarily manifested as reproductive impairment due to maternal transfer, resulting in embryotoxicity and teratogenicity in egg-laying vertebrates. Risk is best assessed using a weight of evidence approach focused on ecosystem services. Risk management should be based on both risk assessment and adaptive monitoring.

Aug 1, 2010

By P. Maltais

Over the last 10 years, Computer Aided Design, Finite Elements Analysis and field testing of prototypes have enabled the cycling industry to grow and to significantly improve its products. However, today&apos;s cyclists have become more and more demanding, making these classical design approaches almost obsolete. Devinci understood that problem four years ago and fully revisited its design approach; to offer bicycle frames better suited to real life riding, one must fully know those real life conditions. In partnership with the University de Sherbrooke, Quebec, Canada, Devinci then developed a bicycle enabling them to measure the actual load applied on a bicycle frame in real-time for real riding conditions: the instrumented bike. Today, Devinci uses its instrumented road and mountain bikes, combined with virtual prototyping and laboratory testing capabilities to develop better bicycles, faster.

Jan 1, 2006

By Y. Chunhua, L. Chunsheng, W. Sheng

"Countercurrent solvent extraction is the dominant industrial rare earth separation method. For the rare earth separation, with low separation factors and multiple components, designing and optimization plays an important role in reaching product quality and reducing separation plant costs. Based on the theory of countercurrent extraction, cost-efficient methods, such as third-outlet separation and hyperlinked extraction processing, have been introduced following computer simulation. The consumption and fixed investment of industrial practice are compared, by which advantages of the optimized rare earth separation process are indicated. INTRODUCTIONThe rare earths (RE) have outstanding optical, magnetic and electric properties in advanced material applications and have therefore received much international attention in recent years. Liquid-liquid extraction is the major industrial RE separation method and is widely used in the industry. Supported by the government and with collaboration from the institutions and enterprises, China has made great progress in RE separation, and has become the dominant supplier of separated RE products. Complicated by multiple elements and low separation factors, careful design of RE separation processes is vital for the quality and cost of production. The theory of separation is the key to basic of flowsheet design and industrial applications.BASIC SEPARATION PROCESS AND THEORYGeneral ProcessAcidic extractants such as P507, P204 and naphthenic acid, are the most popular extractants in modern RE separation industry. In the general separating process, the extractant is saponified with a base, then ion-exchanged with RE solutions, thereby to provide stable and high RE loading in the extractant to fulfill the requirement of production quantity and quality. The RE-loaded extractant is then countercurrently extracted and scrubbed with RE solutions and the RE element thereby is purified. After the countercurrent extraction process, the RE-loaded extractant is stripped with acid to obtain an aqueous RE product, and prepare the extractant for recycling (Xu, 1995)."

Jan 1, 2012

By Bradley Stoughton

The magnetic oxide of iron, F eO4 , contains a theoretically larger amount of iron ( 72.4 per cent.) than any other commercial ore. It is probable that it has originated in many cases by the prolonged exposure of the hydrated oxide, ZF e20 a + 3H20 to heat and pressure which converts it first into hematite, F e20 3, and then into magnetite. It would thus appear as if nature had already done part of the work of removing all the oxygen and that magnetite should be relatively easy to reduce. That it is, in fact, less reducible than either limonite or hematite, is due chiefly to its dense and compact physical structure, which makes it less pervious to the furnace gases, and also to its characteristic action in resisting crushing to a uniform size, with consequent irregularity in reducing conditions within the furnace. The net result is that the magnetic oxide requires more fuel and more time for its reduction in the blast-furnace than any other iron ore of similar iron content and physical condition. There is another very important reason why the smelting of magnetite is more costly than that of hematite, and its treatment viewed with a great deal of adverse prejudice by blast furnace operators, namely, that magnetite decreases the proportion of heat developed by the fuel in the stack of the furnace, and increases the already excessive heat requirements of the heart.

Jan 1, 1924

By Yosuke Ota, Makoto Tawara, Tetsuya Kojima

"Dry-lube has been used in Europe to enhance formability of aluminum sheet for automotive applications, but it is difficult to ensure degreasing performance with lower degreasing bath temperature. However, newly developed, highly lubricating pre-coats utilizing a urethane resin, which is soluble in water, have been found to show excellent degreasing performance. Furthermore, a richer pre-coat weight coincides with a lower friction coefficient and better formability. Combined use of anti-rust liquid oil showed different friction coefficient depending on applied surface pressure.INTRODUCTION The global demand for aluminum alloy products, especially for automotive application, has been increasing because aluminum alloys can offer excellent corrosion resistance with good strength and low density compared with steel. Aluminum alloys can contribute to saving much more energy and greenhouse gas emissions over the lifetime of the product. On the other hand, the amount of aluminum alloys in vehicle architectures is still somewhat limited due to relatively low formability. As a consequence of this low formability, it is necessary to set a certain limit to the shape of an aluminum alloy panel for automotive applications. So far hot melt wax dry lubricants have been in use especially in Europe as they have been recognized to provide better lubrication than conventional rust protection oils (Meiler & Jaschke, 2005). The benefit of hot-melt wax for automotive manufacturing is associated with a more stable forming process and the possibility to avoid extra lubrication in the press shop. But because of the low poorer solubility of hot-melt wax in degreasing aqueous bath solution, a higher degreasing temperature is required so that no remnant of hot melt wax can be carried over to the next manufacturing process. This temperature control is difficult to impress upon a manufacturing degreasing bath originally designed for liquid oil, especially in Japan. The typical temperature of degreasing bath in Europe is around 60°C, while it is only around 40°C. in Japan. Various types of pre-coats other than hot-melt with high lubricity have been reported (Tawara, 1993; Ueda, Hatsuno & Totani, 2013), but a balance between sufficient degreasing performance and high lubricity has not yet been achieved for an actual production process line."

Jan 1, 2018