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By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By A. Zrimsek, G. Vingas, R. Wolke

IN 1952, prompted by the great demand of the Canadian drilling and foundry industries for sodium bentonite, the Geological Department of Magnet Cove Barium Corporation, Limited began an extensive search for bentonite deposits throughout western Canada. Their efforts were rewarded in 1958, when substantial deposits of high quality material were found approximately 100 miles southeast of Edmonton, Alberta. The bentonite material, a part of the Edmonton formation in the Upper Cretaceous, is located approximately nine miles south of the town of Rosalind. The land where the bentonite lies has in places .been eroded by stream and glacial action to form a wide gully, convenient for strip mining methods (see Figure 1). The bentonite bed is almost flat-lying, dipping to the southwest at approximately 12 feet per mile. The main bed is 8 to. 10 feet thick and is covered with 15 to 25 feet of overburden. Before stripping, the area is drilled and sampled to evaluate the quantity and quality of the bentonite.

Jan 1, 1962

By R. E. Stewart

"Using the concept of economic life and marginal analysis, it can be shown that proper equipment replacement timing can save a mining company many thousands of dollars. To assist management with determining the economic life of mining equipment, a new computer package has been developed. The package, called ERG (equipment replacement guide), incorporates all important economic factors related to equipment usage, such as operating costs, maintenance costs, salvage values, depreciation, volume of work, tax credits, inflation rates, ROJ, etc. The information is used in a series of equations which balance the costs of new equipment against the total cost of old equipment. The solution of the equations determines economic life and the point in time when the old equipment should be replaced. IntroductionIn an operating mine, equipment must eventually be replaced or downgraded for a variety of reasons. Fleets of haul trucks, dozers and other major pieces of equipment deteriorate over time until the mounting costs of maintenance and repair force either a major overhaul or the ir replacement by new and more efficient pieces of equipment.The question of determining the best time to replace old equipment has been approached in many different ways. Various methods, ranging from operating experience, intuition and physical necessity to sophisticated computer models have been devised to help cope with equipment replacement decisions . The best of the se will incorporate the most important economic factors related to equipment usage, such as operating and maintenance costs, salvage values, depreciation, work delivered, the cost of capital, tax credits and, of course, the effects of inflation.Economic TheoryThe fundamentals of equipment replacement theory grew out of the interaction between economics, engineering and finance. The use of annual cost comparisons and rate-of return calculations were helpful in handling situations in which assets with different finite lives were being compared. Later developments bringing together the concept of economic life and marginal analysis helped provide additional refinements to the theory. Taylorui showed that the displacement of an aging asset with a similar, but newer, asset can be justified economically when the marginal cost of keeping the asset one more year exceeds the minimum uniform annual cost equivalent of the proposed replacement."

Jan 1, 1980

By K. Nagai

The Asian projects are now in their second terms after the five-year first terms. Ultrafined-grained steels were developed in lab-scale and/or in practical process. Basic approach has been performed to explore the evolution mechanisms of ultrafine-grained microstructures. There have been investigated two approaches to make the ultrafine grains: the "recrystallization route" and the transformation route. In the "recrystallization" route, heavy deformation at low temperature is necessary for the ultra-refinement. In the transformation route, making the high density of ferrite initiation sites in the deformed austenite, especially of the heavily compressed austenite structures, is essential for the ultra-refinement, and further hindering the ferrite growth is also inevitable to utilize the high initiation rate. Strength and toughness are dramatically improved by the ultra-refinement. Fatigue property is also excellent. The poor uniform elongation can be enhanced by the design of the second phase dispersion. At the same time the application has been also pursued from various viewpoints of engineering to take advantages of the ultrafine-grained steels. Bridge, ship, construction, automobile and other high strength parts are being attempted for the application.

Jan 1, 2004

By C. A. Pickles

Nickeliferous limonitic laterite ores contain considerable free moisture. In this research, the application of microwave radiation for the drying of this ore was investigated. The effects of sample mass, initial moisture content and porosity on the microwave drying rate were studied and the results were compared to those obtained with conventional drying. Microwave drying rates of two to three times the conventional values were achieved. Further enhancement of the microwave drying rate was realized by increasing the flow rate of air over the sample or by operating at reduced pressure. The high microwave drying rates were attributed to the inverted temperature gradient which resulted in internal heating and boiling and this in turn promoted movement of the water, both as liquid and vapour, to the surface.

Jan 1, 2005

By Roger M. Nendick

"IntroductionThe stages of development for bringing a mill into production demand that a flowsheet for the process be developed at an early stage. Detailed engineering of the mill may then proceed without duplication of engineering effort on alternative processes. In the case of gold and silver mills, several process alternatives exist which must be evaluated before the flowsheet is finally fixed. The recently developed Carbon-in-Pulp process has added to this choice.Clearly, the major factor in determining the most suitable process is the amenability of the particular ore to a given treatment. Other factors that will also influence the choice are location, climate, power and water supplies, and available capital.Gold and silver milling processes can be divided into three main types:Gravity Concentration;Flotation;Cyanidation.Combinations of the three are frequently used; i.e. flotation followed by cyanidation of the concentrate, or gravity concentration in the grinding circuit with cyanidation of the classifier overflow. The following are the salient advantages and disadvantages of the three main alternatives.Gravity ConcentrationGravity concentration is suitable for free-milling gold ores, i.e. ores in which the gold is relatively coarse and free from sulphides. It should be noted that just because an ore is high grade, it is not necessarily free milling.Gravity concentration methods include jigs, shaking tables, spirals and more recently Reichert cone concentrators. All methods exploit the density difference between gold, which has a specific gravity greater than 15, depending on how it is alloyed, and the gangue, which usually has a specific gravity range of 2.7 to 3.5.A concentrate grade of several hundred ounces per ton might be produced, but recoveries by gravity alone are generally low in comparison to other methods. For this reason, gravity circuits are usually used in combination with flotation or cyanidation circuits."

Jan 1, 1983

By A. Michalkow

DELN ITE Mines Limited is located in Deloro township, on the west end of the south break of the Porcupine Camp. Mining operations are currently being carried out on the downward extension of a system of quartz veins in an andesite zone. This zone has been followed from surface to the present bottom level of 5,250 feet. The changing mineralogy of the vein system has involved an increase in tourmaline content from the surface downwards, so that the veins at the lower levels are composed of dark brown quartz-tourmaline. The drilling problem presented by these extremely hard veins was partially alleviated by the development and adoption of a one-inch drill bit. All blast-hole drilling is now done with the one-inch bit, without any difference in hole spacing.

Jan 1, 1962

By Adam Turcotte

Mining operations consume a considerable amount of energy, and while reduced energy consumption is desirable, it is not always clear how to achieve this goal. Understanding the opportunities to optimize energy consumption is crucial, and the key to understanding is visualization. One option is the Sankey diagram, which has been used for over 100 years to visualize the flow of energy, materials, or cost through various processes. However, there are drawbacks to this approach that must be addressed. In a Sankey diagram, each flow is represented by an arrow possessing a width proportional to the magnitude of the flow it represents. The diagrams show input flows, how energy is converted and into what form, and also output flows. As per the first law of thermodynamics, the total energy output is equivalent to the total energy input, so any energy that is not transferred to another process is considered to be wasted. These waste flows are depicted in Sankey diagrams and make it straightforward to associate energy sources, sinks and waste flows. Unfortunately, Sankey diagrams do not convey all information required to support practical decision making for redirecting individual energy flows. Based only on a Sankey diagram, it may become evident that a significant flow of waste heat is of the appropriate grade (temperature) and volume to meet an on-site heat demand currently being met with paid-for, possibly carbon intensive fuel. However without augmenting the Sankey diagram with 3D spatial, true geometric analysis, the practicalities of the concept or idea may not be fully appreciated. Another issue with a Sankey diagram is that the magnitude of the energy flowing between processes may have temporal fluctuation or variability on different timescales (diurnal, seasonal, interannual). Currently, Sankey diagrams only provide a static picture of energy conversion and consumption, so that, for example, 4 separate diagrams could have to be prepared for each season. A new energy flow visualization technique which we have called Sankey Trees has been developed. Process locations are defined within a 3D model of the site being studied, and the magnitude of the flow between each pair of processes considered is replaced with a time series. Branches of sustained and diminishing flows are represented through variation of the geometric properties of the branches of the trees. These branches are animated to indicate the direction of flow, and branch joints are used to indicate that a process is transporting one form of energy to multiple processes.

Aug 1, 2013

The quality of refractory bricks and castables could be determined by direct measurements of their material properties such as elastic properties, porosity, density, etc. using conventional static or non-destructive testing (NDT) dynamic techniques. Quality monitoring of refractory linings is much more challenging and complicated. The static methods require undesirable drilling and sample extractions from the furnace structure. A more desirable alternative is the use of NDT techniques for material quality estimation. The Acousto Ultrasonic-Echo (AU-E) technique is a new stress wave propagation approach for monitoring the quality of refractory linings in operating furnaces. In this paper, the conceptual methodology for the AU-E technique is described, the capabilities and limitations are expanded, and the results from two case studies are discussed.

Jan 1, 2005

By Malcolm Black

Introduction Before beginning to write this paper, I decided that I should first find suitable definitions of the words Sample and Sampling. The dictionary gives: "Sample.-A portion indicative of the whole"; and according to Baillie (1), sampling is "That process whereby a representative and comparatively small portion of material is selected from a large bulk, and preserved under such conditions as shall prevent contamination or avoidable alteration, with a view to the formation of valid conclusions regarding the suitability of the bulk for specified purposes". These comprehensive definitions are alike in substance, and indicate that unless a truly representative portion is taken, it is not a sample. Ore 'as mined' generally varies a good deal in composition, and, in crushing, segregation takes place. Some of the minerals present, due to differences in hardness and friability, break into smaller pieces than others, and, on reaching the bin, the coarse particles roll away, leaving the fines behind. The result of this segregation is generally quite noticeable on the conveyor feeding the mill, especially when the bin is nearly empty and the crushing plant shut down. Should the sampling period synchronize with either the coarse or the fines, the sample obviously would not be representative. I agree that this is rather far fetched, but I maintain that such a condition is possible. Assuming that a representative sample may be procured from the feed conveyor, the method of cutting it down for assay has considerable influence in maintaining the original condition of the sample. The finer the material is ground after each cut, the more uniform the sample will remain. To illustrate this point, let us take a quantity of fine sand and add, say, three grains of rice to represent metallic particles. We may mix this sample by any of the known methods, then cut it into four equal portions. It is obvious that at least one of the portions will be without a rice grain. But let us grind the three grains of rice into flour and proceed as before. Now there will be a much greater chance of including some of the rice in each portion.

Jan 1, 1935

By Mohammed Rachek

Résumé : la mine d?Elhammam, opération du groupe minier Marocain Managem, est située au sud de la ville de Meknes à 63 km, elle exploite un gisement de fluorine depuis 1974. La minéralisation se présente sous forme de deux filons principaux orientés N45° avec un pendage variant de 65 à 90° NW, entre ces deux filons on note la présence d?une succession de filons satellites sécants. La méthode d?exploitation pratiquée depuis le démarrage de la mine est celle des chambres magasins, elle assure une cadence d?extraction annuelle de 250000 tonnes. Cette méthode favorisée par une très bonne compétence mécanique des épontes de la minéralisation a offert à l?exploitation une rentabilité très satisfaisante grâce à son faible coût mine. Les travaux de recherche géologique menés en parallèle à l?exploitation ont permis la découverte d?un nouveau secteur ?K-Est Gouaïda? (KEG) qui fait l?extension nord-est du gisement principal, la minéralisation de ce secteur se présente sous forme de deux filons très étendus latéralement (900 m d?extension) et présentant une puissance minéralisée irrégulière et très faible 1.2 m en moyenne, les épontes de la minéralisation sont constituées de schistes de qualité mécanique très faible. Vers la fin des années 1990, l?exploitation s?est orientée vers le développement minier du secteur KEG. Ce développement consiste à faire le choix adéquat de la méthode et de l?infrastructure minière pour l?exploitation de ce nouveau secteur, KEG. La méthode des chambres magasins, pratiquée dans le gisement principal avec un faible coût mine, n?est pas praticable dans le nouveau secteur à cause de la qualité de ses terrains, l?irrégularité de la morphologie de sa minéralisation et de la faible puissance des ses filons. Seule la méthode des tranches montantes remblayées (TMR) peut être applicable techniquement vu les spécifications suscitées de la nouvelle minéralisation, la TMR doit être appliquée sous sa variante mécanisée pour faire face au niveau exigé de la production. Après le pilotage de l?exploitation par TMR mécanisée dans le secteur KEG, il a été confirmé que cette méthode donne une grande satisfaction en matière de stabilité des terrains, sécurité, sélectivité, productivité et récupération du gisement, néanmoins elle reste pénalisée par un coût mine trop élevé pour garder le niveau de rentabilité recherché par l?exploitation d?un produit de faible valeur marchande telle que la fluorine. Dans l?objectif de rentabiliser l?exploitation du secteur KEG qui représente en réserves l?équivalent d?une durée de vie de 4 à 5 ans et d?assurer la pérennité de l?activité, l?exploitation en collaboration avec Reminex, la filiale d?ingénierie de Managem, a adapté une nouvelle variante de la TMR mécanisée dite TMR avec plan incliné sur remblai. Cette nouvelle variante de la TMR consiste à réduire au maximum les travaux dans le stérile en reconstituant un plan incliné sur le remblai à l?intérieur des filons pour faire évoluer en vertical l?exploitation des tranches en montant vers la tête d?un panneau de minerai. La variante des tranches montantes remblayées mécanisées avec plan incliné sur remblai a été imaginée et appliquer en 1978 dans la mine de fluorine de Burc située au Sud-Ouest de la France (Sicard et Mailloux, 1983). Imaginée pour une cadence annuelle de 30000 tonnes et une mécanisation très modérée cette variante a été adaptée par l?exploitation de la mine d?Elhammam en 2002 pour un haut degré de mécanisation et une cadence d?extraction annuelle de 250000 tonnes de minerai. Cette variante de la TMR est appliquée depuis le début de 2003 dans les chantiers du secteur KEG, elle présente les mêmes avantages techniques que la TMR mécanisée classique et elle a permis la réduction du volume des travaux d?infrastructure de 17.65 m à 6.25 m de travaux par 1000 tonnes de minerai. Ceci s?est traduit par une baisse du coût technique de la mine de 34% ce qui a donné un nouveau souffle à la mine pour assurer sa production et pour poursuivre la recherche géologique d?éventuelles zones à mettre en valeur.

Oct 1, 2004

By Serge Perreault

Le cuivre est un métal fascinant qui joue un rôle essentiel dans le développement des différentes civilisations depuis 7000 ans. Le cuivre est aussi un métal polyvalent et essentiel qui est très présent dans notre vie quotidienne. L’un des premiers métaux utilisés par les humains, il est un élément chimique qui se trouve à l’état natif, ce qui est rare pour les métaux. Il apparaît principalement dans des minéraux, notamment sous forme de sulfures, en raison de son caractère chalcophile (c’est-à-dire son attraction pour l’élément soufre). Le cuivre se trouve dans la croûte terrestre sous forme de minéraux de cuivre, tels que dans les sulfures dont la chalcopyrite, la bornite, la covellite et la chalcocite. Il est également présent sous sa forme native ou dans des minéraux oxydés comme la cuprite et dans des carbonates hydratés, comme la malachite et l’azurite. La formation de gisements de minerai de cuivre implique des processus géologiques complexes, notamment l’activité hydrothermale, les intrusions magmatiques et l’altération des roches. Les gisements de minerai de cuivre se trouvent dans divers types d’environnements géologiques, dont les gisements porphyriques, les gisements de cuivre encaissés dans des roches sédimentaires, les gisements de type skarn, les gisements de sulfures massifs volcanogènes, les gisements magmatiques de type nickel-cuivre, les gisements de cuivre oxydé, et d’autres [1].

May 2, 2024

By W. L. Uglow

In recent years, the microscope has come to be recognized as a valuable aid to engineers whose business is the discovery, development, concentration or reduction of metallic ores. In many of the large treatment plants microscopical research has already an important status; and in the hands of efficient operators the microscope has indicated methods of solving ore problems resulting in the saving of thousands of dollars that otherwise might have been lost in tailings, or expended in freight rates or smelter charges. Failure to procure all the information that the microscope can supply concerning the physical and mineralogical characteristics of complex ores has in many cases led to the construction of unsuitable concentrators, just as the failure to investigate in detail the geological conditions of an ore deposit has often results in the squandering of money on shaft sinking, and mechanical installations which subsequent development of the deposit failed to justify. The great progress recently made in the selective separation of minerals by means of the various processes of flotation and leaching brings strongly to our attention, the scope of the field in which microscopical methods may be advantageously employed. The microscope enables one to observe the minute details of rock, ore, gangue, concentrate, tailing, matte, slag and metal, that are invisible to the naked eye. Furthermore, the technique of microscopal research has been so highly developed that a microscopist can not only observe, but deter-mine the compositions and measure the diameters of the mineral constituents in the ore to be treated. Magnifications of these constituents up to 3,000 diameters may be produced by the proper combination of eyepiece, objective, and projection apparatus, and the images thus viewed may be photographed through the microscope, and permanent records made of them.

Jan 1, 1924

By G. M. Humphrey

It is a great honour and privilege to be here in this distinguished company of the outstanding men in the mining industry and the political life of Canada. I fully recognize that I am so honoured as a symbol of the combination of American and Canadian leaders in industry who are partners in the sponsor-ship of the Quebec-Labrador iron-ore mining development which we are undertaking, and as such I want to express our great appreciation of the co-operation and assistance we have met on every hand in Canada, and the genuine friendliness and never-failing courtesy which we are always accorded. We are quite aware that it springs primarily from the very high regard in which our partner and sponsor, Jules Timmins, and our other Canadian associates are held. Their high standing among you is well known and we quite naturally fall heir to the benefits of the great esteem in which you hold them. Jules Timmins and his long-time associate, John Knox, were the original inspiration for our participation in this venture. It was their enthusiasm and vision which caught our interest and led to our joining with them in the years of exploration and search which have brought us to the threshold of this great development where we stand today. So much has been written of the details of our exploration and plans for future development that it would bore you for me to review them further here, but there is a phase of this development, and an extremely important phase of it, which I think has passed almost unnoticed and which it may be well worth while for me to bring to your attention this evening.

Jan 1, 1951

The effect of long term exposure of full size bolts to corrosive environments is presented. A special test rig was used to test four bolts under different loading conditions. Four, X-grade identical profile bolts, each of 21.7 mm core diameters (23.7 mm full diameter) were subjected to prolonged corrosion testing using acid sulphate water. The pH value of the circulated water varied between 3.4 and 4.3. The corrosion exposure test period lasted three and half years. Two bolts were axially loaded to 10 and 20 tonnes force respectively, the third bolt was subjected to a 360 Nm torsion load and the fourth bolt was left unstressed to act as a reference bolt. After the test period ended, the bolts were stripped of their corroded coatings and weighted for weight loss. The diameter of each bolt was subsequently measured, and the loaded bolt samples were first tested non-destructively for tensile cracks and then tested for tensile failure. No cracks were found on post corrosion bolts tested non-destructively. The failure strength reduction on all four post-corroded bolts was significant, varying between 21% and 39%. The onset of corrosion was not confined to the targeted mid-section length of the bolt, however, the severest corrosion occurred at the anchored ends of the bolts.

Aug 1, 2013

By George Kellock

In presenting this paper for discussion at the Western Annual Meeting to be held in Edmonton, it is with the idea of creating a full and general discussion by the mining men in the Province as to the best way to eliminate, or at least hold down to a minimum, the dangerous coal-dust which is made in mining pitching seams in our Alberta mines by the chute method. Also, an alternative method is outlined, whereby the percentage of lump-coal mined can be increased, and the mining costs reduced-although the paper does not go into any detailed consideration of costs. The general trend of mining practice and lay-outs is at present towards mechanization, and the results being accomplished by the substitution of machines for manual labour are fully justifying the changes. In the technical mining journals, there are published from time to time papers dealing with a variety of methods of mining, which are descriptions of actual operations, and a great deal of interesting and valuable data is given as to the comparative values of the different methods, insofar as the percentage of grades of coal produced, the cost of production, etc., are concerned; but the mechanical methods described in these papers are nearly always suitable only for flat seams, or seams with a very low inclination.

Jan 1, 1929

By R. W. Allgood

"THE world-wide shortage of elemental sulphur, which became sharply apparent in 1950, has focused attention on the commercial exploitation of sulphur-bearing materials such as pyritic ores, sour natural gas, and smelter gases. Although there •are no known commercial deposits of elemental sulphur in Canada, there are vast quantities of these sulphur-bearing materials. The International Nickel Company of Canada and Canadian Industries Limited have for many years collaborated in an effort to develop economic processes for the recovery of sulphur from the smelter gas arising from Inco's metallurgical operation at Copper Cliff, Ontario. While sulphuric acid has been •produced at Copper Cliff for over twenty years, recent developments will result in a 60 per cent increase in acid production early in 1952 and, later in the year, in commencement of the operation of the largest single unit ever erected for the manufacture of liquid sulphur dioxide.The purpose of this paper is to discuss •briefly the general factors associated with the recovery of sulphur from the Copper Cliff smelter gases and to describe the sulphuric acid operations and the liquid sulphur dioxide development.Processes for the manufacture of elemental sulphur, liquid sulphur dioxide, and sulphuric acid from sulphur-dioxide-bearing smelter gases are well known and in some cases •highly developed."

Jan 1, 1952

By Les F. Sawatsky

Surface drainage, particularly mine closure drainage, must be properly considered during all stages of mine planning because it presents constraints that are critical to economic mine operation, minimizing environmental impacts and ensuring compliance with government regulations. Deficient mine site drainage increases costs of operation, causes unnecessary environmental impacts and may result in regulatory violations. The scope of this paper includes stream diversions around mine areas, drainage systems within the mine disturbed footprint, and closure drainage works to control surface water, ground water, erosion, sedimentation, and seepage discharges following mine operations. Developing selfsustaining drainage facilities upon mine closure, requires a mine plan that develops appropriate topography and constructed drainage courses that replace the function of pre-disturbance drainage systems without aggravated erosion and deterioration. Drainage criteria, particularly closure drainage criteria, represent important constraints on mine planning and are best considered by integrating drainage features into the mine plan well in advance of mining activities. Integrated mine planning by a multi-disciplinary team is recommended to achieve closure objectives at minimum cost and maximum effectiveness The geomorphic approach to channel design is an effective means of providing a drainage system that has the appearance, function and longevity of natural systems. By incorporating this technique into closure drainage planning, mine operators can construct sustainable (walk-away) drainage systems that require little or no maintenance in the long-term. This paper presents a process by which drainage criteria and associated mine plan constraints can be integrated into the mine planning process. This paper outlines the process for detailed design of drainage facilities, particularly closure drainage systems that are designed by the geomorphic approach.

May 1, 2009

By D. Lopez, D. L. Doerr, T. J. Drake

Automated scanning electron microscopy has been widely used in recent years for gold and other precious metals characterization. However, application of this technology is resource intensive and in most instances needs specialized technical personnel to process the samples and information. Newmont Metallurgical Services (NMS) has recently acquired an ASPEX SEM. The ASPEX SEM offers some significant benefits/improvements in sample preparation and sample processing time. NMS and ASPEX have been working together to develop an approach utilizing this technology for the minerals processing industry and specifically for gold characterization.

Jan 1, 2011

By C. Anderson, H. Huang, P. Miranda, E. Dahlgren, I. Chandra, M. Jeffrey

The latter part of the 20th century saw great advances in the treatment of refractory gold ores coupled with increased reliance on the use of cyanide for gold processing. Now, in many parts of the world, there is social pressure to limit or eliminate the use of cyanide. As well, treatment of some refractory ores or concentrates which have excessive cyanide consumption, gold cyanide pregrobbing or significant sulfide content remain difficult. This paper will outline the history of the development of alkaline sulfide leaching as an ancillary process to nitrogen species catalyzed (NSC) pressure leaching. Electrochemical fundamentals and the applicable thermodynamics of the alkaline sulfide hydrometallurgical system will be outlined. As well, examples of refractory gold recovery with alkaline sulfide hydrometallurgy such as an arsenopyrite gold concentrate application, a chalcopyrite gold concentrate application, a pregrobbing gold ore application, and a cyanide consuming gold ore application will be delineated in this paper.

Jan 1, 2005