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By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By D. A. Pirttinen

The promotion of improved coal quality for thermal generation can benefit our national economy. The construction of electric generating facilities in Canada is expanding at a rapid rate to satisfy the demands of a rising population and new uses for electrical energy. With remaining economic water power resources in the process of development, generation from thermal sources continues to grow. The increase in thermal capability has been somewhat arrested by a de-pressed economy, widening of inter-provincial and state transmission networks and decisions to exploit certain water resources before high capital investment is further in-creased by rising construction costs. The introduction of extra high volt-age transmission lines will further delay thermal generation planning, but in due course, when the effects of restrictive factors have been dissipated, steam-electric generation from fossil fuels will rise to considerable proportions. In time, nuclear sources will contribute a growing share to thermal power, but, it is doubtful if nuclear participation will ever displace conventional fuels for steam rising, unless it can be adapted to operate efficiently for variable outputs in peaking service. It appears certain that fossil fueled

Jan 1, 1961

By S. Nafisi

Permanent mould casting may be regarded as a near net shape manufacturing process where simple to very complex shaped engineering components are fabricated with high degree of precision in a metallic mould, In this group, High Pressure Die Casting (HPDC), have attracted more attention because of its production rate, where both liquid and semisolid metals (SSM) can be cast with high degree of precision and versatility. The SEED process, Swirled Enthalpy Equilibration Device, the new process for semi solid metals slurry production route, consists of two steps: The initial step involves extracting specified amount of heat from the molten metal to generate liquid-solid slurry, i.e, mushy structure, followed by drainage of remaining liquid to produce a compact free standing feedstock for rheocasting operation. In this paper, microstructural evolution during the process and some initial casting results of automotive components an also reported.

Jan 1, 2005

By D. O. Tansey

This paper will describe the mechanisms involved in delay blasting and how they are applied with the use of D.S.B. It will examine the control of potential damage resulting from detonations, and show how good fragmentation and efficient recovery of this material blasted can be achieved.

Jan 1, 1979

By D. M. Ramsey

HIGH-INTENSITY magnetic separation as now practised in the commercial treatment of a large variety of industrial minerals is a com-paratively recent development, having had its practical beginning about ten years ago when it became necessary to devise more effective methods for the purification of the electric furnace abrasives and refractories-silicon carbide and fused aluminium oxide. The fundamentals of magnetic separation are, of course, very well under-stood; bur while very, very old in principle, the process has, in recent years, been developed to a point of far greater usefulness than heretofore. In fact, until the development of the high-intensity process,. magnetic separation was limited largely to the removal of tramp iron? with magnetic pulleys and the removal of the very highly magnetic portions of industrial minerals by means of horizontal conveyor-belt-type separators. All magnetic separation processes depend for their success on the fact that various materials are kinetically influenced to a greater or lesser degree by the force that we speak of as 'magnetism'. We have now come to regard 'magnetic separation' and 'high-intensity magnetic separation' as two different and distinct methods. However, both depend upon the reaction of a particle when placed in a magnetic field. The common types of magnetic separators quite generally operate on the principle that a magnetic particle can be lifted by a powerful magnetic force from a stream of material moving on a belt or other type of conveyor. The application of the force removing magnetic material by this scheme is directly opposed to the force of gravity and is, therefore, limited to sub-stances of a relatively high order of magnetic susceptibility, such as metallic iron and magnetite. Until a few years ago, one very important principle was almost entirely overlooked. Practically every substance is susceptible to some extent, at least, to magnetic attraction, and by the application of a magnetic force great enough, and properly applied, separations of materials heretofore considered 'non-magnetic' can be accomplished.

Jan 1, 1937

By Elbasher M. E. Ahmed, Indresan Govender

"A mechanistic model of axial charge segregation in rotating drums is presented. We show that granular material composed of different frictional properties diffuse into axial bands as a consequence of concentration fluctuations in the free surface layer that is caused by friction-limited mobility. A Bagnoldian stress assumption ensures an asymmetric free surface profile thereby providing the essential ingredients for the evolution of axial bands and the subsequent band coarsening observed in the literature. The formulation is sensitive to the boundary conditions of tumbling mills, including particle size and density, mill speed, inter-particle bulk friction, end wall friction and drum geometry (length and diameter).INTRODUCTIONA mechanism to fully describe the axial segregation of charge in a rotating drum remains elusive to the mineral processing industry. With regard to low aspect ratio mills (like ball mills), current thinking favours the use of closed circuit mills with correspondingly low residence times to offset the completely random contact probabilities between particles and balls (Wills & Napier-Munn, 2006). Conical end caps are argued to exploit the centrifugal force to achieve a regular gradation of ball size along the mill with larger sizes at the feed end and smaller ones closer to the discharge. However; segregation along the length has been observed in the absence of conical end caps (Oyama, 1939; Levine, 1999): In these investigations, sufficient differences in the particle’s mechanical properties (particle size, density, shape, surface roughness) was enough to successfully achieve axial segregation. Figure 1 shows the segregation of a bimodal distribution (by size) into bands of larger (darker colour) and smaller (lighter colour) particles."

Jan 1, 2016

By J. A. Vonhof, R. O. van Everdingen

Since 1949, a total of 59 disposal wells have been installed in Canada to inject liquid wastes from refineries, mining operations and chemical plants into subsurface formations at an ever-increasing rate. Well depths range from around 600 feet to almost 5,500 feet; injection rates range from 0.5 (U.S.) gpm to more than 1,000 gpm for individual wells; wellhead injection pressures range from a slight vacuum to over 500 psi. Apart from strictly technical considerations of well design, the geological, hydrodynamic and hydrochemical conditions at the disposal site have a strong bearing on the safety and success of such operations. Prevailing hydrogeological conditions in large portions of the country do not allow safe subsurface disposal.

Jan 1, 1973

By K. Lascelles

ABSTRACT Nickel compounds vary significantly in their toxicological properties, so it is critical that continuing studies to accurately quantify worker exposures consider the processing that accompanies refining nickel-containing materials. The Clydach nickel refinery, which has operated for more than 100 years, was the first nickel-producing facility to show a high risk for lung and nasal-sinus cancers among workers employed since it opened in 1902. Process chemistry and equipment have changed dramatically over Clydach’s history. This paper describes the processing evolution at Clydach with a focus on the propensity for aerosol formation and the forms of nickel in airborne dusts.

Jan 1, 2013

By T. D. Chatwin

Acid rock drainage (ARD) is one of the most serious and potentially enduring environmental problems of the mining industry. High liability costs carried by many mining companies to cover potential obligations of ARD are a clear indication of the gravity of the problem. Unchecked, ARD can result in water quality impacts that could well be the industry's most significant financial and credibility risk. Effectively preventing acid drainage is a formidable challenge that requires the total commitment of the mining industry throughout the entire life-cycle of a mine. To achieve this commitment a strong business case for ARD prevention must be developed. This paper will address the elements of acid prevention and discuss their importance not only to the company but the entire industry as well. The International Network for Acid Prevention (INAP) is an industry-led group created to help meet this challenge. In 2009, INAP published the GARD Guide (www.gardguide.com), a web-base best practices guide for the prevention of ARD [1]. In this paper, the GARD Guide will be used to identify preventative actions for all mining industry stakeholders. It will, in turn, be used to estimate ARD management and mitigation value accrued to the company from ARD prevention, which will be used in developing a business case for acid prevention.

Jan 1, 2011

By M. F. Goudge

This paper is intended to call attention to the manifold uses of limestone in industry; to indicate the types of limestone desired by some of the large consuming industries; and to give some information on the resources of limestone in Canada, so that an idea may be obtained of the present and future possibilities for limestone production. The word limestone is used in the usual broad sense to include both high-calcium limestone and the highly magnesian variety known as dolomite, as well as all intermediate types. Lime is simply calcined limestone, and in this general paper its uses have been included with those of raw limestone. It is of interest, in dealing with this subject, to glance back over the early history of the utilization of limestone, for by so doing we see that limestone has been of importance to mankind since the beginning of civilization and has contributed in no small measure to the development of a number of the arts and sciences. One of the first uses, if not the first use, of limestone was in connection with the making of lime for plastering purposes. This use antedates civilization. In the day of the ancient Greeks and Romans, the art of plastering had been brought to a state of perfection that is not nearly approached by the modern artisan.

Jan 1, 1930

By Chr. Krause

Within the scope the collaborative research centre 599 (Medical University of Hanover, University of Veterinary Medicine Hanover, University of Hanover) the behaviour of the degradation of magnesium materials as implants are investigated by using animal experiments (rabbits). Thus extruded cylindrical pins from the magnesium alloys MgCa0.8%, WE43 and LAE 442 were implanted intramedullary in the tibiadiaphyses. The implantation duration was 3 and 6 month. After the explantation 3 point bending tests were carried out to investigate the possible changes of the mechanical properties. Clearly changes in dependence of the implantation duration could be determined. The three magnesium alloys show a decrease of the mechanical resistance with an increasing implantation time. To evaluate the degradation process, wich is the reason for the changes, micrographs and element analyses (EDX) have been accomplished after the 3 point bending tests. The micrographs show for all used magnesium alloys corroded surfaces but no preferred corrosion on the grain boundarys. The element analyses show beside a layer which is rich in calcium and phosphorus an agglomeration of rare earth elements in this layer. With these results a using of magnesium alloys as a material for implants can be announced.

Jan 1, 2006

By T. R. Stanley

Introduction The purpose of this paper is to interest mining men in the economic possibilities of sand deposits suitable for modern foundry work. Many members of the profession are constantly travelling over the country and it is felt that some knowledge of the necessary properties of foundry sands will enable these men t0 recognize such deposits. It is the experience of the writer that good sands suitable for the varied work of a foundry, such as that of the Consolidated Mining and Smelting Company, at Trail, are almost impossible to obtain from western Canadian sources. It is hoped that the following discussion may arouse some interest in the search for such sands. Sands are used in foundries for two purposes. The main use is for making moulds suitable for receiving hot metal. The mould must retain the? required shape until the metal has solidified. The second use of sand in the foundry is as an abrasive in sand blasting. This is a relatively minor use, and consequently will not be dealt with in detail. Any coarse sand with a high content of quartz will serve this purpose, but round-grained sands are superior to angular types, because they have not the same tendency to shatter on impact with the casting. Sand plays an extremely important part in the successful production of sound castings. This is more evident today than ever before, due to the greater variety of castings and alloys, each of which requires special sand characteristics. Poor sand is responsible for a great many foundry troubles which formerly were attributed to bad? metal; in fact, one investigator goes so far as to say that ninety per cent of bad castings can be traced directly to the sand. Very little of the vast amount of sand distributed over the earth's surface is suitable for moulding. It is the purpose of this paper to describe briefly the properties which are essential in good moulding sand. Sand for this work must be able to withstand the wash and hydrostatic pressure of molten metal, and yet be sufficiently porous to allow the gases generated in the mould to escape.

Jan 1, 1935

By F. W. Gray

Ideal utilization of the heat energy in coal should theoretically be secured by supplying each atom of combustible material present with the exact quantity of oxygen necessary for complete combination. An intimate and equal admixture of the fuel particles with air is therefore to be sought. Coal, or the combustible substances of which coal is composed, may be used in solid or liquid or gaseous form. The use of coal in small particles intimately mixed with air is, in effect, a specification of coal in pulverized or dust form. There has been much important development of this manner of using coal, which may be instanced as the outstanding advance in the use of coal as a solid. The completeness and efficiency of combustion in a properly designed dust-fired furnace permits the use of locally available coals of inferior quality, and enables them to be used commercially instead of imported coals of better quality. That is to say, some grades of coal of low calorific value, that are not economically useable in lump form on grates, are useable in pulverised form, because of the more complete combustion thereby obtained, and the consequent more efficient results. In the case of coals that are unsuitable for steam-raising in grate-fired furnaces, because of clinker troubles, (arising usually from a combination of high sulphur content and low-temperature fusibility of the ash content) use in pulverised form has obvious advantages, and in addition gives the benefit of any heat units that are contributed by free sulphur in the coal.

Jan 1, 1924

By F. Habashi

Lead is an ancient metal, has been produced to-date from its ores exclusively by pyrometallurgical route. The process suffers from high operating cost and excessive pollution problems. Extensive research has been going on since the beginning of the twentieth century to find a non-polluting process for its production and a solution for its complex refining scheme. It has been assumed correctly that the hydrometallurgical route should be the most promising. Pilot plants have been constructed and operated for a reasonable periods, but no process has proved to be satisfactory. As a result, a number of smelters and refineries have been shut down. The present review analyses the situation and suggests that the best route to treat lead sulfide concentrates is by leaching with fluoroboric acid, HBF4, containing ferric fluoroborate, Fe(BF4)3, and electrolyzing the solution in a diaphragm cell - - a process recently invented by Italian metallurgists. In this process, any silver present in the concentrate remains in the residue together with elemental sulfur and can be recovered by known methods.

Jan 1, 2008

By L. A. Anestiev

A method based on use of calorimetric data for the determination of solidification kinetic parameters is proposed. The method incorporates recent theories of nucleation and growth and allows modeling heat fluxes observed in calorimetric experiment. Statistically optimal estimations of the kinetic parameters, which include the activation's energies of nucleation and growth, are derived from experimental data by means of nonlinear regression analysis. The method is applicable to pure substances and alloys. The evaluation of the kinetic parameters characterizing solidification of pure Al is used for clarifying and exemplifying the method.

Jan 1, 2004

By J. R. Shouldice

"IntroductionREEFS of Silurian age are recognized in southwestern Ontario, both in outcrop and from subsurface information. This paper deals with the so-called 'pinnacle' reefs which are known only in the subsurface. For the purpose of this paper, the pinnacle reefs are arbitrarily defined as those structures having a height of over 250 feet and a length of less than two miles. This definition eliminates numerous mounds and other broader, more subdued, structures of less certain origin, found in subsurface beds.The term 'pinnacle reef' is perhaps unfortunate, but it is in common usage in Ontario and is used elsewhere for different types of reefs. A new name is justified by the unusual environment and structure of the Ontario reefs, but it is unlikely that any other term would gain acceptance. Rather than propose a new term which would be ignored or result in further confusion and misuse, the name 'pinnacle', as defined above, is used in this paper.Pinnacle reefs have been found over a fairly large part of southwestern Ontario. The known reefs of this type parallel the southeast edge of lake Huron and •follow the strike of the structure contours which circle the Michigan basin (see Figure 1). In total, twenty-five such reefs have been discovered in southwestern Ontario."

Jan 1, 1955

By Kuwauchi. Y., M. Barati

Recycling of dust using a rotary hearth furnace (RHF) has gained considerable attention in the past two decades for the sustainable production of steel with less environmental impact. In order to further promote the recycling of electric arc furnace dust and carbonaceous wastes using the RHF process, a mathematical model was developed to predict the reaction behaviour of dust-reductant composites. The reduction kinetics of zinc and iron oxides as well as the volatilization behaviour of volatile matter in the reluctant were considered. The modeling approach and some preliminary results are presented in this article.

Jan 1, 2011

By F. T. M. White, W. A. Bardswick

"The parameters of airborne minerallic particulates which create industrial dustiness, together with the physiological hazards caused by their inhalation, are reviewed. Various techniques of dust sampling are discussed and analysed, and the parameters referred to above are classified as the basis for methods of assessing the physical, chemical and mineralogical characteristics of dust-particle suspensions. The paper surveys those methods of assessment currently accepted by various statutory authorities, and reviews other methods that warrant attention and newer techniques that are being developed."

Jan 1, 1969

By R. Noorani, M. Cai

"Excavation of deep underground openings in highly stressed grounds can generate new fractures near the openings. As a result, rock mass bulking may occur, leading to large wall deformation. A better understanding of brittle rock failure and the associated fracturing process at the laboratory scale is an essential step towards evaluating dilation behavior of rocks. A grain-based model that can capture dilation behavior of rocks under various loading conditions at the laboratory scale can be a useful approach to study rock mass bulking at the field scale. The aim of the paper is to study the dilation behavior of rocks at the laboratory scale employing numerical simulation. A modified grain-based model is used to simulate the macroscopic response of crystalline rocks by considering micro-fractures at the grain scale. Grains generated with the Voronoi tessellation are allowed to fail in tension or in shear using a strain-softening model. Damage is represented by either grain boundary fracture or grain failure, or the combination of the two. As stress increases, the process of damage, fracture initiation and coalescence in rocks can be captured.The grain-based model was calibrated using test data of the Lac du Bonnet granite and a parametric study was conducted. Numerical simulation results showed that the proposed modeling approach is able to capture most of the mechanical properties, fracture pattern, and dilation behavior in both unconfined and confined loading conditions. In an unconfined compression test, interactions of microscopic fractures may lead to macroscopic shear or axial splitting failure depending on the chosen micromechanical parameters. Numerical experimental results show that the dilation behavior of the model is strongly related to the failure mechanism of rocks. Tensile-failure-dominated failure mode generates large dilation due to the formation of new cracks that are sub-parallel to the loading direction. On the other hand, shear-failure-dominated failure mode produces small volume increase. One significant finding from this study is that in order to capture large dilation using grain-based UDEC models, intragranular grain failure should be considered."

Jan 1, 2015

By L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes (Venkataramani, 2002). Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid startup and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate (Heberlein et al., 2007). Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates.Industrial plasmas can be broadly classified as thermal plasmas and non thermal plasmas. Thermal plasmas are atmospheric pressure plasmas characterized by local thermodynamic equilibrium (Boulos et al., 1994). Thermal plasmas are typically established between any two current conducting electrodes separated by an insulator. A plasma forming gas is blown between the two conducting electrodes resulting in a high temperature plasma plume. A plasma torch generates and maintains an electrically conducting gas column between the two electrodes; a cathode (negative electrode) and an anode (positive electrode) (Camacho, 1988). If both electrodes are housed in a single housing, resulting in an arc enclosed inside the plasma torch, then such plasma generating torches are termed as non-transferred (NT) plasma torches, whereas, if the second electrode is external to the torch, creating an arc transferred between the cathode and the working piece, then such plasma torches are termed as transferred (T) plasma torches. Depending on the source of the electricity which can be either direct current (DC), alternating current (AC) at main network frequency or at radio frequency (RF), the plasma torches are classified as DC, AC or RF plasma torches (Venkataramani, 2002)."

Jan 1, 2012