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By W. B. Coker

A helicopter-mounted lake-sediment and lake-water survey was carried out over Grenville rooks in the Renfrew area (parts of Renfrew and Lanark counties) during four days of October, 1975. In the course of this survey. 1150 square kilometers were covered, with 246 lake-sediment and 276 lake -water samples collected from every body of water on which the helicopter could land. Sample sites, which averaged one per 4.6 square kilometers, included lakes, ponds, beaver ponds, swamps and marshes. Lake-sediment samples were taken using a G.S.C. sampler. Waters were collected directly into polyethylene bottles. At each sample site , surface and bottom-water pH, dissolved oxygen content, conductivity and temperature were measured using a Martel. Water Quality Analyzer. The lake sediments were air dried and then ball milled to pass a minus 80-mesh sieve. Lake sediments were analyzed for U by delayed neutron activation and for Mo, Cu, Zn, Pb, Fe, Mn, Ni and Co by atomic absorption techniques. The organic content of the sediments was determined by loss on ignition at 450 °C. Lake waters were acidified with nitric acid on the day of collection. The U content of the water s was determined by fluorometry; the Cu, Zn, Pb, Fe, Mn , Ni and Co contents of the waters were determined by solvent extraction - atomic absorption techniques. A close relationship was found between bodies of granitic, syenitic and pegmatitic bedrock and elevated U levels in the lake sediments. The Hurd Lake and White Lake granitic intrusive were encompassed by an annulus of higher U activity. Field inspection revealed that the U concentrations occur within a zone which may represent a contact metamorphic aureole. Within these complexes, anomalous concentrations of U appear to be associated with Mo. Information derived from the lake-water data reinforces the geochemical distributions outlined by the lake-sediment survey . This survey was carried out in order to develop optimum sampling and analytical procedures for geochemical reconnaissance of the Grenville Province that may be carried out under the auspices of the Uranium Reconnaissance Program.

Jan 1, 1977

By Juliana Parreira

The past decade shows record increases in global demand for minerals and metals with an accompanying significant decline in skilled personnel. Mining companies today are examining new technologies to maximize production, reduce costs, and create safer work conditions to deal with this shortfall. Automation of an open-pit mine haulage system is receiving attention as a beneficial option since it provides more consistent and efficient operation of mining equipment, it removes workers from potential danger, it reduces fuel consumption significantly reducing greenhouse gas (GHG) emissions, and it can help optimize vehicle repairs and equipment replacement because of more-predictable and better-controlled maintenance. This paper describes a simulation model under development using the EXTENDSIM software package to examine scale-up issues and constraints of autonomous vehicles in comparison to a manual system. The software can predict and manage Key Performance Indicators (KPIs), such as productivity, safety, cost, equipment failures, fuel consumption, and tire wear under different road and load conditions. By breaking-down the various systems of an autonomous haulage truck and simulating the overall haulage system using a Monte Carlo approach, the model becomes a flexible and powerful tool to use within a mining organization. Direct comparison to a manuallyrun system can be done to show the cost and operational benefits of automation. Project managers can use this tool to guide decision-making about possible application of autonomous haulage trucks at a specific mine site.

May 1, 2010

By L. L. Sirois

Because segments of the Canadian mineral-based economy are dependent totally or in part on foreign sources of certain minerals, their well-being may well be affected by inability to obtain these minerals. Where such dependency exists, it is therefore important that contingency plans be available to counteract possible price increases or lack of supplies by means of technology, developed well in advance of any pending crisis . Canada is vulnerable to possible future real or artificial shortages of certain foreign-produced mineral commodities, and science and technology can provide information for the development of policies for counteracting efforts by foreign exporters to control prices or limit supplies.

Jan 1, 1977

By C. A. Pickles

Microwaves are being applied industrially in a number of fields and possess a number of potential advantages that could be applied in extractive metallurgy. Microwave heating has a number of unique characteristics, which distinguish it from the conventional heating methods. In microwave heating, the absorption of energy occurs at the molecular or atomic level and therefore the heat is generated within the material itself. In conventional heating, the exterior temperature is usually higher than the interior, but with microwave heating, the temperature gradient is inverted and thus the interior temperature can be much higher than that of the surface. The energy densities in microwave systems can be relatively high and this in combination with the low thermal conductivities of oxide ores, can lead to very high internal heating rates. In this research, the application of microwave energy for the reduction of a nickeliferous silicate laterite ore has been investigated. The real and imaginary permittivities are the two fundamental properties which determine the microwave absorption characteristics of a material and these were measured for the ore, both with and without carbon additions using the cavity perturbation technique. The microwave heating and reduction experiments were performed in a 0 to 2 kW CTC microwave system. The effects of power input, processing time, sample mass and charcoal additions on the microwave absorption were investigated. Then reduction experiments were performed and the nickel grade of the magnetic concentrate and the nickel recovery in the concentrate were determined.

Jan 1, 2005

By N. Golchinfar

Tunnels in deep mines are subjected to high stresses. Fracture and failure of the rock mass around an opening can occur when mining-induced stresses are high. In burst-prone grounds, mining-induced seismicity can cause additional dynamic loading which can further increase the stress around the tunnels. When the dynamic stress reaches the rock mass strength, fracturing can occur and rockburst may happen (depending on loading stiffness around the failed rock mass). Rock support installed in the tunnel must be capable of dissipating dynamic energy and holding the failed rocks. Hence, it is important to estimate the depth of failure for rock support design. This paper focuses on how to model depth of failure under dynamic loading. In the modeling, two scenarios of rock failure are considered. In the first scenario, rock failure occurs under static loading and subsequent dynamic loading further increases the depth of failure. In the second scenario, no failure occurs under static loading but in the subsequent dynamic loading, failure around the tunnel is created.

Aug 1, 2013

By W. J. Langford

"Conventional design criteria assume that the fracture strength of a structural material exceeds its yield strength. Fracture below the design load is not expected, y et many structures have failed in this way. The causes of the fractures are almost always discontinuities such as cracks and welding defects. Linear Elastic Fracture Mechanics (LEFM or simply 'fracture mechanics') provides an analytical framework for assessing the influence of sharp defects on the load-bearing capability of a structure. Fracture mechanics techniques have reached the point of acceptance by ASME Design Codes for nuclear components, and ASTM Standards now include well-defined rules for measuring fracture toughness. Starting with a simple equation which relates applied stress and crack size, the influence of the material's thickness and yield strength can be calculated. Thus, the size of defect which will cause failure under the applied stress may be determined. Armed with this information, the metallurgist can assess the safety of a structure from the viewpoints of non-destructive testing standards, construction standards and conditions of operation throughout its service life."

Jan 1, 1976

By Niels Verbaan, Ernesto Bourricaudy, Ronald Molnar, James Brown, Sunil Jayasekera

"SGS Minerals commissioned an internal R&D program to develop in-house expertise to design, set up and operate REE separation pilot campaigns at its Lakefield, Canada site. A team approach was used that included expert consultants in the field of REE separation as well as in-house expertise supported by the on-site Analytical Laboratories.A mini pilot scale SX circuit was designed and constructed consisting of several modular banks of 30 stages each. About 80 stages of mixer-settlers were used to separate Pr and Nd from La and Ce contained in a synthetic REE chloride stream simulating the raffinate from an initial La-Nd|Sm-Lu+Y separation.Two pilot campaigns were operated totalling 25 days of 24/7 operation with 99.4% plant availability in the final 20 day campaign. Purities of > 99.9% in the Pr-Nd strip liquor and > 99% in the La- Ce raffinate were achieved and simultaneously sustained in the second campaign for prolonged operating periods. Key to controlling and adjusting the circuit was the rapid assay turnaround (as low as 2 hours) provided by the on-site SGS analytical lab. This permitted the operating team to modify conditions and observe the effect of changes relatively quickly considering the large number of stages. A portable XRF analyser was also used to track evolving assay trends in the circuit. The small physical size of the circuit enabled longer operation with a limited amount of sample.This paper discusses the design of the circuit, operating conditions, some of the key operating factors and controls and results obtained.INTRODUCTIONSGS Minerals commissioned the design of and built a solvent extraction (SX) pilot plant for the separation of rare earth elements (REE). The plant consists of a battery of 120 mixer-settlers set up in a dedicated piloting facility.The purpose of the programme was to develop capabilities and in-house expertise in REE SX separation technology. The program aimed to establish operating procedures, sampling regimes, and analytical methodologies and protocols for this type of process/plant. A team comprised of SGS personnel and several external consultants with prior industrial and REE separation piloting experience was assembled to achieve these objectives."

Jan 1, 2016

By Antonio Segatori, Bjørn Holmedal, Kai Zhang, Trond Aukrust, Knut Marthinsen

"The visual appearance and mechanical properties of aluminium alloy extrusions are strongly dependent on the microstructure and texture of the extruded profiles, where the desired microstructure and texture may depend on the specific applications. In the present work, the evolution of deformation, as well as recrystallization textures during extrusion of AA6xxx aluminium alloys, have been experimentally and numerically investigated. Extrusion trials were performed in a laboratory extrusion set-up, which enabled immediate water-quenching of the profiles at the exit of the die, and thus the possibility to capture the deformation texture prior to post-extrusion recrystallization. The textures and their through-thickness variations were experimentally measured by the electron back-scatter diffraction technique (EBSD, and the deformation textures numerically modelled by coupling FEM flow simulations and crystal plasticity (CP) simulations. Different CP models as well as different choices of model parameters were employed and evaluated for texture predictions. With an appropriate choice of crystal plasticity model and model parameters, the deformation texture can mainly be predicted, although the accurate intensities are hard to reproduce. The corresponding recrystallization textures, either generated through spontaneous recrystallization of the extruded profiles or through post-extrusion annealing, are far more challenging to reproduce with available recrystallization models.INTRODUCTION Extrusion is a widely applied thermal-mechanical process to produce aluminium profiles. The properties of the profiles, for example mechanical, fatigue, fracture, corrosion as well surface appearance, are strongly dependent on the underlying microstructure and texture, and the requirements with respect to these aspects may vary with applications (Ralston et al., 2010; Dumoulin et al., 2012; Donati et al., 2013). Moreover, it is often a challenge to produce extrusions with a consistent and homogenous grain structure and texture along as well as through the cross section of the profiles. It is thus vital to understand and be able to predict (model) how different microstructures and textures are formed and how they evolve during and after extrusion, as basis for controlling the final appearance and properties of extruded profiles."

Jan 1, 2018

RÉSUMÉ Cet article traite d’une analyse technique et économique du concept du triage optique en vue d’améliorer la rentabilité des opérations minières. Le principe du tri optique et les principaux systèmes et modules servant au fonctionnement de l’appareil de triage sont décrits. un modèle a été développé pour analyser l’intérêt économique d’une opération de triage optique. L’étude est basée sur des données provenant d’une halde de minerai à faible teneur en or, déposé à la surface, et de minerai extrait des opérations souterraines courantes de la mine Beaufor au Québec. Les résultats de cette analyse indiquent que l’opération de triage optique permet d’améliorer grandement la performance économique; l’opération devient alors rentable pour des teneurs en or relativement petites.

Jan 1, 2010

By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By John B. Hodgeson

AMMONIA is an essential constituent in the production of the ammonium-sulphate and ammonium-phosohate soil fertilizers manufactured by the Consolidated Mining and Smelting Company of Canada, Limited. The fertilizer plant, built in 1930 at Warfield, near Trail, provides a means of utilizing the large amount of sulphuric acid produced from the sulphur dioxide which is removed from the smelter smoke. The plant has an avail-able source of cheap power which makes the production of fertilizer economically possible. The fundamental operations involved in the production of ammonia at the Warfield plant are, first, the manufacture of hydrogen by the electrolytic dissociation of water; next, the recovery of nitrogen by the fractional distillation of liquid air; and finally, the combination of hydrogen and nitrogen in proper proportions and under suitable conditions to form ammonia.

Jan 1, 1938

By Yves Gagnon, Nicole Gauthier, Daniel Kelly, Michel Rocheleau

"The Larder Lake-Cadillac Tectonic Zone in Rouyn-Beauchastel area (a 20 km long segment) contains distinct lithotectonic units bounded by artastomosing or sub-parallel shear zones. The gold deposits in the area are located within highly strained portions of E-W striking shear zones. The ore-zones are structurally controlled disseminated and vein-type lodes. They are spatially related either to megascopic z-shaped folds which refold E-W shears, or to areas of intersection between E-W shear zones and late NE-striking faults. Several ore bodies are enclosed within ultramafic rock units or at their contacts with adjacent units. All the lenses are elongated down dip and distributed, both loterally and vertically, ""en echelon"" . The ore zones tend to decrease in size and number away from the hinge zone of the megascopic z-shaped folds.Two main styles of mineralization are recognized at the Astoria deposit and at for most of the deposits in the Rouyn-Beauchastel segments a discontinuous ""Carbonate Ore"" and a more continuous, albitic sulphide-bearing ""Flow Ore"" (terminology used at the Kerr Addison mine).The typical ""Carbonate Ore"" zones are found within strongly arbonatized blocks bounded by conjugate late NE or NNW-striking fralls. The carbonatized blocks display features characteristic of llrittle to brittle-ductile deformation developed in shear zone system. Vein systems in the ""Carbonate Ore"" occur within shear fractures(D R)tension fractures (T), or within brecciated rocks adjacent to NS llrilcing faults. The ""Carbonate Ore"" zones are displaced by numer IU lole E-W, NNE, NW and N-S faults.The ""Flow Ore"" zones are found within predominantly ductile portions of E-W shear zones. The sulphide mineralization is finely disseminated and regularly distributed within mylonitic foliation or associated with veins and veinlets sub-parallel or oblique to the mylonitic foliation, in which case the mineralization is coarser grained. The gold mineralization is a late Archean event postdating the formation of the penetrative fabric, and synchronous with the end of the dextral oblique-slip motion."

Jan 1, 1990

By Ralph W. Edie

"IntroductionTHIS PAPER deals with chemical and mineralogical changes in wall-rocks associated with pitchblende mineralization in the Gold-fields area of Saskatchewan. The localities at which the rock specimens studied were collected, and descriptions of the various rock-types referred to, are given in a previous paper by the author (5).The geological field work upon which this paper is based was carried out while the writer was employed by the Eldorado Mining and Refining Company during the summers of 1948, 1949 and 1950. The laboratory work§ consisted largely of quantitative spectrographic analyses for both major and minor elements, supplemented by an examination of 250 thin sections of both altered and unaltered rocks.Character of the AlterationHydrothermal alteration, with associated pitchbende mineralization, is widespread in the Goldfields area of Saskatchewan. The most intense alteration is restricted to the immediate vicinity of fault or breccia zones, but large areas are affected to a minor extent.In detail, the relationship between alteration and pitchblende mineralization is complex, as individual veins do not in general have separate alteration halos. Pitchblende generally occurs in gash-like calcite veins or stringers in wide, fractured zones associated with faulting. Large, lenticular and tabular masses of slightly to intensely altered rock occur in the same wide fracture zones as the mineralized veins. However, vein deposition appears to be-long to a later fracturing period, after hydrothermal alteration was more or: less completed. Generally, the veins transect and are confined to highly altered rock, but on the other hand many highly altered zones intersected in diamond drill-core are barren of mineralized veins."

Jan 1, 1953

By A. Y. Smith, R. J. Allan, E. H. W. Hornbrook, R. W. Boyle, W. Dyck

"HYDROGEOCHEMICAL METHODS in the Canadian Shield can be based on analyses of the following :(1) spring waters and their precipitates;(2) stream and river waters;(3) lake and muskeg waters;( 4) ground waters from drill holes, wells, faults, etc.;(5) waters issuing from diamond drill holes, faults, shear zones, etc. into mine workings and open pits; also analyses of precipitates associated With these waters.The first four can be utilized in both reconnaissance and detailed surveys. The last is suitable only for detailed work.For hydrogeochemical methods of prospecting to be effective, the following conditions must be present. 1. Natural waters must come into contact with mineral deposits and remain in contact with them long enough for the solution of detectible amounts of ore, gangue or indicator elements. 2. Dispersion patterns must be present in the hydrologic systems in order to trace the elements back to their source. These patterns may take the form of trains (e.g., increasing amounts of elements upstream toward t he source (s), Figure 1 ) or halos (e.g., increasing amounts of elements in bodies of water toward the source (s), F igures 2 and 3)."

Jan 1, 1971

By CH. Liu, H. X. Jiang, X. Xiao

"A study has been conducted to characterize the fatigue life in 7050-T7451 thick plate by the comparison between an experimental alloy and commercial alloy. The fracture origins were specified and their sizes were measured by scanning electron microscope (SEM). Additionally, the size, number density and spatial distribution of porosity in the experimental material and commercial material were characterized and compared, using X-ray Computed Tomography(XCT). The results showed that microporosity was the predominant site for crack nucleation and subsequent failure of the experimental alloy. However, as for the commercial alloy, fatigue cracks were found to originate from constituent particles. The presence of microporosity in 7050-T7451 thick plate reduced fatigue life of an order of magnitude or more compared to the commercial alloy. The relationships between size of origin and fatigue life were proposed. It was showed that the fatigue endurance was reduced when the size of porosity increased.INTRODUCTION 7xxx series aluminum alloys, due to their combination of high strength, high resistance to stress corrosion cracking, and good fracture toughness, are widely used in structural engineering applications where high-strength and low-density characteristics are fundamental design requirements (Williams& Starke, 2003). Every designer is striving to find an optimal combination of properties including strength, corrosion resistance and fatigue resistance (Wanget al., 2016). Based on the design principles of aircraft, a higher fatigue resistance of aluminum alloys are required. Thus, many investigations have been carried out on the microstructures and its effect on fatigue properties of the 7xxx series aluminum alloy (Robson, 2004; Schubbe, 2009).Microporosity, which is a common defect in casting materials, can lead to a significant deterioration of mechanical performance and fatigue resistance, especially in the high alloyed 7xxx aluminum alloys. The actual valid loading area decreases due to microporosity, which results in detrimental effect on the mechanical properties. Many experimental studies have been conducted in this research field. Mayer et al.(2003) investigated the fatigue properties of magnesium alloys produced by high-pressure die-casting. The results show that porosity in magnesium alloys greater than0.18mm diameter may be considered as the most important material defect for high cycle fatigue and fully reversed loading conditions. Nadot et al.(2004) found that the near surface defects are much more dangerous than the internal defects. Wang et al.(2001a) used the Weibull statistics method to analysis the influence of the microporosity, oxides and particles on the A356-T6 alloy fatigue life. The results show that, the porosity is more detrimental to fatigue life than oxide films and particles. With regard to fatigue resistance, although the deleterious effect of microporosity has been generally acknowledged, a quantitative understanding between casting microporosity and fatigue life in 7050-T7451 plate is not well established."

Jan 1, 2018

By C. Villaseca, F. Penna, R. Villarroel

Acid mist is the undesired result of copper electro-winning (EW) process, generating a contaminated and hazardous environment in the working areas, as well as promoting high corrosion conditions for structures and equipment in the EW tank-house due to the buoyancy of sulfuric acid in aerosol form. Likewise, organic entrainments that occasionally occur in this process contaminate the cathodes, as well as increasing the risk of fire. LateralVex® and LateralFlow® are technologies that effectively and efficiently solve these problems, without affecting the usual activities of the operators, thus presenting a significant distinction with respect to other technologies that seek to solve these problems. Minera Antucoya, an AMSA group company, which produces 80,000 tons of electrolytic Cu per year, decided to install both technologies for its EW tank-house, LateralVex® in commercial cells and LateralFlow® in scavenger cells to keep both the acid mist and the organic entrainments under control. This paper presents the effects of applying these technologies in Minera Antucoya’s electro-winning plant, the challenges addressed, the difficulties encountered, the problems and opportunities that their implementation involved, as well as the surprising results obtained at the time of measuring the acid mist— less than one hundred’s part of the Allowed Weighted Limit—in samples taken with the plant operating at maximum current capacity. Additionally, the paper includes some of the improvements identified during the period, more than 3 years, in which these technologies have been in operation in Minera Antucoya. INTRODUCTION Electrowinning is the most used electro-chemical process in the hydrometallurgical industry for the recovery of highly pure metallic copper as its final product, which is formed in previous stages in an aqueous medium that goes through a selective process using organic solvents to separate impurities and concentrate the metal in a sulfuric acid solution. In the last stage, this solution goes through a process in which high- density current at a low voltage is applied, so that the metal in the solution will deposit in solid state on a plate, usually a stainless-steel plate. This last process involves the generation of other sub-products due to the electro-chemical dissociation of the electrolyte’s components, or to the addition of chemical additives, or due to specific physical conditions or lack of controls during the operation.

Jan 1, 2019

By L. A. Wrigglesworth, A. S. Dadson

The orebodies of the Giant Yellow-knife mine occur in zones of schist, in an assemblage of typical Precambrian greenstones which form part of the Yellowknife Greenstone Belt. One of the most interesting problems at the mine concerns the fold-like attitudes assumed by the schist zones. The internal structure of the zones and orebodies provides much evidence of folding. A logical conclusion would be that the zones represent a single horizon which has been folded and drag-folded in the ordinary course of mountain building. However, surface mapping, and correlation of certain marker horizons, in underground work, indicate a homo-clinal succession of steeply dipping flows. If this concept of the geology is correct, the zones must cross-cut the regional strike at a small angle and, in the over-all aspect, the regional dip at a large angle. A mechanical interpretation of the zone structure is presented as a suggestion for the present until new evidence is found.

Jan 1, 1959

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By Gonzalo Mato, Colin Godwin, G. Ditson

"The mid-Cretaceous Seagull batholith intruded Mississippian sedimentary and volcanic rocks and Jurassic(?) granitic and ultramafic rocks within the Omineca Crystalline Belt in the Yuk on Territory near the British Columbia boundary. Leucoerotic fluorine- and boron-rich granites of the batholith exhibit many textural variations from aplite to pegmatite, but are dominated by a coarse-grained seriate unit and a fine-grained porphyritic unit.Four distinctive tin vein occurrences within and near the batholith are described, the most interesting of which is the MC showing of quartz-calcite-chlorite-cassiterite veins in intensely fractured zones of sedimentary and volcanic rocks. Three other showings occur within the batholith:J) the EC showing of quartz-fluorite-cassiterite-sulphide veins with prominent muscovite-illite alteration;2) the DU showing of quartz-hematite-fluorite-sulphide- sulphide-cassiterite with considerable manganese staining and sericitic alteration; and3) the VAL showing of quartz-tourmaline-cassiterite-fluorite-arsenopyrite veins with little associated alteration.Most cassiterite occurrences are within easterly-trending, vertical structures and all occurrences are thought to represent parts of a single system. These mineralogical and physical variations are apparently related to the distance from the upper contact of the batholith.For the Seagull batholith, Rb-Sr isotopic data give a 100±1.4 Ma isochron age that is concordant with the K-Ar model age from biotite of 101±4 Ma. Initial Sr isotopic ratios for the batholith are high at 0.712, indicating an old, sialic crustal source for this pluton. This initial ratio is similar to values for granitic rocks associated with tungsten deposits in the Yukon Territory. The high initial ratio for Sr, the high Si02 content, the high s/I index, the presence of normative corundum. leucogranitic composition and associated lithophile-tungsten mineralization demonstrate that the Seagull batholith is probably an S-type granitic body. This factor is significant to regional exploration jar tin and tungsten in the Canadian Cordillera."

Jan 1, 1983