Search Documents

By Edwin F. Nelson, Charles Wirth, Gustav Egloff, C. D. Maxutov

The treatment of emulsified crude oils has been a problem for years in the petroleum industry. Until comparatively recently various methods of settling with and without chemicals have been used with indifferent success. Since wells have been acidized, emulsified crudes have been produced, which add considerably to the need for improved methods of treatment. The presence of large quantities of salts in the oils from acidized wells has presented several new problems to the industry. The use of hydrochloric acid in well treatments has caused the formation of sodium, magnesium, and calcium chlorides by interaction with the dolomitic limestones. These salts dissolve readily in the water normally present in the oil, and they are therefore incorporated in the emulsified oil. The crystalline salts have also been found in the oil, prevented from settling by protective films such as asphalt, resins and petrolatum. In some instances, free hydrochloric acid has been found. The salts may be present in crude oil in amounts ranging from a few pounds to over 1000 lb. per 1000 bbl. of oil. The transportation of these crude oils through pipe lines has led to erosive and corrosive effects, which are a tremendous cost to the petroleum industry. During 1937, more than 1,200,000,000 bbl. of crude oil was transported through pipe lines. Of this quantity approximately 10,000,-000 bbl. was water, and considerably more than 50,000,000 lb. was salts. If the crude oils were treated at the producing wells to remove the salts and water, an appreciable saving would be possible. The treatment would not be difficult, since it has been found that these oils are more easily treated at the time they are produced than after the aging and more stable emulsification that occur before they reach the refinery. Since great costs are involved in the use of these salty crudes at the refinery, treated oils essentially free of salts would naturally command a premium. The real added costs lie in refining salt-containing crude oils. Severe corrosion of refinery equipment in both topping and cracking installations has appeared in many refineries. Chemicals such as ammonia, lime and

Jan 1, 1938

By Richard Borg

The partial molal free energy of Cd in each of the four intermediate phases, Cd3 Cu, Cd8 Cu5, Cd3Cu4, and CdCu2 is determined using the Knudsen vapor pressure technique. Measurements are made also within the two-phase regions, and thus the variation in FCd is now known across the entire phase diagram. The absolute values are all less the 2.0 kcal and increase regularly with increasing Cd concentration. The small absolute value of the free energy precludes the possibility of obtaining highly accurate values; nevertheless, the results are compatible with those previously reported for the liquid phase. Additional results are reported concerning the lattice parameters of the 6, E, and b phases. THE elements Cu and Cd combine to form four intermediate phases which are designated* and E and which include respectively the following inter metallic compounds: CdCu2, Cd3Cu4, Cd3 Cu5, and Cd3 Cu. The extent of each phase with respect to temperature and composition is shown in Fig. 1 which is the equilibrium diagram drawn according to Hansen.1 All four phases are brittle, and most probably are true intermetallic compounds. Only the crystal structure of the 6 phase has been thoroughly investigated.2,3 The structure is cubic and isotypic with y brass. The structure of Cd3 Cu has not been previously reported, It is hexagonal with a = 8.11 and c = 8.76 0.02Å and the structure is presently being determined.* The compounds Cd3 Cu4 and CdCu, have been each previously the subject of a single investigation. Cd3Cu, is presumed to be cubic4 with the space group Fd3m, whereas CdCu2 is hexagonal2 with the C14-type structure. Cu2 Cd is found by X-ray analysis to be hexagonat with lattice parameters a = 5.00A and c = 16.17Å. The material appears to be pure Cu2Cd as all reflections could be indexed on the basis of the single hexagonal structure. These values disagree with those of Kripyakevich and coworkers5 who report a = 4.96Å and c = 7.98Å. Their investi-

Jan 1, 1962

By James P. Kimball

Sulphur is always present in mineral coal of every variety. In the oxidized state it may exist as sulphuric acid in combination with a base. In the unoxidized state it exists in combination with iron as bisulphide of iron. It is also supposed by some chemists to exist in unknown combinations with the organic elements of the coal. This supposition requires the demonstration as a fact that certain coals yield more sulphur than what may exist in a free state, or what belongs to recognized combinations, not only with the accompanying iron but with other inorganic bases abundantly occurring in coals, but which unfortunately are very rarely estimated. This practically as well as theoretically important question it is at present impossible to decide, simply for want of available thorough ultimate coal analyses including the ash. Such analyses, at the best imperfect, are luborious and intricate, and therefore seldom made, the much simpler proximate analyses, so-called, being resorted to by most chemists for technical purposes, and commonly substituted for more scientific work even in the laboratories of government surveys. And it is unfortunate enough that few ultimate analyses are extended to the composition of the ash, much less to its relation to the original constitution of the coal. Sulphur chiefly occurs in most coals in the form of yellow pyrites (pyrite) and white pyrites (marcasite), both minerals, characterized by differences in crystalline form and in physical properties as well as in color, but having the same chemical composition (FeS2). No coal is entirely free from one or both of these dimorphous forms of bisulphide of iron. It may be disseminated through the mass so as to be invisible, in plates or scales between the laminæ of the coal, or in conspicuous segregations or nodules, sometimes of considerable dimensions. Coals greatly differ as to the proportion of sulphur which they contain. They also differ as to the relative proportion in which its several forms of combination occur. Such qualitative and qnantitative disparities arc scarcely, if at all, more marked in separate coal seams of a uniform type than in different parts of one and the same coal seam, whether it be considered locally as constituted of several

Jan 1, 1880

By James P. Dr. Kimball

SULPHUR is always present in mineral coal of every variety. In the oxidized state it may exist as sulphuric acid in combination with a base. In the unoxidized state it exists in combination with iron as bisulphide of iron. It is also supposed by some chemists to exist in unknown combinations with the organic elements of the coal. This supposition requires the demonstration as a fact that certain coals yield more sulphur than what may exist in a free state, or what belongs to recognized combinations, not only with the accompanying iron but with other inorganic bases abundantly occurring in coals, but which unfortunately are very rarely estimated. This practically as well as theoretically important question it is at present impossible to decide, simply for want of available thorough ultimate coal analyses including the ash. Such analyses, at the best imperfect, are laborious and intricate, and therefore seldom made, the much simpler proximate analyses, so-called, being resorted to by most chemists for technical purposes, and commonly substituted for more scientific work even in the laboratories of government surveys. And it is unfortunate enough that few ultimate analyses are extended to the composition of the ash, much less to its relation to the original constitution of the coal. Sulphur chiefly occurs in most coals in the form of yellow pyrites (pyrite) and white pyrites (marcasite), both minerals, characterized by differences in crystalline form and in physical properties as well as in color, but having the same chemical composition (FeS2). No coal is entirely free from one or both of these dimorphous forms of bisulphide of iron. It may be disseminated through the mass so as to be invisible, in plates or scales between the laminæ of the coal, or in conspicuous segregations or nodules, sometimes of considerable dimensions. Coals greatly differ as to the proportion of sulphur which they contain. They also differ as to the relative proportion in which its several forms of combination occur. Such qualitative and quantitative disparities are scarcely, if at all, more marked in separate coal seams of a uniform type than in different parts of one and the same coal seam, whether it be considered locally as constituted of several

Jan 1, 1880

By R. D. Lindsay

Originally the focus of Deak Resources Corporation Business Plan was to establish a method for treating small gold and possibly base metal mineral deposits located in the Kirkland Lake - Noranda area of Northeastern Ontario, Northwestern Quebec at a central treatment facility. Since the establishment of this original business plan in 1988 other processing options have availed themselves for handling the base metal ores off site at a central facility which may preclude their processing at Deak.The site selected for the Deak processing plant was Kerr Addison's Virginiatown operation. At the time this property was acquired from the Receiver following Golden Shield Resources' Bankruptcy in 1989 the mill had been processing in the order of 1, 100 SDT per calendar day through one processing module; a module originally designed to process 1,500 SDT/day of a free milling gold ore. This tonnage level however had not been achieved since 1966 when an average throughput of 1481 SDT per calendar day was recorded.In order to realize Deak's overall Business Plan it would be necessary to expand the mills processing capabilities to provide:(1) A 2200 SOT per day circuit capable of processing a free milling, medium work index gold ore;(2) a 1 ,000 SDT per day flotation and/or cyanidation circuit capable of processing refractory gold bearing materials containing refractory minerals (i.e. copper) that should be removed prior to cyanidation; and possibly(3) a 1200 to 1500 SDT/day base metal circuit capable of processing the broad range of Deaks' Base Metal Property ores. If this circuit were introduced it would be completed in two tonnage phases.Further, it was recognized when operations resumed under Deak in 1990 that the existing tailings dam was suitable for, and had sufficient capacity for additional gold tailings with necessary physical modifications and changes in disposal techniques (including the construction of containment storage cells) that would allow storage for an additional 3.4 million tons of gold ore tailings approximately 1.0 million of which has been deposited since 1990. The focus of Deak's long term tailings disposal strategy is to acquire the Barber Lake Basin which is currently adjoined to our main tailings system which will provide an additional 10 million tons of storage capacity.

Jan 1, 1993

By E. C. Harder

CERTAIN typical characteristics of bauxites, ores of aluminum permit their classification into a number of categories, each of which has special features that enable grouping within it deposits from widely scattered bauxite fields. There may be local variations in conditions that have introduced differences of lesser importance between similar deposits in different fields, resulting perhaps from the influence of factors other than those that have produced the distinguishing features of each of the different groups, but in general the similarity between the deposits in each group is sufficiently striking to make the grouping indicated of interest. Several factors and conditions enter into the decomposition process that results in the development of bauxites and laterites and affects their character. The principal conditions favoring optimum bauxitization are: (1) pres- ence of rocks with easily soluble minerals yielding residues rich in alumina; (2) effective rock porosity, enabling easy access and free circulation of water; (3) normal to abundant rainfall alternating with dry periods; (4) vegetation, including bacteria, advantageously distributed; (5) available sources of appropriate solution and precipitation agencies; (6) a tropical or at least a warm climate; (7) low to moderate topographic relief, allowing free movement of the water table but a minimum of erosion; and (8) long quiet periods in earth history. Assuming that all of these factors are operating to a greater or less degree, it seems that the one that affects most the physical character of the resulting bauxite or laterite deposits is the chemical and mineralogical composition of the rocks that by their decay yield the bauxite deposits. This factor is used in the classification followed in this paper. In the process of weathering of ordinary silicate and carbonate rocks of the earth's crust, whether of igneous or sedimentary origin, it is the minerals of the alkalies that yield most readily to attack. The alkaline earth compounds also offer no great resistance, particularly the carbonates. Thus, among the rock-forming elements, those producing the most insoluble compounds are aluminum, iron, and silicon, together with certain ones of less importance, such as titanium, manganese, and phosphorus. In normal weathering processes such as prevail in temperate regions, the common minerals of rock decay are

Jan 1, 1952

By M. J. Sinnott, J. C. Tobin

A technique for collecting and analyzing the small quantities of gases desorbed on heating metal powders has been developed. The gases collected from copper powders of various types of manufacture have been analyzed and found to contain H2O, CO2, and SO2. The quantities of gas evolved vary from 0.05 to 1.0 milliliter, under standard con-ditons of temperature and pressure, per gram of powder. The source of the gas has been traced to surface films on the powder. IN the powder-metal industry it is recognized that the presence of gases in the powders affects the processing and resulting properties of the sintered product. Several sources for these gases are possible; namely, chemical reactions with the sintering atmospheres, inclusion. of gases during compacting, dissolved gases in the metal powder, and sorbed gases on the metal-,powder surfaces.1, 2, 3 Since the quantities of the gases are relatively small, no direct attempt has been made to collect and analyze them nor to isolate their source. The work that has been done has been concerned with the dimensional stability of the product., its porosity, density, or mechanical and physical properties. Conclusions are drawn on the basis of studies of this type as to the probable effect of gases on these properties. 4, 5, 0 In the present investigation an attempt has been made to obtain quantitative data on the analysis and quantities of gases associated with copper powders manufactured in different ways. Apparatus was constructed to collect gases evolved from loosely packed powder samples on heating to various temperatures under a reduced pressure of helium. The powders were outgassed thoroughly in a vacuum prior to starting the collection operation in order to eliminate mechanically entrapped gases and to prevent the possible reaction of the powder with these gases. Experimental Procedures Materials—The major portion of the investigation was carried out on a single heat of water-atomized, oxygen-free, high-conductivity copper. A relatively coarse fraction of this powder, 20 to 100 mesh, was tested as a mixed powder and as various graded size fractions. The microstructure of this powder showed equiaxed grains and was clean and free from oxides and oxide eutectic. The particle size, as determined

Jan 1, 1959

By S. F. Shaw

In 1913, the Tiro General mine, at Charcas, S.L.P., Mexico, which had been making from 125 to 150 gal. of water per min., was allowed to become flooded, after all the pumps had been removed, and in 1918 the problem of unwatering it came up for solution. There are two vertical shafts, the Tiro General, 1390 ft., and the San Fernando, 1225 ft. in depth, with five connecting levels between them. The San Fernando shaft had been partly retimbered, while the Tiro General had been newly timbered from the collar to 1090 ft. in depth. It had been possible to place guides in only one compartment of the Tiro General, from the collar to the seventh or 850-ft. level, to which it was necessary to lower the water before station pumps could be installed. Soundings indicated that compartments in the Tiro General were open to 1082 and 428 ft., and in the San Fernando shaft to 471, 488, and 586 ft. The water had risen to a point 140 ft. below the collar of the Tiro General shaft.. Pumping Equipment The steam plant at the Tiro General shaft includes one 300-hp., one 150-hp. and one 100-hp. Erie City water-tube boiler, and two 160-hp. Heine water-tube boilers. All but one of these boilers were supposed to be in good shape, but it was soon discovered that six years of idleness in a climate that is foggy for several months of the year had left them in poor condition. The compressed-air plant comprises one Nordberg cross-compound compressor with piston displacement of approximately 2500 cu. ft.of free air compressed to 96 Ib. per sq. in.; and another Nordberg cross-compound with piston displacement of 1235 cu. ft. of free air, to the same pressure. The main pump station is on the seventh level where had been installed a Prescott pot-valve plunger pump with capacity of 200 gal. per min.; also a Gould triplex plunger pump with capacity of 135 gal. per min., driven by a 6 1/2 by 10 by 12 in. steam engine. From the lower levels, the water had been raised to the seventh level by small station pumps and sinking pumps.

Jan 1, 1920

By Sir Robert Hadfield

LAST year this Institute was good enough to accept some remarks by the writer regarding sound steel, entitled Plant for Hadfield Method of Producing Sound Steel Ingots, being a continuation of a research in which for some time the writer has been engaged, and full particulars of which were submitted in papers entitled A New Method of Revealing Segregation in Steel Ingots, and Method of Producing Sound Ingots, read before the Iron and Steel Institute in October, 1912. These papers gave rise to a very interesting discussion, both in England and America. This question is one of vital importance, as unless sound steel in the form of ingots is first obtained, sound steel in the finished forms of rail billets, rails, bars, sheets, and other forms cannot be expected. The working stresses demanded by modern conditions are so great, each year they probably approach nearer to the limit of safety, that without doubt those who produce steel will be compelled to pay the attention which this subject deserves. Moreover, the problem is not an insuperable one, as shown by the writer in the papers above referred to. In view of the information which has already been presented in these papers, it is not now necessary to go into details of the system advocated by the writer, except to repeat that the ingots and steel now referred to were produced by employing in the first place sound fluid steel, free from blowholes, this being poured into ordinary ingot molds, provided with the necessary feeding heads, the insulating slag medium, also charcoal and air blast or other suitable form of applying heat to the head portion of the ingot. Tile upper or head portion of the ingot is kept fluid by the intense heat generated by the air blast and charcoal, so that such fluid steel passes into the body of the ingot below the head, thus feeding and avoiding the shrinkage or piping which would otherwise occur. The result is the production of a sound steel ingot, free from blowholes, segregation and piping, and in which the waste portion, usually termed the discard, is but little over 7 or 8 per cent.

Jan 4, 1914

By H. S. Martin

ALTHOUGH it was known some years ago at the- Utah Copper Co. mills that fine grinding improved flotation recoveries, no accurate data were available until recently as to just how far the grinding could be carried economically. In 1923 the ultimate degree of fineness for flotation feed was supposed to be about 10 per cent. on 65 mesh, with approximately 55 per cent. through 200 mesh, which meant that most of the mineral would pass 100 mesh. At this time Garfield and Wilfley tables were used ahead of flotation and a good deal of the coarse mineral removed prior to the ball mill regrind. Shortly afterwards, mill-scale tests developed the fact that on a feed containing not over 10 per cent. +65¬mesh material flotation alone would give a copper recovery equal to that obtained by the combination of tables and flotation, but that on much coarser feed the recovery with flotation alone was lowered. This was at a time when all the sulfide minerals were floated if possible, so that the only requisite was to grind fine enough to free the mineral from gangue. EARLIEST USE op MICROSCOPIC EXAMINATION OF TAILINGS As early as 1921, the writer had attempted to determine by chemical analysis the relative proportions of copper minerals in tailings from an ore that made extremely poor flotation results. Chemical analysis was not satisfactory or conclusive, and samples of these tailings were sent to the U. S. Bureau of Mines Station at the University of Utah for micro-scopic examination. The question at that time was to determine, if possible, which copper minerals had been lost and why, but R. E. Head, in his report, revealed other interesting data. He said in part: Briefly stated, the mineral particles or grains may be classified into separate groups as follows: 1. Free grains of pyrite, chalcopyrite, chalcocite and bornite, respectively, which contain no other included sulfides; 2. Grains in which all three of the copper sulfides are represented (the core may he of chalcopyrite, partially altered to bornite, these two minerals being entirely surrounded by a shell of chalcocite); 3. Grains composed of equal amounts of bornite and chalcocite or chalcopyrite and chalcocite.

Jan 1, 1929

By T. H. North, A. G. Glover, R. J. Pick

"Girth welding operations represent the rate-limiting step in pipeline construction. A joint industry-university program was set up to establish the field welding characteristics of large-diameter, high-strength line pipe.Theoretical work carried out at the University of Waterloo showed that pipe wall thickness and joint misalignment prior to welding has a marked influence on the lifting stresses acting on the root pass of girth welds. Pipe diameter and pipe ovality had negligible effects. Super-position of lifting and residual stress (caused by the fusion welding operation) highlighted regions of the weld bead most susceptible to hydrogen-induced cracking.The field welding characteristics of 1219-mm-diameter, 13.72-mm-wt Grade 483 line pipe were evaluated using a specially designed test rig. The principal test variables were lift height, delay time after root pass deposition, preheat temperature, pipe composition and joint misalignment prior to welding. For any given life, preheat and joint misalignment prior to welding had the most significant effect on cracking tendency.The output of this program has industrial significance and illustrates the beneficial features of university-industry collaboration.IntroductionField welding operations comprise the rate-limiting step during pipeline construction. Crack-free girth welds must be made in a wide range of weather conditions and consequently the field weldability of line pipe compositions directly affects pipeline integrity and construction economics.Pipe-laying practice comprises root bead deposition followed by a skidding operation involving lifting (or lowering) the pipe length onto skid s so that the next pipe length can be aligned prior to welding. Consider pipeline construction using 24.4-m lengths of 1219-mm-diameter , 13.72-mm-wt Grade 483 pipe weighing approximately 10,000 kg. Skidding involves loading a 3-mm-thick root bead by moving the free end of the pipe through vertical distances of up to 700 mm . The likelihood of cracking in these circumstances depends on the inherent crack susceptibility of the pipe composition employed, on the hydrogen content of the deposited weld metal and on how well the joint handles the external stressing caused byskidding."

Jan 1, 1981

By R. L. Templin

The increasing use of aluminum and its alloys in commercial fields tias demanded a better understanding of their machining properties. This fact is exemplified by problems that have arisen in the automotive and airplane industries, but many in other fields might be cited. As pure alunlinum and its alloys in their various commercial conditions show appreciable differences in their machining properties, it is not surprising that quite divergent solutions have been offered for the machining problems encountered. However, if the fundamental requirements of the most suitable cutting tools for these metals are understood, these machining problems lend themselves more readily to satisfactory solutions. Since the machining of free cutting brass and mild steel is understood by most persons accustomed to working these metals, it may serve our purpose better to first make a general comparison of the tools more commonly used in machining these metals with the tools most suitable for machining aluminum, then proceed to a more specific discussion of the individual tools. Comparison oF Cutting Tools Cutting tools commonly used for machining free cutting brass usually have little, if any, top and side rake; they are ground on a medium to coarse abrasive wheel and used without any cutting compound or with a cutting compound that has a paraffin base. Those ordinarily used for steel have some top and side rake, are usually ground on a medium to fine abrasive wheel, and are often used with soluble-oil cutting compounds. The proper tools for aluminum and its alloys should have appreciably more side and top rake than the tools for cutting steel; should have very keen edges obtained by grinding with fine or very fine abrasive wheels supplemented in many cases by hand stoning with an oil-stone; and should be used with suitable cutting compounds whenever possible. In many cases, tools suitable for machining aluminum and its alloys are not appreciably different from tools commonly used for cutting hardwoods. The front clearance of a tool most suitable for machining aluminum and its alloys should be about 6°, the top rake from 30" to 50°, making the total angle of the cutting edge of the tool from 35' to 55". A side

By K. J. Brouwer, J. P. Haile

"Construction of the first stage of the tailings disposal facility for the Montana Tunnels Project was completed in October 1986. The project is located 37 km south of Helena, Montana, and involves mining of42 million tons of weathered diatreme are at a rate or 13 500 tpd to produce a gold/silver dore, as well as lead and zinc concentrates. The tailings disposal facility for the project includes a fully drained tailings impoundment for storage of the tailings solids, and a process waterpond for storage of all decanted water prior to recyling to the mill. The over-all facility is designed to achieve the basic objectives ofminimizing seepage to the environment in the short- and longterm, and achieving a fully drained stable tailings mass suitable for immediate reclamation on completion of mining. Specific features of the design include a soil bentonite seal and drainage system within the tailings basin, a free draining embankment with a design flow-through capacity of 4000 US gpm and an ultimate height of 230 ft (70 m), and a soil bentonite lined make-up water pond with a capacity of 420 acre-feet (530 000 m'). The tailings will be discharged in a rotational sequence through multiple spigot offtakes to achieve a thin-layer low energy laminar flow. This 'sub-aerial' deposition results in higher stored densities and maximizes liquid-solid separation on the tailings beaches. The over-all design played a major role in the successful permitting of the project, and was significantly cheaper than a conventional wet disposal system, with overall unit costs for tailings disposal of less than US$0.36 per ton.This paper outlines the site characteristics and the tailings material properties and their influence on the design. Extensive use was made of naturally occurring free draining materials as well as bentonite modified soil liners within the tailings basin, embankment and retention ponds. General construction procedures for the various components are described, as well as on-going construction requirements utilizing materials from the open pit. Finally, the over-all costs and unit costs for tailings disposal are presented."

Jan 1, 1988

By R. L. Templin

THE increasing use of aluminum and its alloys in commercial fields has demanded a better understanding of their machining properties. This fact is exemplified by problems that have arisen in the automotive and airplane industries, but many in other fields might be cited. As pure aluminum and its alloys in their various commercial conditions show appreciable differences in their machining properties, it is not surprising that quite divergent solutions have been offered for the machining problems encountered. However, if the fundamental requirements of the most suitable cutting tools for these metals are understood, these machining problems lend themselves more readily to satisfactory solutions. Since the machining of free cutting brass and mild steel is understood by most persons accustomed to working these metals, it may serve our purpose better to first make a general comparison of the tools more commonly used in machining these metals with the tools most suitable for machining aluminum, then proceed to a more specific discussion of the individual tools. COMPARISON OF CUTTING TOOLS Cutting tools commonly used for machining free cutting brass usually have little, if any, top and side rake; they are ground on a medium to coarse abrasive wheel and used without any cutting compound or with a cutting compound that has a paraffin base. Those ordinarily used for steel have some top and side rake, are usually ground on a medium to fine abrasive wheel, and are often used with soluble-oil cutting compounds. The proper tools for aluminum and its alloys should have appreciably more side and top rake than the tools for cutting steel; should have very keen edges obtained by grinding with fine or very fine abrasive wheels supplemented in many cases by hand stoning with an oil-stone; and should be used with suitable cutting compounds whenever possible. In many cases, tools suitable for machining aluminum and its alloys are not appreciably different from tools commonly used for cutting hardwoods. The front clearance of a tool most suitable for machining aluminum and its alloys should be about 6°, the top rake from 30° to 50°, making the total angle of the cutting edge of the tool from 35° to 55°. A side

Jan 1, 1928

By R. Herrera-Urbina

Measurements of the electrophoretic mobility of bastnaesite in aqueous solutions of sodium nitrate reveal that the isoelectric point (iep) of this cerium fluocarbonate occurs at about pH 9.3. These results also indicate that the pH affects significantly the electrophoretic mobility of bastnaesite, which becomes more positive as the pH decreases and more negative as the pH increases from the iep. Computations of solid-solution equilibria for the bastnaesite-H2O system closed to the atmosphere as a function of pH indicate that cerium fluoride precipitates in acidic solutions, whereas cerium hydroxide precipitates in alkaline solutions. When the initial amount of bastnaesite is fixed at 0.05 wt.% (the solids concentration used for electrokinetic experiments), these computations reveal that bastnaesite is the only solid phase in the pH range from 5.75 to 8.55, it coexists with CeF3(s) between pH 5.22 and pH 5.74, and with Ce(OH)3(s) between pH 8.56 and pH 10.12. Cerium fluoride and cerium hydroxide are the only solid phase below pH 5.2 and above pH 10.2, respectively. According to these computations, the dissolution-precipitation processes that occur when bastnaesite is equilibrated in aqueous solutions at different pH values determine the solid phases present in the system. In turn, these processes must affect the electrokinetic potential at the solid-solution interface, and they must be considered for explaining electrokinetic measurements as a function of pH when bastnaesite is the original solid phase in aqueous suspensions.

By Chu E. Ho, Paul Napoli

A new waterfront park was developed on Long Island in close proximity to the East River and Newtown Creek. The existing ground consisted of fill over soft organic clay, medium dense silty sand, glacial till and schist bedrock. The ground was initially raised to preload the underlying soft soils to stabilize the ground in preparation for site development. The ground was subsequently cut down to temporary grades for installation of foundation piles for the overlook structures and construction of reinforced concrete cantilever retaining walls forming pathways located adjacent to the water bodies. The retaining walls were located in two rows at different elevations along the sides of a steep embankment. Where the pathways converge, some of the walls were too close to each other, and were redesigned as a combined U-wall with a common base slab. The individual retaining walls were designed for adequate bearing, sliding and overturning resistance. Ground anchors were installed to enhance global stability of the retaining walls. This paper presents the design considerations for the retaining walls for various loading conditions, and evaluation of the trial and proof tests for the anchors. INTRODUCTION The New York City Master Plan included the transformation of an approximately 30-acre parcel of land in Long Island City, Queens, New York from a former manufacturing zone into a residential, commercial and recreational zone for middle-income community. The site was located at Hunters Point South along the eastern shoreline of the East River and Newtown Creek (Figure 1). The development included low to high- rise residential buildings, a public school, and retail structures. Open spaces were provided along the East River and Newtown Creek waterfronts in the form of a continuous park providing for recreational and community-related activities. Waterfront structures included small park buildings, walkways and viewing platforms. The shoreline was surrounded by revetments as part of the flood mitigation strategy. The project involved extensive site re-grading and several retaining walls were constructed. The earthwork volume amounted to approximately 47,000 cubic yard of imported fill and 93,000 cubic yard of cut. The exposed height of the retaining walls ranged from 3 to 15 feet. This paper focuses on the design and construction of the retaining walls for the project.

Jan 1, 2019

The Bureau of Mines has reviewed those portions of the "Tariff Schedules of the United States Annotated 1963" that are of interest to the minerals industry. This study shows to what extent rates of duty were altered (increased or decreased), and provides a bridge where possible from the old Schedule A classification sys tem to the new TSUS system of statistical reporting of import data. In general the new tariff has corrected previous classification defects and inconsistencies, but the rates of duties have not been materially changed.

Jan 1, 1965

By A. S. Watts

The Bureau of Mines has been conducting an investigation of the feldspar resources of the New England and North Appalachian States with a view to greater efficiency and economy in their utilization. Such an investigation was deemed necessary, not only because of the continued and increasing consumption of these minerals, but especially because of the demand for better technical control of the raw materials that are used by the white-ware industries of the United States. Most manufacturers of white pottery wares have only a limited knowledge of the origin, mode of occurrence, and methods of mining and preparation of the materials that they use. Heretofore, owing to a belief that the supply of raw material was unlimited, the manufacturer had concerned himself chiefly with the solution of the problems of manufacture. Within the past few years, however, it has been found that difficulties arise in manufacture which can be traced beyond the manufacturing process and are believed to be due to a need of better control of the materials used. Furthermore, as competition becomes more severe, more attention must be paid to selection of materials in order to minimize consumption and also to avoid unnecessary expense for transportation of material. Doubtless the lack of interest as regards these details has arisen from the fact that in the past a considerable proportion of the whiteware ingredients has been imported and the manufacturer has been forced to rely on the samples submitted and the general uniformity of the source of supply to insure against variation of the material. An extra precaution arising from this lack of definite knowledge still prevails in the common practice of never depending on one source of supply for anyone ingredient. Often the products of three or more producers are blended so that if anyone shall vary without warning the variation arising from its use will not be sufficient to ruin the ware.

Jan 1, 1916

This paper will review some of the work conducted in the past at the Dynamic Effects Laboratory to examine the use of stress waves and fracture mechanics in understanding dynamic fracture and fragmentation in blasting applications. Along the way, we will use photoelasticity and high speed photography to better understand the mechanisms of fracture and fragmentation.

Jan 1, 2015

By C. G. Maier

The fundamental chemistry of zinc smelting, especially that part dealing with the chemical reduction of the zinc-oxide content of a roasted zinc ore, has been discussed by metallurgists in some detail, but, in the light of present knowledge, unsatisfactorily. A considerable portion of the information available has been qualitative, or quantitative in a sense that could not be interpreted chemically. A number of attempts to elucidate the physical chemistry of zinc oxide reduction have been based upon unsubstantiated and, as is now known, incorrect equilibrium data. To write upon the chemistry of zinc smelting at this time, when electrolytic methods for the production of zinc metal from ore are becoming increasingly widespread, may seem a belated effort. So, for example, C. A. Hansen,3 in the communicated discussion of an article by the author,4 writes as follows:

Jan 1, 1930