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By A. M. Bell

General Summary THIS paper attempts to describe in a preliminary and general manner the nature of certain copper discoveries now being developed by Gaspe Copper Mines, Limited, in Holland township, in the interior of the Gaspe peninsula. Some copper mineralization appears to have been known here at the time of the earliest French explorations, was rediscovered in 1921, and has been under intermittent development by Noranda Mines since 1938. In the last two years discoveries have enhanced the picture so that the deposit now promises to develop into one of the important Canadian copper producers. As ideas are constantly changing with continuing development, any picture given now is very partial and tentative and must be subject to future revision. The nature of these copper occurrences differs from others known in eastern America. In many respects they have unique features but they are most closely akin to some copper deposits found away from the intrusive rocks in the porphyry copper districts of the western United States. The most important orebodies are replacement deposits in a limestone horizon in which the ore gangue is converted to skarn. These lie at considerable distances from any known intrusive but seem to have been derived from a buried stock of granite that intrudes the sedimentary rocks of Lower Devonian age. This intrusive has produced alteration effects in the overlying rocks that may afford a key to locating other ore areas in the Peninsula.

Jan 1, 1951

By W. D. Watson

"Early in mine development at Quintette Coal Limited major problems were encountered with the fleets of primary equipment which seriously hampered production. These major fleets (cable shovels, hydraulic shovels, hydraulic drills and electric trucks) have consequently been the focal point of maintenance efforts. Some were prototypes in the Canadian mining scene and brought with them new concerns to test their skills. The problems were studied and the category and areas which were having the greatest impact on the reliability of the equipment were determined. Once defined, priorities were established and a program was initiated which was designed to accomplish a resolution. Resulting from implementation of this systematic approach, over the past three and one-half years, the fleets are now giving good reliability and industry standard availabilities. Along with these significant achievements, cost per operating hour on some of the equipment fleets has decreased substantially and continue a downtrend through 1987. This paper identifies the problems and describes the resolutions. IntroductionIn the early years of the mine development, Quintette Coal Limited (QCL) experienced production shortfalls due to problems with the major excavator and haulage fleets. A large fleet of hydraulic excavators had been purchased, and QCL was among the first northern users of all hydraulic blasthole drills. They were also using some prototype equipment and encountered problems which were not common on other types of equipment or were unknown.Because of these unique problems and lack of experience from other mines to draw on, an analytical approach was taken to areas and associated causes of the delays affecting the availability and reliability of equipment. This was done by dividing the equipment downtime into seven classifications of delays, i.e. maintenance, electrical, hydraulic, mechanical, damage, service and preventative maintenance, and tires; and then each was expressed as a percentage of total downtime. Subsequently each of the delay classification was divided into categories e.g. electrical to six categories - wheel motors, main alternator, relays, cards, no propel, lighting and 24 V system. Then, the basis for further study had been established.From this preliminary analysis of historic records, it was possible to determine the areas which were causing the majority of the downtime. These areas were then analyzed to evaluate causes and to determine possible solutions to the problem s. This paper addresses the major fleets, their problems and eventual solutions. Plea se bear in mind that the over-all objectives were to increase physical availability and reliability."

Jan 1, 1988

By van der Meer. F. P.

High Pressure Grinding Roll (?HPGR?) technology is applied in a broadening range of minerals processing applications for relatively wet or moist materials. HPGR grinding of dry material or involving drying and air classification is more common, for example in cement manufacturing. A number of minerals processing plants are also operating with dry material, either due to process reasons, such as considerations of preceding or subsequent process stages, or as dictated by local conditions of arid areas and scarcity of water. The present world-wide expectation of decreasing availability of water supply urges us to look for alternatives that minimize water consumption. Recently established and envisaged future HPGR applications with dry ores have indicated that the technology of dry crushing and classification as practiced in cement and limestone grinding can be applied in minerals processing. Moreover, dry technology could very well be applied for generating a final fine product at sizes near or below 100 microns, as may be required for beneficiation by, for instance, flotation, magnetic separation or tank leaching. Dry HPGR grinding requires special attention in maintaining suitable process economics, when considering power input in grinding, drying and classification. In some cases, HPGR capacity and roll surface wear life may be negatively affected by a lack of moisture in the feed. This publication summarizes some of the features of, and experiences in dry HPGR applications. This includes design aspects of the classification system and discussion of the wear protection of the roll surfaces. The paper also includes examples of operational experiences of dry practices in minerals processing and cement plants.

Jan 1, 2012

By A. S. Romaniuk

More than a decade ago, CANMET management recognized the need to make better use of existing technological information in mining and extractive metallurgy-two fields basic to the economic well-being of Canada. There were at that time no indexes or files dedicated to disseminating technical information for the many minerals mined and processed in Canada, including coal. CANMET, with the nation's largest research and library resources in the minerals field, was in a unique position to fill this need. Initial efforts were concentrated on building a mining file, beginning with identification of world sources of published information, development of a special thesaurus of terms for language control and adoption of a manual indexing/retrieval system. By early 1973, this file held 8,300 references, with source, abstract and keywords given for each reference. In mid-1973, operations were computerized. Software for indexing and retrieval by batch mode was written by CANMET staff to utilize the hardware facilities of EMR's Computer Science Centre. The resulting MINTEC file-one of the few files of technological information produced in Canada-is the basis for the national literature search service in mining offered by CANMET. Attention is now focussed on building a sister-file in extractive metallurgy using the system already developed. Published information sources have been identified and a thesaurus of terms is being compiled and tested. The software developed for CANMET's file-building operations has several features, including the selective dissemination of information and production from magnetic tape of photo ready copy for publication, as in a bi-monthly abstracts journal.

Jan 1, 1979

"An unparalleled growth in the Canadian coal industry in 1970 coincided with increasing awareness by Canadians of their environment and their geography with its accompanying transportation factors. R and D on coal moved with greater emphasis toward solving problems in these areas as well as continuing with strong interest in coal preparation, carbonization, combustion, ""weathering'', spontaneous ignition, storage, exploration and geology. Long-range ""basic"" research was not forgotten in that work continued on coal-based carbons, coal chemistry and agrobiological uses for coal. This paper reviews the status of these many areas of coal research at the beginning of the seventies and takes note of some of the more significant legislation and projects brought to the author's attention. No attempt is made to itemize or to describe in detail all the worthwhile projects, many of which are reported elsewhere."

Jan 1, 1971

By Erwin L. Zodrow

"IntroductionThrough an extensive coal sampling project in the Sydney coalfield of Nova Scotia during 1981 - 1984 involving a majority of the mineable coals (Zodrow, 1985, Fig. 1), a sizeable inventory on trace, minor and major metals was established. In this paper, results of studying the inventory are summarized, concentrating mainly on the relationship that exists between metal variations and thickness of coal channel samples (i.e. trends) and on explaining the trends in geochemical and sedimentological terms. As an over-all conclusion the Everglades peat of Florida is proposed as a modern-day analogue to Upper Carboniferous peat swamp development that took place in the Sydney Basin.Data InventoryFor this study 17 channel samples were cut , 8 cm to 14 cm channel width and 8 cm to 10 cm depth, from 10 successive coals which in stratigraphically descending order are as follows: Point Aconi (3), overrider Lloyd Cove (2), Lloyd Cove (2), Stubbart (2), Harbour (4), Backpit (I), Phalen (,I), Shoemaker (1) and McAulay (I), where bracketed values signify the number of channel samples cut from a seam (Zodrow, 1985, Fig. I). Each channel sample was subdivided by 15 em incremental length yielding a total sample size of 137 for analysis. By appropriate modern techniques these samples were analyzed to determine concentration levels for 32 chemical elements and ash content, the average results of which are presented in Table 1.Tests were also made for Pd, Pt, Ga, Nb, Cd, Cs, Sm and W but their concentration levels in many instances hovered on the lower detection limits that were used and on this accounts are excluded from discussion. Ashing, when necessary for the determination of concentration levels, was done for 12 hours at a temperature not exceeding 450°C. Concentration levels for the elements are reported in reference to whole-coal or whole-coal equivalents and discussed on this basis. In the course of the analyses, lower detection limits received careful attention."

Jan 1, 1986

By Engineering Staff

"This paper briefly describes the surface mining operations at Smoky River Coal Limited (formerly McIntyre Mines Limited, Coal Division) near Grande Cache, Alberta. Geology, mining methods, equipment, manpower and reclamation and environment topics are discussed. Introduction Smoky River Coal Limited, a wholly-owned subsidiary of McIntyre Mines Limited of Calgary, Alberta, produces a high quality, low sulphur, low volatile bituminous coking coal from its minesite located at west central Alberta, approximately 20 km from the town of Grande Cache and 360 km west of Edmonton (Fig. I). Most of the coal property is contained within a 30 km long by 20 km wide block lying in a northwest-southeast direction in mountainous terrain. Elevations vary from 920 m above sea level ·at the plant·site on the Smoky River to 1,600 mat the upper levels of current and proposed mining operations. A total of 11 coal seams have been identified. Only two seams, No. 4 Seam and No. 10 Seam are currently considered of major commercial value. These seams are recovered by both surface and underground mining. Approximately 650Jo of the plant feed coal is obtained from a conventional shovel/truck surface mine; the balance is mined underground by room-andpillar methods. Background In 1921, McIntyre Mines Limited acquired some 26,300 hectares of coal leases at Smoky River. Since then the leases were explored intermittently by different companies including McIntyre. In the mid-l 960s exploration activities increased and several feasibility studies were completed. Development of the area was undertaken by McIntyre in 1968 and, in August of the same year, a long-term contract was signed with a consortium of Japanese steel mills for delivery of 2 x 106 t of clean coking coal for 15 years commencing in 1970. Production was focussed on underground mining, using longwall methods."

Jan 1, 1985

By W. C. Whittaker

"This paper gives a brief resume of the changes in the market picture for Western coal since 1948. It then analyzes present markets and recent developments in Western Canada, the western United States and Japan, and forecasts future markets in these areas to 1975.INTRODUCTIONCOAL HAS BEEN MUCH IN THE NEWS OF LATE, both in the United States and in Canada. In the United States, this is because of the booming condition of the industry and because of the purchase of control of a number of America's largest coal producers by the integrated oil and metal producing companies seeking additional fossil fuel reserves and diversification. In this regard, it is interesting to note that ownership of America's largest strip coal producer was recently acquired by one of the world's largest copper mining companies. In Canada, the conclusion of several large-scale, long-term contracts for the sale of coal to the Japan Steel Group and the projected use of Canadian coal in steel mills in the western United States has focused much attention on the coal industry."

Jan 1, 1968

By M. Yamine, R. J. Ring, D. J. Waters

"An experimental program has been carried out by the Australian Atomic Energy Commission to compare the effectiveness of Caro's acid as an alternative oxidant to pyrolusite in the leaching of uranium ores from the Alligator Rivers region of northern Australia. Batch leaching tests on Ranger, Nabarlek, Koongarra and Jabiluka ores showed that uranium extraction was unaffected by choice of oxidant, but that Caro's acid reduced acid requirements by 15 - 25%. Lime requirements for neutralization of tailings liquors were reduced by 20 - 30%.The batch studies were extended to a four-stage continuous leaching circuit with a capacity of 400 gore h-I. Comparative leaching tests confirmed the reagent savings obtained in the batch tests. Following these encouraging laboratory results, lnterox Chemicals Pty Ltd carried out plant trials using Caro's acid. Reagent savings in the mill were similar to, or better than, those obtained in laboratory test work. The trials also established that Caro's acid has a number of operational advantages over pyrolusite.IntroductionUranium is most commonly extracted from its ores by leaching in sulphuric acid. Simple hexavalent uranium oxides and compounds are readily soluble but uranium in the tetravalent form is insoluble and must be oxidized for dissolution to occur. The most commonly used oxidants have been sodium chlorate and manganese dioxide. They act indirectly by maintaining iron as the ferric ion which oxidizes uranium by a surface electro- chemical reaction. An Fe3+ concentration of about 1 - 2 g L-I is usually considered adequate for the effective dissolution of uraninite(1)."

Jan 1, 1984

By B. Caldwell

"The CompanyCardinal River Coals is jointly owned by Luscar Ltd. and the Consolidated Coal Company of Canada (Consol). The Luscar mine is operated by Luscar Ltd. and is located 40 km south of Hinton near Cadomin, Alberta (Fig. 1). The plant sits on the old townsite of Luscar, Alberta, which was founded in order to develop the coal in 1912 (Fig. 2). Initially, the coal was mined by Luscar Ltd. for heating and steam generation and used quite heavily by the railways for their steam locomotives. In 1955, the mine was decommissioned as the demand for coal for tl1ese purposes had dropped off. In 1969, the mine was re-established by Cardinal River to provide metallurgical coking coal for its customers in Japan. The coal is mined from the 13m thick Jewel Seam by open pit methods at a 10 to 1 stripping ratio. The run-of-mine coal is then cleaned to meet customer demands.The PlantThe clean coal preparation facilities at Cardinal River were extended in 1980 in order to increase the feed rate from 450 t/h to 800 t/h. The extension is a separate plant which can be operated on its own or in parallel with the old plant. In addition, modifications have been made to the fine coal circuit (hydrocyclones added), the coarse refuse circuit, (refuse bucks replaced by a refuse conveyor which backfills a pit), and the fine refuse circuit (solid bowl refuse centrifuges, refuse classifying cyclones, and hydra-rake thickener no longer utilized) since the plant was built in 1969. The plant production of 3 M t per year with a yield of 78% is achieved by first screening and breaking the run-of-mine material to a top size of 1 ½ in. The feed is then slurried, sized, and processed in three different washing circuits. The washed coal is mechanically dewatered, thermally dried, and then stored in a 14 500 t capacity silo or on a 300 000 t stockpile. The fine refuse is thickened and pumped to the same pit to which the coarse refuse is being conveyed"

Jan 1, 2000

By J. H. C. Scrimgeour, T. Toong, R. E. Hamilton

"The principles involved in the use and application of mathematical models as an aid to the development of advanced process control computer systems are described briefly. This is followed by a brief survey of known models of this kind for the simulation of mining industry processes.The main part of the paper describes a dynamic model of the flotation process developed by Canadian General Electric. Using flotation rate constants for each species of mineral and gangue, the model provides a numerical solution of the differential equations describing cell behaviour. The cell mode] is used repeatedly as a subroutine in the •over-all-plant model. The features of the cell and plant models are described.Simulation runs from the plant model show stream .assays and other indications of plant behaviour printed typically in 1-to 10-minute steps for several hours of •Operation following typical disturbances such as changes in feed rate or reagent addition rate. The simulation can :Show expected behaviour for both uncontrolled and computer-controlled plants."

Jan 1, 1970

By R. O. Burt

The original flowsheet of the TANCO mill consisted of a simple two-stage gravity circuit for the recovery of the tantalum concentrates. With decreasing grade and grain size of the tantalum minerals, considerable modifications to the circuit have been required. This paper discusses the various recent improvements carried out 011 all stages of the flowsheet, which have resulted in a 10% increase in recovery. Future improvements, including on stream analysis, and the possibility of tantalum flotation , are also discussed.

Jan 1, 1979

By L G. White

During 1958, prospecting parties working for the Mackenzie Syndicate in the Flat River area of the Mackenzie mountains, Northwest Territories, identified tungsten mineralization and located the property now being developed by the Canada Tungsten Mining Corporation Ltd. Scheelite mineralization, associated with pyrrhotite and minor chalcopyrite, occurs in lime silicate skarn replacement zones within a limestone-chert-argillite series intruded by granitic dykes originating from the ? main batholithic mass underlying the sedimentary beds. The results of surface outcrop sampling and 15,000 feet of grid-pattern diamond drilling have been combined to outline an orebody estimated to contain 1.32 million tons, grading 2.51 per cent WO after applying a 10 per cent dilution factor for mining purposes. T HE property of Canada Tungsten Mining Corporation Ltd. is located in the upper Flat River area of the Mackenzie mountains, Northwest Territories. Skarn-type replacement deposits containing scheelite mineralization are .situated between elevations of 4,500 and 5,500 feet above sea level along the east flank of the mountain range forming the boundary between the Yukon Territory and the Northwest Territories. The nearest supply center for the area is Watson Lake, Yukon Territory, located at Milepost 635 on the Alaska Highway.

Jan 1, 1963

By W. M. Goodwin

The gold district of northwestern Quebec, though it has attracted such widespread attention during the past year, is still in the prospect stage throughout, and one must preface any remarks about it with the plain statement that its capacity to produce gold commercially is still subject to proof. However, this proof may be forthcoming any day, and from widely separated localities. Consequently it is of interest to note some of the features of the region and of the prospects now being developed. First I shall note the relation of this mining development to the province of Quebec and to the Dominion; then will follow a brief resume of the known geological facts; and finally I shall describe briefly some of the more advanced prospects developed during the past twelve-month. Those that have followed closely the fortunes of the new gold-field will find little that is new in what follows, but it may serve a useful purpose for others by bringing together scattered items of information and presenting them as a whole. GOLD MINING AND AGRICULTURE First let us consider the gold belt in its relation to the province of Quebec. Apart from the world-renowned asbestos camp south of the St. Lawrence, it is the only mineral development of major importance the province has experienced. It is the first important development in the province's vast area of Precambrian rocks, most of which remains as yet totally unexplored and unprospected. The relative importance of this first mining camp in northern Quebec cannot as yet be gauged, but it is bound to stimulate an active interest in the other mineral-bearing areas now known to exist, and in the vast unexplored spaces.

Jan 1, 1924

By Bai-ru Xia, Cang-qin Jia, Qi-wu Huang

Limit Analysis Theorems has revealed to be a powerful tool for the development of numerical models aiming the determination of the load bearing capacity of structures reached by plastic collapse. This work presents a numerical formulation for the computation of strict upper bounds of the collapse loads of rigid-perfectly plastic mechanical systems, derived within the kinematical theorem framework. A key advance of this present method is that the problem is described only in terms of nodes and discontinuities connecting those nodes rather than element or bodies. The alternative approximation procedure to the traditional finite element method might involve discretization of a given body using a suitably large number of nodes laid out on a grid, with the failure mechanism comprising the most critical subset of potential discontinuities interconnecting these nodes. Potential discontinuities which interlink nodes laid out across the problem domain are permitted to crossover one another, giving a much wider search space than when such discontinuities are located only at the edges of finite elements of fixed topology. Highly efficient interior point method solvers can be employed when certain popular failure criteria are specified (e.g. Mohr-Coulomb). By adopting this processing approach it is possible to solve very large problems which normally exceed the memory capacities of a single computer. The developed numerical tool reveals to be robust and versatile, able to solve a wide range of 2D problems. Velocity singularities are automatically identified and visual interpretation of the output is straightforward. Several numerical examples including rock slope are studied by the new method, and the results are very close to those calculated by using analytical method and FEM.

Jan 1, 2015

By Joseph U. Messenger

A method of applying ammonium hydroxide to a drill stem containing hydrogen sulphide gas and hydro-gen-sulphide-bearing oil and water so as to remove the hydrogen sulphide as ammonium sulphide is de-scribed. It was concluded that the method allowed trips with drill pipe filled with sour fluids to be made more safely, more rapidly, and more economically. INTRODUCTION THE DANGER of poisoning rig crews during drill stem tests of sour wells by exposing them to hydrogen sulphide gas is well known in Canada. Concentrations of hydro-gen sulphide in sour gases range from 0 to 40 volume percent. There have been numerous casualties from hydrogen sulphide exposure during drill stem testing. Some have resulted in permanent injuries; in some cases the injuries have been fatal. For example, in Alberta in 1957 there were four deaths and 100 exposures which required medical treatment. These fatalities and injuries indicate the need for a more effective way of handling hydrogen sulphide in oilfield operations.

Jan 1, 1958

By J. L. Huisman, G. Schouten

After pyrometallurgy and hydrometallurgy, bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are getting more and more accepted. In this paper a number of proven and commercial processes will be presented that can be applied for nickel and cobalt recovery and refining. These processes are based on the ability of biomass to convert the redox state of sulphur compounds under ambient conditions. They can be applied to recover sulphate from effluents or SOx from off gases and convert it to H2S or dissolved sulphide that can be reused in production or effluent treatment. Not only does this minimize the costs on resources but it also reduces waste production and improves the quality of discharges even to the point where reuse becomes feasible.

Jan 1, 2005

By David R. Winfield

I would like to thank you for spending the time with me today to review the FLIR PathFindIR thermal imaging camera system: It is truly an innovative safety system that has the added benefit of offering increased efficiency Our company the Winsted Group, specializes in mobile video systems that are fully customizable to address standard and unique operational requirements in a variety of industries from heavy equipment cameras to police and military digital recording systems, high end video camera systems are a hallmark of Winsted?s product line. The use of thermal imaging camera systems to enhance mobile safety is a relatively new concept as it relates to their use in both transportation and heavy equipment operation. This technology, like so many before it, has been adopted for civilian use from its military roots. The identification of enemy combatants through their heat signature has given our troops a decisive edge in military operations in total darkness Likewise, the ability to discern people and objects that give off heat is a significant step forward in collision and accident avoidance. The PathFindIR camera system that I am demonstrating today is so advanced that it cannot be exported outside of continental North America without a US government approved export license I would like to commence my presentation with a short video clip that discusses the technology associated with the FLIR PathFindIR Thermal Imaging camera systems. The video demonstrates the operational effectiveness of thermal imaging camera systems installed on a vehicle operating on the roadway at night, of course there are definite parallels to use in a mining environment, primarily the fact that lighting is limited and the chance for vision limiting dust is ever present. We are, of course more concerned with personnel safety in our mines than encountering wildlife on the roadside. From the same perspective, the transport driver is just as concerned with encountering a stalled vehicle as our mine truck operators are with other mine traffic.

Feb 1, 2008

By G. Archibald, M. McSaveney, J. Wartman, M. Yetton, C. Massey, C. Holden, A. Kaiser

"The 2010/11 Canterbury earthquakes triggered many mass movements in the Port Hills including rockfalls, rock and debris avalanches, slides and slumps and associated cliff-top cracking. The most abundant mass movements with the highest risk to people and buildings were rockfalls and rock/debris avalanches. Over 100 residential homes were impacted by landslides, leading to the evacuation of several hundred residents.Volumes of rock leaving several of the larger cliffs during the earthquake sequence were determined from terrestrial laser scan change models. There were no seismically instrumented cliff sites and there was some distance between the cliffs and nearest strong-motion sites. Therefore, we synthesised free-field rock-outcrop seismograms by employing a stochastic approach controlled by source models and regional parameters derived using spectral inversion of the extensive strong motion data set. Relationships between volumes leaving cliffs during the earthquakes and site peak ground acceleration (PGA), peak ground velocity (PGV) and Arias intensity were compared for different sites. Multiple linear regression was used to analyse the variables that best predict the volumes of debris that fell from the slopes during the main earthquakes. The best correlation between the volume of debris falling per square metre of slope face and the seismic forcing parameters was for vertical PGV. The results from the multiple linear regression incorporating slope height, inclination, PGV horizontal and PGV vertical, improved the statistical relationship.Field data and results from the 2D seismic site response assessment indicate that the following factors affect dynamic performance of the modelled cliffs: 1) cliff geology—mainly material modulus, shear strength and shear wave velocity; 2) slope geometry—ridge-scale versus site-scale effects; and 3) the temporal aspects of the earthquake shaking (i.e., single acceleration peaks of large amplitude versus multiple peaks of smaller amplitude). Model results show that amplification of shaking does not increase linearly with increasing height, but instead reflects changes in the cliff geology where material strength, modulus and shear-wave velocity contrasts lead to acceleration contrasts.These factors show that the use of well documented case histories provide the basis for more certainty in seismic landslide assessments compared to those that are only empirically based."

Jan 1, 2015

By E. Ghali, A. D. Bas

"Treatment of oxide, e.g. roasted gold ores has received relatively less attention than sulphidic ones and recently, handling of oxide gold ores is becoming essential. In this study, the influence of roasted gold ore (RGO) slurry (at 35% solid ratio) on the electrochemical dissolution of gold has been examined using pure gold and iron oxide minerals (hematite, maghemite, and magnetite) as disc electrodes by zeroresistance ammeter mode either in one or two separate containers. The presence of slurry decreased galvanic currents, i.e. corrosion rates due to the release and increase in the amount of soluble and/or insoluble species that could retard further the anodic behaviour of gold. Higher galvanic currents were observed in two separate containers than that in one container indicating the primary importance of galvanic interactions. SEM-EDS results observed iron hydro/oxide coatings on gold surface in case of magnetite test. However, in case of RGO electrode it is not a perfect passivation, although somewhat decreasing trend was observed on gold dissolution. These findings have revealed that passivation is not only a laboratory phenomenon, but also it could be responsible for the slowdown of gold dissolution in industrial practice.INTRODUCTIONThe cyanidation of gold is an electrochemical corrosion process thus; the dissolution of gold can readily be studied by electrochemical techniques. The outcome/summary of previous electrochemical studies of gold leaching can partially be summarized as follows: Filmer (1982) and Lorenzen and van Deventer (1992) reported the negative effect of pyrite and pyrrhotite on gold leaching due to the galvanic interactions; Aghamirian and Yen (2005) studied gold galvanic corrosion in presence of sulphide mineral electrodes only in one cell using zero-resistance ammeter (ZRA) mode; Dai and Jeffrey (2006) discussed, individually, the anodic and cathodic behaviours between gold and sulphide minerals, and Azizi et al. (2010, 2011) used a bed reactor to examine the influence of sulphide minerals on gold dissolution in one and two separate cells. Accordingly, a slowdown in gold leaching has generally been attributed to the passivation phenomenon, although the indication of this phenomenon is still an undergoing debate. For instance, Mrkusic and Paynter (1970) identified the passivation as the film formation of dissolved species from calcine, Crundwell (2014) explained passivation, in the case of corrosion of metals, as the formation of a layer which is composed of a new chemical species on the mineral surface and this layer inhibits or blocks further reactions. He suggested that passivation is related to the oxidation of the metal, and the formation of a passive layer that retards the rate of dissolution by several orders of magnitude. Consequently, galvanic interactions, passivation phenomena, or combinations of them are considered significant electrochemical factors affecting gold dissolution (van Deventer, Reuter, Lorenzen, & Hoff, 1990; Azizi, Petre, & Larachi, 2012). It is important to note that generalizing the influence of a mineral/metal on gold dissolution may not be correct in all cases, since contrary behaviours/results (for pyrite) have been observed (Aghamirian & Yen, 2005). Therefore, electrochemical study of gold is still a subject of research and need to be examined further in detail."

Jan 1, 2016