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By G. L. Bartlett

"INTRODUCTION The major objective of our research is to help reduce the incidence and severity of coal worker's pneumoconiosis (CWP). To that end, this project is designed to improve our understanding of the processes that lead to pulmonary dysfunction following mine dust exposure, and how those processes might be interrupted or attenuated. The response of the lung ' to inhaled particles is complex, and the course of development of disabling CWP is slow and unpredictable. From among the numerous cellular and molecular interactions involved in the pulmonary response to inhaled particles, this project is focussed on the role that the pulmonary alveolar macrophage (PAM) may play in regulating the activity of fibroblasts.The PAM is the lung cell that has the most immediate and the most obvious interaction with inhaled particles. Within a short period after particles are arrested in the alveolus of the lung, they are phagocytized (engulfed) by these specialized cells. The PAM then has a diverse potential repertoire of subsequent activities. Which reaction actually ensues is determined, in large part, by the nature of the phagocytized _particles. Activated PAMs produce a variety of products that may affect adjacent lung tissue, including superoxide free radical, elastase, collagenase, prostaglandins, platelet activating factor, etc. Those may well be important in the pathogenesis of CWP, but they are beyond the scope of this project. Background information that is cogent to this project has come primarily from investigations using animal models of silicosis and asbestosis. PAMs that have ingested silica particles synthesize and release molecules that control the behavior of surrounding cells. One such mediator is interleukin-1 (IL-1), a molecule that plays a central role in many aspects of the response to injury. It can stimulate fibroblasts (the cells that help to hold tissues together) to release the enzyme collagenase, resulting in breakdown of the structural collagen fibers that support the lung tissue. IL-1 also stimulates fibroblasts to undergo mitosis and to proliferate, which is an initial stage of fibrosis. Certain stimulants cause PAMs to release fibroblast growth factors (FGFs) that are distinct- from IL-1. Under other circumstances activated PAMs synthesize and release molecules that stimulate fibroblasts to accelerate synthesis of collagen fibers, thus contributing to fibrosis. Although these observations provide a valuable precedent for analysis of the mechanisms involved in CWP, their relevance to CWP cannot be assumed since most of those studies involved macrophages or fibroblasts obtained from tissues other than the lung, and because almost none of them have used CMD as the stimulating particles. Therefore, the goal of this project is to learn how exposure to CMD affects the behavior of PAMs, and in turn how products of dust-exposed PAMs affect fibroblasts and the process of fibrosis in the lung."

Jan 1, 1988

By Svetlana Krashenina, Nebojsa Petrovic, Oscar Lopez

"As easily mined gold deposits are becoming increasingly rare, gold producers are turning to the processing of ores with polymetallic and copper mineralization. These base metals can create metallurgical and waste handling/disposal challenges, which can render the project uneconomic. Base metals such as copper compete for the cyanide reagent used to extract gold, necessitating the need to increase cyanide volumes and consequently, cyanide consumption costs. Copper will also stabilize in tailings water as weak acid dissociable cyanide, a form that is both difficult and costly to destruct. SART (sulphidization-acidification-recycling-thickening) process technology can be applied to remove base metal interferences in gold projects. SART breaks the copper-cyanide complex and precipitates the copper as a saleable copper sulphide concentrate. With the copper removed, the cyanide can be regenerated as free cyanide for recycle to the gold recovery process. This improves cyanide utilization efficiency and mitigates copper presence in tailings. Additionally, copper recovery generates an incremental revenue source to further improve project economics. Engineering Dobersek GmbH together with BioteQ developed a SART and AVR testing program to recover cyanide and maximize operational efficiencies at a gold processing plant in Kazakhstan with high cyanide consumption in the leach circuit. Results from on-site testing demonstrated that up to 99.98% of copper can be removed and precipitated as copper sulphide and 60-90% of cyanide can be recovered from the AVR and recycled for leaching, reducing total overall cyanide use. This paper provides an overview of the testing methodology and results together with a discussion on the potential of SART to improve gold production operations to deliver both environmental and economic benefits."

Jan 1, 2014

This paper will review some of the work conducted in the past at the Dynamic Effects Laboratory to examine the use of stress waves and fracture mechanics in understanding dynamic fracture and fragmentation in blasting applications. Along the way, we will use photoelasticity and high-speed photography to better understand the mechanisms of fracture and fragmentation.CITATION:Fourney, W L, 2015. The role of stress waves and fracture mechanics in fragmentation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 27–40 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By A. V. Faiberg

Currently, the interest to conditioning of cyanide-bearing recycled solutions with high-grade of base metals, in particular, copper has significantly grown. This can be explained by two major factors. Firstly, there are strict regulations on cyanides amount in tails and higher cost of detoxification processes. This problem can be easily solved during the ore treatment using the conditioning of solutions and water recycling. Secondly, the presence of other metals minerals which react with cyanide during gold leaching resulting in high cyanide consumption. The presence of copper is a major problem. Many copper minerals react with cyanide with the formation of cyanide complexes-Cu(CN)2-, Cu(CN)32- and Cu(CN)43-. One mole of copper consumes 2-4 moles of free cyanide. Availability of cyanide-soluble copper minerals has deleterious effect on gold leaching (gold recovery, cyanide consumption, tails detoxification, efficiency of gold elution and electrowinning). The precipitation of copper from the solutions improves gold recovery by CIL. The removal and recycling of cyanide allowed the reduction of cyanide addition to the process. The recycling of spent cyanide-bearing solutions based on the removal of copper and the return of cyanide bound in complex compounds for leaching process is an optimal way of solving the problem of gold-bearing copper ores treatment. By using the technology, an adverse impact onto gold recovery process is eliminated and at the same time reducing the cyanide consumption. Today, processes and methods of high-grade copper leaching solutions conditioning before and after gold recovery have been developed, which combine two ways of copper recovery: as a saleable product and cyanide to recover gold and reduce total operating costs. They are Cutech, MNR, SART, Cyanomet, AuGment, Vitrokele, Hannah and Cyanisorb. At the same time, these technologies have not been studied enough and described in literature. Data on parameters and operating conditions as well as introduction is not available. The conditioning technology of recycled solutions developed by IRGIREDMET JSC allows copper to be recovered as high quality concentrate and at the same time free cyanide regeneration in the recycled solution which is amenable to gold leaching. This technology was commercialized at a mine in Kazakhstan in 2008. The removal and recycling of cyanide does not require additional cyanide and is cost-effective. More cost-efficiency is achievable through selling copper concentrates, closed water cycle without the detoxification of effluents and enhanced gold recovery by CIL and cathode quality.

Sep 1, 2012

By G. Ferrara

To obtain a reliable comparison between conical and cylindrical separatory vessels used in dynamic dense medium separation systems, the following studies were made: (1) study of the swirling flow in conical and cylindrical vessels using laser-Doppler velocimetry (LDV); (2) study of the behaviour of suspensions of magnetite and ferrosilicon in water in both separators. It was found that: (a) the tangential velocity profiles differ in conical and cylindrical vessels: in a conical cyclone free vortex conditions affect the largest part of the vessel, while in a cylindrical vessel, the motion approaches that of a forced vortex, i.e. that of a centrifuge; (b) the conical vessel manifests higher centrifugal acceleration and very strong densifying; the density differential, and hence the density gradient inside the vessel is large; (c) the cylindrical vessel manifests lower centrifugal acceleration and low densifying, i.e. low density differentials, and hence, the density gradient inside the vessel is small; (c) due to greater densifying, the density cut-point in cyclones is higher than the operating medium density, while in cylindrical vessels the density cut-point is closer to the medium density. The results provide an interesting description of the differing behaviour of conical and cylindrical vessels and help explain the differences in performance between the two types of separators.

Jan 1, 1998

By P. Karimi, A. Akcil, A. Amini, H. Abdollahi

"In this study, cyanidation experiments were carried out on a massive sulfide ore sample, whose grades of the precious metals gold and silver were found to be 4.2 g/t and 311.9 g/t, respectively. Other elements in the ore were arsenic with average grade of 1,751.6 g/t; antimony, 619.7 g/t; zinc, 781.4 g/t; copper, 454.6 g/t; lead, 101.8 g/t; mercury, 324.3 g/t; and bismuth, 0.6 g/t. The first objective of test work focused on determining the best conditions for extracting gold from the ore, ground to less than 75 microns. Different influential parameters such as particle size fraction, cyanide concentration, pH and leaching time were investigated. The optimum parameters were found to be particle size fraction of less than 25 microns, cyanide concentration of 2,000 mg/L, pH of 11 and cyanidation time of 24 hours. In these optimum conditions, the highest gold and silver leaching efficiencies were 76.88 and 59.63 percent, respectively. In addition, roasting as pretreatment at a temperature of 700°C over a period of two hours was evaluated. Cyanidation testing of the roasted ore in the optimum conditions found increases in the gold and silver leaching efficiencies to 85.97 and 67.57 percent, respectively. Moreover, antimony extraction rose to 43.10 percent, from 23.73 percent without roasting.IntroductionGenerally, gold ores can be classified as “free milling” or “refractory,” depending on how they respond to cyanide leaching (La Brooy et al., 1994; Celep et al., 2009). While high gold recoveries (> 90 percent) from free-milling gold ores can be readily achieved, refractory gold ores are often characterized by low gold recoveries (50-80 percent) within a conventional cyanide leaching process (Rubisov et al., 1996; Adams, 2005; Celep et al., 2009). The presence of preg-robber components such as carbonaceous matter, sulfide minerals and aluminosilicate can further decrease gold and silver dissolution rates and recoveries. With the negative effect of the presence of preg-robbers, gold dissolution is considerably diminished in solutions with high cyanide concentration (Tan et al., 2005). In such refractory gold ores, gold particles may sometimes be occluded or included in the sulfide minerals, and pretreatment becomes necessary to break down the mineral structure to liberate gold for subsequent recovery. These ores are usually pretreated with an oxidizing process, after which gold and silver can be recovered by a standard cyanidation process. The main oxidizing processes available for refractory gold ores are roasting (LaBrooy et al., 1994; Angelidis and Kydros, 1995; Li et al., 2009; Karimi et al., 2010; Kyle et al., 2012), biological oxidation (Lawrence and Bruynesteyn, 1983; Komnitsas and Pooley, 1990, 1991; Deng and Liao, 2002; Ciftci and Akcil, 2010, 2013) and pressure oxidation (Mason, 1990; Murthy et al., 1992; Qingcui et al., 2009). In addition, ultra-fine grinding is being used in some plants for the liberation of gold and silver particles that are interlocked in the sulfide or silicate minerals (Celep et al., 2011)"

Jan 1, 2015

By A. V. Bogdanovich

In diamond ores processing, final waste tailings size, rejected to dump, is one of the most important parameters. On one side, it is necessary to minimize losses of diamonds, whose size exceeds 1 mm, on the other side ? to provide for the plant high throughput and sufficiently low capital and energy costs, which is in greater part connected with disintegration process. Extensive laboratory, pilot-scale and commercial-scale dressability studies of different types of diamond ores have been performed at JSC ?Mekhanobr Engineering? in recent years. With that, special consideration was given to determination of the required ores? disintegration size that would provide for a high recovery of diamonds. In diamond ores processing, in order to exclude breaking of large diamonds, stage disintegration is used with regrinding of light fractions and heavy fraction X-ray fluorescent separation tailings. On account of rather weak bonds of diamonds with enclosing minerals, in crushing and grinding of diamond ores, selective disintegration takes place, with aggregates? breakup along plane surfaces of least bonding, which facilitates liberation of diamonds and their transition to free state. Heavy components losses with different sizes of final dump tailings were studied in processing of large samples. It was established, that in order to almost completely exclude losses of heavy components over 1 mm size, light fractions had to be ground to 2.5-3 mm size, while X-ray fluorescent separation heavy tailings of -15+3 mm size do not contain diamonds larger 1 mm in aggregates, and their regrinding does not increase total recovery of diamonds. On the basis of the conducted studies, relationships regarding heavy components and diamonds losses with respect to diamond ores final disintegration size were obtained, providing for more rational organization of the ores disintegration and processing flow sheet. Keywords: diamond, waste tailings size, disintegration process, recovery of diamonds

Sep 1, 2012

By Michael Perch

The fact that coal is a complex organic material and heterogeneous in composition has made its study extremely difficult, particularly in regard to obtaining a fundamental concept of the processes involved in the formation of coke. It has been stated recently that coals are natural polymers and that in a complex reaction such as occurs during carbonization the differences between coals are quantitative and not qualitative. Such being the case, it would be expected, therefore, that a series of coals subjected to exactly the same conditions of coking would produce results that should be related quantitatively to the chemical analyses of the individual coals. In the past, however, this fact was not generally recognized and consequently many empirical test methods were devised for testing coals. The interpretation of the results obtained depended upon comparing a set of data with other data on coals of known characteristics. The testing procedure had to be con- ducted in precisely the same manner each time and not the least requirement in making the interpretation was experience. The test methods varied from those utilizing a gram of coal to the plant-scale tests in which one or more ovens were charged with the test coal. The aim had been principally to find some simple, inexpensive means by which the coke-making and other properties of coal could be predicted. It is not necessary to emphasize the importance of these endeavors, for anyone acquainted with the problems involved in the selection of coals for making coke is well aware of the time and expense involved in making a series of definitive tests.

Jan 1, 1949

By F. Rashchi, A. Ghahreman, J. Moghaddam, S. Karimi

"In this work, the kinetics of ferric-ferrous redox reaction on a passivated sphalerite electrode is studied by the application of chronoamperometry method in 0.5 mol L-1 H2SO4 solution. The electrochemical behaviour of ferric and ferrous couple was investigated on two sphalerite minerals acquired from two different geological regions (Iran and Canada). The carbon paste electrode (CPE) of sphalerite was initially prepared and passivated in 0.5 mol L-1 H2SO4 solution and after reaching the steady-state condition, ferric and ferrous sulfate solution was added. The registered current density differences between the current density of the passivated electrode and that of the electrode in the iron salts added solution were interpreted for kinetics of ferric-ferrous reduction-oxidation reaction. The equilibrium potential for ferric-ferrous couple on sphalerites surface was about 500 mV vs. Ag/AgCl. The exchange current density (i0) for ferric-ferrous redox reactions on the sphalerite samples had the same magnitude of 10–6 A cm–2. The electrochemical impedance spectroscopy (EIS) measurements at 550 mV vs. Ag/AgCl illustrated that sphalerite oxidation was controlled by two charge transfer process in both of Fe-free and Fe-containing solutions. The charge transfer resistance remarkably decreased when Fe salts added to the 0.5 mol L-1 H2SO4 solution, owing to the ferric-ferrous redox reactions being the predominant reactions on sphalerite surface.INTRODUCTION Direct atmospheric leaching processes for sphalerite concentrates are performed by reduction of an oxidant (e.g. ferric ion and oxygen) and oxidation of sphalerite to zinc ions. Oxygen could be an oxidizing agent as well, but the concentration of oxygen is very low in the solution. The role of ferric ions is predominate in this oxidation (Babu, Sahu, & Pandey, 2002). The oxidation reaction for sphalerite in the presence of ferric in can be presented as follows (Lampinen, Laari, & Turunen, 2015):"

Jan 1, 2017

By C. G. Maier

Relatively infrequent use by metallurgists of the term "sponge chromium" as contrasted to more than occasional reference to "sponge iron" may be ascribed to the fact that the former material is not a commercial product, while the latter has been known and used, at least in one form (Swedish sponge iron), for several decades. It is doubtful whether a true sponge chromium ever has been prepared heretofore in the laboratory by more than one or two investigators. Nature presents a much. more difficult problem to the investigator endeavoring to make sponge chromium than pertains to the production of more easily reducible elements such as iron or nickel. Recent widespread interest among metallurgists in the possibilities of powder metallurgy is ample incentive to explore the feasibility of producing pure chromium metal in finely divided form. The shift in terminology of this statement from "sponge" to the "finely divided form" is deliberate in emphasis of distinction between terms that occasionally have been used loosely. It would seem desirable that a uniform usage descriptive of finely divided metals be adopted. While to some it might seem preferable that the terra "powdered" metal be reserved for a finely divided form produced by mechanical means, as, for example, chromium produced by the mechanical comminution of electrolytic sheets or flakes, current usage of the term "powder metallurgy' involves no distinction as to source type of material. It is usually accepted, however, that a sponge metal is one reduced from oxide or other combined form at temperatures below the melting point of metal or oxide so that the particles of metal are pseudomorphic, at least macroscopically, with the source material, and, in consequence of the loss of material without change of external shape of the particles necessarily have an open, porous, or "spongy" structure.

Jan 1, 1942

The Bureau of Mines has reviewed those portions of the "Tariff Schedules of the United States Annotated 1963" that are of interest to the minerals industry. This study shows to what extent rates of duty were altered (increased of decreased), and provides a bridge where possible from the old Schedule A classification system to the new TSUS system of statistical reporting of import data. In general the new tariff has corrected previous classification defects and inconsistencies, but the rates of duties have not been materially changed.

Jan 1, 1965

By K. K. Kelley

"INTRODUCTION The Bureau of Mines nitrogen peroxide process (2) 3/ for extracting manganese from low-grade ores is essentially a two-stage process involving the reversible reactionMnO2 + 2NO2 + 6H2O = Mn (NO3)2 . 6H2O (1).At lower temperatures this reaction proceeds to the rigth and affords a means of dissolving manganece and separating it from unreacted ore. At higher temperatures the reaction proceeds to the left and manganese dioxide is recovered and nitrogen peroxide regenerated for recycling. Evidently, therefore, the energy required for decomposition of manganous nitrate is a matter of practical importance. Similar information for certain other nitrates also is desirable beceuse the nitration step of the process produces appreciable amounts of nitrates of other metals, such as iron, aluminum, magnesium, calcium, and barium, some of which are not broken down in the evaporation and decomposition steps. Thus, a portion of the nitrogen peroxide is not directly available for recycling. Whether or not it is feasible to recover nitrogen peroxide locked in the more-stable nitrates depends partly on the energy required and the conditions necessary for their decomposition.To supply information bearing directly on these subjects, several researches were undertaken at the Pacific Experiment Station: (a) Heats of formation (24, 25, 26) of nitrates of manganese, magnesium, calcium, barium, and aluminum were measured at 298.2° K:; (b) low-temperature specific heats (23), in the range 51° to 298.2° K,, and entropies of nitrates of magnesium, calcium, barium, and aluminumm were determined; and (c) heat contents (21) above 298.2° K. of the nitrates of manganese, magnesium, calcium., and barium were measured. The results of these studies, when correlated by thermodymamic methods, permit evaluation, at any temperature of interest, of the energies required to decomposethe nitrates and furnish information concerning the equilibrium pressure temperature relationships."

Sep 1, 1944

By William Petruk

Image analysis studies were performed on mill products from pilot-plant and laboratory tests that had been conducted to determine the effect of grinding media on the selective flotation of two zinc-lead-copper ores. It was found that, when the ores had been ground to the same degree of fineness with flint pebbles, ceramic pebbles or ore fragments (autogenous grinding) as with steel balls, there generally was increased sphalerite, chalcopyrite and galena liberation in the flotation feeds, depending on the textures of the minerals. The increased sphalerite liberation fully accounted for the improved zinc recoveries that were obtained when steel balls were replaced by either pebbles or ore fragments. The increased chalcopyrite and galena liberation accounted for part of the changed technical efficiency of concentration, but other factors, probably changes in oxidation and reduction of iron and in consumption of oxygen, also contributed.

Jan 1, 1977

By William Petrul

Image analysis studies were performed on mill products from laboratory flotation tests of the Zn-Pb ore from the Faro deposit in Yukon, Canada, to determine mineral liberations at specific grinds and to predict recoveries at optimum flotation conditions. The minimum and optimum grinds for liberating sphalerite and galena were predicted from size analysis data for the minerals in large ore pieces, and determined by image analysis studies of the mill products. The determined optimum grinds are about 2 Tyler mesh sizes larger than predicted because sane of the fine grained sphalerite and galena occurs in interstices between coarser grained pyrite and is liberated when the pyrite grains are broken apart. Materials balance calculations were performed on the analyzed values for the liberated and unliberated sphalerite and galenaa to determine their distributions in the mill products. The laboratory flotation tests recovered 74% of the sphalerite and 83% of the galena in Zn and Pb concentrates respectively. The mineral evaluation study indicates that the optimum recovery for sphalerite and galena are 85 and 83% respectively. The company is currently recovering 80% 'of the sphalerite and 82% of the galena.

Jan 1, 1989

By J. F. Barkley

To aid in winning the recent world war, the Bureau of Mines conducted a National Fuel Efficiency Program, directed to commercial plants throughout the Nation, to save greatly needed fuel, a basic resource vital to industrial production. In planning this program it was realized that to accomplish a satisfactory reduction in fuel consumption in any plant, it would be necessary to reach, enthuse, and usually educate to some extent the actual operators of the various types of plant equipment. A major part of the programs consisted, therefore, of visits to plants and work with the operators, including a review with them of their operating conditions and of educational and guiding literature pertinent to the operating problems involved. Through a Nation-wide organization, local volunteer engineers served in making visits to local plants. Each cooperating plant appointed an employee as the "waste chaser," who headed the work of saving fuel in that plant. The educational literature was designed to interest the operator, as well as serve as a guide in eliminating waste of fuel. Volumes have been written on many subjects relating to the saving of fuel. Writings of the treatise type contain considerable good information but do not have wide appeal and probably will be read only by a few studious operators. The problem is not one of getting clown on paper everything that the experts know and would like to have the operator know, but rather to write something that will actually interest the operator and stimulate him to action. Past experience led to the adoption, therefore, of the "quiz-sheet" type of writing, using a quiz sheet of not more than two pages for any principal item. The results obtained during the National Fuel Efficiency Program in many types of plants further demonstrated that the short quiz sheet is satisfactorily appropriate and does accomplish results. Each sheet was prepared and checked by many engineers expert in the particular subject matter of the sheet. Committees of men with much experience in the manufacture and operation of equipment and in the

Jan 1, 1947

By K. Webb

At both the international and country level, the issue of how the mining sector and indigenous populations should engage on issues of mutual interest or concern has emerged as one of central importance and controversy; involving the mining industry, Aboriginal communities, governments, the courts, and other stakeholders. At its heart, stakeholder engagement is an ethical issue, although it manifests itself in international instruments, domestic laws, industry guidance and agreements. At the international level, the concept of ?free, prior and informed consent? (FPIC), while not subject to widespread agreement on the finer details of evolving definitions, seems to be emerging as an increasingly recognized engagement norm. Within Canada, through a series of decisions, the Supreme Court of Canada (SCC) has articulated a fiduciary obligation of the Crown to consult with and accommodate impacted Aboriginal groups on resource management issues. Provincial governments have been variously attempting to adjust their resource management regimes to stay in alignment with SCC and lower court decisions. Mining sector organizations, working with First Nations partners, have developed agreements to work together for mutual benefit. At the individual mine and community level, there have been instances of constructive engagement, as well situations of physical resistance and legal challenges. The purpose of this paper is to examine the potential impact of new rules under the Ontario Mining Act introduced in 2012 and taking full effect in 2013, which amongst other procedural specifications, addresses the issue of mining industry-Aboriginal consultation in exploration and development activities. Leading up to the passage of the regulations, representatives from some junior mineral exploration companies have been highly critical of the new rules. Similarly, there have been a range of responses to the new rules from some in the First Nations community. The paper will review the regulation in terms of its apparent alignment with SCC decisions and the international norm, compare the regulations with existing mining sector organization guidance documents, and it will draw on the stated perspectives and commentaries of First Nations communities, mining firms, governments, nongovernmental organizations, and others. Building on the foregoing, the paper will provide a preliminary analysis of the perspectives and potential impacts of the new regulation on various stakeholders, and on that basis, possible avenues for further consideration will be suggested.

Aug 1, 2013

By J. W. Thompson, M. N. RICH

That there is wide interest in the preparation and properties of metallic zirconium and its salts is indicated by the many articles recently published in scientific and technical journals and the many patents issued. The compounds of zirconium have numerous important uses and more uses will doubtless be found. In the course of the special work on rare metals that were of military importance during the war, the authors of this bulletin were detailed to the Golden mining experiment station of the Bureau of Mines to prepare metallic zirconium and to investigate its properties. A number of investigations in recent years have indicated that sintered or coherent zirconium metal is very resistive to acids; that it can be used for electrodes, and it probably will find metallurgical uses. A steel containing zirconium has been proposed for use in armor plate and automobile parts, and nickel-zirconium alloys have been suggested for high-speed cutting tools and for cutlery. Numerous articles in scientific journals have recommended the use of zirconium oxide as a refractory, an abrasive, a pigment in paints, and as an opaquing agent in enamel ware. The salts have been used in the textile industry' as a mordant and also for weighting silk. When the authors began their investigation, they found it necessary to collect all of the available literature on the general subject of zirconium and its compounds. Pure salts could not be obtained on the market, and in order to get these, as a preliminary step to the preparation of the metal, the literature had to be classified and the methods of preparing the salts investigated. Also, there was much difficulty at first in making satisfactory analyses, and this phase of the work received careful attention. As it was necessary to begin with a historical review of the literature, such a review is given as Part I of this report, and a bibliography is included as Part IV. References to the numbered items in this bibliography are made throughout the text, the usual footnote references being omitted. Analyses of the products and conclusions as to their purity are given under the descriptions of methods of preparation. A table showing the properties of the amorphous metal, and another showing the properties of the coherent metal, will be found under appropriate headings in Part II. No attempt has been made in the historical review to discuss fully all the published information about zirconium and its compounds, but only such material has been assembled as has a direct bearing upon the present work. Considerable difficulty was experienced in collecting this material because of the confusion of terms by various authors who perhaps did not thoroughly understand the chemistry of zirconium.

Jan 1, 1921

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

By K. Darcovich

The wettabilities of agglomerates made from coals of several different ranks were measured by the adhesion technique. Oil levels from 0 to 10% by weight were used. As was expected, it was found that higher-rank coals are more easily oil-wetted and that the surface properties of the agglomerates correlate with agglomeration recovery and ash removal data.

Jan 1, 1992

By R. E. Morgan

Two sizes of Pennsylvania anthracite were gasified in the new-type Lurgi pressure generator at the Dorsten, Germany, works of the Steinkohlengas, A. G. These tests demonstrated that Chestnut-size anthracite and a Rice-Buckwheat mixture containing 27 and 19 percent ash, respectively, could be gasified satisfactorily at an elevated pressure in a fixed bed with oxygen and steam. These coals were especially prepared to approximate a rough-cleaned coal and a washed and screened product. The operating data obtained from the two tests and materials requirements are summarized. A wide range of reactant ratios could not be tested, nor could optimum operating conditions be determined, as the generator was being used throughout the testing program, employing normal operating practices, to produce gas for the gas grid; and the most economical coal, steam, and oxygen ratios may not have been used. Comparative costs are presented of the raw materials required for producing a high-B.t.u. gas, based on the operational data obtained from these tests and, to some extent, on data extrapolated from laboratory experimentation. A flowsheet of a proposed process for producing a high-B.t.u. gas by Lurgi gasification, followed by methanation, is also included.

Jan 1, 1958