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By Liu Zhonghua

Hydrogen reduction of cobalt sulfide (Co9S8) was experimentally investigated in the temperature range 813-1053 K. The results revealed that the reaction kinetics can be described by the shrinking core mod¬el in chemical control regime at low temperatures, it is of first order with respect to hydrogen concentration, and the reaction activation energy is 67.4 kJ/mol. The SEM second electron images of the samples before and after experiments showed that the swelling of the sample above 973 K is due to the formation of metallic cobalt whiskers.

Jan 1, 1992

By Otis M. Clarke

Although most bauxite mined is used to make metallic alu¬minum, more than a million tons of bauxite is used annually in the United States in the manufacture of refractories, chemicals, abrasives, and cement. Raw material requirements are becoming increasingly difficult to meet because high-grade bauxite, required for some uses, is limited. The supply of raw material for high-alumina refractories is most critical because a low-iron bauxite is needed. Although there are substantial bauxite reserves in the world, bauxite suitable for use in refractories is limited to a few districts.

Jan 1, 1977

By Lewis T. Wright

IT is commonly believed by metallurgists that in copper-smelting, the copper in the slags, which is irreducible by continued smelting, is retained in the form of "prills" of matte. I have frequently held well-settled slag in a molten condition for a long period without being able thereby to reduce the copper-content. The slag acted as though it contained a minimum of dissolved or combined copper that could not be settled out by gravity. I have used reagents, but without satisfying myself in what form this copper existed. The same slags, by fine grinding and elutriation, could not be separated into portions containing more or less copper than the average content. By treating copper-slags in an electric furnace an impure button of copper. was produced, but the high temperature and the strong reducing-action of the furnace were influences that suggest an explanation of a result not obtainable with ordinary smelting-temperatures. If all the copper in the slag were in the form of copper-matte, and not existing as a dissolved compound with some of the elements of the slag, then the other metals in the matte, such as gold and silver, should occur in the slag in the same ratio to the copper as to the copper in the accompanying matte. This reasoning led me to study the ratio of metals in the products of smelting, and, apart from the issues discussed in this paper, the research has proved both interesting and illuminative. On the assumption of a similar ratio of metals in matte and slag, if the percentage of copper in the slag accompanying; a matte containing 50 oz. of silver and 1 oz. of gold per ton of copper was 0.3 per cent., or 96 oz. per ton of slag, there should be found 0.15 oz. of silver and 0.003 oz. of gold per ton of slag:; but, in my experience, there is less silver and much

Sep 1, 1909

By Alan Kissock

MOLYBDENUM is thought of as one of the rarer elements, for though it occurs in almost every country of the world it is seldom found in commercial quantities. In this country, however, there is one deposit which makes the term "rare" a misnomer. There are two commercially mined molybdenum minerals: molybdenite, the sulfide, and wulfenite, a lead molybdate. Of these two only the former is of any con- sequence but wulfenite is of mineralogical interest. It is frequently associated with oxidized lead ores and particularly in arid sections. Deposits, however, are usually quite superficial. It is highly oxidized and yet it does not appear to be an alteration product for it apparently disappears below water level and I know of no case where primary molybdenite, or in fact any molybdenum whatever has been identified below these surface wulfenite occurrences. The genesis of wulfenite would make an !- interesting study.

Jan 1, 1933

By P J. Borrington

Offering 1000 hour salt spray protection, the KEYCOAT 1000 coating presents no chipping, cracking or deformation when hammered or flexed through 90 degrees or more. This cost-effective metal protection system features lubrication performance equal to molybdenum disulphide and Poly Tetra Fluoro Ethylene (PTFE) grease providing complete anti-seize protection whilst aiding assembly and disassembly. In addition, the coating is impervious to acids, alkalis, solvents and attack by oils and all fuels. KEYCOAT 1000 has been exhaustively tested in three main industry sectors - automotive, heavy earthinoving vehicles and chemical - where it lias been proven to outperform conventional systems in all respects and as the film formed is less than one thousandth of an inch thick (typically 20 microns), it rarely presents the engineer with any tolerance difficulties. KEYCOAT 1000 is one of a w ide family of products which offer protection and lubrication to a wide industry base, from aerospace to food and with temperatures ranging from minus 190 C to plus 30 C.

Jan 4, 1997

By J. Kent Smith

VANADIUM is generally spoken of as a rare element; but, even in the light of our resources as known a couple of years ago, this description could be accepted in a qualified sense only. In fact, vanadium is very widely distributed, being a constituent of most clays, while even caustic soda has been shown to contain almost regularly a minute proportion of it, although the quantity in each case is so small as to render impracticable the extraction of the metal there from with profit. The opening-up of a large deposit of vanadium sulphide ore in South America has put a new phase on the commercial outlook of vanadium, the technical value of which for the improvement of steel has been proved by rigorous scientific investigation.

Sep 1, 1907

By Laura Suarez, Jörgen Kajberg, Pär Jonsén

How does an investigation into the breakage characterization of electric arc furnace (EAF) manganese slags contribute to a more responsible usage of resources throughout the life cycle of steel products and reduction of carbon emissions? The main goal of this study is to increase the knowledge on the mechanical response of manganese slag to open the potential of pyrometallurgical residues to become secondary material in industrial applications such as infrastructure construction, fillers, binders and soil stabilization, among others.

Mar 1, 2024

By Philani Larrance Ngwenyama, Ronald CW Webber-Youngman

The survival chances of trapped miners in underground mines depend on how quickly they can be located and rescued post-accident. During entrapments, emergency rescue is highly desired but can be hindered by the lack of positioning information when a fit-for-purpose missing-person locator system is not available. Various types of missing-person locator systems are available to aid search-and-rescue operations. From the wide range of the available systems, selecting the most suitable one becomes the next challenge. The available systems have not been measured if they are fit-for-purpose or not, and to what situation. This study proposes user requirements that can be used as a guideline to facilitate the system selection process. These user requirements provide a framework for the design and development of a fit-for-purpose missing-person locator system. The user requirements can also be used for evaluating the performances of a particular system, predict its success, and also drive future research toward developing new technology to enhance the capabilities of the current systems.

Apr 1, 2024

By AMAN SONI, JONATHAN G. BAGGETT, Nino Ripepi, JUAN J. MONSALVE, Richard Bishop

Underground stone mines are vulnerable to karst void formations due to the erosion of carbonate rocks by groundwater flow. The voids or cavities may lead to hazards including ground collapse and sudden outflow of clay-rock sediments during the development of the mine. This study evaluates the effect of karst voids on the strength of pillars in an underground room-and-pillar limestone mine. Ground-penetrating radar (GPR) surveys were interpreted to map the void boundaries inside a karst-affected pillar. A combination of LiDAR scanning and virtual discontinuity mapping is used to formulate the discrete fracture network (DFN). Discrete element modeling (DEM) helps simulate the effect of karsts and discontinuities in the pillar models with varying stress. It is observed that the cavities may lead to a significant reduction in pillar strength. Apart from posing a hazard to miners and machinery, any advance into these cavities may disrupt mine operations. This research serves as an initial step toward understanding the importance of pillar design in underground stone mines affected by karst voids to prevent local instability or pillar failures.

Sep 1, 2022

By Manuel Pérez-Tello, María M. Salazar-Campoy, Óscar Rodríguez-Hoyos

The Kaldo furnace is a type of top-blown, rotary reactor that is widely used for the production of precious metals. During the production of doré, a gas jet of compressed air is injected through a water-cooled lance to impinge upon the molten bath surface in the presence of molten metal and a slag phase. A common problem during operation is the difficulty in controlling the distance that the injection lance can penetrate through the reactor mouth without being splashed by the molten phases. Splashing may produce accretions on the lance surface as well as plugging of the nozzle at the lance tip. An additional problem may occur when the gas jet impinges upon the furnace wall and causes rapid wearing of the refractory linings. Because the conditions prevailing in the Kaldo furnace offers poor visibility to the human eye, its operation mostly relies on the empirical knowledge of plant operators and process engineers. A systematic study in a scale model of the Kaldo furnace under controlled laboratory conditions may be valuable to estimate the maximum penetration distance of the injection lance, and thus help improve the operation of an industrial reactor. From a fundamental perspective, the observation of the basic features of the flow patterns in the scale model may help elucidate the relevant phenomena governing the hydrodynamics in this type of system.

By JOHN HOMER, KATHLEEN STABRYLA, JACOB L. CARR, JONATHAN K. HRICA, JENNICA L. BELLANCA

Given the recent focus on powered haulage incidents within the U.S. mining sector, an appraisal of collision avoidance/warning systems (CXSs) through the lens of the research literature is timely. This paper aims to evaluate the maturity of CXS technology through the application of a technology readiness assessment (TRA) to research literature identified by systematic search methods. Results indicate that much of the evidence for CXS performance is at lower levels of maturity: that is, components and prototypes tested in a laboratory and in relevant environments. Less evidence exists for CXS performance at higher levels of maturity — that is, systems evaluated within operational environments — despite the existence of commercial products in the marketplace. This lack of evidence at higher maturity levels within the scientific literature highlights the need for more peer-reviewed research to evaluate CXS technologies. Additionally, results of the review reveal that most of the literature relevant to CXS technologies is focused on vehicle-to-vehicle interactions, which contrasts with haul truck fatal accident statistics that indicate most are due to vehicle-to-environment interactions, such as traveling through a berm. Lastly, the relatively small number and segmented nature of relevant studies suggest there is a need for more incremental research that would better facilitate the improvement of CXS technologies. This progression could be achieved through continued long-term interest and support for CXS technology research.

Mar 1, 2023

By Kristian E. Waters, Hao Ma, Haibei Wang

Heavy metal ions exist in waste effluents including mining tailings, manufacturing discharges, and smelting and metal plating process wastes. Various methods are available to treat industrial effluents containing high levels of metal ions, but when confronted with wastewater that has low metal ion concentration below 500 mg/L, most techniques suffer from low removal or separation efficiency as well as high operating cost. ELM-based techniques can be used to solve these problems.

Apr 1, 2023

By Qinghua Tian, Zhipeng Xu, Dong Li, Xueyi Guo, Liu Zhu

Tellurium (Te) is an important scattered metal. Known as the vitamin of modern industry, national defense and cutting-edge technology, it is the supporting material for new high-technology materials. Currently, its separation and extraction from Te-bearing materials face problems such as long flowsheets and high reagent consumption, giving rise to an urgent need to develop new methods for its recovery.

By YONGQIONG YANG, Ning Wang, CHONGGUANG LUO, LI ZHU, Hanjie Wen, SHENGJIANG DU, Hannian Gu

Kaolin clay from Late Permian sequences has been considered a potential resource for niobium (Nb) due to high concentrations reported at several hundred micrograms per gram and large areal distribution. A previous case study identified titanium (Ti)-bearing minerals associated with kaolin clay as the main host phases for niobium. Correlation between the Nb and Ti concentrations was poor, however, and the types of Ti-bearing minerals and modes of Nb occurrence were unclear. To investigate this, typical kaolin clay samples from Late Permian sequences in southwest China were characterized, and final products derived from them were investigated using X-ray fluorescence (XRF), inductively coupled plasma-mass spectrometry (ICP-MS), X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and energy-dispersive X-ray spectroscopy (EDS). The results revealed three types of titanium dioxide (TiO2) mineral phases in the clay samples: (1) massive TiO2 minerals, (2) aggregates of nano TiO2 minerals and (3) granular TiO2 minerals. The first two did not contain niobium. From the EDS analysis, the granular TiO2 minerals, including anatase and rutile, were the source of Nb in the kaolin clay samples. 

By Rambabu Pothina, Rajive Ganguli

The economics of a mineral-processing circuit is dependent on the numerous sensors that are critical to optimization and control systems. When a sensor goes off calibration, it results in errors that can have a severe impact on plant economics. Classical statistical approaches fail to detect when errors are “subtle,” unless they grow and become large enough to be “gross,” whereas methods based on signal processing and artificial intelligence fail in dealing with the complexity of process fluctuations. Due to the sheer volume of sensors, undetected errors are not remedied until the next calibration, which on average are a year apart across all industries [1]. This research aims to detect such subtle errors (2 percent bias) in shorter time spans of about a month — rather than wait for errors to grow — using innovative data-mining techniques and algorithms.

By Ning Wang, Tengfei Guo, Wanyan Li, Hanjie Wen, Hannian Gu, Zehai Li

Red mud has been reported as a potential resource for lithium. To investigate the leaching behavior of lithium, a lithium-rich red mud was neutralized with hydrochloric or oxalic acid and then leached with acetic acid. When red mud was neutralized using dilute hydrochloric acid, about 58 to 60 percent of lithium was leached with 25 percent acetic acid at 95 °C for 60 min, while more than 95 percent of sodium and 85 percent of calcium were dissolved in the leachate solution. When oxalic acid was used to neutralize red mud prior to acetic acid leaching, lower lithium leaching efficiencies of about 42 to 47 percent were observed. Nevertheless, these leaching efficiencies of lithium were close to that of calcium and much higher than those of sodium under the same conditions. In this study, 25 percent (v/v) of acetic acid at 85 °C for 60 min was demonstrated to be the optimum conditions for lithium extraction from oxalic acid-neutralized red mud using acetic acid. The results are useful and of interest for lithium recovery and purification from red mud.

By A. ALLANORE, OLIVEIRA M. DE, D. CICERI, D. P. CHEN

The alkaline hydrothermal processing of K-feldspar rocks in an autoclave can be a pathway to synthesize a potassium fertilizer for tropical soils that is potentially cheaper and more efficient than traditional potash (KCl). When K-feldspar undergoes hydrothermal alteration in the presence of calcium oxide (CaO), it generates a complex mixture of calcium-aluminum-silicate-hydrate (CASH) minerals that incorporate K atoms stochastically in their structure. These atoms are subsequently released, as shown in a test-tube leaching test, indicating a possible uptake by crops. The relationship between the processing temperature and time in the autoclave for the hydrothermal reaction and the resulting mineralogy and elemental release are only partially understood and are investigated in this study. Elucidating that relationship is the key requisite for subsequent techno-economic analysis, and ultimately for the development of a fertilizer that can be considered as a feasible alternative to KCl.

By Mustafa Kumral, Mehmet Balci

Strategic mine planning focuses on cutoff grade selection, capacity planning and block sequencing. Despite significant knowledge accumulated, potential value can be added to mineral sourcing by addressing various aspects. A case study on a metallic deposit with a lognormal grade distribution examines if grade/metal distribution influences cutoff grade selection. Six data sets with different shape and scale factors, but the same ore tonnage and metal quantity, are analyzed. Results indicate deposits with lower shape and scale factors are more sensitive to metal price and discount rate changes. The study also investigates the effect of economies of scale (EoS) on project value, focusing on the ratio of variable cost to total cost (capacity factor). Two regression analyses are conducted for optimal capacity planning and cutoff grade selection. The first shows capacity planning is highly sensitive to the EoS of mining and mineral-processing costs, with grade variability and metal distribution being negligible. In the second analysis, grade variability and EoS of mineral processing costs are vital for cutoff grade selection.

Sep 1, 2024

By Fouad Faraj

For every blast pattern, zones of unique material types need to be classified before mining. Most material types can be summarized into different kinds of ore and waste. Blocks generated from blasthole assays are too small to be selectively mined, so areas with a single material classification meeting the mine’s selective mining unit must be defined. Current industry standard practices are to manually draw ore/waste dig limits, but this process is subjective and results in quantities of dilution and ore loss that can be improved upon to enhance the profitability of mining operations. In this study, two weeks of production data from a homogeneous copper (Cu) porphyry and heterogeneous manto-type Cu deposit were used to assess the variability in the hand-drawn dig limits of 20 geologists, mining engineers and ore control specialists, which were compared with the optimal ore/waste delineation. The profit for 20 distinct hand-drawn dig limits for the homogeneous mine varied by 3.7 percent, from $10.5 million to $10.9 million, averaging at $10.8 million. The percentage was nearly double for the more heterogeneous mine at 5.9 percent, from $17.9 million to $19.0 million, averaging at $18.6 million. Using the optimal ore waste delineation, the profit increased to $11.0 million (1.9 percent increase) and $19.3 million (7.0 percent increase) for the homogeneous and heterogeneous deposit, respectively. The natural variability, diggability requirement and selectivity are identified as the main drivers of ore loss and dilution. Recommendations are provided for reducing the subjectivity in manual hand-drawn dig limits by integrating dig limit optimization algorithms as a tool to assist practitioners.

Oct 1, 2024

By THOMAS BAMFORD, Dale S. Preece, Amir Behbahanian, Mick Lownds

An important aspect of blasting is rock movement and final muck configuration. Computer modeling of this process has been done in 2D for many years, revealing insights into the blasting process and enabling some design optimization. Since blasting is inherently a 3D process, 2D modeling misses the 3D aspects of blasting results and can lead to inaccurate conclusions. Software development environments in many fields are evolving in 3D, enabled by steadily increasing computer speed, memory, and software efficiency. These same environments are also available for modeling of many physical processes, including rock blasting. This paper documents the development of 3D blast movement modeling techniques that utilize 3D computational mechanics and modern computing environments to predict explosive induced movement of hundreds of thousands of distinct cubic elements representing the rock mass. Blast induced ore travel and final location can now be predicted with reasonable accuracy and acceptable run times. The importance of Energy Partitioning was documented and demonstrated by GEM-2D (Geologic Element Motion) at the ISEE conference in 2024. This software is titled GEM-3D and includes this Energy Partitioning capability. This paper documents a GEM-3D example of ore movement during rock blasting and demonstrates ore dilution as well as the final location of different rock types as influenced by the blast.

Jan 26, 2026