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By V. G. Papangelakis, J. E. Dutrizac, G. Azimi

A new model capable of predicting the solubility of calcium sulphate solid phases in zinc sulphate processing solutions from 25 to 95°C was developed. The model uses the Mixed Solvent Electrolyte (MSE) model of the OLI systems software to calculate the mean activity coefficients of the electrolyte species. The model was tested using recently developed experimental measurements. It was shown to predict accurately the solubility behaviour of calcium sulphate in multi-component zinc processing solutions containing ZnSO4, H2SO4, MgSO4, MnSO4, Fe2(SO4)3, Na2SO4 and (NH4)2SO4. The model can also explain the complex effect of coexisting metal sulphates on the solubility of the CaSO4 phases. The model is a practical tool for assessing the process chemistry of a wide variety of complex aqueous processing streams.

Jan 1, 2008

By H. Miki, S. Wheatley

The addition of precipitated silica greatly enhances chalcopyrite leaching in the presence of sodium chloride at moderate temperatures (65-90°C) in acid media with ferric ions as the oxidant. The beneficial effect increases with the increase in chloride concentration and temperature. The addition of sodium silicate and silica sand has no significant influence. The analysis of solubility data in acid/salt solutions indicates that the solubility of silica as Si(OH)4 as the dissolved species is controlled by the activity of water, as expected from the hydration theory. Kinetic analysis shows the trends that copper dissolution from chalcopyrite in the presence of precipitated silica with sodium chloride follows a shrinking sphere model indicating a chemically controlled surface reaction. The effect of temperature on copper dissolution in the presence of both precipitated silica and sodium chloride was also larger compared to the results in sodium chloride alone. The SEM analysis shows that chloride and silica facilitates the precipitation of sulfur on the surface of the silica particles rather than the chalcopyrite particles which avoids the blockage of the mineral surface and thus improves the leaching kinetics.

Jan 1, 2014

By Egbert Burchardt

The challenge of "ore bodies getting steadily harder and lower in grade" was brought to light during the first oil crisis in the 70's. Shortly afterwards, HPGRs appeared on the scene with the promise of saving energy. This combined with developments in wear protection for the rolls ushered in a period of trade-off studies that considered the HPGR as an option to improve project economics or to even make projects feasible at all. Since then, applications of HPGRs at Cerro Verde (Freeport), PTFI Grasberg (Freeport), Mogalakwena (Anglo Platinum), Tarkwa (Goldfields), Boddington (Newmont), Penasquito (Goldcorp), and others have contributed to the creation of a formidable basket of operating experience. Collected through years of successful operation, this information has been used to validate design criteria, scale-up factors and establishing a clearer picture of what "to do" and what "not to do". This paper compares results from various mining operations using HPGRs in their processing plants. Some of the lessons learnt in different operating environments are reviewed in order to support proper implementation and operation of HPGR's. Some of the development programs that have been initiated to improve wear life of the tyres and to reduce overall operating costs are reviewed. It is timely to summarize today?s experience and analyse its implications for existing and new operations.

Jan 1, 2012

By C S. Stevens

This paper describes the problems encountered and the steps taken to solve them in milling an ore containing relatively large amounts of pyrrhotite. A complex and greatly lengthened flotation circuit was required to recover the pyrrhotite. A very low pH had to be maintained in the cyanide circuit in order to get good recovery of the gold and maintain reasonable cyanide recovery. Introduction D ELNITE Mines Ltd., a gold mine situated about 5 miles by road south and east of the town of Timmins, Ontario, is serviced by two shafts. No. 2 shaft extends from surface to the 2875-ft. level, and No. 3 shaft, an internal winze, extends from the 2875-to the 5275-ft. level. No. 2 shaft was stopped at the 2875-ft. level because of a heavy band of chloritic schist which necessitated a drive to the north for 1000 feet, where No. 3 shaft was sunk. The latter bottomed in the schist at the 5275-ft. level. From the 2500 to the 2875-ft. level in No. 2 shaft, the ore was

Jan 1, 1965

By S. Kelebek

Batch flotation tests were carried out using samples from stockpiles that were up to 1.5 months old as well as fresh samples oxidized in the lab for up to six months. Head grades and size distributions of samples were equalized whenever possible. The samples from stockpiles and oxidation experiments produced inferior nickel grade-recovery compared to the fresh sample. The poorer grade-recovery performance was attributable to two factors. First, a significant dilution effect was observed due to complete flotation of pyrrhotite. Secondly, the same stockpiling conditions caused nickel losses that were attributable to non-floatability of some pentlandite. Application of a high pH of 10 compared to the regular pH of 9.2 slowed down pyrrhotite flotation kinetics, but was not able to prevent complete flotation after 8 minutes. The samples oxidized in the lab did not match full characteristics of stockpile samples. They provided somewhat better selectivity for pentlandite. Some correlations were observed on a qualitative basis between surface characteristics such as elemental sulphur formation, activation and flotation behaviour. Oxidation conditions, which induce floatability on pyrrhotite while causing incremental loss in pentlandite floatability appear to be the root cause of difficulties in the processing of oxidized forms of these ores.

Jan 1, 2006

By E. Michelotti, M. Cardu

This paper presents the results of a new method that has been tested to recover metallic cobalt lost by diamond beads from rock cuttings. When dimension stones are cut using diamond wire saws, the beads become worn and, before the end of their cycle life, lose a certain amount of material; this material is prevalently made up of sintered metal and diamonds. The material is then washed away, together with rock debris, in a dilute pulp. In effect, this process involves the dispersion of economically valuable, but potentially polluting, materials (such as cobalt) that are used to confer indispensable technological features to the beads. This current research aims to develop a waste-processing pilot plant (High-gradient Magnetic Separator or HGMS) to recover metallic components from the pulp by means of a suitable separation. The research\u2019s purposes are two-fold: a. to remove the polluting components from the rock debris before their disposal and b. to start a recycling process of the valuable metals.

Jan 1, 2010

By J. Finch, Wei Zhang

In this paper we describe the synthesis of a new homologous series of linear Polyglycol-based frothers that consist of Ethylene Oxide (EO) and hydroxyl as hydrophilic groups and Propylene Oxide (PO) and alkyl chains as hydrophobic groups. The synthesized frothers were of two types: Alkyl-Ethoxy-Propoxylate (abbrev. CnEOlPOm) and Alkyl-Propoxy-Ethoxylate (CnPOmEOl) giving: (a) different number of groups and chain length, and (b) different locations of the groups. The identities were confirmed by proton nuclear magnetic resonance (NMR) spectroscopy and total organic carbon (TOC) analysis. The characterization of the products was carried out in a bubble column. At steady state, bubble size, gas holdup and water overflow rate were measured as a function of frother concentration. The results indicate that increasing number of PO groups led to significant decrease in bubble size, and increase in gas holdup and water overflow rate. Increasing the alkyl chain length, gave similar but less pronounced trends. There was no impact of increasing the number of EO groups on bubble size but there was an in increase in gas holdup and water overflow rate. Changing the location of the PO and EO group had a significant effect on all three parameters.

Jan 1, 2015

By C. E. Baltzer

This paper highlights the electric power situation in Canada, and introduces brief explanation of the salient differences between electrical practice in the United States and Canada. The availability of bask energy in the two countries is touched on, also the hydro versus thermal outlook as applying to Canada. De-v2lopment of thermal-electric power is dealt with in some detail, followed by Canada's thermal-electric power requirements, present and future. The fuel requirements for steam-electric generating plant are assessed on the basis of a survey recently made, and the location and size of the major thermal plant operations are given. Fuel contractual obligations on the part ?of suppliers and consumers are mentioned. Finally, an opinion is expressed in regard to the types of f.uel in ?demand on a regional basis with emphasis on the need for coal in the several areas dealt with.

Jan 1, 1958

By K. Ebrahimi-Nasrabadi

The dependence between the extent of conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally in the temperature range of 400?1200 °C and for calcination times up to 8 h. A TGA?DTA analysis showed that decomposition begins at temperatures as low as 340 °C and is completed at 600 °C. Measurements of specific surface area (SSA), iodine adsorption number (IN), crystallite size, and loss on ignition were carried out to characterize the product quality. It was found that while all the parameters are dependent on the extent of calcination, densification of the product caused by grain coarsening affects their final values. As a consequence, SSA and IN went through a maximum with time. The study showed that high quality caustic calcined magnesia can be produced in a narrow range of temperature (600?650 °C) and time (1?4 h). Medium quality caustic calcined magnesia can be made within a wider range of parameters.

Aug 1, 2013

By Wei Yun-Jie

Columnar jointed basalt is a fractured rock, with a lot of small spacing structural planes and poor integrity of the rock mass. On the basis of the comprehensive study of the columnar shape of Columnar joints, rugosity of the fracture surface and the chemical composition of basalt, columnar joints of Bai hetan dam area were formed as a result of the cooling and shrinkage effect of magma. Columnar joints basalt are mainly chlorite, kaolinite, epidote, tremolite chemical reactions and the content of columnar joints are mainly chlorite by slice identification and chemical analysis. Columnar joints basalt showed high uniaxial tension test, low coefficient of friction and high cohesion by indoor physical and mechanical test. Columnar joints rock mass showed high strength and large deformation by field shear test and deformation test. Columnar joints basalt can be used directly as a foundation of dam as long as we follow the rules and reduce disturbance strictly.

May 1, 2009

By G. P. Kundargi

India is one of the fastest growing economies in the world. The role of the Iron & Steel industry is very important for the development of the country. Iron and steel are among the most important components required for the infrastructure development of the country. This is one of the fastest growing sectors. The demand drivers for the Indian Iron & Steel industry are increase in the activities of the manufacturing industry and infrastructure development. Indian Iron & Steel industry with its strong forward and backward linkages contributes significantly to overall growth and development of the economy. The industry today directly contributes 2% of India?s Gross Domestic Product and its weightage in the official Index of Industrial Production (IIP) is 6.2%. Manganese is a main ingredient for production of steel. Almost 90% manganese is being utilized by the steel industry worldwide. Globally, there is no substitute for manganese as on date. There is huge gap between demand and production of manganese ore in the country. To meet this demand gap and to support for growth of national economy, MOIL Limited (formerly Manganese Ore India Limited), a Government Enterprises, producing annually around 1.1 million tonnes (mt) of manganese ore and value added products, has geared up with various infrastructural activities to increase the present production capacity of 1.1?1.5 mt in 2016?2017 and 2.2 mt in 2020?2021. The paper deals with the technological improvements and infrastructural development activities of MOIL; this will help MOIL to become the market leader in manganese ore production globally in the coming years.

Aug 1, 2013

By The Staff

"THE property of Red Mountain Mines Limited is located 11/2 miles north and west of the town of Rossland, in southern British Columbia. The mine is situated on the flank of Red mountain, famous in pioneer days as the site of a number of profitable gold-copper producers. Mining and milling commenced in May, 1966, and by the first of July the concentrator was treating close to its average design capacity of 400 tons per day. The following description of the property and its operations is divided into three parts, dealing respectively with geology, mining and milling.GeologyAll the known ore reserves of Red Mountain Mines occur on the Coxey claim, on the west slope of Red mountain. Although there are indications of molybdenite mineralization elsewhere on the Company's property, these have not been developed.The Coxey and adjoining areas are underlain by the Mount Roberts formation of the Rossland volca-nics. This formation consists of an interbedded series of volcanic and sedimentary rocks, mostly brecciated and silicified near the ore zone, and all intruded by igneous rocks which occur in various forms, and vary in composition from basic to acid. The country rock in the vicinity of the mineralization seems to be mostly a volcanic, approximately andesitic in composition, and possibly a surface flow. There is much banding, some of which is undoubtedly due to tuff and agglomerate layers, and some to narrow, siliceous, sedimentary horizons such as the surface exposure of the main ""A"" orebody, much of which was a thin capping of greyish banded rock that looked like quartzite. The drill holes also intersected occasional layers of black, argillaceous quartzite, sometimes altered to a greenish colour. The whole assemblage has been silicified with varied intensity, sometimes to such an extent as to have obscured or obliterated the original characteristics. The mineralized zone has also been strongly brecciated, the fragments varying in size from less than an inch up to large masses, best described as a mega-breccia. Anomalous results obtained in drilling, such as sedimentary sections that do not appear in adjoining holes, may sometimes be due to the presence of these large blocks, no longer in their original position. The whole volcanic unit is thus very complex and confusing. For practical purposes, the ore may be said to occur in a greenstone formation with minor sedimentary interbeds and considerable later igneous material."

Jan 1, 1967

By Oleg G. Tovmachenko

We have studied optical properties of fluorescent nanoparticles. These particles consist of a metal (gold/silver) core, an empty and a dye labelled silica shells. The different dye molecules with moderate quantum yields (about 0.3) has been used. Almost all of types of nanoparticles show fluorescence enhancement. This enhancement is strongly dependent on the degree of the overlap between the surface plasmon band of the metal and the absorption/emission band of the dye molecules. The results are interpreted in terms of competition between local field enhancement and quenching of fluorescence by the metal surface.

Oct 1, 2003

By S. Hill

For a mining operation, the determination of the best place to build haul roads is typically done by hand, or with the assistance of rudimentary shortest path optimisation algorithms. Straight line, point to point, modelling of costs is often used with distances multiplied by constants that are based on rise of the road between the points. Failings of this approach are that straight line approximations are notoriously poor as they do not take into account areas where a truck cannot travel. In addition, the rise and fall of the road may vary considerably over the truck journey meaning acceleration/deceleration and varying truck speeds are not taken into account. Lastly, the use of rudimentary optimisation algorithms means properties a truck must obey such as minimum turning circles, line of sight restrictions or even that the truck must travel forward at all times are not taken into account. Thus solutions generated may not be feasible, let alone optimal. In this paper we discuss a state of the art parallel Artificial Intelligence tree search technique for solving haul road location problems. As well as the above properties, factors such as road utilisation, cut and fill, and construction costs are taken into account. The combination of advanced modelling and fast computing and optimisation techniques produces significant benefits both in terms of time to generate roads and cost savings. Preliminary results where this method has been used are discussed.

Aug 1, 2013

By Richard Howie

Avian Diversity ?? Pre-mining ?? 110 - 125 species would have occurred ?? Dominated by forest species ?? Wetland productivity unknown ?? Post mining ?? 192 documented ?? Forested species in reduced numbers ?? Increase in wetland species ?? Increase in open country/grassland species

May 1, 2008

By Y. G. Yaroshenko, V. Y. Baldin, Y. M. Gordon

The manufacture of sulphuric acid from the off-gas of pyrometallurgical processes in the production of heavy metals is one of the common methods of effective recycling of sulfuric anhydrite. The new Impact-Inertial Devices with the rectangular contact channels (IIRCh) and the internal circulation of liquid allow the injection of an absorber into the phase's interactive cell by utilizing the gas stream energy and by this way increasing the sulphuric acid yield and reducing the power consumption. These devices have the following advantages: simplicity of design, smaller size, low capital expenses, absence of irrigating system, high operational reliability, simultaneous cleaning of solid, gaseous and liquid impurities and also cooling of gases etc. The IIRCh efficiency is almost 18 % higher and they require 1.3-2 times lower energy when compared with Venturi Absorbers. Also the elevation of spraying nozzles or injectors is 1.5 times lower in the IIRCh case.

Jan 1, 2004

By A. C. Headon, K. W. Lam, D. P. Dautovich

"Microbiological activities affecting the performance of materials have been encountered in diverse situations within Ontario Hydro. Case histories of bacterial problems which are presented include ground rod corrosion at transformer stations, corrosion of a bare steel cooling water intake structure in Lake Huron and corrosion of steel components in a nuclear generation station vacuum building. Possible microbiological activities which may affect the corrosion behaviour of containers for the disposal of nuclear fuel waste in the future are discussed, as are bacterial actions suspected of causing an odour problem in residential water heaters.IntroductionBacteria are ubiquitous. Except by use of sterilization methods, bacteria -free environments are no t possible to find. Bacteria lie dormant in hostile environments, spread easily through air and water currents and reproduce rapidly under favourable conditions. Although different types of bacteria have different preferable conditions for growth, they are highly adaptive and in general, whenever there is a source of water and carbon (carbon dioxide or organic matter), there will be bacterial activities . These activities often induce or enhance costly metallic corrosion in industries and water odour problems in rural water supplies . Underground structures and systems in contact with natural water or water containing organic matter are most susceptible to bacterial attack.The types of metal-degrading bacteria , their characteristics and the conditions for growth have been reviewed extensively in the literature(1,2,3). There are several often encountered groups of bacteria which, through their metabolic processes, may lead to the degradation of metals. A large variety of bacteria produce corrosive in organic or organic acids as waste, such as the well known formation of sulphuric ac id by aerobic sulphur oxidizers . Anaerobic sulphate reducers produce hydrogen sulphide which is corrosive and has an obnoxious smell, slime-forming bacteria from slime which shelters sulphate reducers and iron bacteria oxidize ferrous to ferric ion which precipitates as hydrated oxides creating oxygen concentration cells . The following are bacterial problems encountered in Ontario Hydro. Although the number of recognized cases has been few, they show the diversity of location and environment where bacterial problems could arise. These include ground rod corrosion at transformer stations, corrosion of bare steel in a water intake structure, corrosion of steel in a nuclear generation station vacuum building and an odour problem in residential hot water tanks. In addition, possible bacterial- enhanced corrosion in containers for future disposal of nuclear fuel wastes are also discussed."

Jan 1, 1984

By J. F. J. Thomas

"AbstractBoth the quantity and quality of waters available as raw materials are important to Canadian industry and to the national economy. The huge demands of many Canadian industries is illustrated by tabulated figures, based on the 1950 Canadian production of certain products, and on United States figures for the gallons of water required to produce a unit quantity of each product. It is suggested from comparison with American survey results and figures that Canadian industrial water consumption is 1 to 11/2 billion Imperial gallons per day. Since present information on Canadian usage is meagre and it is not certain that American survey results can be directly applied to Canadian industry, this estimate must await confirmation in future studies.The hydrologic cycle and the principal factors affecting the quantity and quality of water, namely, climate and season, topography, geology, vegetation, and human activities, are discussed and the principal salts dissolved in water which affect industrial use are enumerated.The present survey studies by the Mines Branch on water quality are outlined. Besides chemical analyses of municipal water supplies within a watershed, periodic sampling and analyses of major surface waters for a one-year period is being carried out. The importance of studies on seasonal variation in quality is stressed by comparing the dissolved salts in various river waters with river flow. Figures showing such relationships in the Rideau river and Ottawa river at Ottawa, the Columbia river at Trail, B.C., and the Battle river at Unwin, Sask., are presented. Different rivers show different quality changes with changing flow, and possibly only after long-term studies can the relationships be predicted.Quality studies on water may be as important as studies on many other raw materials. The quantity of the raw material, water, is not inexhaustible nor is the quality indestructible, and more realization of its importance, followed by conservation and intelligent use, is desirable."

Jan 1, 1952

By Ellis Thomson

The microscope is now used extensively not only in the examination of solid ore but also in the determination of fragmental mill products. It has therefore become a matter of paramount importance to be able to mount and polish fragmental as well as solid specimens in the easiest and most efficient way, so that the minerals present may be readily determined. In the case of the solid ore the ordinary mount of plasticine set on a glass or metal slide serves for most practical purposes. An improvement on this is furnished by the small brass container inside of which the specimen is mounted in a cementing medium of sealing wax. The latter is the method in use at Harvard University. It has the advantage of uniform height, thus obviating the necessity of a slide of any sort. It is also easily catalogued as the brass holder may be stamped with a convenient series of letters and numbers that will serve as a label. Other advantages of this type are the ease with which any particular part of the section may be re-located, the excellent storing facilities afforded by mounts of uniform size, and the possibility of polishing ten or a dozen sections at the same time by means of a holder which is placed over the polishing wheel, is geared with it, but revolves the opposite way.

Jan 1, 1926

By G. A. Van Wielingen

"The conditioning of natural gas to meet contract pipeline specifications involves in the majority of cases in Western Canada, the appropriation of substantial capital expenditures for treating and processing installations. It is therefore of vital importance to the owners and producers of natural gas to arrive at an appreciation of the economics pertaining to the production and surface handling of their gas reserves at the earliest possible stage of field development. The treating and processing of natural gas often results in considerable changes in composition and related physical characteristics between the wellhead and the point of delivery of the saleable gas. This paper presents a general outline of engineering calculations which can be applied in the pre-determination of the effects that surface handling of gas will have on the composition and physical characteristics of sale-able gas. Emphasis has been placed on the calculation of hydrocarbon dew-points, heating values and shrinkages prevailing at the various stages in the surface handling of natural gas. It is believed that advance information indicating the approximate ranges of these physical properties will facilitate process selection and will provide a basis for the estimation of capital and operating costs of process installations."

Jan 1, 1960