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By A. G. Scobie

THE research laboratory of this Company was recently faced with the problem of determining trace amounts of tungsten in a series of classifier sands. A spectrographie survey revealed the feasibility of using this instrument in the final evaluation, but a check of the common methods in use for the isolation of tungsten (3, 4) showed these methods to give incomplete separation for trace amounts. An investigation into the possibility of modifying these procedures, or developing others, was thus indicated. ASSAY PROCEDURE Weigh 10 grams of 200-mesh ore or concentrate into a 400-ml. beaker, wet the sample well with about 20 ml. of water, and add 100 ml. of hydrochloric acid. Cover, digest at 60° to 70° C. for about 1 hour, and then boil down to approximately 25 ml. Cool, add 25 ml. of hydrochloric acid and 10 ml. of nitric acid, and again boil to former volume. Add 20-ml. portions of nitric acid with successive boiling clown until chemical action is complete. Then add 20-ml. portions of hydrochloric acid until all nitric acid is removed. Take nearly to dryness on a law-temperature hot plate, but do not bake. Take up in 10 ml. of hydrochloric acid and 20 ml. of water and heat on a law-temperature hot plate until all iron goes into solution. Dilute to 200 ml. and heat to just below boiling. Stir in pulp of about half of a No. 41 Whatman filter paper (12.5-cm.) and continue digestion on plate with occasional stirring for 15 to 20 minutes.

Jan 1, 1943

By S. A. Pence, A. I. McCallum, V. de Korompay

"Special salt protection rings containing a water-swell• able, polymeric sealant are in successful operation in Canadian potash shafts. Installed above the Prairie Evaporite salt formation at a depth of 3,000 feet, the sealant is preventing formation water migration into the salt and pressure build-up on the concrete lining of both production and service shafts. The salt protection rings are not under the hydrostatic pressure of the formation water.The chemical sealant in use has the unique property of imbibing water and swelling. •Therefore, any water at• tempting to flow by the seal ring actually produces a tighter seal.The purpose of this paper is to discuss the sealant and its properties and uses. Installation of the material and its operation in two Canadian mine shafts is described."

Jan 1, 1971

By J. W. Bingay

The expansion of the mining industry, with other industries, of course, is dependent upon a supply of fresh capital from year to year. Mining is a speculative form of investment, though there is a wide range of risk as between indiudual undertakings. All of the leading financial writers, nowadays, agree that expansion is being seriously interfered with by the unprecedented load of taxation Canadians are carrying. Individuals have less for investment and corporations are obliged to defer necessary expenditures in order that the demands of the taxing authorities may be met. Naturally, speculative investments such as mining exploration suffer first. Undoubtedly, a great deal of cash raised by taxes, if left in the hands of individuals and corporations for investment and expansion, would have been far more beneficially used and would have developed the country more than any use made of it by the government, in the way of bonusing new industries, or the undertaking of large schemes of development. Government undertakings of this nature are often entered into without a proper knowledge of cost and probable return. Expert expenditure of the same sums by business men or corporations undoubtedly would generally produce more prosperity for the country as a whole. The absolute necessity for lower taxation is being increasingly known to the public at large, and eventually it is hoped that our governments will see the economic impossibility of continuing the present rate of expenditure. The successful Finance Minister of the near future will not be the one who can borrow the most money.

Jan 1, 1924

By Laura A. Sanders

Mineral scale formation is prevalent in numerous mining operations. Such scale formation can occur in the direct-contact heat exchangers ahead of an autoclave. In these heat exchangers, the incoming slurry comes into contact with steam in a stage-wise fashion, which is re-circulated from the downstream flash vessels to heat the slurry in stages ahead of the autoclave. Calcium sulfate scaling causes severe problems in mining operations where increased temperatures are involved due to rising temperatures promoting calcium sulfate scaling through a decreasing solubility. In a number of these operations, the scale formation can occur in the presence of mineral solids, where fine-grained charged particles are at concentrations in excess of 35%. Scale prevention is not difficult in standard aqueous systems; however, the presence of solids leads to significant deficiencies in the prevention of scale due to the adsorption of the polymer onto the charge solids instead of the polymer interaction with the scale. Therefore, a technical solution to prevent mineral scale build up occurring in presence of pulp slurry in mining operations is needed. Several novel antiscalant technologies were developed and evaluated which provided a substantial improvement in the scale prevention in such systems.

May 1, 2013

By T. M. Waterland

A GREAT deal of work has been done at Britannia during the past three years in improving and standardizing rounds for development headings, and the results obtained have been very gratifying. The round which has recently been adopted as a standard for all drifts and cross-cuts has, in some instances, doubled the average length of break formerly obtained. It has also increased the footage of advance per labour shift and reduced explosives' consumption. At the present time, with a shortage of skilled labour, more control is necessar7 in directing the drilling of rounds. The use of a standard round has been o great assistance to the foremen and shiftbosses. NATURE OF GROUND Most of the ground encountered consists of a moderately silicified chlorite schist, known locally as G.M.S (green-mottled schist). It cannot be termed hard ground, because a three and one-half inch Leyner will drill at an average rate of twelve inches per minute. Due to the abrasive nature of the ground, the gauge of the steel wears rapidly and in most cases one set of steel is needed for each hole. The ground is not 'free breaking and holes must be spaced correctly to obtain a maximum break. DEVELOPMENT OF STANDARD ROUND FOR THREE-SHIFT OPERATION Late in 1940, a development programme was started involving 7,000 feet of drifting, 6 ft. By 7 1/2 ft. In cross-section, in two headings. Plans were drawn up to advance the headings on three shifts. Equipment used in the headings was as follows: D.A.35 Leyner?machines, Eimco Model 12B mucking machines, nine one-ton end-dump cars, one Mancha Little Trammer on the longest heading, 20-pound rail, 4-in. 15 compressed-air line, 15-in. Fan pipe connected to 5 h. P. Coppus fan. Diamond-drill cross-cuts, 16 feet in length, were cut every 250 feet. Switches were installed at these cross-cuts and they served as passing points for the cars. One siding seventy feet in length was cut in each heading at approximately the half-way point. The cycle of operations planned was to muck out, drill, and blast each shift. Previous performance in this type of ground indicated that a daily advance of 12 feet to 14 feet might be made. However, if a better type of round could be developed, an increased daily advance would be possible. A study of the time available for each operation in a net working shift of six and one-half hours indicated that the maximum depth of round that could be mucked, drilled, and blasted each shift would be six and one-half feet. When this maximum depth was decided upon, the next problem was to develop a satisfactory round. Due to ventilation difficulties and to the short net working shift, the whole round had to be blasted at one time. In other words, no blasting of the cut-holes could be done.

Jan 1, 1942

By J. A. Hillier

The staff of the Hudson Bay Mining and Smelting concentrator have developed a new type of reagent feeder. Several factors encouraged the development of such a system: varying heads caused by the mixing of ores from several mines, the increasing number of flotation circuits operated and reagent feeding stations remote from the flotation operator's work area. The reagent feeders also had to be compatible with future plans for reagent control from an on-stream X-ray analyzer and computer system. The new feeder is a positive-displacement pump set to deliver a constant volume per stroke. At a remote panel, the feed rate is altered by changing the time between strokes. The feeders have been found to be reasonably trouble-free and accurate to less than 2 per cent error.

Jan 1, 1973

By Eliodor Stoian

PRESSURE information has earned a place of recognition to almost everyone interested in oil and gas production. This interest is due chiefly to the multitude of uses to which it can be put. A sub-surface pressure test, conducted for as little as $60, may yield data worth many times its cost. To the uninformed, the testing techniques may seem complex. Fundamentally, however, they consist merely of the application of common sense. At one time, sub-surface pressure data were used only in identifying individual well problems and in finding appropriate solutions. Today, it is generally acknowledged that sub-surface pres-sure .data are essential for the proper evaluation and exploitation of oil and gas pools. The following is a review of significant applications of sub-surface data with regard to: (A).-Development (B) .-Completion and work-overs (C) .-Production (D) .-Reservoir engineering (E).-Proration (F) .Other applications of pressure data of a more general nature.

Jan 1, 1958

By H. U. Ross

ROASTING is usually thought of as a process in which finely crushed or ground ore is heated with air in a suitable furnace in which the ore is rabbled or agitated in such a way as to insure complete reaction between the oxygen of the air and the oxidisable constituents of the ore. Roasting in this sense is used only to a very limited extent in the iron and steel industry. This is because, in most iron ore deposits mined today, the ore is of a type that does not require roasting. Where this process is used, it is usually because of some special circumstance, such as a peculiar economic condition, that warrants it. If roasting is looked upon in the broader sense as a gas-solid chemical reaction carried out at an elevated temperature in which both gaseous and solid products are formed, then the process is used in the iron and steel industry to a greater extent

Jan 1, 1961

By C. W. Jr. Waterman

INTRODUCTION MY SUBJECT is one which would require several speakers and many hours of time for adequate presentation in all its many facets. Because of the widely varying market requirements and coal seams mined, the coal industry of the United States bas of necessity employed many types of preparation facilities to satisfy its needs. Predominance of Baum-type jigs, however, bas marked the mechanical cleaning installations since the early thirties, and these machines continue to hold the lead. CLEANING As a matter of record we find that, at the end of 1948, we had 480 mechanical cleaning plants in operation. Of these, 19 used air cleaners only,?400 used water washers only, . and 61 used dry and wet washers in combination . Due to the increased use of spray water underground on cutting and mechanical mining equipment, there has in recent years been a marked downward trend in dry cleaning installations. In fact, the moisture in dry-cleaned fines has been increased to such an extent by spraying that recent dry cleaning installations have incorporated thermal drying ahead of the dry cleaning units in an effort to overcome the varying and increasingly higher moisture percentages in their raw coal feeds. While on the subject of dry cleaning, it might be well to bring to your attention one of our most recent developments in this art. I refer to the McNally-Brusset vacuum jig.

Jan 1, 1951

By N. O. Lotter

The connection between mineralogy and metallurgical performance in a plant was recognised long ago (Gaudin, 1939; Petruk, 1976; Petruk and Hughson, 1977; Cabri, 1981; Petruk and Schnaar, 1981; Kinloch, 1982; Peyerl, 1983, Baum et al 1989 for example). The modern toolbox that we now routinely use for flowsheet development took decades to develop (Lotter et al., 2002; Baum and Lotter, 2004; Lotter, 2011 for example). Many workers contributed considerable time and effort to this overall mission of connecting sampling, mineralogy and mineral processing to integrate the flowsheet development activities. Certain key milestones marked this journey, such as Gy’s treatise on the sampling of particulate materials in 1979, which was later added to by François-Bongarçon, Pitard, Minnitt, and Holmes for example. The development of QEM*SEM by Gottlieb et al. of the MLA by Gu et al. constituted a huge leap forward in accuracy and mineral measurement capacity, as well as a reduction in standard errors of mineral characterisation. The advancement of the microprobe to an automated platform made a significant difference to detailed compositional mineralogy. This led to a strong position from which to draw meaningful processing implications from the mineralogical data. Reproducible flotation testing and reliable plant survey material for characterisation was dealt with by, amongst others, High Confidence Flotation Testing ( Lotter, 1995: Runge, 2010, and Bradshaw, 1997); and Statistical Benchmark Surveying (Lotter, 2005), with earlier prototypes which were steadily improved (Lotter, 1994; Restarick, 1976). The sterling work of Napier-Munn in engaging sound statistical methods with mineral processing led to the successful design and use of methods that could identify and quantify small recovery gains in plant scale trials. This history and present capability are reviewed, including leverage into asset management.

Jan 1, 2018

By L. Vollert

"The application of pneumatically-assisted fluidized bed flotation, specifically the ERIEZ HydroFloatTM technology, has found widespread use in non-sulphide processing (particularly phosphate, potash and coal) for the recovery of coarse particles. In gold processing, centrifugal gravity circuits and flash flotation cells are typically employed for the recovery of coarse and near-size liberated gold which tends to accumulate in recycled grinding streams due to bypass to the classifying cyclone underflow streams owing to the higher specific gravity of these gold particles. Early removal of this gold from the grinding circuits contributes toward the reduction of downstream processing losses as a result of overgrinding and particle shape deformation in the case of flotation processing, longer leach residence times in the case of extractive processing, and surface occlusions in the case of both flotation and extractive processing. Furthermore, recovery to bullion attracts higher payment terms by way of comparison to concentrate sales in the case of copper-gold concentrators. This paper assesses the application of pneumatically assisted fluidized bed flotation for the recovery of coarse liberated gold through the analysis of piloting data generated from the operation of a continuously operated 16 inch ERIEZ HydroFloatTM unit treating a sized coarse grinding circuit stream. The paper presents the stage recovery by size performance of the ERIEZ HydroFloatTM unit together with quantitative gold deportment analysis to demonstrate the efficiency with which gold was recovered during this pilot campaign and then compared to more conventional processing units – centrifugal gravity and conventional flotation.INTRODUCTION Newcrest Mining Limited (NML) has identified that an opportunity exists for improving the recovery of coarse composite particles at its current operations, both as a means for improving overall recovery and as an opportunity for early gangue rejection. As such, Newcrest Mining Limited has taken an interest in the application of pneumatically-assisted, fluidized-bed flotation i.e. ERIEZ HydroFloatTM technology. This interest dates back to 2011 with sighter testwork carried out on their Australian-held ore bodies (Kohmuench et al, 2013). Newcrest continues to assess ERIEZ HydroFloatTM potential for coarse composite recovery and, in the case of the topic of this paper, coarse gold recovery based on examples in the literature which demonstrate the efficiency of this technology in this regard (Carmona Franco et al., (2015); Miller et al., (2016); and Kohmuench et al, 2013)."

Jan 1, 2017

By O. D. Maurice

Feldspar mining in Canada came to an end during 1972 after many years of continuous activity. The deposits are not exhausted and the domestic demand for this product is expected to continue at about the same level as in recent years. The size of the industry does not justify the installation of expensive equipment in the mills, but it is believed that a modest profit could be made by a small operation using rudimentary methods of separation. Largescale and accurate mapping of the pegmatite dykes could help in planning mining operations for a better recovery of a uniform product.

Jan 1, 1973

By The Staff

"IntroductionThe difficulties to be overcome in shaft sinking and development at depth are centred at McIntyre in and around No. 12 shaft. Generally they have been due to increasing pressures and temperatures and to changes in geological structure. This paper describes the difficulties and the measures taken to meet them.No. 12 ShaftEarly in 1932 McIntyre decided to sink an internal shaft from the deepest level, the 3875, to explore and develop known veins extending below that horizon. The location selected was a point 1,500 feet south and 1,000 feet east of No. 11 shaft, the main operating shaft through which the men, ore, and most of the materials are handled Shaft and auxiliary equipment we1e laid out for 3,000 feet, that is to 7,000 feet below the surface. The shaft was to be capable of handling 1,500 tons of ore daily from the lowest level, and was to provide ventilation, compressed air, water, and electric power to service all levels.No. 12 is an internal, vertical shaft extending from the 3875 to the 6825 level and bottoming at 7,007 feet. It is a rectangular, four-compartment shaft, 21 ft. 9¾, in. by 6 ft. 3¾ in. outside the timber (Figure 1).There are two hoisting compartments and one airway compartment, each 4 ft. 10¾ in. by 5 ft. ¾ in. inside dimensions, and a combined manway, pipe, and cable compartment 4 ft. ¼ in. by 5 ft. ¾ in. Levels have been established at 150-foot intervals, pump stations and sumps at 1,000-foot intervals, and. there are two loading pockets, one at the 5525 and the other at the 6900 level.The shaft was sunk in two stages. The first stage, consisting of preparation above the 3875 level and sinking to 5585 feet, was completed by March 31st, 1935. The second stage of deepening the shaft from 5,585 to 7,007 feet was started August lst, 1946, and completed three years later."

Jan 1, 1950

By Torsten Zeller

Due to the increasing worldwide demand for raw materials and the resulting rise in commodity prices more expensive processing that is able to utilize complex ores becomes economically viable. This and increasing ecological awareness is why the interest in recycling and urban mining is steadily growing in Germany. In addition to that; landfills do also contain elements, which were not targeted over the period, when they were being accumulated. Examples are rare earths, indium, gallium, cadmium, arsenic, selenium and tellurium. Also copper, zinc and lead, the target components of ancient mining, can be obtained due to more effective processing and smelting technologies. Funding by the German Federal Ministry for Education and Research, entitled "r³ ? Strategic Metals and Minerals ? Innovative Technologies for Resource Efficiency" also indicates the high level of strategic interest. It is against this background that the research project "Exploitation of the Raw Material Potential of Mining and Metallurgical Tips in Respect of Sustainability as Exemplified in the West Harz Mountains (ROBEHA)" has been implemented. A major concern of this project is the possible transfer of results to landfills in other areas. Therefore the development of an expert system based on the innovative processing methods and a method manual for urban mining are the central components of the investigation. This will provide an important contribution to the cost optimization of ensuing urban mining projects. To ensure the success of landfill mining projects it is necessary to record the composition and quality of the deposits accurately. Also the environmental impact caused by landfill mining and changes in the natural and cultural landscape will be considered in a multicriteria evaluation method. Depending on their origin the tips are divided into the categories mining, processing, and smelting. The content of a landfill and thus the economic potential in terms of urban mining is dependent on the type and composition of the deposits (host rock, gangue, and ore mineral), the available processing and smelting technology, and the target components at the time of mining. Zinc, for example, was not been processed until the 19th century, when it gained attention as being material of economic importance. After such knowledge about a landfill is obtained the decision for further investigations can be made. For a total of 158 landfills in the Harz Mountains, both the volume and the approximate contents of copper, zinc, and lead has been estimated for the different types of tips within past research projects. Based on the prices of the London Metal Exchange (LME) and a euro/dollar exchange rate of 0.76 (as of 03/05/2012) and assuming a minimum density of ? ? 1.5 t/m³ a average value of 1.6 billion ? in copper, zinc, and lead can be obtained. Although only these three metals are considered in this first estimate, it demonstrates the potential of landfill mining and the need for further research. KEYWORDS Urban Mining,

Aug 1, 2013

By W. A. Toohey

Introduction From the earliest times it has been an inherent trait of man to build or create something for his own use or convenience. The need of some form of shelter other than that of the caves led him to bind together stones and other materials to form walls for his abode. Moistened clay which hardened upon drying was no doubt first employed. The Assyrians and Babylonians appear to have employed it or the bitumen found in their country. The early Egyptians and Greeks used some form of lime in their construction work. In addition to these shelters, other structures received attention, and, long before the Roman Empire was established, the Carthaginians made use of a natural cement as binding material. Portions of an aqueduct, seventy miles long, in Northern Africa, built in those early days, are still in use. The Etruscans were the first people in Italy to employ a mortar in their buildings. The Romans, learning the art from the Etruscans, improved the mortar by using a mixture of lime and volcanic ash, called 'puzzolan', and built not only roads but those famous structures, the ruins of many of which exist to this day. The Pantheon at Rome, built by Hadrian about 120 A.D., is perhaps the finest example of the early use of cement in building construction. With the decline of the Roman Empire, the art of making cement seems to have been lost, and for centuries the builders of Europe used only lime mortar. Pure limestones were selected for making the lime and great care was taken in the preparation of the mortar, the supply for one year being made the previous season and left to thoroughly slake or 'ripen' in pits covered with earth. The mortar thus produced gave excellent service above ground or where it was exposed to the hardening action of the air, but would not harden under water.

Jan 1, 1927

By T. Schepp, T. Friedrich

"The natural stage of deep mines operation is a closure of unnecessary shafts. It is extremely important to ensure a proper shaft closure to avoid stability loss and the associated damage to surface facilities in the future. For the still active shafts, it can be done by a dedicated shaft closure design, but even then, depending on the shaft closure method, it may be necessary to perform regular shaft inspections. The paper presents a short overview of shaft closure methods and available tools and devices developed in the last time for such shaft inspections. INTRODUCTION The natural stage of deep mines operation, commonly occurring after depletion of the reserves of mined materials, is a closure of unnecessary shafts. All over the world, the number of liquidated shafts grows continuously and the problem of shafts disposal is especially critical for deep shafts. The typical depth of 600 m of currently liquidated shafts in Poland may already be seen as a challenging task. The greater is the challenge of shaft closure in Germany where the last active coal mines for shafts with a depth of up to 1,300 m have been recently closed. It is therefore extremely important to ensure a proper shaft closure to avoid stability loss and the associated damage to surface facilities in the future. For the still active shafts, it can be done by a dedicated shaft closure design, but even then, depending on the shaft closure method, it may be necessary to perform regular shaft inspections. In many cases, it is more important to inspect old, abandoned shafts, where the wall stability or even liner type are not fully known. SHAFT CLOSURE METHODS Abandoning a shaft is a complicated task, as shafts, being the link between the surface and an underground network of workings, disturb hydrogeological and gaseous conditions in the rock mass (Sztelak, 1991). Closure procedures at older mine sites have been carried out in accordance with earlier legislative requirements. For very old shafts (+100 years), it means in many cases only a sealing of the shaft entrances by means of timber or concrete slabs. In the 20th century, the shafts were also closed by means of filling with grainy materials, but even then the retrospective activities at abandoned mine sites were extremely limited and in most cases no further monitoring measures were performed. The possible consequence of an improper shaft closure and lack of monitoring is presented in Figure 1."

Jan 1, 2019

By Kevin J. Melong

"Redpath Canada Limited and joint venture partner Thyssen Mining and Construction Canada have recently completed the sinking of the Scissors Creek service in Saskatchewan through its joint owned company, Associated Mining Construction (AMC). The Scissors Creek service shaft was sunk at Nutrien’s Rocanville mine. The following paper outlines the shaft sinking plant and the methodology related to sinking and shaft lining. KEYWORDS Hydraulic shaft jumbo, Hydraulic shaft mucker, Potash shaft sinking, Shaft lining, Sinking galloway INTRODUCTION The sinking and lining of shafts at mines to access mineral deposits has always been one of the great mining challenges for owners, engineers and contractors. Over the course of history in Canadian mining, the sinking of potash shafts through the notorious Blairmore formation of Saskatchewan has proved to be some of the most challenging shaft sinking projects on record. There is no doubt that today’s shaft sinking business demands the utmost in safety performance while delivering projects within schedule and budget. Given these requisites, Redpath and TMCC (executed under the joint venture company, Associated Mining Construction or AMC), were taxed with developing the shaft sinking system to deliver this program in the safest and cost effective manner, with due regard to schedule and quality. Traditionally the potash shafts sunk in Saskatchewan involved a significant level of manual labour, owing to the methodology of excavation by means of chipping the frozen shaft sections with hand held pneumatic machines, and manually placing tubbing segments or steel liners of the shaft lining system. Most certainly, the AMC team wanted to make a step change from those earlier sinking programs and develop systems for sinking this potash shaft that removed the high level of manual work, thus making this project inherently safer, while endeavoring to sink more efficiently. With that in mind, the team embarked on a design program to improve its overall shaft sinking systems without the requirement for excessive capital and methodology flexibility to adapt to potential changing conditions expected to be encountered during shaft sinking. This was especially important should the new approach be met with less than expected success, and retrofitting of the system was required. The concepts were developed to provide for a much improved work environment, while easing the manual labour burden on the workers with innovative equipment and approach to the work."

Jan 1, 2019

By A. E. Cameron

The theory of atomic distribution of the stranger atoms in the space lattice of the solvent metal has been well developed by Rosenhain. It has long been known that the addition of one metal to another to form a solid solution increases the strength and hardness of the solvent metal. This increase is practically proportional to the amount of added substance up to the limit of solid solubility. To account for this increase in hardness and strength, Rosenhain assumes that the stranger atoms occupy positions on the solvent metal space lattice. Atomic attractions about the stranger atoms will not be the same as in the case of the pure metal, and there will thus be a disturbance of the orderly arrangement of the atoms on the space lattice, or a distortion of the lattice. Such a disturbance would interfere with the ease of slip along the planes and would thus tend to promote strength and hardness. Rosenhain notes that not only may there be a local disturbance of the lattice about the stranger atom but there may well be also a measurable change in the dimensions of the lattice as a whole. The relative amounts of local and general distortion of the lattice will depend upon the nature of the lattice itself. As Rosenhain says, "If the lattice is comparatively soft and flexible the distortion is likely to be largely local. In a stiff lattice, however, local distortion will be resisted and there will be a correspondingly increased general distortion."

Jan 1, 1927

By Farzad Mohammadi, David Kratochvil, Patrick Littlejohn

"With more rigorous regulations being enacted in the mining industry, a need exists for cost effective and environmentally compliant technologies to remove selenium from mine impacted waters to ultra-low concentrations. Existing selenium treatment methods have high life cycle costs, introduce risks of acute fish toxicity, and produce biological waste residues that represent future liabilities. Furthermore, achieving selenium discharge limits of less than 4 ppb is a challenge for existing technologies. Selen-IX™ is a technology developed by BioteQ that selectively removes selenium from mine impacted waters to less than 1 ppb. The technology is purely physico-chemical and takes advantage of the basic principles of ion exchange and electrochemistry. Unlike conventional electrocoagulation that removes suspended solids and breaks emulsions or oxidizes heavy metals, the electrochemical process employed by Selen-IX™ relies on creating conditions where iron acts as a highly effective reducing reagent transforming selenium from a dissolved species into elemental selenium bound in a solid phase. The iron-selenium by-product of Selen-IX™ is an inorganic, non-hazardous and chemically stable solid. Due to their high iron content, the solids produced by Selen-IX™ are of interest to the steel making industry as a low cost feedstock. This offtake potential can not only reduce the life cycle cost of selenium removal by reducing disposal costs but more importantly, eliminate the risk of future environmental liabilities. In this paper, the basics of Selen-IX™ technology are presented along with results of successful piloting on streams from coal and copper-gold deposits.INTRODUCTIONVarious contaminants are released into mining wastewater during the extraction and processing of metals. One such contaminant is selenium. A naturally occurring element found in rocks and minerals, mining activities accelerate its release into the environment. Selenium in trace quantities is essential to all life forms but at higher concentrations it can be harmful, especially to aquatic life where selenium bioaccumulation can lead to reproductive deficiencies."

Jan 1, 2016

By Michael S. Moats, Alex Luyima, Tomas Oliveira

Some commercial copper electrowinning facilities use Cyquest N-900 (a polyacrylamide) or HydroStar (a modified polysaccharide) to improve the density and smoothness of copper electrodeposits. However, the effects of these additives have not been studied extensively in the open literature. Thus, the electrodeposition of copper at 40 oC from a non-stirred synthetic electrowinning electrolyte (40 g/L Cu2+, 160 g/L H2SO4, and 20 mg/L Cl-) in the presence of various concentrations of either additive was evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). CV results show that neither additive has much effect on the nucleation overpotential of copper electrodeposition on stainless steel. However, Cyquest N-900 polarized the copper deposition reaction upon the return sweep. The EIS data indicates that Cyquest N-900 increases the reaction’s charge transfer resistance and creates a second low frequency loop. HydroStar had minimal effect on the electrochemical data generated by CV or EIS. Thus, the mechanism by which HydroStar affects the copper deposition reaction still needs to be determined.

Jan 1, 2014