Search Documents

By W. K. Smith, V. P. Krueger, D. C. Mulder

"AbstractThis paper describes the geological procedures used to evaluate two mineable high-volatile C bituminous coal seams at Coal Valley , located in the outer foothills belt of the Rocky Mountain Eastern Slopes in west-central Alberta. Lexco Testing Ltd., the exploration arm of Luscos: Ltd., owns and operates an all -weather geophysical logging system which provides gamma, focused density , single-point resistance and caliper logs in a single pass. A mathematical analysis for a theoretical interpretation of the single-point resistance log confirms empirical research that bed boundaries are located at a point 10% from the bottom of the curve. A unique and efficient triple-tube, wireline rotary coring system cuts an undisturbed 0.076m- diameter core in a plastic liner at recoveries exceeding 90% . Although only 10% of the total footage is cored, it provides vital analytical and geotechnical data, and, when integrated with the geophysical logs, improves the quality and extends the usefulness of interpreting both sets of data. All data are programmed to produce computerized structure contour, isopach, isoratio and isoquality maps, and volume calculations.General IntroductionTHE COAL VALLEY AREA is located in the outer foothills belt of the Rocky Mountain Eastern Slopes, 60 miles (96 km) by road southwest of Edson, Alberta. Luscar Ltd. holds leases which total 49,000 acres (19,830 ha) , of which 18,300 acres (7,410 ha) have been assigned to the Coal Valley mine area (Fig. 1 ) . There are two Paleocene high-volatile C bituminous coal seams initially developed for mining within a total stratigraphic interval of 750 feet (230 m ) (Fig. 2 ). These seams strike generally NW, and in the undisturbed areas generally dip westerly from 10 to 30 degrees."

Jan 1, 1977

The use of QemSCAN in providing mineralogical input to detailed ore and product characterization has proved of immense value in recent years. In this paper, a brief review of selected Cu-case studies is presented to demonstrate the versatility of automated, quantitative mineralogy by QemSCAN. This versatility ranges from measurement and analysis strategies through to data processing and presentation. As a rapid diagnostic service, it is common to find that only grain size, the degrees of liberation and/or ore mineral modal mineralogy are of interest. By contrast, the detail afforded by the simultaneous determination of both gangue and ore minerals can alert mineral engineers to fatal flaws and attributes deleterious to processing that are directly a function of silicate and other gangue mineralogy. Examples of the latter effects include the influence of micaceous minerals and acid consuming species, while the former include fluorine minerals, which can provide both processing and environmental challenges.

Jan 1, 2007

By A. Azizi, P. Blatter, A. Bouajila

ABSTRACT In-situ monitoring of gold dissolution by means of a rotating electrochemical quartzcrystal microbalance unveiled dramatic decreases in gold leaching from sulphide-rich ore after 360 minutes in an actual cyanidation circuit. Pre-oxidation was effective in enhancing gold extraction by preventing a passive film from forming on gold surfaces. This work aims to highlight efforts undertaken to determine (1) how gold cyanidation is limited by passivation, (2) what reactions and mechanisms are involved during sulphide-rich ore cyanidation, and (3) how peroxidation efficiency of an industrial sulphide ore is controlled by galvanic associations between its sulphide constituents.

Jan 1, 2013

By Krishna Parameswaran

"This paper discusses energy use and conservation in the primary copper industry and illustrates eco-efficiency considerations, using select examples of practices at ASARCO LLC, an integrated primary copper producer and others in the industry that promote eco-efficiency. The World Council for Sustainable Business Development first publicized the concept of eco-efficiency at the Rio Earth Summit in 1992. Eco-efficiency is a management concept linking environmental and economic performance and is aimed at generating added value for a business through, among other things, increased resource and energy conservation and reduced environmental impacts throughout the life cycle of the product or service. This concept differs from sustainable development in that focus is only on economic and environmental factors and does not include social considerations. In the metal mining and processing context, this added value can be realized by implementing practices that promote conservation of water and mineral resources, conservation of energy, minimization of waste, reduced emissions and effluents and increased recycling. The examples from the primary copper industry used to illustrate eco-efficiency considerations include: water and energy conservation in mineral processing, adoption of flash and bath smelting processes, emission reduction and process improvement associated with fire-refining, implementation of green chemistry in electrorefining, promoting product stewardship initiatives and fostering renewable energy project on disturbed mined lands.INTRODUCTION ASARCO LLC (Asarco) was organized in 1899 as the American Smelting And Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co-products. Grupo México, S.A.B. de C.V acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, molybdenum, selenium and tellurium. Asarco operates three open-pit mines and mills, two leach, solvent extraction-electrowinning (SX-EW) plants and a copper smelter in Arizona and a copper refinery in Texas."

Jan 1, 2017

By C. A. Sosa-Blanco

Minera Sabinas in central Mexico treats a complex sulfide ore containing galena, chalcopyrite, sphalerite and argentite as valuable minerals, and in some cases important amounts of non-magnetic pyrrhotite. For high pyrrhotite ores, results obtained by selective flotation showed good grades and recoveries in the lead-copper circuit, but a commercial zinc concentrate could not be produced due to the high floatability of pyrrhotite. When this is the case, an alternative method was proposed to produce a bulk concentrate by flotation which is then leached to recover copper and zinc from liquor in a SX-EW circuit. Leaching was conducted in an autoclave in order to study the effect of temperature and pressure, but bioleaching tests were also conducted. Leaching lead-silver residues were treated by cyanidation in order to recover silver values. The results obtained by selective flotation and by bulk flotation with leaching of the bulk concentrate showed that the latter alternative increased zinc recovery by 30 % with similar recoveries of the other metals.

Jan 1, 2007

By L. B. Tsymbulov, N. A. Fedorova

The equilibrium of exchange reaction (Cu20)+[Ni]=(Ni0)+2[Cu] taking place in the course of interaction of metallic nickel-containing copper melts with different oxide melts (Cu20-NiO, Cu20-NiO-Si02, Cu20-NiO-FeO(Fe203)) in the area of their homogeneity has been studied. The studies, based on the known value of equilibrium constants and defined copper and nickel activity indices in metallic melts and equilibrium concentrations of Cu, Ni, Cu20 and NiO, determined the YNio/ycu2o ratios in the oxide melts of the above systems. For the equilibrium between nickel-containing copper and binary oxide melt Cu20-NiO, values of YNiO and Ycu2o were determined both by calculation and experimentally. Based of the data conclusions regarding oxide melts construction are presented.

Jan 1, 2007

By T. Vovan, A. Galibois, M. Fiset

"In order to establish some links between the 22 specimens found on the site of Les Forges du St. Maurice, their slag inclusions have been analyzed by electron microprobe. Comparison between their contents of various specific oxides allowed us to segregate them into two major groups and even to isolate two sub-groups possibly characterized by some equilibrium between their oxides and/or the type of ores used.In all probability, limes/one coupled systematically with a soil rich in hydrated aluminum silicates was used as a flux.Based upon the existence of a pseudo equilibrium between the slag and the metal, the elaboration of the bulk of the specimens can be ascribed to the indirect rather than the direct method whereas the process temperature can be estimated at at least /400°C.RESUMEDans le but d'etablir des liens entre les 22 objects provenant des Forges du St-Maurice, leurs inclusions de scories ont été analysées par microsonde. La comparison des teneurs en divers oxydes a permis de les séparer en deux groupes majeurs et même d'y distinguer deux sous-groupes pouvant être reliés à la forme d'équilibre entre certains oxydes et/ou au type de minerai utilisé. Selon toute vraisemblance, le fondant utilisé était de la pierre à chaux à laquelle on ajoutait systématiquement une terre riche en silicates hydratés d 'aluminium.Des considérations sur l'existence d'un certain équilibre entre les scories ei le métallaisset croire que la plupart des objets ont été élaborés plutôt par la méthode indirecte que directe et que la température d'élaboration se situait à au maint 1400°C."

Jan 1, 1984

By P. -A. Bosse, J. Robitaille, P. Blatter

The LaRonde ore is a Cu-Zn-Pb ore with gold (3-4 g/t) and silver (60-100 g/t). The precious metals are recovered with copper concentrate, zinc concentrate and cyanidation of zinc tails via Merrill Crowe precipitation. Subsequent to a recent mill expansion, excessive gold was reporting to zinc concentrate with a concurrent decrease in gold to copper concentrate. Owing to the higher return obtained from the metal, the mill endeavors to recover additional gold and silver to the copper concentrate and minimize the placement of precious metals to the zinc concentrate. A gold deportment study showed that the gold occurs mainly as küstelite, with a moderate amount of electrum and a minor amount of native gold. It also showed that various sulfur-based Au-and/or Ag-bearing coatings on liberated küstelite and electrum were the major mineralogical factors that caused gold and silver to report to zinc concentrate. By frequency, such coatings were observed on 70-80% of total liberated gold particles reporting to the zinc concentrate. Based on the gold deportment and the chemistry of the coatings, the collector chemistry was reviewed and a new collector was added into the circuit which resulted in a significant increase in gold and silver recovery to the copper concentrate. The information obtained from the mineralogy confirmed and guided other process optimization. In this paper, the authors will describe the process mineralogy of the LaRonde ores, and in particular, the mineralogical evidence diagnosing the problem. Reference will also be made to the rationale behind how the problem was solved, the results achieved, and future steps in optimization.

Jan 1, 2005

By A. Valdivieso

Reducing accident rates keeps getting more and more complex as the usual tools enter a curve of diminishing results. Fortunately, nothing modifies behaviour in a stronger and wider way than having a robust safety culture. On the other hand, managing cultural change is difficult and the risk of back-fire is very high, especially if the workforce does not trust our intentions. A personalized approach of well chosen and targeted actions tends to be the only yet difficult option. We have found, via experience in the metallurgy and chemistry industries, a way of preparing the company and the workforce to accept these sorts of culture changing measures faster and easier. Using company-wide changes based on workplace perception, yields the most optimal acceptance. It is based in the principle that we all use clues in our environment as guides to choose our behaviour. So, controlling the perception that our workplace generates can affect behaviour and simplify our task before it even starts. It is a matter of using the tools that other disciplines such as marketing, social engineering and architecture bring to us and adapting them to a very defined objective: Having our installations “sell” safety so that our people unconsciously believe that they must adapt to safety values in order to “do well” in said environment. INTRODUCTION After decades of improvements in accident rates, we are understandably hitting a diminishing results curve: most actions that spectacularly reduced accidents in the past (e.g., Innovation in Personal Protection equipment, adapting international standards and legislation, and innovative safety programs; Figure 1) now hardly get us the exponential gains we saw years back, regardless of the investment we put on them. Furthermore, the improvements in safety of the last 3 decades have been creating new sets of issues that start to show their face such as: By reducing accidents we can create feelings of invulnerability as we lose view of the consequences. With innovative protection equipment we increase Risk Homeostasis, meaning that people behave in a more dangerous way in order to maintain a constant level of risk in their lives (Getting closer to fire after getting better fire-proof garments for example). Too much Legislation can create a feeling of disengagement from personal responsibility. And despite improvements, we haven’t really solved the production vs safety confrontation, it is now stigmatized and less visible, yet it tends to reappear in moments of weakness.

Jan 1, 2019

By N. J. Duncan

"Coal mining, whether surface or underground, has hazards that make it unique in the field of industrial safety and health. The often soft, faulted and folded sedimentary strata make wall or roof movement a risk to the safe and economic removal of the coal, while the extraction and handling of coal may create an explosion hazard even in surface operations, In Canada, these problems are compounded by the situation of the coal fields which range from deep undersea deposits in Nova Scotia to steeply pitching thick coal seams high in the Rocky Mountains. Climate too can create its own problems, particularly the effect of metals of minus 40°C temperatures, as crumpled dragline booms at prairie strip mines witness. Because of the difficult and sometimes hazardous conditions, Canada's underground colliery managers, in common with those of other Commonwealth coal-producing countries, must have a government ""certificate of competency"" before being appointed as mine managers. Certification of assistant managers (""under-managers"") and foremen (""fire-bosses"") is also a legal requirement for all of Canada's underground collieries, while the province of Alberta requires certification of surface management personnel. Electricians and mechanics who install and maintain the specially designed equipment underground and in hazardous areas of surface mines and processing plants, and mine surveyors who ensure accuracy of the location of underground workings, must also hold government certificates of competency. The requisites for all certification include a minimum work experience and knowledge of coal mining technology and mine safety and health legislation. Despite recognition of the hazards and increasing knowledge of methods of preventing explosions of flammable gas and coal dust in Canada's underground mines, there have been several disastrous explosions such as those at Springhill Colliery in Nova Scotia in 1891 with the loss of 125 lives, at Hillcrest Colliery in Alberta in 1914 with 189 dead, and more recently · explosions and fires in No. 20 and No. 26 Collieries in Cape Breton. Preventing explosions has required developing optimal ventilation techniques, reducing ignition potential, suppressing ignition at source, draining flammable gas before it can enter the air courses, and preventing, or sealing off, autogenous heatings with their associated carbon monoxide or explosion dangers."

Jan 1, 1985

By C. R. Larsen, R. G. Bradburn, A. L. Mular, B. C. Flintoff

"Following the acquisition of grinding- circuit data at Brenda Mines Limited for simulation purposes, various methods to mass balance the circuit were evaluated. Unfortunately, different answers were obtained for different balancing methods. A data-adjustment procedure was therefore developed. The procedure assumes that all ""best-fit"" criterion. A search is conducted with the minimum set of water masses and narrow size ranges of solids around the circuit (called search variables), which permit the computation of any of the measured data points. Search variables are used to calculate measured values for an objective function of the form: [ ] where W, is a weighting factor•, M1 is a measured value and M. is a corresponding . value calculated from search vanables. The best values of M, are those which minimize R. The above method is compared with others that have been utilized for mass balancing circuits."

Jan 1, 1976

By G. A. Vissac

IN THE preliminary design of a coal washery, the most important factor to evaluate is the ash content of the final product. The ash content permissible may be imposed by market demands, but, in the final analysis, sooner or later - as most consumers today are buying coal on a 'heat value' basis - the coal operator has a certain margin of latitude. and the ash content of the coal to be delivered can be determined on the basis of maximum returns and highest profits. A few years ago, the most desirable separation was selected on the basis of the plus-minus 0.10; that is, the most desirable gravity of the separation was selected at the point showing a minimum amount of near gravities in the raw coal. The reason for this was an expected wide error over these near gravities. Today with the recent development of cry accurate, automatically controlled cleaning apparatus, a much larger latitude is possible, and the most desirable gravity of separation can be selected, almost exclusively, on the basis of the economic factors involved. To illustrate these new methods of investigation we shall give two examples, based on actual coals from the western United States.

Jan 1, 1957

By E. C. W. Perryman

Materials research and development has played an important role in the commercial success of the CANDU- PHW nuclear reactor and in the production of heavy water. Both capital investment and energy conservation demand very high component reliability in such systems. The interactions among reliability, plant performance and economics will be discussed in relation to materials research and development. Likely materials requirements for the nuclear industry over the next twenty five years will also be discussed.

Jan 1, 1977

By W. G. Millar

Until a fire occurs, insurance and prevention work are often looked on as unavoidable necessities, but as insurance is back of all business credit, it is essential to know that in case of damage money will be available to cover the loss; while the interruption of production, often caused by a fire, brings home the realization that if prevention work avoids such an interruption, it is well worth while. Fire insurance is a legal contract guaranteeing the payment of large amounts to an owner, but it is possible there is no other important contract that receives so little consideration. Although previously carried on elsewhere, it is only of recent years that insurance engineering has been actively followed up in Canada, with inspections of an owner's property carried out for his benefit. Now inspections of this kind are made, advice on fire prevention and protection work ?is available, reports with recommendations with regard to the above are furnished periodically, and with this method applied the owner receives the broadest possible cover and security at the lowest cost. Rates are set by the underwriters by rating schedules which charge for defects in a building and allow credits for protection and other favourable features . These schedules are based on the past record of loss of mining properties as a class, so that a fire in another mining property indirectly affects you, but the amount paid is reduced in proportion as your property is improved. The writer feels, from personal experience, that there is no industry where fire prevention receives more attention than the mining industry, and it is a pleasure to advise that, due to this co-operation, some reduction in the basis rates for mining risks is now being made by the underwriters.

Jan 1, 1928

By D. M. Baird

"THE Island of Newfoundland lies on the extreme eastern edge of the continent of North America and at the extreme northeastern end of the Appalachian geological province. Its belonging to the Appalachian province is shown in the geological history of the region and in the rock types and structures.Geosynclinal sedimentation in early and middle Palaeozoic times was interrupted by Taconic and, more profoundly, by Acadian, mountain building activity. Mid-Palaeo-zoic intrusions range from masses of serpentinized ultrabasic rocks to granite batholiths. A Carboniferous overlay of continental and shallow, drying sea types covers the earlier developed complex. Local basins in these times were filled with products of the erosion of tl1e earlier rocks, and, locally, grew the right kind of vegetation to make thin, discontinuons seams and pockets of coal. Post-early Pennsylvanian history is one of erosion and pene-planation with renewal of movement along many of the older fault systems."

Jan 1, 1960

By K. J. G Hedges

"Once a health based guidance limits for exposure to diesel exhaust have been established, and as part of a multi-disciplinary team, the program for exposure reduction should incorporate the plan-do-check-adjust cycle. Setting a suitably protective (health based) occupational exposure limit (OEL) for diesel particulate matter (DPM) and nitrogen dioxide is a key driver to reduce exposure. It is important to go beyond regulations and reduce exposure to diesel exhaust, DPM, as low as reasonably achievable (ALARA) such as that prescribed under the Australia, Queensland Mining and Quarrying Safety and Health Regulation 2017 where under section 135 Limiting workers exposure, the workers exposure must not exceed the exposure limit applying to the worker for the hazard; and is ALARA. It appears that previously acceptable OELs are no longer safe. Therefore it is important that the internal responsibility system be implemented and the precautionary principle approach be followed, especially as it may be some time before a suitably protective OEL specifically for DPM is in place. One leading multi-national mining company BHP Billiton has acknowledged a significant lag that exists between regulatory action and the level of science that informs health risk. This company is managing exposure to diesel exhaust to as low as technically feasible. This same company that has set an interim target for managing diesel exhaust to 0.03 mg/m3 is achieving these levels which paves the way for other mining companies and general industry including construction. The Occupational Cancer Research Centre 2017 recommends reducing personal exposure to within 0.02 mg/m3 (EC) for underground mining and 0.005 mg/m3 for other workplaces. Controlling DPM is important to prevent cancer however it is also important that that nitrogen dioxide (NO2) be reduced (ALARA) and that careful selection of control technology be considered such as the proper selection of a diesel oxidation catalyst so that the level of NO2 does not in fact increase. The example from BHP Billiton provides a leading practice including using a multi-disciplinary approach and the importance of controlling emission at source and having an auditable diesel emissions based monitoring program in place."

Jan 1, 2019

By A. Montera, M. Loken

"The process of blending consistent and predictable feed for the roasters is critical for optimizing product quality and controlling production costs. To assist in this process, online PGNAA slurry analyzers have been installed and evaluated at a Sudbury Ontario smelter. They are used to measure 100 % of the full process stream to obtain elemental composition data in real time. This paper explains the application details at Sudbury and the benefits achieved from their full stream, elemental slurry analyzers.INTRODUCTIONSudbury Integrated Nickel Operations (Sudbury INO), a Glencore Company, consists of two underground nickel/copper mines in Sudbury, Nickel Rim South and, Fraser, along with the Strathcona mill and the Sudbury smelter. The facilities are spread throughout the 60 kilometer-long, oval-shaped geological formation known as the Sudbury Basin (Figure 1). The company has been mining nickel-copper ores in the Sudbury area since 1929. Nickel and copper are the primary focus of operations at Nickel Rim South and Fraser. Other base metals such as cobalt and precious metals are also produced.The Strathcona Mill receives ore from Nickel Rim South, Fraser, and third-party miners to produce two concentrate streams. One is a nickel-copper concentrate for use by the Sudbury Smelter; the other is a copper concentrate which goes to other Glencore operations for smelting and refining. The Sudbury Smelter converts the mineral concentrate into a high grade matte containing nickel, copper, cobalt and platinum group metals. This matte product is shipped to Glencore's Nikkelverk refinery in Norway for further processing. In 2015, the Sudbury INO Smelter completed the first phase of the Process Gas Project (PGP); a series of process changes and capital investments designed to reduce sulphur dioxide (SO2) emissions in accordance with Ontario Regulation 194. A critical element of the planned emissions reduction was the elimination of a higher percentage of sulphur contained in input concentrate streams, which can then be captured and converted to sulphuric acid."

Jan 1, 2017

By D. B. Hyma

"The Raglan Ni/Cu property is located on the Ungava Peninsula in Northern Quebec, Canada, at a latitude of61°42' and a longitude of73°40', approximately 40 km southwest of Douglas Harbor. Geological reserves are estimated at 18 million tonnes, grading 3. 1 % nickel, 0.9% copper and smaller amounts of cobalt and platinum group metals.Extensive project development has defined the concentration process, concentrator sizing, tailings and environmental management required for this project.The grinding circuit selected is a fully autogenous primary grind, with pebble crushing and a pebble mill for secondary grinding to produce a product of 80% -70 microns for flotation.The flotation circuit is a simple circuit utilizing roughing, a regrind of rougher concentrate to 80% -20 microns, two stages of column cleaning with a cleaner scavenger bank on the column tails.Concentrate handling options were thoroughly reviewed because of the pyrophoric nature of the concentrate, remote site location and long distance to downstream processing. The preferred option, currently.is to dry the concentrate at Raglan to less than l % moisture and then pneumatically handle the powder.A detailed analysis of tailings placement options, suggests filtered tailings placement to be the preferable route for the Raglan site.INTRODUCTIONThe Raglan Project, as proposed by Falconbridge Limited, will develop extensive nickel-copper deposits in the Ungava Peninsula, Quebec, Canada. The project schedule and construction conditions in the project area are demanding. The Raglan mineral deposits have been the subject of numerous studies and evaluations over the last thirty years and the Phase I 1991 pre-feasibility document includes exploration information obtained in the 1989 and 1990 drilling seasons. This review concluded that an 800,000 tonnes of ore per year mining and concentrating complex located at Katinniq could produce 20,000 tonnes per year of nickel at competitive costs."

Jan 1, 1993

By T. N. MacAuley

"The Ingerbelle and Copper Mountain deposits are located near Princeton in southern British Columbia. They are owned by Newmont Mining Corporation's wholly owned subsidiary, Similkameen Mining Company Ltd. The property includes the Copper Mountain mine, a former producer. Ore reserves recoverable by open-pit mining are estimated to be 76 million tons containing 0.53% copper. Production commenced during 1972 at a rate in excess of designed capacity (15,000 tpd). All of the known major copper deposits in this area lie in a 14,000- by 3,500-foot belt of Triassic volcanics (Nicola Group) that is situated between a well-defined syenitemonzonite- diorite stock on the south and a variable intrusive complex on the north. The Nicola rocks consist of andesitic tuffs and agglomerates with lesser amounts of flows and some lensy siltstone layers. The orebodies are essentially disseminated sulphide deposits, although fracture-fillings are also important in many areas. Total sulphide content is usually less than 5%. At lngerbelle, and at Pit 2 and most of Pit 1 at Copper Mountain, the sulphides are chalcopyrite-pyrite. In part of Pit 1 and most of the former underground mine they are chalcopyrite-bornite. At lngerbelle the predominant alteration associated with mineralization is a pale greenish-gray bleaching of the dark andesitic rocks. This has been identified as albitization, with lesser amounts of epidote, chlorite, biotite, scapolite and calcite. This bleaching is plentiful at Pit 2, but K-feldspathization is also evident here. These orebodies can better be classified with pyrometasomatic deposits than with typical porphyry coppers. Their relationship to intrusives, the probably extensive metasomatic replacements, the evidence of pneumatolytic activity, the formation and redistribution of magnetite, and the irregular distribution of mineralization are all characteristic of this class. Deep-seated faults probably acted as channelways for mineralization; fracturing, faulting and rock contacts influenced ore localization in detail."

Jan 1, 1973

By Donka H. Andreeva

Gold catalysts based on different supports, titania, zirconia, ceria and mesoporous titania and zirconia, nonpromoted and promoted by vanadia in the reaction of complete benzene oxidation have been studied. XRD, HRTEM, TPR, Raman and ESR spectroscopy were applied for the characterization of the catalysts. The influence of gold on the reduction behavior, state and structure of vanadia on the surface was studied, as well as the role of supports nature on the properties and catalytic activity. A strong synergistic effect between gold and vanadia was observed for the all studied catalysts with an exception of the catalysts supported on mesoporous zirconia. In the last case the catalysts containing gold and gold-vanadia exhibit high and equal catalytic activity. The catalysts on ceria show highest and stable catalytic activity in the studied reaction among the all studied catalysts.

Oct 1, 2003