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By L. D. Eccleston

Any man-made structure will eventually decay, but we are basically concerned with the prevention of corrosion within a fairly limited time span. How corrosion can be minimized by design, the removal of oxides and a careful choice of paint systems is discussed, and mention is made of the electrical nature of most anticorrosive systems. Also discussed are the characteristics of certain paint binders and how mechanical properties will differ for various environments. Corrosion of a substrate by acidic breakdown products of some paints is mentioned in conjunction with a discussion on convenience versus ultimate performance. A brief mention is made of the three main components of a paint system, and the principal types of paint are placed in broad categories, with the main strength and weaknesses of each type listed.

Jan 1, 1979

By R. J. Traill

Introduction Following the discovery of high-grade deposits of pitchblende in the Great Bear Lake area of the Northwest Territories by Mr. Gilbert LaBine in May, 1930, samples were submitted to the Mines Branch for examination and investigation as to suitable methods of treatment (1). The purpose of this paper is to present, briefly, the results of the investigative work conducted on the ores and an outline of the methods developed for the extraction of the radium content and recovery of the by-products. The paper is presented in two parts. Part I gives a review of the history of radium production and of the principal processes used in other countries. Part II describes the work and gives the results of the Mines Branch investigation. Part 1-Radium Production In Other Countries Historical Outline Uranium was discovered in 1789, and more than a century later Madame Curie, while studying the physical properties of this element, observed that the ore of uranium exhibited greater activity than the pure uranium com-pounds she had prepared and traced the cause to the presence of a new element which she named radium. Eventually, research proved radium to be a disintegration product of uranium, and always present in uranium ores.

Jan 1, 1933

By J. E. Murphy

Purification of samarium metal by sublimation and by vaporization from a low-melting metal flux, at the same temperature, were compared. Vaporization proved more effective for removing impurities such as magnesium, calcium, and manganese. Recovery of samarium, however, is more rapid by sublimation because of its constant rate of distillation.

Jan 1, 1970

By M. Nilmani, H. Pham

"A mathematical model was developed for the dissolution of particles in gas-stirred liquid baths, linking the hydrodynamic flow field of the bath, the average particle trajectory and liquid-side mass transfer controlled dissolution kinetics. The model was validated by comparison with experimental data for the dissolution rates of urea particles in gas-stirred aqueous CaCl2 solutions measured during this study. The dissolution rates of urea. particles were measured using an image analysis system.The effects of operating conditions on the dissolution rates of urea particles were investigated. It was found that the key operating parameters influencing the utilisation efficiency of particles were the gas flowrate, particle diameter and lance submergence. An optimisation of the operating conditions for the model urea-aqueous CaCl2 system indicated that the utilisation efficiency increased with decreasing gas flowrate and decreasing particle size for a given lance submergence.IntroductionThe utilisation solid reagents in molten baths varies from one process to another, depending upon the rates and mechanisms of the reactions between the particles and melts, as well as the trajectory and residence time of the particles in the melts. Previous studies have not attempted to predict the utilisation efficiency of injected solids by coupling the motion of the particle with its dissolution rate. Instead, the particles have usually been assumed to remain suspended in the bath until completely dissolved, and the mass transfer coefficients were based on the average specific mechanical energy dissipation rates in the bath. Investigations of this nature relevant to the present study have been undertaken by Apelian et al. [1], Brucato et al. [2] and Langberg and Nilmani[3]. The objective of the present study was to develop a mathematical model, incorporating both the reaction kinetics between the particles and liquid and the particle motion simultaneously, to predict the dissolution rates and times of the particles. The mathematical model was validated by comparison with experimental dissolution rates of a cold model analogue system measured using an image analysis technique, and then applied to optimise the operating conditions in the model system."

Jan 1, 1996

By Henry W. Busch

Determination of the aldehyde content of Diesel-engine exhaust gas has proved rather cumbersome and unsatisfactory when carried out in its entirety in field investigations; therefore, studies were conducted with a view to developing methods by which samples might be collected in the field and trans-ported to the laboratory for analysis. Experience also indicated that aldehyde samples collected in water solution and then transported to the laboratory sometimes underwent serious changes in composition if several days elapsed between sampling and analysis. Polymerization of the aldehydes, which takes place readily in dilute aqueous solutions, may have been the cause of such changes. Because of these difficulties, experiments were conducted to find a suitable stabilizer or preservative for dilute aqueous solutions of the aldehydes that occur in Diesel-engine exhaust gas, so that in field studies a known volume of gaseous sample might be collected and brought into contact with water, and the resulting solution of aldehydes analyzed in the laboratory at some later time with reasonable certainty that the results would represent the composition of the original sample,

Jan 1, 1949

By R Wei, Y Peng

With the depletion of high-quality ores, the efficiency of extracting difficult gold ores through flotation and leaching becomes very important in the mining industry. Iron contaminants, sulfide and carbonaceous coatings on the surface of gold and gold bearing minerals significantly hinder the recovery of gold during gold processing. As the surface of gold minerals is easily contaminated, coatings of iron oxides and iron hydroxides originated from the grinding process and oxidation of iron sulfides will cause a retarding effect on both gold flotation and leaching.To mitigate the processing issues caused by undesirable surface coatings on gold minerals, a new technology in treating surface coatings of iron contaminants has been developed. The pulp potential and pH of the slurry are altered to allow dissolution of surface coatings which are further excluded by the use of complexing reagents. The current work shows that iron contaminants can be removed from the surfaces of gold through Eh-pH adjustment and chelation which result in significantly improved gold flotation response. The addition of complexants aids the formation of iron chelates to prevent the iron species in the solution from forming iron oxide and iron hydroxide in the flotation conditions.CITATION:Wei, R and Peng, Y, 2014. Mitigating the effect of surface coatings on gold processing, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 187–192 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By André Laplante

The mineralogy of the Joe Mann mine differs from that of other deposits of the Chibougamau area that are exploited by Les Mines Camchib Inc.. It is characterized by very fine first generation gold and very coarse second generation electrurn. Successful milling required adjustments of the processing flowsheet, which includes gravity, flotation, and cyanidation. A study of coarse gold liberation in the gravity/grinding circuit is described. Modifications to the flotation circuit and the reconditioning of a small capacity cyanidation circuit are presented. As a result of the circuit modifications, gold recovery increased from 65 to 81% in flotation and cyanidation. Overall gold recovery increased from 77% to 88-89%. These improvements are mostly attibutable to the recovery of -10 urn gold, whose presence in the Joe Mann ore and original circuit tails had been identified by process mineralogy.

Jan 1, 1989

By Muamer Medusalic, Kim Henley, Lucas Bottomley

The period from 2009 to 2012 has witnessed a large rise in the number of blast-generated fume events in Eastern Australia, where highly visible oxides of nitrogen (NOx) are produced from coal mine blasting. Fume production mechanisms have been poorly understood by mine operators, and practical measures to reduce fume were initially elusive. Over time, data on fume events has been collected and analysis has pointed to a range of contributing factors associated with fume production.

Jan 1, 2012

By Gus Van Weert

Hydrometallurgical oxidation of sulphides is capital and energy intensive, with autoclave and bio-technology competing for lowest overall cost status. The use of surface aerators instead of stirred tank reactors could provide lower costs for bio-oxidation of concentrates. With this in mind, the Delft Inclined Plate reactor was designed with inclined plates above a settler shaped reactor to continuously return slurry from the lowest point in the settler to the surface of the liquid. The multiplate superstructure overcomes the scale-up restriction of the standard circular surface aeration patterns. DIP aerator energy and volume requirements for oxygen transfer from air will be presented in terms of kg O2/kWh and kg O2/m3/h transferred as a function of wt % sand in the slurry and compared to stirred tank performance. Scale up from the 4 m3 pilot unit will be discussed.

Jan 1, 1996

By H. V. Fairbanks

It is estimated that millions of tons of coal fines are unsaleable each year due to difficulty of drying them economically with conventional mechanical dewatering and thermal drying equipment. The difficulty is due to the fact that coal of small particle size presents a large surface area with polar groups which have a great affinity for water. In order to remove this water thermally, a high temperature is necessary which oxidizes the surface of the coal. This substantially reduces the heating value of the coal. If drying could be satisfactorily carried out at a lower temperature, much more of the heating value of the coal fines could be retained. It was conjectured that acoustic energy applied during the drying process might prove to be of value since acoustic energy has the property of producing cavitation at a liquid-solid interface when the intensity is sufficiently great. This cavitation process produces water at room temperature which can be carried away from the solid surface by a flow of relatively cool air. Hence, moisture removal is made possible at a lower temperature.

Jan 1, 1966

By C. Villa Diniz

It is proposed that battery grade Mn02 can be produced directly from a manganese ore from Azul Mine in Brazil, by leaching with HCI to remove heavy metals selectively. We are working to find a way of selectively separating Cu, Ni, Co, Pb and Fe from the resulting acidic manganese chloride solution, to detoxify it and produce marketable chloride solution. Chelating ion exchange resins are proving more promising for this separation than solvent extraction with commercially available reagents. Results from batch and column ion exchange tests that characterize the behavior of copper, nickel, cobalt, lead and iron are reported.

Jan 1, 1999

By Patrick R. Taylor

Keywords: Thermal Plasma, Electroreduction, Electrolysis, Transition metals, Waste treatment, Molten oxides, Chromium oxide. An innovative process to treat transition metal oxide waste materials from diverse sources is presented. This technology involves using reverse-polarity DC plasma driven electrolysis in molten oxides. The process results in the recovery of the transition metal and other heavy metals from waste. By-products generated throughout the processing was converted to environmentally acceptable slag. The significance of this technology is that the treatment of the waste is accomplished in one step which in turn lowers the cost of remediation. Moreover, this process uses high temperature properties of thermal plasmas, which makes it possible to use molten oxides instead of halides as electrolytes. Chromium was successfully reduced from chromium oxide through the plasma driven electro-reduction process. It was shown that the selection of the appropriate ionic conducting oxides was critical for the formation of a slag that would enhance the reduction of chromium oxide.

Jan 1, 2004

By F Soleimani

Coal and gas outburst is a common hazard in coalmines and due to the complexity of its nature, efficaciously predicting the possibility of its occurrence is intricate. The mechanical and gas flow properties of coal, in situ and mining-induced stresses and geological structure are involved in outburst occurrence, whereas suggested thresholds for its prediction do not consider them all. Numerical modelling is known as an effective method that can not only consider couple the effect of different physics but also analyse the effect of associated parameters. In this paper, a coupled fluid flow and geomechanics model has been developed in COMSOL Multiphysics to simulate outbursts by considering the effect of gas pressure and composition, damage mechanics on related coal properties, and progressive excavation and mining-induced stress. For the proposed fully coupled outburst model, the effect of pore pressure and sorption are applied to the stress while the influence of stress changes and damage are considered in updating coal porosity and permeability in each time step. In addition, to study the effect of mining-induced stress, the excavation process is simulated by changing the material properties over time according to the schedule of heading development. Then, outburst initiation is analysed from the energy point of view by using the concept of energy conservation law. The simulation results are used in calculating energy sources of the outburst initiation, also, the effect of particle size and ejection velocity are studied, and the significance of particle size effect on the energy analysis and deformed coal on outburst initiation is discussed.

Oct 12, 2022

By Guowen Dong, Qiyong Li, Qiang Li, Tiejun Chen, Zhihong Wu, Junying Wan

In order to search for a more economical and effective roasting additive for extracting vanadium from stone coal and solve the question of the disposal of PVC waste, PVC waste was proposed as a novel roasting additive to enhance extraction of vanadium from stone coal and realize the comprehensive utilization of resources. By adding this roasting additive, the leaching rate of vanadium reached 94.5% under the conditions that the PVC waste addition was 10 wt%, the roasting temperature was 800 °C, the roasting time was 1 h, the sulfuric acid concentration was 15 vol%, the liquid-to-solid ratio was 1.5 cm3 /g, the leaching temperature was 95 °C, and leaching time was 4 h, which increased by 8.4% compared with that of blank roasting. The thermodynamics calculation showed that the decomposition reaction of mica was performed easier with the participation of HCl produced by pyrolysis of PVC. Meanwhile, The SEM-EDS and aperture test analyses demonstrated that more cracks and voids appeared in the roasted sample by roasting with PVC waste, which could facilitate the release and extraction of vanadium. Additionally, the TG-DSC analyses indicated that PVC could provide large amounts of heat for the roasting process to promote the decarbonization and roasting efficiency of stone coal because of its high calorific value.

By Ken-ichiro Uemura

"The DIOS process has been developed for eight years since 1988. The research project was started with the element studies carried out by each of the five integrated steel making companies in Japan, the final two and half years were spent for the pilot plant studies. Operation were conducted in the entirely closed and pressurized system successfully as planned. From the result, the DIOS process was proved to be viable as a future iron-making process substitutable for the conventional blast furnace. In addition, a lot of findings were obtained. Hot metal productivity was primarily determined by a oxygen flow rate, and a coal consumption varied depending on the productivity. The post combustion ratio was a little lower than expected from the result of the element study. It was supposed to relate the gas-reforming with coal or volatile matter in the free space of the furnace. Hot metal carbon content seemed to depend on the char content in slag.INTRODUCTIONThe JISF's DIOS pilot plant (DIOS=Direct Iron Ore Smelting Reduction Process) has finished its last campaign of the operations in January 1996. The project was started in 1988 as a joint research of the Center for Coal Utilization, Japan and the Japan Iron and Steel Federation (JISF) with a subsidy for promoting coal productions and utilization technologies from the Agency of National Resources and Energy, the Ministry of International Trade and Industry(MITI). Throughout the pilot plant test, a total of over 20,000 tons of hot metal was produced for more than 2,000 hours of the operation. Recorded production rate was 538 ton/day for 3 days at a specific coal consumption of approx. 1,000kg/hmt. Long-term operation was carried out in the fifth campaign for 18 days, which has proved that the entirely closed and pressurized DIOS process works well as planned. In Figure 1 is shown the representative operational performance obtained in the first five campaigns. The project is going to be finished by the end of March this year after investigating the technical viability and economic potential of the process, and completing the conceptual design of the DIOS commercial plant. In this paper, the system and facilities of the DIOS process are first introduced and some of the results of the pilot plant test are detailed later."

Jan 1, 1996

By N. S. Dalal, Xiaoya Sun, Xianglin Shi

"The in vivo toxicity of vanadium(V) has been found to correlate with the depletion of cellular glutathione and related non-protein thiols. With a view to understanding the mechanism for this observation, we have investigated the oxidation of glutathione, cysteine N·acetylcystcinc and pcnicil· lamine by vanadium(V), using electron spin resonance (ESR) and ESR spin trapping methodology. The spin trap used was 5,5-dimethyl-l-pyrroline I-oxide (DMPO). It is found that the oxidation of these thiols by vanadium(V) generates the corresponding thiyl radicals and vanadilim- (IV) complexes. The results suggest that free radical reactions play a significant role in the depletion of cellular thiols by vanadium(V) and hence in vanadium(V) toxicity. 1. INTRODUCTIONThis communication reports on the identification of thiyl radicals formed as intermediates in the reaction of vanadium(V) with glutathione (GSH) and related nonprotein thiols. This study was undertaken because the biochemical mechanism of vanadium toxicity is still not fully understood,. despite being a topic of current research activity [1-20). As to possible clues, it is known that vanadium is most toxic when administered in its pentavaient state [21), and that vanadium(V) administration into laboratory mice reduces cellular levels of NAD(P)H and GSH [22). While the oxidation of NAD(P)H by vanadium has been studied extensively [16-20), that of glutathione and related non-protein thiols has been paid less attention. On the other hand, GSH and related thiols are important cellular antioxidants [23). Their functions include decomposing lipid peroxides and protecting cell membranes [23-25). Thus any reduction in the cellular contents of such nonprotein thiols after vanadium exposure may result in the accumulation of lipid peroxides which might ultimately lead to tissue injury. With a view of finding the mechanism for this thiol depletion process, we have investigated reactions of non-protein thiols with vanadium(V). Particular attention has been paid to the detection of thiyl radicals, since it has been postulated [l] (but not experimentally proven) that the glutathionyl radical (GS·) might be an intermediate in the reaction between vanadium(V), NADH and GSH. We have used electron spin resonance (ESR) and ESR spin trapping methodology for investigating the reactions of GSH, cysteine, N-acetylcysteine and penicillamine with vanadium(V). The results show that the corresponding thiyl radicals are indeed formed in the one-electron reduction of vanadium(V) by all of the above mentioned thiols."

Jan 1, 1990

By A. J. Kraemer, H. M. Thorne

The following account of oil-shale operations in Australia is based upon infor- mation obtained by the authors while visiting Australia from September 15 to October 7, 1947, supplemented by published data, and augmented by analyses of samples of oil shale and its products at the Oil-shale Research and Development Laboratories of the Bureau of Mines at Laramie, Wyo. The primary objective of the authors' trip to Australia was to obtain, first hand, information regarding the equipment and methods used by National Oil Proprie- tary, Ltd., at Glen Davis, New South Wales, in mining oil shale, extracting oil from it, and refining the shale oil. This company was operating the only oil-shale plant that had been active in Australia since 1945. The plant comprised an oil-shale mine, 104 modified Pumpherston (Fell) retorts in 2 batteries, a hele refinery, and a 3-inch gusoline pipeline to the railroad loniing terminal t Sun Junction, 30 miles away. There were, also, the usual and necessary any uralities, such as a power house, mechanical shops, offices, and laboratories One Information regarding the company's operations was wance because of its bear- Ing upon the synthetic liquid fuels program of the Bureau of Mines, pursuant to the Synthetic Liquid Fuels Act of April 5, 1944 (30 U.S.C., 321-325, as amended). objective of the Bureau's program. In accordance with the maniate of the Act, is to furnish American industry cost and engineering data necessary for the development of synthetic-liquid fuel industry, and an obvious means of obtaining some of these data is to learn how oil shale is being mined and retorted and how shale oil is re- rined in countries where these operations have been conducted on a plant scale for many years. The authors spent 2 weeks at the plant of National Oil Proprietary, Lt., at Glen Davis, and were afforded every opportunity to obtain letailed and specific information regarding all aspects of the company'a operations.

Jul 1, 1951

By D. A. Meyn, R. L. Holtz, C. S. Pande, M. A. Imam, D. J. Singh

"Various theoretical and experimental techniques used to search and develop new metal hydride systems suitable for hydrogen storage are described. The main theoretical technique under study makes the use of electronic structure of the candidate materials. Microstructural characterization techniques like transmission electron microscopy are being used to study the hydride formation. Novel processing techniques for material preparation such as those needed to produce thin films or amorphous phases are also being utilized. The techniques are illustrated with results from Pd, FeTi and Mg2Ni systems.IntroductionOf the four methods of hydrogen storage, compressed gas, cryogenic liquid, metal hydrides, and gas-solid adsorption, the metal hydride storage method is more attractive from the point of view of high volumetric density and safety. Compressed gas storage has disadvantages of extreme pressure, weight, and volume requirements, whereas storage of hydrogen as cryogenic liquid is unattractive due to the requirements of extremely low temperatures and high consumption of primary energy. Moreover, the number hydrogen atoms present in a volume of 10- 22 Cm3 (nH) in liquid hydrogen state (- 20K) is 4.2 whereas number of hydrogen atoms that can be accommodated in a free volume of 10-22 cm3 of various hydrides are as follows: LiH--5.9, TiH2--9.2, ZrH2--9.2, VH2--l0.2. High hydrogen concentration is usually associated with a large H/Metal atomic ratio but is also a function of structure."

Jan 1, 1994

By K Mayank, A N. Mainza, I Govender, M Narasimha, A Mittal

In mineral processing industries grinding is the most energy-consuming process. A tumbling mill is an essential grinding equipment widely used for particle size reduction. Power consumption, impact forces and trajectory paths are critical parameters for characterising a tumbling mill to determine grinding efficiency. The effect of lifters and mill speed plays a vital role in such parameters. However, most of the studies ignore the impact of the lifter and do not investigate the effect of slurry dynamics on charge motion. The focus of the present work is to prepare a computational model that can accurately predict the complex multi-phase dynamics of charge particles, air and slurry inside the mill using a model that couples computational fluid dynamics (CFD) and the discrete element method (DEM). The details of impact forces with lifter profiles and mill speed variations will be refined even further using the CFD-DEM coupling approach. The slurry-air free surface is modelled using the volume of fluid (VOF) method, and the charge motion is modelled using the DEM. The phases are coupled using the interface momentum exchange between the charge and the fluid slurry. The coupled model is validated against experimental results from the positron-emitting particle tracking (PEPT) data. The validated model compares the effect of slurry content on charge dynamics with the dry DEM model. The presence of slurry is observed to dampen the tangential and shear contact forces.

Aug 24, 2022

By Roy L. Soderberg

The Bureau of Mines has conducted substantial research on the design, construction, and operation of metal and nonmetal tailings ponds. This design guide, like related Bureau publications that preceded it, is produced to assist the industry in the management of mill tailings disposal. It covers the site selection, sampling, laboratory testing, design, construction, operation, and inspection of tailings embankments. The effects of environment, topography, and hydrogeology are also included, and various methods of stability analysis and factors affecting stability are reviewed. Because of the diversity of problems encountered in tailings embankments, specific solutions are not intended. The guide is, however, a useful checklist for designers, operators, and inspectors of this type of structure.

Jan 1, 1977