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By E. R. Darby

When bronze is melted in open-flame furnaces a considerable amount of slag is formed during the melting operation. This slag may be incidental to the melting practice or it may be formed intentionally by slag-forming constituents added to the furnace charge to provide a covering for the melted metal When this slag is removed from the furnace, it contains, in addition to the free metal carried with it by the skimming operation, a considerable amount of metal as oxide either combined or mechanically mixed with it. By the usual crushing and washing methods this metallic oxide generally goes to the tailings pile, so diluted by other foundry waste that its recovery is economically impossible. If this furnace slag is not inixed with other foundry waste, practically all of the metal oxide as well as the free metal may be recovered by some form of smelting operation. The first side of the problem to be considered is the amount of slag produced. It may not be true that the majority of foundries have no record of the amount of slag made, but it is certainly true that a very great many either have no record or pay little attention to it. Usually the collection of furnace slag for one normal week's run will be sufficient to determine the advisability of its being handled in a different manner from the crushing and concentrating generally employed. If a large representative sample of the accumulation is crushed and concentrated and the recovery compared with the results of a careful assay, it will be found that a large percentage of the total metal content was lost in the washing process. The percentage of loss will be greater than the metallic oxide content, as some free metal in extremely fine particles always is carried away in grains of slag. From such a comparison, it may be determined whether or not the slag should be melted, sold or treated as before. An example of an actual test of this kind is given below. In a foundry melting 50,000 to 80,000 Ib. of bronze per day, a week's accumulation of furnace slag and ladle skimmings amounted to 16,500 1b.—over three times as much as the foundry superintendent estimated before the accumulation was made. Two tons of this material was taken as representative of the lot. This was ground through a thoroughly cleaned ball-mill and concentrated over a Wilfley table. The

By M. J. Kovalik, D. E. Wolfson, F. Fischler

Plastometric tests were made to determine the maximum thickness of the plastic layer for different U.S. coals . The effect of test variables on the maximum thickness of the plastic layer was studied . The values for the maximum thickness of the plastic layer were found to be related to the Gieseler maximum fluidity , plastic temperature range , free swelling index , and other plastic properties of coals . Only a general relationship was observed between the plastometric parameters obtained in these tests and the coking properties of coal .

Jan 1, 1964

By W. W. Weller

Heat capacity measurements of anhydrous cobalt sulfate (CoSO4), copper sulfate (CuSO4), nickel sulfate (NiSO4), and zinc sulfate (ZnSO4) were conducted over the temperature range 51° to 298° K. The results were used to evaluate the following entropies at 298.15° K (cal/deg mole): CoSO4, 28.1; CuSO4, 26.8; NiSO4, 24.8; and ZnSO4, 26.4. Entropies were combined with heats of formation to give free energies of formation.

Jan 1, 1965

By C. B. Manula

This report is mainly concerned with the modification and development of a users manual for the Open-Pit Materials Handling Simulator (OPMHS) developed at Penn State. Model Modifications included the introduction of a free-format input, the application of a Weibull random generator, facilities to stochastically simulate shovel-dragline operations, and routines to increase the flexibility in making truck assignments. At the same time, core storage requirements and execution times were minimized and all P.S.U. conventions were removed to allow operation on other computing systems.

Jan 1, 1976

By Kwangmin Kim, Taehee Lee, Minkyu Kim, JUNHYEOK PARK

Mine tailings storage facilities (TSFs) can be a significant source of fine, respirable dust. About 25 percent of the mass fraction of tailings from a hard-rock mine consists of particles of a respirable size (smaller than 10 μm) [1]. This dust poses concerns, especially for nearby communities, because of its detrimental impact on respiratory health. Respirable tailings dust, primarily composed of quartz or free silica (SiO2), may cause silicosis, chronic pulmonary disease, bronchitis, collagen vascular diseases, and chronic granulomatous infections [2]. 

By K. K. Kelley

This report contains heat-content values for hexagonal crystalline germanium dioxide between 298.15° and 1,350° K., and for germanium dioxide glass between 298.15° and 1,800° K. experimentally determined by the Federal Bureau of Mines. No similar data for these substances are to be found in the literature. The heat-content and corresponding entropy-increment data are presented both in tabular form and by equations. Free energy of formation values are estimated for germanium dioxide glass at 298.15° and 1,800° K.

Jan 1, 1961

By J. E. Hamak

This publication contains analyses and related source data for 151 natural gas samples from 19 States. Of the total samples, 138 were collected calendar year 1989. The remainder were collected earlier, but releases to were not received until 1989. All samples were obtained and analyzed as part of U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1990

By Alexandre Bonan

The paper reports on the results of a kinetic study on the oxidation reaction of aqueous free cyanide ions with H202, in the presence of Cu(2+) catalyst. The variables and respective ranges studied were the following: (CN) ° = 10 -100 mg/l pH = 10 -11 (H202/CN) mol ratio = 1 -3 (Cu/CN) mol ratio = 0 -0.25 The results lead to the development of a semi-empirical model whish incorporates both the useful oxidation reaction and the parallel alkaline decomposition of H202.

Jan 1, 1992

By M. Niec

Lignite deposits in Poland occur within clastic Tertiary series at the depth suitable for opencast mining. Aboundant aquifers with the good quality waters that should be protected against contamination or depletion often accompany them. Landscape and underground water protection are the main regional environ-mental factors that limit the possibility of exploration and mining; presented on map of lignite bearing series distribution allow to delimit areas "free" for exploration and mining and areas where some limitations can be met up to no admittance of any industrial activity.

Jan 1, 1994

By Alejandro Berrios, Matheus DaSilva, Erick Siqueira

Vazante mine is an underground polymetallic mine that produces zinc, lead, and silver, which belongs to Nexa Resources in Minas Gerais, Brazil. The mine, a sublevel stope underground mine, mainly applies two subvariants: VRM – Vertical Retreat Mining and Open Stope. In a specific place of the mine, the geology allowed the design of a production stope with larger dimensions than the standard stopes, commonly called Super Stope. At this place, the plan was to apply both sublevel variants simultaneously. This mining block comprises rings in two different levels, with access by two ore drives on each level; the dimensions would be approximately 50 meters high, 50 meters long, and 35 meters wide. Opening the Free Face to mine the whole Stope was a challenge due to operational issues, such as hazard risks from loading over void space, exposure to uncontained places, and the impossibility of implementing the optimal blast sequence. Wireless blasting initiators have gained popularity recently due to their convenience, safety, and efficiency. This initiation system was applied to preload all the rings required to open the Free Face, ensuring a safe and optimal blast sequence. Wireless initiation prevented hazard risks, enhanced the blast sequence to guarantee the required void space, and optimized the equipment's operational cycle. The blast crew carried out the activity without exposure to the risk of loading over void space. The wireless detonators also avoided after-blast activities, which were required to provide secure access to the blast crew, optimizing the operational cycle.

Jan 21, 2025

By J. L. Hill, M. A. R. Sharif, J. Lin

"A numerical algorithm has been developed to simulate the movement, breakup, and entrapment of the oxide film inclusions encountered during the mold-filling processes of aluminum castings. The flowfield is solved using the well-known Marker and Cell (MAC) method by a time marching process. The Volume of Fluid (VOF) method is used to track the free surface boundaries. A kinematic approach is employed to track the movement and breakup of the oxide films on the free surface or in the bulk liquid metal. The computer program based on the proposed algorithm is able to model the flow behavior and oxide film movement, breakup, and entrapment in mold cavities for aluminum castings.IntroductionMetallographic and fractographic studies of the aluminum castings show tangled networks of oxide films in the castings. These oxide films can form in the furnaces or during the mold filling processes. Green and Campbell [I] concluded that the oxide film defects dominate the strength of aluminum castings. The main cause of oxide film entrapment into the bulk molten metal during the casting processes is the surface turbulence. In film-forming alloys, if the surface breaks, due to a drop, a fountain, or a breaking wave, then the surface film is folded over and incorporated into the bulk liquid. The incorporation of surface films leads to cracks in the casting and other defects that are nucleated by the presence of the folded films, such as porosity and hot tears. Campbell [2] estimated that up to 80% of scrap in light-alloy casting is the result of surface turbulence."

Jan 1, 1999

By Henrique Kahn, Daniel Uliana, Carina Ulsen, Guilherme Nery

"Gold has been a material in high demand since the dawn of humanity. After hundreds of years of exploitation, the increasingly search for gold occurs in lower grade deposits with greater extraction difficulty. Therefore, for maximum efficiency, deep knowledge of the characteristics of these minerals and their associations is crucial, which is acquired through an accurate and rigorous routine of process mineralogy and batch extraction tests. The industrial gold process extraction occurs by gravity concentration, sulphides flotation and cyanidation. For gravity concentration, it is fundamental to establish the proportion of free or coarse gold grains and its association to heavy minerals; regarding flotation, the most relevant data are the proportion of gold associated to sulphides and their liberation by the surface area; for cyanidation, it is crucial to evaluate gold accessibility and the kinetics of leaching. Thus, the characterization of gold associations and liberation is vital to establish the plant design, to optimize operating plants and to reduce gold losses. Our aim is the characterization of gold occurrence in low-grade Brazilian deposits with complex mineralogical assemblages to support processing flowchart definition and to predict metallurgical recoveries. Gold distribution in light and heavy minerals was evaluated by heavy liquid separation and the occurrence of gold in free or locked particles was carried out on heavy products by SEM-based automated image analysis using the MLA system. All the products of heavy liquid separation were cyanidated in head samples with different milling conditions to evaluate the reaction kinetics and maximum recovery."

Jan 1, 2014

By R. Agius, A. Nacu

"Adoption of the International Cyanide Management Code, regulatory requirements and community concerns have increased the need to implement suitable cyanide destruction processes at gold operations to meet ever more stringent discharge limits. As standards set for the allowable concentrations of cyanide, cyanide compounds and other contaminants may vary from country to country, jurisdiction to jurisdiction, and even from site to site, there is no “one size fits all” technological solution. Currently the most common cyanide destruction processes used in industry are sulfur dioxide/oxygen, hydrogen peroxide and Caro’s acid. Regardless of the process used, cyanide destruction plants must be reliable and achieve permit guidelines at all times. The selection of the most appropriate cyanide destruction process for an operation depends on several factors, including permit discharge requirements, tailings chemistry, location, site-specific climatic conditions and size of the operation. Only after considering all these factors together can the most effective approach be selected to achieve the permit guidelines economically and technically feasible. Finally performing the correct test work program is the most important step to ensure that the correct process design criteria can be determined to accurately calculate capital and operating costs.IntroductionThe adoption of the International Cyanide Management Code in 2005, stricter regulatory requirements and community concerns prompted by environmental incidents involving cyanide have increased the need to implement cyanide destruction processes at gold and silver operations.Process solutions associated with the extraction of gold and silver contain several forms of cyanide. The most toxic form of cyanide is free cyanide, which can be present as a dissociated cyanide anion (CN-) or gaseous or aqueous HCN. Weak or moderately stable cyanide complexes such as those of zinc, copper and nickel are classified as weak acid dissociable (CNWAD). Although less toxic than free cyanide, weak acid dissociable cyanide complexes are considered “ecologically sensitive” forms of cyanide and are regulated in most jurisdictions. In practice, reported WAD cyanide values are comprised of both free cyanide and weak acid dissociable cyanide complexes. Cyanide complexes with gold, mercury, cobalt and iron are referred to as strong acid dissociable complexes (CNSAD) and are much more stable even under mildly acidic conditions. Another term commonly used in cyanide chemistry is total cyanide, which represents all cyanide compounds present in solution, with the exception of cobalt complexes. Total cyanide levels in solutions are in most cases higher than WAD cyanide values and the difference between the two usually indicates the presence of iron-cyanide compounds. Typically, in Canada CNTOTAL levels cannot exceed 1 mg/L in solutions."

Jan 1, 2017

By John Nagy

Experience and research have shown that an effective way to reduce structural damage from explosions is to provide adequate pressure-relief vents in the walls of equipment and buildings within which explosions might occur. In general, free or unrestricted openings represent the most efficient type of vent. However, in many manufacturing operations it is impractical to use free vents, and it becomes necessary to cover the openings with diaphragms or blow-out disks, hinged panels, or other devices, in order to give protection against weather changes, to prevent the efflux of dusts or vapors from equipment during normal operations, or for other reasons. A few data on the pressure-relieving capacities of hinged panels and a paper diaphragm were published in Bureau of Mines Report of Investigations 3924, which covered the first phase of the dust-explosion venting study made by the Bureau. The present report describes recent experiments that were made to determine the relative effectiveness of an unrestricted vent and 22 types of closures, including various paper, cloth, and metal-foil diaphragms, hinged doors or panels, and several kinds of scored and unscored glass panes. The tests showed that many of the vent closures were effective in releasing the explosions rapidly during their incipient stage, so that the development of destructive pressures was prevented. Vents of this type should prove useful in safeguarding industrial equipment from severe explosion damage. The experiments disclosed that the venting capacities of the diaphragms are approximately inversely proportional to their static bursting strengths.

Jan 1, 1950

By J. E. Zeilinger, John Nagy, Irving Hartman

"INTRODUCTION Experience and research have shown that an effective way to reduce structural damage from explosions is to provide adequate pressure-relief vents in the walls of equipment and buildings within which explosions might occur. In general, free or unrestricted openings represent the most efficient type of vent. However, in many manufacturing operations it is impractical to use free vents, and it becomes necessary to cover the openings with diaphragms or blow-out disks, hinged panels, or other devices, in order to give protection against weather changes, to prevent the efflux of dusts or vapors from equipment during normal operations, or for other reasons.A few data on the pressure-relieving capacities of hinged panels and a paper diaphragm were published in Bureau of Mines Report of Investigations 3924,4/ which covered the first phase of the dust-explosion venting study made by the Bureau. The present report describes recent experiments that were made to determine the relative effectiveness of an unrestricted vent and 22 types of closures, including various paper, cloth, and metal-foil diaphragms, hinged doors or panels, and several kinds of scored and unscored glass panes.The tests showed that many of the vent closures were effective in releasing the explosions rapidly during their incipient stage, so that the development of destructive pressures was prevented. Vents of this type should prove useful in safeguarding industrial equipment from severe explosion damage. The experiments disclosed that the venting capacities of the diaphragms are approximately inversely proportional to their static bursting strengths."

Jan 1, 1950

By M. B. Shongwe, G. Freemantle, M. Botha, S. Brill, J. D. Steenkamp

During steelmaking, one important factor for production efficiency is the free opening of the ladle nozzle during continuous casting. Free opening occurs when the well filler sand and the steel flow freely when the slide gate is opened. Well filler sands are used for the slide gate of a ladle to separate the slide gate refractory and the molten steel. The well filler sand is partially sintered by the heat of the molten metal, which can result in the ladle nozzle failing to open if the sand is not sintered to an appropriate extent. It is therefore of great importance that the sintering behaviour of well filler sand is understood. We studied the effect of the well filler sand chemistry on its sintering properties. Samples of well filler sand with various chemical compositions were sintered in a high-temperature chamber furnace. Quantitative X-ray diffraction (XRD), inductively coupled plasma optical emission spectrometry (ICPOES), and wavelength dispersive spectrometry (WDS) by electron microprobe analysis (EMPA) were used to analyse the various well filler sand mixes. Points of analysis were indicated on backscattered electron (BSE) micrographs. Quantitative element mapping was undertaken by energy dispersive spectrometry (EDS). Thermodynamic calculations in FactSage predicted the percentage liquid phase present for the various well filler sand compositions at equilibrium conditions. The results of this work show that the degree of sintering of chromite-silica well filler sand depends strongly on the silica content. The amount of liquid phase formed increases with increasing silica content.

Feb 2, 2022

By D. Scott Scovira, Thomas Gustavsson

The potential of hydrogen peroxide explosives was introduced to Thomas Gustavsson and Robert Håkland by Dr Miguel Araos through his development of hydrogen peroxide gel compositions (HPG). In 2020, Thomas and Robert developed a concept project with Boliden Minerals and received Swedish government funding to evaluate HPG technology in a mine environment. The project showed HPG reacted violently with mine mineralization and concluded that HPGs did not offer a commercial solution due to safety concerns. Thomas and Robert engaged with Stefan Nilsson to develop hydrogen peroxide emulsion (HPE) compositions and the process techniques to manufacture them. In 2021, laboratory work produced a promising low carbon intensity, nitrate free, ammonia free, emulsion formulation based on industrial grade hydrogen peroxide and a fuel-emulsifier phase. Design and construction of an HPE pilot plant and underground charging unit commenced. The manufacture of hydrogen peroxide emulsion shares several similarities with the production of nitrate-based emulsions in that the plant is a facility to blend a strong oxidizer solution with a liquid fuel phase into a finished emulsion. A key differentiator between HPE and nitrate-based emulsion is that the manufacture of HPE is a cold production technology in that neither the oxidizer phase (HP) nor the fuel-emulsifier phase requires high temperature heating to prepare raw materials. A successful proof-of-concept HPE evaluation ran from April 2022 to October 2022 at Boliden’s Kankberg underground mine in Sweden. This evaluation demonstrated HPE technology's safety, performance, production, handling, and indicative environmental benefits.

Jan 21, 2025

By W. T. Gotheridge

The principal sources of coal-dust underground are, of course, coal, and the working of coal. Coal-dust is most dangerous when it is in the finest state of division. This class of dust is found mostly on the roads, being blown or shaken off the loaded trams in transit, or carried in suspension by air currents. The air current passing from the working faces may also carry dust in suspension into the return airway, and the air current from the surface may carry dust from the shakerscreens into the intake airways. The mosl dangerous dust we have to contend with is, (a) that which is most finely divided, and (b) that which contains the most volatile matter, including the inflammable occluded gases, and also oxygen absorbed from the air. According to experiments, coal-dust in a fine and dry state would intensify an explosion, in air free from fire-damp carrying in excess of 3 ozs. of fine dust or 6 ozs. of coarse dust per cubic yard. The volatile matter in the dust must be between 12 and 31 per cent. in the ash-free coal, the latter percentage giving the highest flame velocity. It is vary difficult to propagate flame where coal-dust contains a large percentage of stone-dust, (say 50 per cent.). Shale-dust or other incombustible dust containing no volatile hydro-carbons or carbonaceous matter will prevent the extension of an explosion if mixed with coal-dust in proportion of say 70 per cent., and if the dust is finely divided and dry.

Jan 1, 1924

By E. P. Pfleider, W. G. Pariseau

Even as the rational selection of excavation equipment requires a matching of machine performance capabilities to rock response characteristics, the functional features of transportation systems must be matched to the characteristics of the materials handled in order to secure optimum, trouble-free operation. In particular, ore passes and chutes must be designed for flow in order to insure controlled draw whenever a chute is opened. The alternative to quantitative design is, of course, the well known ad hoc procedure of freeing plugged ore passes, cleaning up spillage from flooded chutes, etc., after installation of the system. Since the voluminous empirical work sporadically undertaken through the years evidently had not led to reliable design methodology, it seemed worthwhile to attempt a rational and complete description of the movement of material through ore passes. The concepts of de- formable body mechanics applicable to gravity-induced flows of granular media or "soils" were involved. Accordingly, the mathematical theory of soil plasticity was adopted as a working hypothesis, and a two-dimensional laboratory model of an ore pass constructed in order to investigate the appropriateness of the theory. The general experimental strategy consisted of formulating the movement of material in ore passes as a boundary value problem in soil plasticity, determining the required boundary values of stress and velocity experimentally, and then using these data for the initiation of a theoretical solution for stress and velocity throughout the moving mass of material. A comparison between the theoretical and experimental constituted the test of the original hypothesis.

Jan 6, 1968

By C. B. Manula

This report is volume 9 of an eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment. The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation,' and ventilation. This volume of the final report describes the Water Generator subsystem of the Master Design Simulator. This subsystem simulates the flow of water through a typical watershed-reservoir combination to predict mine drainage quantities in underground workings. The model is a integrated one which handles both the unsaturated and the saturated flow domains as a unified system. The solution of the model is achieved by numerical tech¬niques of finite difference method coupled with finite elements analysis. The Water Generator can be operated either as a free standing model or in connection with the Geology and Reserves subsystem as a part of the Master Design Simulator. A case study is included illustrating the application of the model to actual data. The appendices of the report constitute a user's manual for the program, and include a program listing.

Jan 1, 1975