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By M. A. Cornachione

The west central upper Peninsula of Michigan contains a large resource of graphitic slate. The slate has potential industrial use as a substitute for shale currently used in the production of portland cement. Some of the unweathered slate, however, has a high concentration of pyritic sulfur which can create emission problems when processed in a kiln. A low cost method to reduce the sulfur content of the slate through the optimization of pyrite oxidation in a bio-heap leaching operation was investigated.

Jan 1, 1992

By Yan Zeng

Lithium metal silicates (Li2MSiO4, M = Fe or Mn) composed of abundant and non-toxic elements are important cathode materials for Li-ion batteries (LIB). In contrast to solid-state or sol-gel methods, hydrothermal synthesis conducted in pressure reactors is a favorable processing route as it provides the potential for scalable production and is environmentally benign. However, the key is to control the precipitation reaction to obtain powders with desired properties to meet battery specifications. Through a systematic study, we have found that Li2MSiO4 with tunable size from 300 nm to 1.5 μm can be produced by adjusting precursor concentrations, temperature, and reaction time. Under optimum conditions, high purity Li2MSiO4 with minimum defects were successfully produced and examined as an LIB cathode. The use of complexing agents promoted the formation of unique hollow particles via the self-assembling of elongated crystals. A four-step formation mechanism is proposed based on extensive characterizations with XRD, HR-TEM, SEM, and Mössbauer spectroscopy.

Although Canadian bentonite is competitive in quality for most uses, it has not been accepted for the pelletizing of iron ore concentrates. In 1962, Canada consumed about 10,000 tons of imported bentonite for this use. By the end of 1965, the planned domestic consumption for this purpose alone will probably be more than 100,000 tons a year, valued at about $3 million. Consequently, a challenge exists for the establishment of a Canadian source of high-quality bentonite for pelletizing. Such a bentonite would also be suitable for the two other major applications -well drilling and foundry use. Brief mention is made of such topics as the identification, 1noperties, occurrences, exploration, applications, technology and laboratory testing of this clay. In particular, the type of bentonite in demand, the geological horizons warranting exploration, and simple preliminary test methods are discussed.

Jan 1, 1964

By Yutaka Shiraishi

Two methods were developed to measure the viscosity of the slag from the glassy to the liquid states in an ascending temperature process. The first method employs rotating parallel plates within which is placed a solid cylindrical sample in line with a sphere. The second method uses a tube which is pushed into a sample held in a rotating crucible. Both methods were tested using standard glasses, including boron trioxide and NBS standard glass #711. The main difference between these two methods is in sample preparation. Comparative measurements between two methods were performed using a sodium boro-disilicate glass containing 5%mol of alumina. The results showed good agreement in the mid-range of glassy viscosities, 105 to 107 Pa.s. In the liquid state, there were no significant differences between the two methods.

Jan 1, 2003

By C. Fuellenbach, J. Brune

"INTRODUCTION Mining activities must be safe and profitable. These two requirements influence each other. The purchase and implementation of safety improvements costs money. Injuries and illnesses at mines stop or delay production and may result in additional costs or a loss of profit. Other effects of injuries and illnesses include the negative influence on employee morale, corporate reputation and conflicts with contract partners. Based on this researchers asked the question: are mines with lower rates of injuries and illnesses more profitable than mines with a higher frequencies? One aspect of this research is the evaluation of the safety situation and the measurement of benefits of safety improvements in the German mining industry. In the following paper, this part of the research will be examined. The main aim is the evaluation of injury rates in different German mining sectors and regions in Germany. SELECTION OF GERMAN MINING OPERATIONS The research team decided to focus the study on the salt and potash and the aggregate and industrial minerals mining industries in Germany. These two mining industries are different in the number and size of operators, structure of the industry, pricing and markets. The selection of two different industries adds to the clarity of the evaluation. Salt and potash mining industry The German salt and potash industry is primarily located central Germany. All salt and potash mines in Germany are underground operations. In 2015, the German potash industry employed 8,100 employees and generated a total revenue of 2 billion Euros. German potash reserves include magnesium compounds like kieserite (MgSO4·H2O), in addition to sylvite (KCl) and carnallite (KMgCl3·6(H2O)). The German salt industry employed 2,300 people in 2015 and generated revenue of 800 million Euros (Krueger, 2015) There are seven mining companies with salt and potash operations: esco-european salt company GmbH & Co. KG, K + S Kali GmbH, Saline Luisenhall GmbH, GSES Glückauf Sondershausen Entwicklungs- und Sicherungs-gesellschaft GmbH, Südwestdeutsche Salzwerke AG, Wacker Chemie AG and Südsalz GmbH. In this way, esco – european salt company GmbH & Co. KG is an affiliated company. Esco was founded as a joint venture of K + S and Solvay in 2002, since 2004 K + S is the sole holder (esco - european salt company GmbH & Co. KG, 2016). Likewise, the Südwestdeutsche Salzwerke AG has a controlling interest in Südsalz GmbH (Südsalz GmbH, 2016). Aggregate and industrial minerals mining industry The aggregate mining industry in Germany is comprised of many small mining operations and relevant companies. According to the German Department of Economics (BMWi, 2015), the following industrial materials are classified as aggregates: fluorite, barite, kaolin, quartz and quartz sand, quartzite, silica, loamy and foundry sand, pegmatite sand, shale, clay, bentonite, schistose, limestone and dolomite, gypsum and anhydrite, basaltic lava and lava sand, gravel and split, pebble and silicic sand and peat."

Jan 1, 2017

By R. Hogg

Sedimentation in highly flocculated suspensions of fine particles such as clays occurs through individual settling units (flocs) which have very open structures and correspondingly low density -typically less than 5% solids by volume. It follows that such settling processes rapidly lead to the build-up of a bed of flocs which are essentially close-packed, with inter-floc porosity of perhaps 50%, but with an overall solids content of no more than about 2-3 percent by volume. An important consequence is that the thickening process is dominated by the consolidation of this bed rather than by simple settling of the individual flocs. Experimental measurements of sediment consolidation in flocculated clay suspensions indicate that for a given system, consolidation rates are essentially determined by solids concentration and can be evaluated using the classical Kynch treatment. However, these rates are strongly dependent on the physical as well as chemical conditions of the flocculation process. Furthermore the extent to which gravity consolidation proceeds depends on the total weight of sediment (i.e. on both height and solids concentration). The implications with respect to thickener operation and the requirements for laboratory testing for thickener design are discussed.

Jan 1, 1992

By M. Feinendegen, Ph. Siebert, C. Clauser, K. Willbrand, M. Ziegler

"Three institutes of RWTH Aachen University collaborate on laboratory tests and numerical simulations of hydraulically driven fractures in igneous rocks. The project´s target is to enhance the understanding of hydraulic induced fractures for deep geothermal energy exploration. Based on the idea of creating new discrete fractures in hot dry rock (HDR) reservoirs, the current project stage deals with this process on a laboratory scale. Especially for this purpose, a new testing facility has been developed and laboratory tests are performed to verify a hydraulic fracture propagation code based on the extended finite element method (XFEM). The testing facility enables us to initiate and propagate fractures in large samples of dense rock under triaxial confining pressures and to monitor the fracture propagation by extensive measurements. This contribution gives a short introduction to the project‘s background and mainly focusses on the test facility, the experimental procedure and exemplary results.INTRODUCTIONThe most efficient technique to increase the permeability of subsurface rock is to initiate and open fractures by applying hydraulic pressure from a packed borehole-section and to inject fluid into these fractures to propagate them. Since its first use in petro industries to enhance the production of wells in natural gas and oil reservoirs, the interest in targeted creation of hydraulic fractures has increased exponentially. As the key technology to the extraction of unconventional gas from shale, hydraulic fracturing (HF) became a major topic in a heated public debate. Based on the fact that a fracture tends to propagate in a direction perpendicular to the minimal principal stress, hydraulic fracturing has become an established tool for estimating geological stress states in almost any depth. Enhanced geothermal systems (EGS) in HDR reservoirs use engineered fractures as a heat exchanging system for a cycling fluid driving a power plant."

Jan 1, 2015

By Oszkar Bíró, Peter Mittag, Bernhard Aigner, Stefan Pirkeri, Philipp Glttleri

"This paper considers CFD modeling of processing and melting of small metallic particles by means of electrical heating. The particles fall continuously onto a liquid metal bath which is heated by an electric arc. After melting of the particles liquid metal is tapped.The charging behavior of the particles in the supply unit as well as in the reactor freeboard is studied by means of Euler-Euler granular simulations. The flow situation in the metal bath due to gas injection and magnetic fields is calculated by combining Navier-Stokes and Maxwell solvers. The macroscopic melting process occurring during the continuous charging of the particles is studied by kinetic laws for melting reactions. The temperature field is evaluated by balancing heat sources due to Joule's heating and heat losses due to latent heat of melting as well as convection and radiation.As a result of these simulations the fully three-dimensional flow fields of particles and gas in the atmosphere is obtained. Furthermore the flow field as well as the magnetic field in the metal bath can be studied. As a main result the three-dimensional concentration field of the still unsolved particles in the liquid metal can be evaluated.IntroductionIn this paper a metallurgical process for melting small iron particles is investigated by means of CFD-simulations. In a first process step the preheated and already mostly reduced iron particles fall continuously into the reactor through a vertical tube mounted at the lid of the furnace. In a second step the particles are melted in the liquid metal bath. Meanwhile the melt is heated by electric arcs to provide the heat needed for melting the incoming particles.In Figure I a sketch of the geometry setup considered in this paper is provided. The particles fall from a height of approximately 12 meters onto the bath surface in the center of the furnace. The melt is heated by electric arcs that are placed symmetrically around the center axis."

Jan 1, 2001

By J. W. Shield

Refractory sulfide flotation or gravity gold concentrates are coated onto a sized support matrix and placed in a heap configuration for biooxidation. The surface coating is typically less than 0.05 in. thick and the support matrix is preferably composed of 0.375 to 0.75 in. diameter material. The exposed thin coating of sulfides reduces biooxidation rate limitations due to oxygen mass transfer. The large spaces between matrix particles reduce resistance to fluid percolation and aeration in the heap. The capital and operating costs for this biooxidation configuration are significantly less than for concentrate biooxidation in stirred tanks. After 30 to 90 days of biooxidation, sub- sequent gold recoveries exceed those seen in whole ore heap biooxidation and are comparable to recoveries obtained from stirred tank biooxidation processes. Results from laboratory and pilot testing indicate that this technology is a viable alternative for pretreating sulfide refractory gold ores.

Jan 1, 1997

By Theodore H. Eyde

In 1971, the Minerals Division of The Superior Oil Company acquired exploration rights to an unpatented claim group in the Superior (Pioneer), Arizona mining district, lying west of the Concentrator fault. This major post-mineral fault displaces the Magma vein-fault, which is mined in the Magma Mine at Superior, Arizona. The Magma vein-fault and the enclosing section of pre-mineral rocks consisting of Paleozoic and younger Precambrian sediments and diabase, is overlain by a thick section of post-mineral rocks, consisting of the Gila conglomerate, the Apache Leap dacite, and the Whitetail conglomerate. Geologic information on the thickness and attitudes of the rocks obtained from previous diamond drilling indicated that the section of post-mineral rocks might be from 3,000 to over 4,010 feet thick in the target area. (Figure 1) The Magma vein-fault is a steeply dipping vein which has produced nearly a billion dollars of copper, zinc, silver, and gold. It has been mined continuously for nearly 10,000 feet along the strike and nearly 5,000, feet vertically down the dip. It ranges from less than a foot to over 50 feet wide and contains sulfide mineralization con¬sisting of pyrite, chalcopyrite, bornite, and chalcocite.

Jan 1, 1973

By Laura Steeves, Inoka Eranda Perera, Jhon Silva, Arend Spaeth

"This paper reviews the main concepts ruling the design, implementation and performance of active explosion barrier systems for underground coal mines in the USA. The document examines the parameters needed for the design of this type of system, such as overpressure and flame speed, suppressant deployment speed and duration time of the active barrier. The document also discusses the available solutions for gassy mines and the concepts behind the selection of machined mounted and roadway active explosion barrier systems. The paper includes a review of active explosion barrier systems developed in the USA and South Africa. The paper provides an overview of the current status of this technology in the underground coal mining industry in the USA, and the possible implementation of such systems. The paper concludes with the identification of the future work needed for the successful implementation of the systems in several conditions to enhance the safety of underground coal mine operations and to provide more tools to the miners for their safety.INTRODUCTIONUnderground coal mine explosions can be addressed in two ways, through prevention or mitigation. The United States mining industry practices have emphasized the prevention of explosions in underground coal mines, with little being done to mitigate the explosion once it occurs. Despite successful practices for the prevention of underground coal mine explosions in the US, the threat of an explosion does still exist. Other mining countries around the world have developed and implemented mitigation systems such as active explosion barriers in their underground mines. In the 1970s, the United States Bureau of Mines (USBM) carried out extensive research on the use of active or triggered explosion barrier systems in the US; however, they are not currently used.Explosion barrier systems do not prevent explosions but mitigate the propagation of the shockwave and flame to other areas of the mine. The use of active explosion barrier systems enhance the safety of underground coal mines. Active or triggered explosion barriers will detect the arrival of the shockwave or flame front of the explosion and release inert material to suppress or extinguish the flame. The technology required for active barrier systems is readily available based on their presence in other mining countries and must be adapted for their use in US coal mines. The adaption must consider the coal dust and methane concentrations in US coal mines, the mine geometry, and the mining equipment used."

Jan 1, 2019

By Bruce H. Baker

Studies of used or unused refractory materials are excellent examples of applied mineralogy in industry. Refractory materials are mineral substances containing ceramic or chemical bonding systems. Knowledge of the mineral composition, bonding, and textural relationships often explains the resulting physical property values of a refractory and contributes to the interpretation of refractory wear mechanisms occurring in steel plant service.

Jan 1, 1982

By Nicholas C. Lias

Quartz crystals are the raw material from which are made the crystal units utilized in filters and oscillators so vital to the performance of all long distance communications systems. These devices act as the heart of equipment that permits a single telephone cable to carry hundreds of conversations simultaneously. Quartz crystals are of value in communications because of this piezoelectric nature, that is when an electric signal is applied to the quartz, there is a resulting mechanical motion and conversely, a mechanical stress results in an electrical output signal. A plate cut from a quartz crystal will oscillate at some specific frequency, which is determined by the physical dimension of the plate. During the early stages of telephony, all quartz plates were cut from natural quartz, which was imported mainly from Brazil. Since the source of this important raw material was based upon a foreign supply which is located at a great distance from the user and could be vulnerable in time of a national emergent, it became necessary to maintain a large inventory of this strategic material. Also due to the considerable cost of natural crystals of a size and quality suitable for Bell System use, an investigation was made by Bell Laboratories into the possibility of developing a substitute material. The effort was successful and led to a joint development program between Bell Laboratories and Western Electric. This program brought about the design of manufacturing facilities capable of producing large quantities of cultured quartz at Western's Merrimack Valley Works, No. Andover, Massachusetts.

Jan 1, 1973

By John D. Thornley

Alaskan villages typically store a one-year supply of fuel to reduce significant delivery costs. Alaska Village Electric Cooperative (AVEC), an electric utility cooperative providing power to 51 Alaska villages, has made a concerted effort to upgrade and improve their undersized and aging facilities. The Village of Stebbins, located south of Nome on Norton Sound is receiving upgrades to its AVEC bulk fuel facilities. Stebbins offered unique challenges from a foundations perspective due to the nature of the soil. The geotechnical investigation found the soil below roughly a third of the footprint of the bulk fuel facility to be thawed with seasonal freezing and the remainder was found to be warm permafrost with ground temperatures of between 30°F and 32°F. This is a unique and challenging arctic engineering design issue because foundations are designed differently for frozen ground conditions. Driven piles were selected because of site constraints, such as the design flood elevation and the change from thawed to frozen ground conditions. The pile design specified that the pile embedment depths would be selected based on the results of pile driving analyzer (PDA) testing during construction in the thawed ground and maintained within the frozen ground portion of the footprint. Difficulties during pile driving in the frozen ground resulted in several piles becoming severely damaged, requiring subsequent removal. This resulted in a reevaluation of the means and methods for pile installation. Additional fieldwork was performed to further characterize the subsurface soils and their frozen nature. Options for installation of piles in difficult areas were evaluated including ground thawing, predrilling, and reducing embedment depths. Presented within this paper are the findings from the initial and subsequent field explorations, discussion of the design methodology, and the decisions that led to successful installation of piles at this challenging remote village.

Jan 1, 2017

By B. Morris

This presentation will describe the process by which the Quebrada Blanca (QB) copper project in northern Chile was financed. It will also show how a relatively junior mining company addressed the problems created by its inability to provide its share of the equity funding and the guarantees required by the project lenders. QB is located in the semi-arid Andean highlands of northern Chile, 170 kilometres southeast of the port of Iquique and 30 kilometres west of the border with Bolivia, at an altitude of about 4,300 metres (14,000 feet). Figure 1 depicts the project's location. The QB orebody is a secondarily enriched porphyry copper deposit containing reserves of 85 million metric tons grading 1.3 percent copper. Underlying the enriched zone is a significant primary ore zone containing several hundred million metric tons grading about 0.5 percent copper. In the late seventies and early eighties Falconbridge and its affiliates spent $20-30 million dollars exploring the deposit and conducting feasibility studies. For a variety of reasons they decided not to develop the property which was returned to its owners, Empresa Nacional de Mineria (ENAMI), which is a Chilean state mining corporation. In 1988 ENAMI announced its intention to privatize the property through a public bidding procedure.

Jan 1, 1993

By Leonard Obert

This report describes the development of a dynamic strain gage and a companion amplifier and recording camera -an apparatus designed to pick up and record the strain waves produced in rock by a nearby explosion. Also included in the report is a discussion of the relationships connecting the strain with the displacement, velocity, and acceleration for both plane and spherical waves. The proposed tests for which the strain gages were intended required making measurements in solid rock, a factor that necessitated the development of a gage that could be inserted and anchored in a small-diameter diamond-drill hole. The restriction on the diameter of the drill hole is required so that the presence of the hole in the medium will not influence the propagation of the strain wave. The gage should respond with fidelity to the frequencies present in a wave pulse generated by the nearby detonation of a small quantity of high-velocity explosive. Preliminary tests showed that this frequency range extends from 200 to 10,000 c.p.s. or greater. Also, the gage should be capable of measuring strains ranging from a few micro-inches per inch to several thousand micro-inches per inch. Other desirable design specifications included a low gage output impedance to permit the use of long cables, and a low gage cost, particularly in view of the fact that for the final design none of the gages can be recovered from the medium.

Jan 1, 1949

By Richter, E. Charikinya

"Mineral processing unit models require information on particulate properties such as particle size, solids flowrate and mineralogical composition to model their operations. Process models that describe the separation process can be classified based on the level of information required from the ore, i.e. the feed stream to the separating unit. The most comprehensive level of mineral processing models is the particle-based modelling approach. Particle based modelling describes a modelling approach where mineral composition, mineral liberation and textural information of particles making up the process streams is used in modelling. The advantage of this approach is that all model streams carry particle level information (size, liberation, shape). This information is obtained by applying automated mineralogy techniques such as Quantitative Evaluation of Minerals by Scanning Electron Microscopy (QEMSCAN) analysis which provide accurate and detailed information on process stream particle properties. Currently the use of liberation information in modelling and simulation is rare, due to the limited number of separation models that liberation data as input. The objective of this study is to develop a particle based model for a dry magnetic separator, where mineralogical information is used directly to simulate a dry magnetic separator operation. Magnetic separation tests were carried out on high, medium and low grade magnetite ores using a laboratory magnetic separator. Streams from the separator were sampled and sized for chemical and liberation analyses. A sized mass and elemental balance around the magnetic separator was carried out. The elemental assays of each stream were converted to mineral quantities and a sized mineral balance was done. QEMSCAN measured liberation data was reconciled to the mineral balance based on mineral quantities obtained from chemical assays. This was followed by the development of a particle based model that calculates the trajectory of a single particle based on its mineral composition and textural properties. The model was tested on experimental data and was able to predict the effect of variation in process feed stream mineralogical attributes (liberation, grade, particle size) on magnetic separation performance. Results of this study highlight the benefits of the particle based modelling approach. INTRODUCTION The extraction of mineral values from ore requires liberation of the value minerals from the gangue followed by their separation. Liberation is achieved by size reduction operations (Desmond, 2008; Fuerstenau and Abouzeid, 2002). Separation of gangue material from value mineral takes place in various mineral upgrading stages such as classification, magnetic separation and flotation. In these concentration stages value minerals are separated from gangue minerals based on the physical properties of the ore particles making up the feed such as size, liberation, volume of magnetic material and density. The success of separation is related to the liberation of the feed particles, the performance of the separation technology applied, as well as the inherent characteristics of the feed material (Leißner et al., 2013)."

Jan 1, 2018

By Ekin Güngor, Berkant Ozdemir, Erkan Bayrak, Serdar Ergün, Sedat Esen

"This paper presents the final wall blasting practices at Eldorado Kisladag Gold Mine in Turkey. Benchmark and improved wall control designs were explained in detail. Kisladag Mine has been implementing a high quality slope stability program on-site. The quality of pit walls is generally considered excellent, with very few wall failures being evident and with presplit hole barrels prominent in most areas of the pit. However, a minor scale slope failure occurred recently at the north-east section the pit. A project was initiated to diagnose the cause of the crest loss and evaluate ways to limit its effect on final walls. Final wall blasting practices and geotechnical designs were evaluated. The work presented in this paper showed that changes to the blasting and geotechnical parameters are required atthe north-east section of the pit. Geotechnical design changes were 10 m bench heights with 70 ° slope face angle at that specific area. Having implemented several geotechnical and blast design changes (elimination of the subdrill for the catch bench, appropriate primer location, more favorable blast tie-up and delays), the crest loss was minimized significantly (<1.5 m) (<5 ft)."

Jan 1, 2017

By Z. Smieszek, J. Botor, Z. Miczkowski, S. Sobierajski

"From 1978, the direct process for the smelting of chalcocite concentrates in a flash furnace by the Outokumpu method has been applied at the Glogów II copper smelter. The chemical composition of these concentrates make it necessary to control the process very strictly. In this paper, the method for controlling and measuring the main technological parameters of the copper production by flash smelting is being presented. It includes the determination of the chemical composition of the concentrate, its grain structure, the temperature of liquid products of the process, oxygen content in process gases, as well as lead concentration in copper and copper concentration in slag.The main process parameters are determined from the mass and energy balances. The relations between parameters, such as an effect of grain structure of a concentrate on oxygen and oil consumption, and dependence of chemical composition of a concentrate on capacity and products quality are discussed. 1. IntroductionThe Polish copper concentrates, as most concentrates occurring worldwide, contain from 18% to 30% Cu, and less sulphur (7-11%) and iron (2-5%). The main copper-bearing mineral contained in the concentrates is chalcocite, while bornite and chalcopyrite are present in smaller quantities. Moreover, the organic carbon (5-7.5%), arsenic (0.05-0.3%) and lead (1.2-3.0%) are also contained in the concentrates. The gangue consists mainly of silica, aluminosilicates, calcium carbonate and magnesium carbonate. Their proportions make the addition of slag-forming agents unnecessary.The composition of Polish concentrates, especially their low iron content, allows their application in the direct flash smelting process for blister copper production. Low sulphur content is the factor which determines the necessity of oxygen application in this process."

Jan 1, 1989

By T. Tumidajski

The purpose of the separation processes in coal processing is obtaining products of certain ash contents. In the most of cases it is assumed that the separation process is described by one, selected parameter, which usually is grain size or material density. The separation may be described by means of statistical distributions of random variables, what allows forecasting the separation results of certain enrichment method. There are very well known the applications of approximations of Tromp separation curves or distribution functions of Erasmus, Meloy or Weibull. It is necessary to say that if the fitness of the approximation more suitable, then the characteristics of the process itself is also better. In purpose of obtaining more appropriate results, these methods were modified by application the mathematical functions, as i.e. hyperbolic tangens function. Furthermore, on the basis of empirical data, so-called interpolations may be performed in purpose of getting more appropriate results of approximation. One of the most known techniques of interpolation is Hughes method. This method for interpolating standard data involves breaking down each interval into a number of smaller sub-intervals. The results of such one-dimensional approach not always contain the full in-formation of the searched distribution. It happens because such interpretation of the problem is not completely correct. In practice, the separation process depends not only on the one parameter (i.e. grain size), but also on many other features characterizing certain material (i.e. its density). It seems then that in some cases the application of multidimensional grain characteristics distributions will be more appropriate. In this paper, the technique of joining the distributions of grain size and density by means of so-called Morgenstern distributions is shown. The general form of these distributions is as following:

Jan 1, 2014