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By J. I. Paige

The effect of fluoride inclusions on the properties of titanium produced from the Bureau of Mines-developed induction slag melting process is of concern to the titanium industry. The objective of the research was to determine the effect of removing the nonconductive molten calcium fluoride (CaF2) slag used as an insulator between the titanium and the segmented copper crucible. The data were obtained from single-induction-melted ingots prepared with no CaF2 insulating slag and an ingot prepared with the normal addition of 4 pct CaP2 slag. The results showed that the mechanical properties of single-induction-slag-melted and annealed Ti-6AI-4V alloy exceed the minimum values specified in "Aerospace Materials Specification for Titanium Alloy Bars and Forgings AMS4928H." High-cycle, tension-tension fatigue testing yielded similar results. The data from 44 of the 45 specimens were contained within the typical scatter band for fatigue data on wrought Ti-6AI-4V alloy. Although the removal of the insulating slag is a desirable change, the data from the specimens with the previously standard 4 pct slag addition showed no detrimental effect from the slag inclusions.

Jan 1, 1988

By Yong Pan, Purushotham Tukkaraja

Block caving is a preferred underground mining technique due to its high production rate and low operation cost. Before its final step into a mature caving system using gravity to break rock, drilling and blasting are required to form drawbells to connect the production level and undercut level and induce the initial caving propagation in undercut level. A large amount of toxic fume generated by blasting activities poses a big threat to people working in a confined environment and ventilation is assumed to be the most economical and efficient way to deal with this issue. Past research shows that it’s common to use traditional methods like using a formula or using numerical method (Computational Fluid Dynamic (CFD)) simulation to predict re-entry time after each blasting, but it fails to consider the percentage of toxic fume entrapped in muckpile, which could reach up to 70%. In this paper, CFD was used to investigate the blasting toxic fume characteristics under different entrapping percentages and under changing muck pile properties like broken rock size and porosity. It showed that CFD was a very useful method to study blasting fume in an underground mine and it took much longer time to dilute toxic fume into a safe level with higher entrapping percentage. The dilution time increased with a decrease of broken rock size and porosity.

By John Wallace, Chib Iheagwara

"Refinements in sensor design have produced low-cost rugged elements to act as loop coupled with stable detection hardware for eddy current measurement in difficult environments. This has allowed direct dimension gauging of nonferrous and ferrous products above the curie point for absolute dimensions and electrical conductivities independently. The software was developed for the analysis of electrical conductivity profiles in CZ silicon crystal growth, then refined for monitoring bar properties and tube properties. Since in most metal working operations, speeds at the minimum of a few hundred feet per minute are encountered the design of the gauge was optimized for a rapid measurement. Independently extracting electrical conductivity provides data in some metal systems for determining the temperature of the monitored product.IntroductionThe primary reason for the use of eddy currents in gauging is that in hostile environments of metal working techniques such as laser gauging and ultrasonics are not always robust enough for in process measurements. Our goal is to use the technique of eddy current measurement as a quantitative control element in various hot and cold processing operations. Inspection in the early stages of metal and semiconductor processing is usually too costly to introduce in a well developed process and these tools are usually only employed in process development. Until recently there has been no efficient general analysis to allow real time measurements in the cylindrical and the probe geometry that could separate dimensional changes from material property changes both which effect the eddy current response. The basis for these measurements is that forward electromagnetic problem for conductors can be solved exactly for the test geometry which allows an inverse analysis to be made by relaxing the dimensions and conductivity to values which reproduce the measured response[!]. This transformation is based on analysis developed in Robert Siegfried' s thesis and was explored both by modeling and by physical measurement. This analysis was extended over the last few years to allow a more compact data set to be used to exact physical properties. The main result was that the technique would work on high ·quality physical data on as little as three test frequencies with the penalty being that the analysis is computational intensive. The main result of this work was that a quantitative inverse analysis of eddy current response would allow a general instrument to be used for a variety of measurements rather than being tailored for a specific measurement on a specific material test geometry. The development of these instruments has progressed over the last ten years for monitoring real time solidification, crystal growth[2] and hot seamless tube forming where the use of standards in traditional eddy current is limiting. The specific instrument design was dictated by the requirements of the algorithm for both frequency selection and levels of systematic noise that could be tolerated. Because the data is need for real time information this dictated that the system be a parallel multifrequency eddy current instrument feeding the same sensor. The sensor have to be simple and robust and usually a single loop or several loop of heat resistant wire or tube. This presentation is about using inversion of multifrequency eddy current data in real time to produce dimensional and property data on cylindrical conductors and planar conductors in real time. The object of the measurements is to produce dimensional outputs on measurements of conducting material without having to establish a detailed standard for each material or size tested. The dimensional measurements using eddy currents is complicated by material variations in conductivity due to temperature and composition. Those variations that are not geometric are often not of critical interest and complicate the measurement. The dimensional changes are often of more importance"

Jan 1, 1997

By R. Bryce, T. J. Doughty, K. Stoll

Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Ca6Al2(SO4)3(OH)12•26H2O Ettringite readily precipitates in high pH water and by doing so, removes sulfate from impacted waters. The SAVMIN process, piloted in South Africa, is one method to produce ettringite. In this process, aluminum hydroxide is the aluminum source. The Cost Effective Sulfate Removal (CESR) process is similar to SAVMIN, but uses a proprietary aluminum source instead of aluminum hydroxide. Outotec and Veolia also have their own versions of the process using their specialized process equipment. TWC patented a version of ettringite precipitation using metallic aluminum as the aluminum source for ettringite formation. The benefit of using aluminum metal is that no additional ions are added to the process. At high pH, the raw aluminum corrodes in water causing hydrogen gas generation as the water is chemically reduced. This reaction is shown below:

Jan 1, 2019

By B. Pesic

Manganese is about twelfth in the list of the most abundant elements in the earth's crust (Reidies, 1981). More than 150 known minerals contain manganese as an essential constituent (Mellor, 1932). In general, ores containing at least 35%Mn are classified as manganese ores, ores with 10-35%Mn are called ferroginous manganese ores, and ores containing 5-10%Mn are known as manganiferrous ores. One very important class of manganiferrous ores are manganiferrous-silver ores. They occur in the oxidized portions of the silver deposits of the Western United States. Silver is very often associated with manganese oxides which in some ore deposits are dispersed through calcite, causing the black color of the host rock, which is known as black calcite. Black calcites can occur in carbonate rocks (10-1500oz Ag/ton) and in volcanic rocks (less than 1.0oz Ag/ton).

Jan 1, 1986

By N. N. Orekhova, I. V. Shadrunova, N. G. Novikova, N. ?. Volkova

The purpose of the research is scientific substantiation and formulation of strategy and technical solutions of handling liquid wastes of plants producing and refining copper-zink pyritic ores. In the course of research studied are chemical composition of technogenic waters of mining plants as well as water and alluvia of intake river within and outside a sanitary zone of Southern Ural mining plant using inductively coupled plasma mass-spectrometry and X-ray fluorescence analysis techniques. A particular focus is made on microcomponent composition. Novel data on Cd, Li, Be, Mn, Co, Cu, Zn migration with technogenic flows and accumulation of these elements in alluvia is obtained. It is showed that extraction of valuable components from technogenic waters is a novel problem for refiners that can be solved only in cooperation with mining industry ecologists. Laboratory research of selective copper and zink extraction into corresponding practical products by galvanocoagulation and sulphide precipitation is carried out. Common factors of phase formation are studied using physicochemical modeling, X-ray phase analysis and electronic microscopy. Methods of intensification of processes and increasing of extraction ratio of metals in products are elaborated. A technology of comprehensive processing of undersoil waters is proposed. Enlarged laboratory and pilot plant tests of technological solutions for protecting hydrosphere and extracting metals from mine waters carried out on several plants of UMMC-Holding Corporation showed a possibility of obtaining additional products having weight content of metal which is profitable for consequent metallurgical processing and purification of waters to comply with quality standards. A possibility of transformation of technological chain depending on season variability of water quality is put behind the designed technological schemes.

Jan 1, 2018

By L. P. Srivastava

Rock bolts have been used since long to enhance the shear strength response of jointed rocks in civil and mining engineering structures. However, the assessment of strength response of a rock mass reinforced with rock bolts remains an unresolved problem till date. In the present article, an attempt has been made to study, through physical model tests, the shear strength enhancement of a blocky mass due to provision of passive rock bolts. Direct shear tests were conducted on large specimens of size 750 mm x 750 mm x 900 mm of rock mass under a normal stress varying from 0 to 2.0 MPa. Concrete was used as a model material to simulate intact rock and, elemental blocks of size 150 mm x 150 mm x 150 mm were used to form the mass specimens. Steel bolts of 6 mm diameter with 2 mm thick grout were used to reinforce the mass. Three different configurations of bolts were adopted. Observations were made on shear stress, horizontal shear displacement, and dilation during the tests. Effect of normal stress and reinforcement on peak shear stress and shear stiffness was studied. It is observed that the rock bolts enhance the shear strength of the mass by preventing sliding along the shearing plane, and by inducing additional normal stress due to tension mobilized in the bolts. The rock mass, therefore, becomes stronger due to the high degree of interlocking produced by the bolts. Shear strength of the mass increases with increasing numbers of bolts. In the case of reinforced mass, the enhancement in shear strength due to provision of bolts decreases with an increase in normal stress. The provision of bolts improves the cohesion of joints substantially. The effect on friction angle is low. The shear strength enhancement depends on the area of the bolts, spacing of the joints, spacing between the bolts and the cohesion of the intact material. A correlation has been established using which the enhancement in shear strength due to the provision of bolts can be assessed.

Jan 1, 2015

By Flavio Begazo, William A. Enrico

"Southern Peru Copper Corporation's Ilo Refinery, the largest in Peru, began operations in 1975 with a production capacity of 165,000 stpy. Southern Peru bought the Refinery from the state owned Minero Peru SA on June 1, 1994.The Refinery processes blister from Southern Peru's I/o Smelter. Blister copper is processed in an anode plant equipped with two 365 st tilting reverberatory furnaces, a 26 mold casting wheel and an anode press machine. Copper is electrorefined in a tank house equipped with 768 commercial cells, 44 stripper cells, and 40 liberator cells, utilizing two electrolyte circuits and a 21,000 Ampere rectifier.During 1989 through 1994 a program for improving productivity was carried out by increasing the number of cells and increasing current density to the total rectifier capacity. As a result, a capacity 215,000 stpy of refined copper, 2 million tr. oz silver and 6,000 tr. oz gold per year was achieved. In 1994 Southern Peru announced plans to increase capacity to 250,000 stpy of cathode with a US$ 18 million investment and a US$ 2 million investment in environmental improvement projects, as part of the purchase agreement with the Peruvian government.This paper outlines the scope of the SPCC lio Refinery modernization and environmental program. It describes the implementation of the Electrolytic Plant expansion based on instaliation of polymer concrete cells, a new rectifier, a new selenium roaster and a Precious Metal Plant upgrades."

Jan 1, 1997

By N. Merriam

This report describes Koppelman's work to develop the K-Fuel® Series C Process used to dry and stabilize Powder River Basin coal. It also contains summaries of the results of bench-scale and pilot plant tests conducted to prove the Series C Process. The process is being used by the KFx-Thermo Ecotek partnership for a 500,000 ton per year commercial plant that has been constructed near Gillette, Wyoming. The plant is presently undergoing shakedown.

Jan 1, 1997

By Feng Liu

A thermal upgrading process by which nickel value can be concentrated in a ferronickel alloy is a possible alternative to treat Sudbury pyrrhotite (Po) tailings with nickel content of 0.5–1.5 wt%. The basis of this process is precipitation of Ni from Po at high temperature once Fe/S ratio in the iron-deficient Po is shifted towards stoichiometric or near stoichiometric FeS (troilite) either by the addition of iron and/or the removal of sulfur. For the iron addition route, the reaction between elemental iron and nickeliferous pyrrhotite to produce ferronickel alloy and Ni-depleted iron sulfide phase plays a critical rule. In this paper, the formation mechanism of ferronickel alloy was investigated using the diffusion couple technique to better understand the nickel diffusion behavior in the iron and sulfide phases.

By P. Comba

The U.S. Bureau of Mines investigated a hydrochloric (HC1)-calcium fluoride (CaF2) leaching procedure to treat domestic manganese (Mn)-bearing silicate resources. The proposed process is an alternative to high-temperature and energy-intensive extractive techniques. Single-stage leaching with a stoichiometric amount of HCl and a F-Mn mole ratio of 0.2 extracted 96 pct of the Mn when the leach conditions were 50° C, 3 h, and 35 pct solids. Ninety-eight percent of the Mn was extracted during countercurrent leaching at similar conditions. A process flowsheet was developed that incorporated HC1-Cab leaching, excess leach acid utilization, fluoride (F) recycle, and Mn recovery. When the domestic manganese silicate ore was processed, 98 pct of the Mn was extracted, 99 pct of the Cab was reclaimed, and a leach residue was produced that passed the Environmental Protection Agency (EPA) Extraction Procedure (EP) Test for nonhazardous waste.

Jan 1, 2010

By R. L. Derick

The Orchard Valley Mine, a large underground coal mine located in western Colorado, experienced a major mine fire during an idled Sunday on June 1, 1986. This mine had extensive problems with spontaneous combustion near the coal outcrop. Spontaneous combustion has been determined to be the probable cause of that fire. Preparing for a mine emergency was an on-going task. Once the emergency occurred, much of the preparation work was implemented and aided in controlling the situation. Later, the successes and shortfalls that arose from that emergency were analyzed for future course of action. This paper summarizes the activity that led up to the major fire, the handling of that emergency, the lessons learned, and the changes implemented.

Jan 1, 1993

By C. M. Iheagwara

An overview of the scope and ramifications of scrap recycling in the Nigerian metallurgical industries has been presented in this paper. The modern state-of-the-art processing techniques and the operational strategies employed in the recycling plants are discussed. Optimization techniques for cost effective recycling operations are highlighted. As new units within existing metallurgical plants and new metal working plants approach commercial operations, expansion of existing recycling plants and the emergence of new ones have been showing to hold the key to their profitability from the raw material standpoint. The present economic predicament of the entire industrial sub-sector, lack of sufficient foreign exchange to procure new machineries and the emergence of a maintenance culture have triggered a phenomenal increase in the number of spin-off industries which depend on metal recycling activities. This, it is argued, widens the horizon for scrap processing/recycling.

Jan 1, 1992

By C. Leal

Modern production has as goal to reach high and uniform quality in their products. To success with this, it is essential to have a good knowledge of the different variables involved in the process. Investigation or analysis of a process or system has as references the measurements of the variables. These measurements are presented normally in form of data. These data are measured in intervals over time. The aim with measurement of the data in a process is to obtain information about the state of it in order to have it under control. Other goal is to know how the results are affected by the process variables to improve upon product quality, redunding manufacturing cost, better pollution control etc.

Jan 1, 1994

By D Cliff, K Bailey

Traditionally occupational health and safety (OH&S) has been managed for the direct benefits of reducing injury and illness to workers on mine sites. In the current skill shortage climate it is important to recognise the value that OH&S management can have in assisting mines in minimising their exposure to this issue. In times of skills shortage turnover is high as mines poach personnel from each other. This leads to loss of corporate knowledge and loss in productivity through the need to train new personnel in mine-specific operating procedures. In addition absenteeism can significantly disrupt production as there may be no ready replacements available for key jobs. Pressure will be placed upon workers to remain at work even though they are not completely fit for work, leading to presenteeism and consequently loss in productivity. In addition to the threats to routine operation, the loss of management and professional staff can significantly increase catastrophic risk through loss of experience and corporate knowledge. There is increased pressure to focus on events that occur regularly in the here and the now and underestimate the rare, or unlikely, events.The theme of this paper is that by properly addressing OH&S management at mine sites, companies can minimise their exposure to these problems. Put simplistically, a safe and healthy mine is a sustainable and productive mine. Case studies and relevant literature will be used to support this premise.CITATION:Cliff, D and Bailey, K, 2012. Health, safety and sustainability, in Proceedings International Mine Management 2012, pp 53-58 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 20, 2012

By Raymond F. Farrell

A goal of the U.S. Department of the Interior, Bureau of Mines, is the advancement of minerals technology through the development of improved metals and minerals processing. In support of this goal, the Albany Metallurgy Research Center has developed atomic absorption spectrographic methods for the rapid analysis of A1203, CaO, Fe203, MgO, MnO, and Si02 in steelmaking slags. The application of these methods is discussed using an inexpensive pressure dissolution system. The overall coefficient of variation is 5 pct. The accuracy is the same as the reproducibility.

Jan 1, 1979

By D. R. East

Recent experiences within certain sectors of the international mining industry suggest an underestimation of the environmental risk associated with the design of mine waste management facilities. These experiences show that the technical and managerial challenge of responsible mine waste management is not always fully appreciated. Unfortunately, the image of the mining industry's environmental performance is negatively impacted by a relatively few number of failures. This negative view overrides the many positive contributions made by the majority of mining companies. The fact that these failures continue to occur to this day in both developed and developing countries is indeed remarkable, and indicates a degree of risk-taking approaching unacceptable levels. The design requirements for tailing storage facilities are, in many cases, more demanding than those of conventional water dams, because seepage of fluids which contain dissolved metals may pose a greater threat than the mere loss of water.

Jan 1, 1999

By Martin Encinas, Jesús L. Valenzuela, Jose R. Parga, Salvador Aguayo, Roy G. Lewis

Continuous laboratory solvent extraction of gold from cyanide solutions using LIX?79 guanidine based extractant has been investigated. Different variables that affected the selectivity and extraction include aqueous pH, extractant concentration, and modifier concentration. The extraction isotherms of the aurocyanide complex with respect to the other cyano anions were compared, and the following order of selectivity Au > Ag > Zn > Cu > Fe was observed. According to the pH isotherms, aurocyanide can be extracted in an alkaline media, and a better separation with respect to the other cyanoanions was obtained in the pH range 10.5-11.2. From the McCabe Thiele diagrams, better recovery was predicted when using LIX?79 extractant and tridecanol modifier at 10 vol.%. Stripping of the gold from the loaded organic was carried out at pH > 12 using NaOH and NaCN solution. The continuous tests indicate that a two-stage extraction followed by a single stage strip is adequate to obtain an overall process efficiency of >90%. Better results were obtained using a copper wash stage before gold stripping.

Jan 1, 2014

By F. J. Tozer

Canal communication between Lake Erie and Lake Ontario has been one of almost constant enlargement and reconstruction to meet the rapid growth of trade and commerce, and the consequent steady increase in the size of vessels plying the Great Lakes. The original canal was built by the Welland Canal Company. The first sod was turned in 1824 and the first vessel passed through in. 1829. There were 36 lift-locks, built of oak timber, 110 feet long and 22 feet wide, with a depth of water over the sills of 8 feet. The second canal, now known as the 'Old Welland Canal' was built by the Dominion of Canada (1842 to 1850). There were 26 masonry locks, 150 feet long, 26.5 feet wide and with a depth of water over the sills of 9 feet. The walls and banks were raised in 1853 to give a 10-foot draught. The third canal, known as the 'New Welland Canal, built by the Dominion of Canada, was started in June 1874 and the first boat passed through in the spring of 1882. There are 25 masonry lift-locks, 270 feet long, 45 feet wide and with a depth of water over the sills of 12 feet. The walls and banks were raised in 1891 to give a 14-foot draught. This is the canal in use at present.

Jan 1, 1926

By J. E. Miller

This paper reports experimental determinations by the Bureau of Mines of compressibility factors to 4,000 pounds per square inch absolute (p.s.i.a.) for helium at temperatures from -10° to 130° F. and for 16 helium-nitrogen mixtures at 70° F. This information is needed for computing accurate discharge volumes and is necessary for determining an average-density value for use in orifice-meter formulas. In thermodynamic calculations, several functions of the compressibility factor with pressure and temperature are required. The data in the original publications (6, 8)5 of this study have been reexamined and have been given a more comprehensive treatment. The recalculated compressibility factors are higher by approximately 0.2 percent because in the earlier work a linear relationship between the compressibility factor of helium and pressure was assumed.

Jan 1, 1961