Search Documents

By Lang SC

The Broken River Province, in the northern part of the Tasman Orogen, is divided into the Camel Creek and Graveyard Creek Subprovinces. In the Late Cambrian to Early Ordovician, and again in the Late Ordovician, the northern part of the Tasman Orogen was probably a convergent margin with calc-alkaline volcanism. These episodes may have been separated by a passive phase in which quartz-rich flysch and tholeiitic volcanic rocks were deposited. Subsequently, in the Silurian, the region underwent extension forming a large turbidite basin which included the Camel Creek Subprovince and the Hodgkinson Province to the north. Melange is pervasive in the Camel Creek Subprovince which was folded twice in the Devonian. The melange may be related to thrusting accompanying D1. No rocks younger than Early Devonian have been recognised whereas, in the Hodgkinson Province, deposition continued until the latest Devonian. The Graveyard Creek Subprovince formed adjacent to the Camel Creek Subprovince, probably as a pull-apart basin on stable crust. The deformation history of the Graveyard Creek Subprovince contrasts markedly with that of both the Hodgkinson Province and Camel Creek Subprovince. In the Graveyard Creek Subprovince, melange is only present in Early Ordovician rocks. No major angular unconformities have been recognised in the overlying marine to non-marine sequence, which ranges from Early Silurian to Early Carboniferous. Several hiatuses and a slight angular unconformity, all within the Devonian, may be related to the major events in the Camel Creek Subprovince. A major deformation in the Graveyard Creek Subprovince in the Early Carboniferous had only slight effects in the Camel Creek Subprovince. Movement on the Clarke River Fault was probably an important influence on sedimentation and deformation in the Broken River Province.

Jan 1, 1990

By M Chen, W S. Ng, Y Liu

In the processing of refractory gold-bearing sulfides, pressure oxidation (POX) is commonly known for its role in liberating the gold in solid-solution via oxidation of the sulfide occlusions. For deposits that contain arsenic-bearing species including arsenian pyrite and arsenopyrite, POX serves an important secondary function in the fixation of arsenic, via the hydrothermal precipitation of stable arsenates such as scorodite and basic ferric arsenate sulfate (BFAS). There have been various investigations on the impact of different POX conditions on arsenic precipitation and the stability of the formed phases, but less is known about the changes to the arsenic carrier that occur in the curing stage, which follows directly from POX. The primary function of curing is to coax the dissolution of sulfates to reduce lime consumptions during cyanide leaching, and the slurry is kept at elevated temperatures near 100°C to achieve this. While the arsenic-bearing phases are expected to undergo transformation during this stage, there has thus far been limited experimental evidence. In this study, the effect of curing time and curing temperature on the arsenic-bearing species and arsenic deportment in the POX product has been investigated. Leaching of the curing products was also conducted to examine the stability of the arsenic species in the solid precipitates.

Aug 24, 2022

By Elford H. S

Australia has many potentially important tin deposits, particularly on the eastern shore of the continent and in Tasmania. A number of these have been worked on a meagre scale, while some of them, because of metallurgical, transport, and other difficulties, have not as yet been developed.Believing that the full development of the tin fields of the Commonwealth of Australia is in part dependent upon the adoption of the most efficient methods of milling and smelting, the Development and Migration Oommission arranged for the first-mentioned author to visit the mining fields of Cornwall, one of the oldest tin-producing districts of the world, and prepare a report for the information of the Commission.This paper, now presented to the Australasian Institute of Mining and Metallurgy with the hope that it will assist the full development of tin mining in Australia, is the joint work of both authors.For over two thousand years tin has been produced from the Cornish mines. Even the ancient Greek historians made mention of tin mining in Cornwall, and it is probable that during the earliest periods the mining was alluvial. As early as 1602 a stamp battery working in Cornwall was described, and in 1671 calcination and buddling was a recognised scheme of treating pyritic ore. In the first half of the 16th century the output of tin from Cornwall was 700 tons per annum, and, from then on, production increased to the maximum in 1914 of 6500 tons. At present (Oct., 1929) the Cambourne-Redruth area produces over 95% of the Cornish tin output. This area includes such mines as the South Crofty, East Pool, Dolcoath, Parkanchy, Polhigey, and Wheal Kitty. The remaining 5% is largely supplied by the Levant and Geevor mines at Pendeen, St. Just area, near Land's End.

Jan 1, 1930

The paper re-visits an old and proven concept of winzing, a method widely used in the past to gather exploration data for accurate definition of the orebody. It is proposed to use a mobile Supersucker (a giant vacuum cleaner also known as vacuum lift), to carry out winzing activities underground. A brief description of conventional underground winzing used in the past is provided, together with a discussion on other underground bulk exploration methods used in Australia to date. Historical background, principles of the proposed system, Supersucker construction details and productivities, and benefits and advantages of the proposed system in comparison with other exploration methods, are outlined. Other relevant applications of the mobile Supersucker, including surface winzing, are also briefly discussed in the paper. With a view of using the mobile Supersucker to recover all broken ore stocks underground, included are also results of floor sampling conducted recently in the in-stope decline excavated in a coarse gold type, high-grade orebody.

Jan 1, 2002

By Hare S. M, Lumsdaine I, O&apos

Converter slag assaying 3.7 per cent Cu is produced by Mount Isa copper smelter at a rate of up to 180 000 tonnes per annum.Priority is given to the processing of ore, however concentrator capacity periodically exceeds that of the mine and the opportunity is taken to treat converter slag. It is processed in batch campaigns, typically through the Copper Concentrator, but the Hilton Concentrator has also been used. Slag and ore are kept as separate as possible, since each has an adverse effect on the flotation performance of the other.

Jan 1, 1993

By K Haroon, J D. Speed, S P. Wood

Online analysis of continuous and batch processes has seen a dramatic increase in recent years, with examples ranging from petrochemicals to pharmaceuticals, to industrial biotechnology and food and drink. The particularly challenging environment of alumina processing has meant that instrumentation needs specific features and characteristics to be truly suitable, features such as: robustness, resistance to caustic conditions both in the analyte and the ambient environment, and reliability for long-term continuous use. Here we present the development of a novel FTIR spectrometer that achieves these requirements through the use of a static optics arrangement of mirrors, and stable diamond-tipped light-pipe probe. Firstly we give a very brief explanation of spectroscopic analysis, and the difference between FTIR and other infrared methodologies. Next we outline the novel arrangement of mirrors required to produce an interferogram without moving mirrors, and compare the benefits and drawbacks of this approach instead of conventional designs. We then share the results of laboratory analysis of synthetic Bayer liquors, with detection limits for aluminium hydroxide, sodium hydroxide, sodium carbonate and various sodium salts of organic acids. We then share the results of analysis on production samples, both in idealised laboratory conditions and then online in the process itself. Lastly we present work on in situ ultrasonic descaling solutions to avoid scale build-up and provide continuous cleaning of the probe – preventing the need for probe removal and manual cleaning.

Aug 24, 2022

By M Lewis, A Cook

This paper is based on the technology and functionality of a Modular Mining IntelliMINE« system which is a real-time decision-making tool. The IntelliMINE« system, incorporating Dispatch, is a fully Integrated Mine Management System. Measuring, quantifying and analysing the performance of mining is considered a fundamental and strategic step towards changing the nature of technical and operational decision-making at the majority of international mining corporations. Successful implementation of electronic data capture devices and computerised tools have enabled many mining operations to improve their competitive position with an improvement in the utilisation of the key assets, mineral resources, capital mining equipment and human resources. Real Time Mine Management Systems are designed to direct the emphasis away from collecting data and focus decision makers on the real issues with well-presented and reliable information. The systems provide a common stream of information to enable senior management, operations, maintenance, technical and process plant staff to make complementary decisions based on reliable, accurate and timely data. The mine asset information tools focus all employees on performance and give them feedback on their area of responsibility. The resulting tangible benefits can be delivered in different forms depending on the mining method, ore type, workplace culture and the current competitive position. Typical areas of improvement reported by system users are:reduction in capital expenditure on mining equipment fleets; more effective planning and budgeting parameters and procedures; increased control over ore-extraction and processing; increased employee accountability and organisational performance; and improved co-ordination between planning, operations, maintenance and processing. These improvements can be delivered in different forms depending on the status of the mine and commodity markets. In times of market oversupply and low commodity prices, the benefits can be delivered to the bottom line in terms of reduced cash costs, reduced capital and operating resources to maintain constant production. In times of market expansion, existing capital resources will be more productive delivering increased production and revenue. Mine management systems have the potential to transform a traditional mine operation into a learning organisation with an improved understanding of the critical performance issues and enable development of relevant strategies to continually identify and eliminate operational inefficiencies. The effectiveness of each strategy and operational change can be accurately monitored and its success (or otherwise) will be quantified. The latest downturn in the world metal prices has forced many mining companies to focus on cost reduction and productivity improvements as a means of remaining competitive. Maintenance represents a significant proportion of the overall operating costs in the mining industry. A structured proactive maintenance approach such as Reliability Centered Maintenance (RCM) can achieve significant cost reductions and productivity improvements. Remote condition monitoring systems are becoming increasingly commonplace and have the potential to identify problems prior to failure. Detection of equipment degradation prior to failure will enable repairs to be scheduled, thereby reducing costs and interruptions to production.

Jan 1, 2000

By H F. Galbiatti, G J. I dos Santos, A de C Zapparoli

The Grao Para and Rio Maria greenstone banded iron formations (BIFs), within the Carajas mineral province, exhibit distinct lithological and petrographic fabrics, together with pronounced differences in their surface expression, real thickness, iron grade and tonnage. These geological differences support a new model for the regional distribution of iron formations in the Carajas Mineral Province.

Jan 1, 2009

By J P. Sykes, T C. McCuaig, J E. Vann

Resources added to the global metal inventory through exploration over the past 15 years have been generally of poor quality (declining grades, recoveries and lack of acceptable financial return). Similarly, companies opting for an acquisitions-based strategy have had to pick from a group of poorer quality resources left from previous exploration booms, and will struggle to deliver this metal to market economically. Increasing difficulty in obtaining sufficient social and community acceptance of mining projects and potentially an energy-constrained future may exacerbate this problem, redefining what is considered ‘ore’. There will need to be more focus on deposit quality, defined as sustainable margin in the future business environment.Traditionally there has been a lack of translation of ‘mineralisation quality’ back to mineral project design and mineral exploration. This disconnect is due to two main factors: the first is technical – inherent deposit variability; and the second is organisational and socio-psychological –the mindset of explorers and project managers themselves.There are four elements to value realisation for a mineral deposit: (1) social licence to operate; (2) geological factors (depth, geometry, water and geotechnical, and geometallurgy – influenced by texture, mineralogy, chemistry and grades); (3) financial engineering (capex, opex, future commodity prices, future energy prices), and (4) operating factors (production rate, recovery, energy consumption). These elements are strongly interdependent, and geology underpins and drives linkages between them. A quality deposit addresses all of these elements and thus can be developed in a time frame that allows acceptable returns to the owners of the invested capital.Geological drivers of the above elements can be measured and mapped throughout a deposit. Moreover, when viewed in the context of mineral systems, a predictive understanding of the common causative processes of quality (despite deposit-scale variability) is emerging, and with it the ability to target quality of mineralisation, not just quantity of mineralisation.The second factor is a ‘heuristic software problem’. Current lines of education (and consequently organisational and professional structures) are discipline-based, producing ‘silos’ that do not speak each other’s language and work with different ‘mental models’. People who effectively recognise systemic links between these silos are called ‘boundary spanners’, of which we propose two distinct types: outside-insiders and inside-outsiders. Outside-insiders are people who are within a community, but recognise advances in outside fields and effectively integrate them into the community. Inside-outsiders start outside of a community, and successfully bring new ideas into it. Common traits in boundary spanners are: they seek exposure to (and embrace) key ideas that are outside of the framework of their own specialisation; they have high mental processing ability (MPA) – the ability to connect systems that are currently not perceived to be connected; and they introduce ideas from outside a field into a new context in a way that re-frames the field.The challenge is to identify and nurture potential boundary spanners that can build critical links, in particular between the (largely geoscientific) mineral exploration mindset and the (largely non-geoscientific) project development mindset. Critical linkages to be built are between mineral system science, targeting science, and whole of value chain modelling.CITATION:McCuaig, T C, Vann, J E and Sykes, J P, 2014. Mines versus mineralisation – deposit quality, mineral exploration strategy and the role of ‘boundary spanners’, in Proceedings Ninth International Mining Geology Conference 2014 , pp 33–42 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By Winrove G. S, Herdie G. J, McCarthy C. A

Production of hot metal from the Hlsmelt Research and Development Facility at Kwinana, Western Australia commenced in October 1993. The stand-alone facility is a unique, coal-based, integrated ironworks equipped to process iron ore fines to pig iron and simultaneously undertake a wide range of research tasks. The data generated will be used to verify the commercial potential of the technology and to set the design and operating parameters for a full-scale production plant. The design, construction, commissioning and initial operation of the HRDF has required many innovative and practical solutions to be developed and implemented by the international group of organisations contributing to the Hlsmelt Project. Initial operation has produced results which demonstrate the potential of the unique process technology associated with the core plant smelting unit. The recent achievement of post-combustion levels of 60 per cent with heat transfer efficiencies greater than 85 per cent demonstrates that the performance obtained with the Small Scale Pilot Plant in Maxhutte, Germany can be reproduced at a larger scale. The results presented in this paper support the thrust for further intensification and future commercialisation of the process.

Jan 1, 1995

By S Phinn, V Glenn, P McKenna, P D. Erskine, D Doley

The key goals for mine site rehabilitation require mine managers to demonstrate that rehabilitation is safe, stable, self-sustainable and non-polluting. Within this context, it is reasonable for stakeholders to expect that mine site rehabilitation is resilient to disturbance impacts such as fire and drought. However, mine managers actively avoid fire on rehabilitation; and as a result have limited understanding of fire behaviour on revegetated landforms, the long term implications for site stability and the potential risk to site relinquishment. An experimental fire that was conducted at the Curragh Mine site in May 2015, burnt 117 ha of 19- to 21-year old mine site rehabilitation, mimicking wildfire conditions and creating a mosaic of fire impacts across the landform. Using a combination of ground surveys and remote sensing assessments, we demonstrate that over a two year period, ecological metrics such as species richness, woody density and understorey biomass all recover to pre-fire levels for both grassland and open woodland areas. This is supported by WorldView-3 satellite imagery and the remote sensing assessment using the differenced Normalised Differenced Vegetation Index (dNDVI) which shows high regrowth within the burn area in 12- and 24-month image captures. The results suggest that within the recorded conditions, this site is resilient to fire impacts, and has the capacity to recover to pre-fire levels within the first two years following the fire.CITATION:McKenna, P, Erskine, P D, Phinn, S, Glenn, V and Doley, D, 2018. Measuring the recovery of coal mine rehabilitation following fire in Queensland using remote sensing and ground surveys, in Proceedings Life-of-Mine 2018, pp 141–146 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By Hendon G. W, Carr F, Jiang Y

A vast majority of the operating longwall sections use shield-type face supports to provide ground control in the United States. As a co-operative research program between the University of Alabama (UA) and Jim Walter Resources, Inc.(JWR), a joint research program is underway to study interaction of shields with surrounding rock masses. A series of analyses on the response of shields are performed using monitored data at a longwall face in a deep coal mine. In this paper, various effects of parameters, such as leg pressure, setting load, developing load, maximum loading rate, pressure in capsule, and convergence between canopy and base, are discussed and recommended as stability indices. A microcomputer program is being developed for instantaneous interpretation of the shield monitored data, and for giving warnings of potential problems. The preliminary results define the effects of the setting load, developing load, and rate of developing load or leg closure rate. The objective of the study is to understand the shield characteristics and their interaction with surrounding strata in real time, then develop a reliable program for maintaining longwall stability.

Jan 1, 1992

The seminar had its origins in an Inquiry into the Box Flat Disaster and one of the conclusions from this Inquiry was that there should be a better dissemination of technical knowledge and the results of research work. As a result of this Mr. W. Roach, Chief Inspector of Coal Mines in Queensland and Mr. R. Menzies, Chief Inspector of Coal Mines in N.S.W. had a meeting to see how this could be done. They concluded that it would be difficult to have the sort of regular meetings that would be possible where distance was not significant, but a seminar would be a major step toward satisfying this particular conclusion of this Inquiry. As a consequence, Mr. Roach, who is on the Committee of the Southern Queensland Branch of the Institute, suggested when the Branch programme was being planned this year that a meeting of this type should be held, and the Mine Fires Seminar which was held today is the result. We have received a great deal of support in arranging the Seminar. First and foremost I wish to acknowledge support from the National Coal Board in United Kingdom. Not only have they released Dr. Willett for a period of six to seven weeks to visit Australia, conduct the Seminar and give a series of lectures in various areas through the country, they have also borne the brunt of the financial support that has been necessary to make this possible. In addition we have received considerable support from many organisations in Australia. I 'mentioned this

Jan 1, 1973

By D Caffrey

To demonstrate the advantages of using electronic delay detonators over pyrotechnic detonators, a trial using the DNES Dynatronic System was conducted at the KCGM Mount Charlotte operation in 1998. The trial clearly demonstrated that accurate control over the firing delay time between blastholes can lead to fragmentation improvement and ground vibration energy control which are two important issues for the Mt Charlotte underground operation. Excellent fragmentation was achieved by employing a 12 ms delay sequence. Detailed fragmentation analysis has shown a 10 to 20 per cent passing increase for the rock fragment size from 0.1 to 0.4 m compared with the pyrotechnic detonator firing. There was no increase in ground vibration level on the surface with the electronic detonator firing even though the electronic detonator firing had a much shorter blast duration than the pyrotechnic detonator firing. In fact, our energy calculation has clearly shown that much less energy had been propagated to the surface from the blast using electronic detonator firing.

Jan 1, 1999

By J F. Colinet, G, J A. Zimmer, R J. Timko

It has long been known that ventilation is a cost-effective method to lower respirable dust concentrations in all types of mining applications. The National Institute for Occupational Safety and Health has been working on a number of different research techniques that use ventilation as a critical component to lower respirable dust levels at surface and metal/non-metal operations in the United States. This article presents five such research efforts. The first research area discusses how improving the ventilation flow patterns in an iron ore mill facility lowered respirable dust concentrations by 31 per cent throughout the primary grinding area. The second research area examines how respirable dust levels were lowered at a dimensional stone shop by using air cleaning units suspended from the ceiling. A third area discusses how improvements in ventilation at underground limestone mines lowered respirable dust concentrations. The fourth area examines how improvements in dust filtration and pressurisation systems significantly impacted the air quality in enclosed cabs of surface mining equipment. The last area presents a newly developed clothes cleaning technique. This technique uses an air spray manifold to blow dust from a workerÆs clothing in an enclosed booth, which confines the dust for capture and removal by a baghouse dust collector. These research areas represent an array of different control technologies to lower respirable dust concentrations. Ventilation is an integral part of these control technologies.

Jan 1, 2005

The Maddingley brown coal seam at Bacchus Marsh, where mined and bored, tends on the whole to a higher content of volatile matter than the Latrobe Valley brown coals, and this masks the presence of lignitic or earthy coal bands in the bore core analyses. Visits to the Lucifer Open Cut, at Bacchus Marsh, during 1948, revealed, however, a banded condition in the coal seam, as shown in Fig. 1. This banding showed in a face that had been exposed for a considerable period of time, permitting partial drying out and oxidation of the surface coal. The bands consist of different coal types, ,comparable with those found in the Yallournand Latrobe brown coal seams(l).The' light coloured bands in Fig. 1 consist of a buff to light-brown earthy coal of low specific gravity, that closely resembles the pollen coal, that occurs, as similar thin bands in the Yallourn and Latrobe seams. The 40 ft. of coal above the uppermost of these light coloured bands dries out on exposure to a black, closely cracked surface, composed of small dice-like fragments of a lustrous vitrain-like substance, and in every respect resembles the lignitic coal bands of the Yallourn and Latrobe seams.The coal between and below the light-coloured bands develops fewer and more widely spaced shrinkage cracks on drying out, and remains brown in colour and earthy in appearance, resembling the earthy coal of the Yallourn and Latrobe seams.Representative samples were cut of these coals, taking care to exclude surface coal, and analyses were made of them by the Metropolitan Gas Company, through the kindness of Dr. R. S. Andrews, Chief Chemist to the Company...

Jan 1, 1948

By J Taylor, A Dubowik

To increase the efficiency and improve the quality of diamond drilling at Olympic Dam, mine geologists have adapted and modified common practices in order to overcome the challenges imposed by such a unique environment. Mine geologists have to take into account both the complex geology during the diamond drill hole design phase, as well as incorporating diamond drilling into the larger-scale scheduling process already employed at Olympic Dam. This study seeks to explore how such modifications have evolved over time.The geology of Olympic Dam influences the design process of diamond drill holes, particularly due to the variation of lithology and alteration, as well as the presence of magnetite and major structures within the orebody. Exclusion zones are used to manage interactions with existing and planned mining activities, and their size is dependent upon the geology of the area. Specific deviation checks are used to monitor the deviation of diamond drill holes with respect to these?zones.The highly interactive environment of Olympic Dam requires unique planning for diamond drilling, resulting in the production and implementation of both long- and short-term schedules. Long-term schedules are targeted at determining drilling locations and ensuring drilling is completed prior to stope planning, while short-term schedules aid in enabling access to ensure timely set-up of drill sites. Estimated drilling rates, determined by expected lithologies and historical data, feed into the short-term schedule to assist in managing the operation and minimising the downtime of diamond drill rigs. A mine geologist is appointed as a diamond drill coordinator to organise and manage diamond drilling at a scheduling and operational level, streamlining the entire process.Analysis of historical data shows a strong correlation between implementation of the aforementioned practices and improved drilling rates. This study shows the importance of adapting universal tasks to particular environments and circumstances. Mine geologists at Olympic Dam continue to acquire knowledge to further improve the modified drilling practices as operational requirements, production pressures and economic factors change.CITATION:Taylor, J and Dubowik, A, 2014. The evolution of diamond drilling practices at Olympic Dam, in Proceedings Ninth International Mining Geology Conference 2014 , pp 271–280 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By A G. Guinea

Every person in an organisation has what could be called ‘a different take’ on what it means to be a safety leader. The directors will tell you they are ultimately responsible for everyone’s safety and that they can be imprisoned as a consequence of a workplace fatality. Managers, take more of a focused approach and would explain that they are totally responsible for the safety of their teams. And then there are front-line leaders. Those that not only have the responsibility (like directors and managers) but they also have the accountability, and the ability, to influence how safely their teams work. But it is not just physical safety that leaders should be concerned with.

May 5, 2022

By N Mangadoddy, P Jampana, S Diddi

The study of air-core dynamics in hydrocyclone operation is essential for predicting separation efficiency in mineral processing. Electrical resistance tomography (ERT) allows non-invasive measurements of hydrocyclone internal flow dynamics. Existing regularisation methods such as Gauss-Newton and TV norms rely on optimisation techniques which have very high computational cost for very fine meshes. In contrast, the monotonicity method has much lower computational cost as it does not solve such minimisation problems. In this paper, results from the monotonicity method, Gauss-Newton (GN) (Tikhonov) and Total-Variation (TV) norm-based minimisation methods for estimating the air-core diameter in hydrocyclones are compared. We study these methods on the laboratory hydrocyclone experimental two-phase flow data. The results obtained are validated against High-speed video (HSV) imaging and Computational Fluid Dynamics (CFD) results. The results on different mesh sizes, in particular for very fine meshes with the number of cells ranging from 30 000 to above 100 000 are also investigated. The data used in this study is obtained from ITS Z8000 ERT system. This system does not measure the voltages on the current carrying electrodes. Since these voltage values are required for the monotonicity method, we implement an interpolation method to compute them. The results show that the monotonicity method provides a closer approximation of the interface between air and the water phases.

Aug 24, 2022

By S H. Li, H Z. Gu, A Huang

High aluminium steel is a promising advanced steel known for its exception properties and holds significant economic and strategic importance. However, the CaO-Al2O3-SiO2 based slag with high alumina content reacts vigorously with alumina refractories during the smelting process at high temperature, seriously affecting the safe and efficient production of furnaces and resulting in the formation of Al2O3-MgO non-metallic inclusions within the molten steel. This is a bottleneck problem for high-quality steel refining, and the key reaction path during the corrosion remains unclear. The dissolution reaction mechanism of alumina refractories in high alumina CaO-Al2O3-SiO2 slags under a weak static magnetic field was investigated in this work, using high temperature laser confocal microscopy and in situ radiation spectroscopy techniques. The results indicate that the interaction between the high alumina slags and the alumina refractories is governed by free radical reactions. The dissolution of alumina forms AlO and AlO2 radicals. The reaction rate increases with the C/S ratio of the slag due to its low polymerisation. The reaction between non-bridging oxygen and AlO2 free radicals accelerates the generation of AlO and O2ꞏ- radicals. The reaction layer composed of calcium aluminate is formed through the recombination of AlO, Caꞏ+ and O2ꞏ- radicals. The weak static magnetic field induces the Zeeman splitting of free radical pairs and intersystem crossing occurs, promoting the formation of triplet free radical pairs through the hyper-fine coupling effect. The reaction can be significantly inhibited as the triplet free radical pair does not meet Pauli’s incompatibility principle. This discovery perfects the structure theory of molten slags with radicals and provides supplement to the design of the highly slag-resistant refractories, and provides the theoretical basis for the development of external field protection technologies for high-quality steel refining.

Jun 19, 2024