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By E. Johansson, T. Siren, K. Kemppainen

"As part of the preparations for the design of an underground repository for radioactive waste at Posiva’s Olkiluoto site on the west coast of Finland, there has been considerable site investigation work. Except the extensive surface based investigations, Posiva started in 2004 the construction of an underground characterisation facility termed the ‘ONKALO’. The ONKALO has now been completely excavated to the anticipated repository depth i.e. -430–450 m. The research conducted in the ONKALO gives further information on the bedrock and groundwater conditions of the final disposal site, as well as on the impact of the construction. The ONKALO provides an excellent opportunity to investigate the rock at tunnel scale, to conduct in-situ testing in rock, to develop excavation and final disposal techniques in realistic conditions. The ONKALO has aided in collecting the data needed, supported by a Preliminary Safety Assessment, for the application of the construction license that was submitted in the end of 2012. The target is to begin disposal operations in 2022. According to current plans, the final disposal would end in 2112 and the repository would be sealed up by 2120. The testing in the ONKALO still continues several years. This paper presents the current characterisation and research activities in the ONKALO. INTRODUCTIONAfter the Finnish Government's favourable policy decision in 2001, Posiva Oy, which is an expert organisation responsible for the final disposal of spent nuclear fuel of the owners in Finland, has focused further investigations at the Olkiluoto site, western Finland (Figure 1) and has started in 2004 the construction of an underground facility termed the ‘ONKALO’. The ONKALO is not a nuclear waste repository, but more than just an underground research laboratory URL – it is an underground rock characterisation facility. The ONKALO has now been completely excavated to the anticipated repository depth i.e. -430–450 m. In addition to facilitating bedrock research, the ONKALO also provides an opportunity to develop excavation techniques and final disposal techniques in realistic conditions. Later, the ONKALO facilities can be put into use when building and using the repository. The construction methods and materials have been selected in order not to jeopardise the long-term safety of the repository site. The findings of the ONKALO and other investigations will provide the knowledge needed for an application, supported by a Preliminary Safety Assessment, to construct a final repository for spent nuclear fuel at the site. Posiva has submitted an application for the construction licence for a disposal facility in the end of 2012. The target is to begin disposal operations in 2022 and the repository would be sealed up by 2120."

Jan 1, 2015

By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978

By Xiaowen (Wendy) Ma, Hans Liang, Xiaoying Chen, David Way

"The mineralogical characteristics of the process streams provide key indicators to the potential improvement in the metallurgical performance. Therefore, the process mineralogy and diagnostic metallurgy have been widely used as a tool to assist the metallurgists at the operating plants. The challenge of this study was then how to characterize the diagnostic flowsheet of the minerals of interest in the process streams across the flotation circuit. The investigation from this study indicates that the minerals chematic flowsheet can visibly demonstrate the sources that caused the gold losses during the mineral processing.In this paper, we present studies of the flotation process stream samples, representing the feeds, intermediate products, final concentrate and final tails, which were produced from the flotation concentrators of Mt Carlton mine in Queensland, Australia. This study was focused on characterizing the process streams and learns how the gold in the process streams was associated with other sulphide minerals and host minerals on a size by size basis. The automatic QEMSCAN/MLA Particle Mineral Analysis (PMA) and Trace Mineral Search (TMS) were applied to identify the minerals and to detect the gold in the sized fractions of process streams. The Laser Ablation ICP-MS (LA) spot analysis, QEMSCAN EDS spot analysis and electron microprobe spot analysis were employed to identify and quantify there fractory gold concentrations in the sulphide minerals, like pyrite, and the elemental concentrations of visible gold grains. The diagnostic flowsheet of gold recoveries by the process streams, by mineral association classes and by the particle sizes were generated and discussed."

Jan 1, 2017

By Mingxia Liu, Hao Li, Qi Liu

"Laboratory batch flotation tests were carried out on fine (-20 µm) hematite to investigate the non-polar oil’s influences when sodium oleate, octyl hydroxamic acid, or oleyl hydroxamic acid were used as a collector. Batch flotation tests were performed with artificial mixed minerals (hematite:quartz = 1:1) under natural pH condition and kerosene was utilized as the model oil. The experimental results showed that kerosene emulsion behaved differently when used in conjunction with the three collectors. Kerosene helped improve the flotation when sodium oleate or oleyl hydroxamic acid was used as a collector. Nevertheless, it reduced concentrate weight yield, grade and recovery to a noticeable extent when octyl hydroxamic acid was used as a collector, especially at low dosages. In addition, single hematite batch flotation kinetics tests coupled with water recovery measurement were carried out to study the role of kerosene at different collector dosages. It was observed that water drainage and the resulting froth destabilization by kerosene was dominant at low collector dosages, especially in the flotation using octyl hydroxamic acid. At higher collector dosages, the water drainage and froth destabilization effect by kerosene was possibly counter-balanced by the higher hematite hydrophobicity and bubble surface tension gradient, which led to more stable froth layer.INTRODUCTION The minerals industry is facing a steady decline in ore grade, compounded by increasing complexity of mineral dissemination. As a result, the ore has to be ground sufficiently fine to have a suitable degree of mineral liberation, which produces large percentages of fine and ultrafine particles outside of optimal size range for ore dressing. Due to the unique characteristics of fine particles, i.e., small mass, high specific surface area, and problems such as increased solubility of complex minerals (Finkelstein, 1997; Finkelstein & Allison, 1976; Fornasiero & Ralston, 2005), high reagent consumption, fast surface oxidation in the case of sulfides (Collins & Read, 1971; Klassen & Mokrousov, 1963), severe particle entrainment (Subrahmanyam & Forssberg, 1988; Warren, 1984), low flotation rates (Glembotsky, 1953; Philippoff, 1952; Ye & Miller, 1988), slime coating (T. K. Mitchell et al., 2005; Parsonage, 1984), etc., flotation performance of these finely ground ores is very poor in terms of low concentrate grade and recovery."

Jan 1, 2017

By Norman R. Ball

"Many people in the mining and metallurgical industries were brought up to embrace Henry Ford's pronouncement that ""History is bunk"" but it is not generally known that the same Henry Ford created and paid for one of the finest technological museums in the Western World. I am aware that many people feel that industry history is something you ask aging executives to do or that history is a clip-andpaste compendium of pictures re-discovered every 25 years or on the occasion of issuing a press release on plant expansion. Moreover, there are many who fear historians as somewhat deranged individuals interested only in corruption, injustice and sensational labour strife. Good history lies somewhere between the controlled P.R. handout and the hysterical attack. Writing good history is a difficult creative act based on the application of experience, insight, wide knowledge and careful reasoning to available evidence. To date, the Canadian mining and metallurgical industries have achieved a great deal but left too little evidence and it is this lack of evidence which must be corrected before it is too late. It is the purpose of this article to stimulate thoughts with regard to archives, one of the more important vehicles for the preservation of such evidence."

Jan 1, 1999

By R. R. Bassermann

THE property of Howey Gold Mines, Limited is situated at Red Lake, Ontario, one hundred and seventy-five miles east of Winnipeg and eighty miles north of the Canadian National Railway line. The mine has been a continuous producer since April, 1930, and at present is hoisting 1,350 tons of ore per day. The shaft consists of three compartments (see Figure 1, sketch B). Hoisting is done by two skips in balance, one of which is interchangeable with a cage. Sinking had been carried out at three different periods. From the surface to the 550-foot level, the sets had been spaced at seven-foot intervals, from the 550-to the 1,060-foot level at six feet, and from the 1,060-to the 1,500-foot level at five feet. During the five years of operation, the shaft had become so badly worn, due to spill from the tipples and, to a certain extent, from the loading pockets, that re-timbering was considered necessary. It should be explained that no crushing is done underground because of the ad verse effect this would have on the efficiency of the sorting. The grizzly rail clearance above the ore pockets is fourteen inches and consequently the ore hoisted is extremely coarse. More than average spill from the loading pockets and tipples under such conditions is inevitable, and it is debatable whether underground crushing with consequent increased sorting costs would not be justified. The cost of complete re-timbering according to standard practice would have been prohibitive both directly and indirectly: A lengthy shut-down of the shaft, with the consequent disorganization of the staff and workmen, could not be considered. Accordingly, it became necessary to devise some method of repair that could be carried to completion in a very limited period of time. The shaft timber for the first 250 feet was not in need of repair. From the 250-foot to the 1,060-foot level the wall plates, posts, and blocking were in good condition. These had been protected by a one-inch plank lining put in at various periods during the past three years without interfering with hoisting operations. The end plates and dividers, however, could not be protected in this manner because of the lack of skip clearance. It was decided that, if the dividers in this section could be replaced, the shaft would be as satisfactory as if completely re-timbered. Several factors had to be taken into consideration in deciding on a suit-able method of repair. In the first place, the tipple plates had to be re-designed. To complete the job in a reasonable time, not only had work to be done on the tipple, but simultaneously from several points in the shaft itself. Since all power cables, pipe lines, etc., were in the manway compartment of the shaft, this compartment had to be left undisturbed.

Jan 1, 1935

"Conveyed coal flows have been diverted on the basis of real time ash analysis since the 1980s. Many coarse particle separation methods are available through screens, jigs, heavy media separation, particle sorters, to name a few, however bulk diversion requires a representative, continuous analysis to ensure diversion decisions can be made with confidence. Sensors also need to be able to provide measurements at useful time increments so that small tonnages can be diverted for maximum selectivity. Particle separation typically requires high capital costs and there are limitations either in throughput tonnage or particle size or both. Few techniques are able to provide robust and representative analysis of conveyed flows in a useful time basis. Prompt Gamma Neutron Activation Analysis provides multi-elemental analysis of conveyed bulk materials and has been proven in the minerals industry since 2003. This paper outlines the success of this technology in minerals applications in iron ore, phosphate rock and most recently in copper-gold ores, including its use in bulk diversion.INTRODUCTION Naturally occurring quality variability, or heterogeneity, in mineral deposits enables separation and recovery of the valuable components through mining and processing operations. There are distinct advantages in processing the minimum quantity of material to achieve the highest possible yield. Unfortunately, declining ore grades has resulted in larger scale operations and a subsequent loss in selectivity for mining operations. As limits are approached on the practical size of equipment, there is more motivation to investigate alternative solutions. Mining companies are subject to increasing social resistance to growing waste disposal requirements in addition to higher energy and transport costs. Major savings are available by reducing the quantities of material processed where pre-concentration can be effectively applied at early stages in the process. One of the simplest ways to pre-concentrate is to measure the bulk material and reject waste soon after mining so that minimal expense is incurred and that only higher quality material is sent to processing operations. This bulk sorting can occur within the mining operations and has major benefits through energy and other consumables savings. This paper discusses the application of real time analysis technologies suitable for bulk sorting within the minerals industry. Technology that has proven representative for conveyed material bulk analysis and its successful applications to date is explained. Analysis using a sensing technique is only one component of a successful bulk sorting process; the importance of effective diversion systems and a bulk sorting strategy are also discussed. The bulk sorting stage may be one component of a system that could include additional downstream technologies such as particle based sorting systems on a diverted stream."

Jan 1, 2018

By L. Xia, B. Hart, G. Gingras, M. Furlotte

Plant and laboratory test work was performed in order to optimize a copper/zinc flotation separation circuit at Matagami concentrator, Canada. The testing identified a significant difference between the laboratory testing and the plant flotation, particularly for the sphalerite recovery in the rougher copper concentrate. Tests indicate that sphalerite recovery of the flotation concentrate in the laboratory testing was significantly higher than in the plant. The ToF-SIMS surface analysis identifies surface species responsible for the discrepancy in Zn recovery. It shows that sphalerite flotation is in response to the collector attachment and a significant enrichment of Cu on the surface of sphalerite grains. A comparative surface chemical analysis was performed on both sphalerite and chalcopyrite grains from the plant flotation and laboratory testing in order to identify surface species variability between the two testing. Two significant observations were revealed. First, there is considerably more hydrophilic iron oxyhydroxide on sphalerite surface from the plant flotation sample relative to those from the lab testing. The secondary coating likely completely or partially passivates sphalerite surfaces, reducing Cu enrichment and hence sphalerite floatability. Secondly, comparing the surface chemistry on sphalerite and chalcopyrite, the hydrophilic iron oxyhydroxide species have preference for the sphalerite grains relative to chalcopyrite. Despite numerous studies on the effect of galvanic coupling during grinding, there is limited documented evidence on the effect of the milling environment on the flotation and plant operations. This observation suggests that interaction between sulphide minerals and grinding media have a significant influence on subsequent flotation. This paper discusses the results of a detailed surface chemical evaluation of sphalerite grains from both the plant and laboratory testing in the context of grinding environments and pulp chemistry.

Jan 1, 2016

By J. T. Kalala

The High Pressure Grinding Roll (HPGR) is gaining acceptance in the mineral processing industry and has become a competitive technology in reducing the specific energy consumption in Mineral processing plants. The amount of samples required for HPGR amenability testwork and HPGR wear tests is usually high and often cannot be available at early stage of projects were only a few drill cores are available. Although HPGR was initiated from small scale piston die compression tests, the development of small scale piston die test to predict the performance of HPGR has been slow. The objectives of this paper was to present the designs, operating procedure of piston-die press and operating conditions which have resulted in similar particle size distribution obtained from a piston die test and HPGR Labwal unit starting from the same feed size distribution. Testwork were conducted using a 2 MN piston-die press and a Labwal HPGR unit on major South African ore types, viz, gold, platinum and iron ores. The results obtained show that piston-die test can generate data to predict energy consumption, product size distribution, and even to evaluate the edge effect.

Jan 1, 2012

By F. Awotwe-Appiah, P. Koshy, J. Dankwah, J. R. Dankwah

This research investigates the generation of an effective carbonaceous material from waste ‘pure water sachets’ and their subsequent utilisation as reductants for the reduction of the Opon Mansi iron ore. Composite pellets of Opon Mansi iron ore and pulverised carbonaceous material generated from waste pure water sachets were heated from room temperature to 1200 °C in a gas fired furnace for seventy minutes. The reduced pellet was analysed chemically for its oxygen and carbon content using a LECO Oxygen/Nitrogen and LECO Carbon/Sulphur analysers, respectively. It was observed that nuggets of metallic iron were readily produced with the carbonaceous materials acting as an effective reductant and source of chemical energy. XRD analysis of waste ‘pure water sachets’ revealed that the polymer was semi-crystalline with peaks that were identical to those of high density polyethylene (HDPE). Gas emission behaviour of the iron ore-PWS pellet was studied in a horizontal tube furnace at 1200 °C using an infrared gas analyser; the results revealed an exhaust gas rich in the reducing gases CO and CH4 along with CO2.

Jan 1, 2015

By W. G. Stevenson

With the author's background of extensive experience, this paper delineates the role of the prospector in modern-day exploration programs. The stages in the development of a prospect to a producing mineral district are outlined, and examples are given from the Ross River area of the Yukon Territory and the Peachland and Highland Valley areas of British Columbia.

Jan 1, 1970

By D. E. Deegan, P. M. Keeley, N. A. Rowson, T. Stachowski

An investigation into the use of Tetronics International’s thermal plasma technology based pyrometallurgical smelting process for the recovery of both platinum and rhenium was conducted. 1000 kg of Pt-Re catalysts containing 0.36 wt% Pt and 0.21 wt% Re was blended with fluxing agents, reducing agents and an iron based collector metal precursor and then fed into a plasma furnace over five individual trials at Tetronics International’s facility in Swindon, UK. Both platinum and rhenium partitioned to an iron rich collector metal phase in the furnace, which formed in-situ and accumulated beneath a less dense slag phase, derived from the inorganic substrate of the catalyst, and was easily separable. The levels of Pt and Re concentration achieved in the iron collector made it suitable for subsequent final refining. Technical recovery efficiencies of =98% for both platinum and rhenium were achieved and the concentrations of the metals in the recovered metal bullion were 2.23 wt% Pt and 1.35 wt% Re.

Jan 1, 2015

"The Cooperative Research Centre for Mining Technology and Equipment (CMTE) is funded by the Commonwealth Government, by its mining research members — the Universities of Queensland and Sydney and the CSIRO1, and by its industry members — BHP Coal, RioTinto R&TD, Hamersley Iron, Mining Technologies Australia, Pasminco, Shell Coal, WMC Resources, Advanced Mining Technologies, and Aberfoyle. The Centre conducts work aimed at improving the competitiveness of the Australian mining industry. The current work is focused in four areas: new mining and drilling systems, geological sensing, automation, and equipment maintenance and reliability. This paper describes much of the work in these program areas that relates to metalliferous mining. Mechanized Rock ExcavationThe disadvantages of the drill-and-blast excavation method are widely recognized and the last half of the 20th century has seen mining companies and mining research organizations aggressively pursue technology to excavate rock by other means. As discussed below, despite considerable effort and large amounts of funding, the quest for mining’s “Holy Grail” has been unsuccessful in all but the weakest rock types.COMRO (the Chamber of Mines Research Organisation) supported by the South African gold mining industry, spent three decades and (probably) tens of millions of dollars developing prototype drag bits and, later, impact breaking machines aimed at the mechanized stoping of narrow, tabular reefs. This work has not yet produced a commercially-attractive mining system. Work continues in South Africa to mechanize these stoping operations although now the emphasis is on the use of diamond-wire sawing techniques. This work remains in the experimental phase.Both British Coal and Germany’s Bergbau- Forschung spent many years developing techniques trying to extend the range of rock types which roadheaders could cut economically. Again, although new knowledge was produced, it is difficult to claim that any new commercial mining systems emerged from this work."

Jan 1, 2001

By David A. Edgecombre

This paper discusses modern practices in the extrusion of steel. Particular emphasis is given to a description of the Ugine Sejournet method of extrusion, involving the use of glass as a hot work lubricant. Other methods are also mentioned. A brief history of extrusion is presented; present practices in the quality extrusion of tubing and solids are described; and the future potentials of the) process as a tonnage producer are briefly discussed. The advantages of extrusion and the reasons for the use of a glass lubricant, as well as the various methods of using glass, are given. The process, as described, is being used in the manufacture of large commercial quantities of stainless steel tubing and sections. This extrusion process is an essential and unique means of forming such atomic-age materials as titanium, zirconium, molybdenum and other super alloys all of which are materials required in the creation of nuclear installations.

Jan 1, 1963

By Harry Jomini

Introduction The Wakefield plant of the Aluminum Company of Canada, Limited - a member of the Aluminum, Limited, group of companies - produces magnesia, magnesia fertilizer ingredient, and hydrated lime, from brucitic limestone. Wakefield is on the Gatineau river in Wakefield township, Quebec, some 22 miles north of Ottawa. The plant is near the western bank of the river adjacent to the Ottawa-Maniwaki highway and branch line of the Canadian Pacific railway. The plant is unique in the sense that it is the only place in Canada where brucite is processed. It is also distinguished for its outstanding safety record, as not a single lost-time accident occurred during either 1948 or 1949. The plant is amply provided with safety and comfort provisions in keeping with the standard practice in all of the twelve plants operated in Canada by Alcan and its associated companies. History Following the identification of brucite in the Rutherglen and Bryson districts in Ontario, occurrences of the mineral were discovered in the Wakefield area, Quebec, in 1939. After exploratory work on these deposits and investigation by the Bureau of Mines, Ottawa, on a method of extracting the brucite from the ore, a plant for treating the ore from the Maxwell property was built in 1941 by the Aluminum Company of Canada and commenced operations in early 1942. The process used is more or less in accordance with the method worked out by Mr. M. F. Goudge of the Bureau of Mines.

Jan 1, 1950

By T. J. Wells

THE blast furnace is the base of the steel industry, since there is no commercially practical way of converting iron ore directly into steel. In three hundred years, the blast furnace has developed from a small unit using charcoal as fuel and producing about one ton of iron in twenty-four hours to a furnace making upwards of 1,500 tons a day. The principle of the blast furnace is briefly this: A descending column of stock, consisting of ore, fuel, and flux, is met by an ascending stream of gases, consisting in part of gases formed by the combustion of the fuel and in part of pre-heated air which is blown into the lower part of the furnace. The flux combines with the impurities in the ore and the ash in the fuel to form slag, which is drawn off as liquid.

Jan 1, 1943

In April, 1961, a large pillar was removed by blasthole mining methods at Inco's Murray mine. More than half a million pounds of explosives were used to break 2,120,000 tons of ore in a single underground blast. The 5, 10 2-inch boreholes, involving 435,815 feet of drilling, were loaded over a three-week period, using conventional explosives and short-period electric caps. From this blast, more than half a million tons of ore have been removed to date (April, 1962) through slusher trenches situated in the footwall of the ore body. T HE Ontario Division of The International Nickel Company of Canada, Limited, operates six underground mines and two open pits in the Sudbury district in the north-central part of the Province. This paper describes the removal of a large pillar at the Murray mine (Figure 1), where 2,120,000 tons of ore were broken in a single underground blast by the blasthole mining method. This is the largest underground blast achieved to date (April, 1962) at Inco mines.

Jan 1, 1963

By D G. Boxall

As an alternative to heavy water cooling, reactors cooled by organic liquids are being actively developed in Canada under the sponsorship of Atomic Energy of Canada Limited. One of the areas in which development has been required is that of core materials. The factors affecting the selection of fuel canning and coolant tube materials are discussed. It is shown that S.A.P. is a potentially attractive material for these applications. The fabrication of fuel sheathing is discussed. Difficulties met due to large inclusions and blistering due to high hydrogen contents have been overcome by magnetic separation and vacuum sintering of the powders. High-quality tubes can now be produced by extrusion to finished size. A study has been made of the mechanical properties of fuel-sheathing tubes and bar stock. The stress rupture properties of the tubes subjected to uniaxial and biaxial stress have been determined. The biaxial stress tests were performed by internal pressurization. For times in excess of about 200 hours, the curve of stress against time to rupture is extremely flat. The secondary creep rates of

Jan 1, 1965

By D. Milne, G. Snell

"A new method to predict stope hangingwall failure in underground excavations is proposed. This method compares movement rate for stope hangingwalls, determined from changes in strain or deformation, with changing opening geometry. This geometry is represented by the effective radius factor (ERF), a measure of relative distance to supporting abutments from an opening surface point. This strain-ERF (SERF) approach is applied to an instrumentation program for Brunswick mine near Bathurst, New Brunswick. The SERF method for this case study predicted failure at an ERF of 13.9 m and hangingwall failure actually occurred at an approximate ERF of 12.4 m.RÉSUMÉ Cet article propose une nouvelle méthode permettant de prévoir la rupture de l’éponte supérieure des chambres d’abattage dans les excavations souterraines. Cette méthode compare la vitesse de mouvement des épontes supérieures des chambres d’abattage, déterminée à partir des changements aux niveaux des contraintes ou de la déformation, à la géométrie variable de l’ouverture au jour. Cette géométrie est représentée par le facteur du rayon effectif (ERF, de l’anglais Effective Radius Factor), une mesure de la distance relative jusqu’aux appuis latéraux de soutènement à partir d’un point de la surface d’ouverture au jour. Cette approche contraintes-ERF (SERF, de l’anglais strain-ERF) est appliquée à un programme d’instrumentation pour la mine Brunswick située près de Bathurst, dans le Nouveau-Brunswick. Pour cette étude de cas, la méthode SERF prévoyait une rupture à un ERF de 13,9 mètres (m); la rupture de l’éponte supérieure s’est effectivement produite à un ERF d’environ 12,4 m.INTRODUCTIONUnderground stope design can be improved with the installation of field instrumentation. The most commonly used instrumentation for monitoring rock mass behaviour around open stopes is extensometers. The y-axis of Figure 1 represents how the changing rate of movement, measured using either displacement- or stress-type instruments, can be observed over time. The magnitude of movement measured by extensometers can give an approximation of the load on installed support (Milne, Pakalnis, & Lunder, 1996) and a changing rate of movement can indicate approaching instability."

Jan 1, 2018

By D. Haraguchi, S. Izawa, C. Tokoro, S. Owada

"Arsenic is widely known as a toxic element for humans, animals and plants. Because of more stringent wastewater standards not only in Japan but also around the world, research for appropriate and efficient treatment method for arsenic is becoming increasingly important. Coprecipitation or adsorption process using ferrihydrite is widely implemented for dilute As(V) removal from wastewater. In this study, the sorption mechanism of dilute As(V) with ferrihydrite in coprecipitation or adsorption process was investigated. To accomplish this, we conducted batch experiments of coprecipitation or adsorption and compared these results for sorption isotherm and zeta potential. These experimental results showed that sorption mechanism in coprecipitation process depends on the initial As/Fe molar ratio; simple twodimensional adsorption onto the surface of ferrihydrite when the initial As/Fe molar ratio was < 0.4, and some three-dimensional uptake with ferrihydrite when it was = 0.4. We also evaluated the sorption mechanim by analysis of X-ray diffraction (XRD) and X-ray Absorption Fine Structure (XAFS). XRD or XAFS spectra showed that surface precipitation of amorphous ferric arsenate was formed when the initial as/Fe molar ratio was = 0.4, beyond the thermodynamic bulk precipitation range for ferric arsenate.INTRODUCTIONArsenic is toxic to animals, including humans, and long-term exposure to arsenic via drinkingwater causes cancer of the skin, lungs, urinary bladder, and kidneys, as well as other effects on the skin such as changes in pigmentation and thickening (Ghosha et al., 2008). Elevated levels of arsenic are often present in the environment as a result of the weathering and dissolution of minerals as well as in response to numerous anthropogenic sources including the discharge of mine wastes, coal fly ash and the use of pesticides that contain arsenic (Nriagu, 1994; Singh et al., 2007). Indeed, the potential for arsenic exposure affects many people, as evidenced by several million people in Bangladesh and India being at risk of exposure via drinking water obtained from contaminated groundwater sources (Ahmed, 2001).Acid mine drainage (AMD) containing arsenic is a global environmental problem (Dold, 2008; Liang and Thomson, 2008) that also affects Japan, which has many abandoned or closed mines that have been generating AMD for the last few decades (Masuda et al., 2008). Several such facilities in Japan produce AMD containing dilute concentrations of arsenic that exceed Japanese effluent standards (0.1 mg/dm3) (METI, 2006). For example, AMD from the abandoned Horobetsu sulfur mine, the largest AMD source in Japan, contains approximately 10 mg/dm3 arsenic."

Jan 1, 2012