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By Bent Babel, Martin Rudolph

"The characterization of reagent-mineral interactions in flotation systems of finely intergrown ores holds difficult challenges for the applicability of standard techniques like Hallimond tube tests and contact angle experiments or renders them impossible due to a lack of sufficient samples in terms of quality and quantity. This disadvantage may not apply to more sophisticated techniques, but these often do not work in an aqueous environment. We present the utilization of an atomic force microscope with a hydrophobic colloidal probe to characterize the wettabilities of individual mineral domains of an ore sample, while additional spectral information is gathered by Raman spectroscopy. The exemplary ore sample investigated is mainly containing cassiterite and quartz, therefore the reference measurements like Hallimond tube tests and contact angle experiments were carried out with this binary system as a comparison. The focus of the study lies in the correlation of data gathered by the atomic force microscope and the Raman spectrometer with data from standard techniques. Finally, the applicability of the colloidal probe atomic force microcopy technique for reagent-mineral investigations is critically evaluated.INTRODUCTIONThe focus of this paper is the application of colloidal probe atomic force microscopy (CP-AFM) for theinvestigation of reagent-mineral interactions on a binary system of cassiterite and quartz. This and similar concepts using hydrophobic AFM probes have been applied by multiple authors (Rudolph and Peuker, 2014a; Rudolph and Peuker, 2014b; Wada et al., 2017; Xie et al., 2017). The hydrophobic interaction is the main interacting mechanism for the hydrophobic colloidal probe with hydrophobic sample surfaces and the long range attractive component has been accounted to nanobubbles on the interacting surfaces (Yakubov et al., 2000). More detailed information on nanobubbles are available in two reviews compiled by Attard and Hampton (Attard, 2003; Hampton and Nguyen, 2010). This paper is based on the work by Rudolph and Peuker comparing different AFM based measuring concepts, additionally gathering data with Raman spectroscopy and correlating results of microflotation and CPAFM measurements (Rudolph and Peuker, 2014a; Rudolph and Peuker, 2014b)."

Jan 1, 2018

By Hitch M.

Many mining wastes, especially those from the metal mining industry, have traditionally been treated as a matter of little or no value and in practice a cost burden. Some wastes, due to their reactivity characteristics, have emergent values that go beyond purely economic and into the environmentally beneficial realm. This paper discusses the changing paradigm of mine waste management. Such fundamental parameters such as cut off grade, and strip ratio, are positively impacted by the revaluation of waste rock material. Mine rock waste can now be seen as a commodity of value, similar to the underlying ore being mined and influences the economic performance of suitable projects. This valuable material can be used for industrial purposes including acid neutralization as well as the capture and long-term disposal of anthropogenic carbon dioxide. The Turnagain Nickel project, located in northern British Columbia serves as an example of how waste rock material can become an important matrix for carbon capture and sequestration and can benefit economically from it. By producing material that has emergent economic value as well as carbon capture and sequestration capabilities, the sequestration matrix producer is a beneficiary of new carbon credits that have a market value and is looked upon favourably by regulatory authorities and affected stakeholders.

Jan 1, 2010

By J E. McMynn

The development of the Granduc mine presents a number of problems which are peculiar to its location and surrounding terrain. Because the development tunnels portal onto an area which is covered by an extensive glacier, and the mountain-side is subjected to dangerous snow slides, it was decided to construct an underground powerhouse to supply the necessary electric power and compressed air. This paper deals with the special problems inherent in the design and -construction of an underground plant. It involves the installation of diesel-electric generating equipment having an aggregate capacity of 1,050 kw.,and of air compressors with a total capacity of 2,400 cfm. Items dis-cussed include the selection of equipment to meet site conditions, the ventilation and cooling of the underground room, and the protection of personnel and equipment from explosions and fire. A short discussion on the automatic supervisory and alarm installation is also included. THE Granduc mine is located 135 miles north of Prince Rupert and 25 miles north of Stew-art. This seems quite accessible, mileage-wise, but, due to mountains,

Jan 1, 1963

By O Aydan, R Ulusay

Blasting is the most commonly used excavation technique in mining and civil engineering applications. Blasting induces strong ground motions and fracturing of rock mass in rock excavations. Particularly, high ground motions may also induce some instability problems of rock mass and structures nearby. Furthermore, it may cause some environmental problems due to noise as well as vibrations of structures near the populated areas. Furthermore, flyrocks is another major issue for the safety of people and damage to machinery and equipments when blasting is employed. In this study, the authors explore the ways how to estimate the ground motions as a function of distance, amount of explosive, number of holes. The ground motions were measured by stand-alone accelerometers developed by the first author and some empirical relations are developed. The effect of ground motions on the instability issues of benches such as sliding, toppling and rockfalls were investigated. Furthermore, the flyrock issue is investigated and some empirical relations to estimate the maximum distance of flyrocks from the blasting relations are compared and discussed. CITATION:Aydan, O and Ulusay, R, 2018. The ground motions induced by blasting in open pit lignite mines and its environmental effects, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 142–151 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By Chao Li, Kym Runge, Saeed Farrokhpay, Dee Bradshaw

"It is well known that froth phase has a controlling influence on the overall flotation performance. Froth recovery is expected to be affected by froth transportation behaviour. The latter has been represented by different volume balance and energy balance based models. In froth transportation models based on a volume balance, the froth phase is divided into different zones. The total froth residence time is the sum of the time spent in each zone and is dependent on the cell geometry, bubble burst rate and the position that bubbles enter into the froth phase. Alternatively, the froth transportation model based on an energy balance treats the froth phase as a block. In this model, froth height above the concentrate lip is being predicted by minimising the energy of the system which is dependent on the froth geometry, froth stability and froth rheology. The froth height can be used to calculate the froth efficiency of delivering mineralized bubbles from the pulp to the concentrate lip. This paper critically analyses the current models of froth transportation in flotation, and examines the limitations of these models. The importance of froth rheology, which is the resistance to the froth flow towards the discharging weir, in determining froth transportation, is also highlighted."

Jan 1, 2014

By D François-Bongarçon

The theory of sampling (TOS), and therefore representative sampling, is based on three fundamental principles: sample correctness, which handles the search for non-bias; segregation, the effects of which must be eliminated or minimised; and variance control to help achieve the desired reproducibility. After briefly reviewing these very few, albeit essential first principles of Gy’s TOS, the state-of-the-art in TOS is examined through the prism of these principles and the prospects for the future are explored, with suggestions for further research where relevant. Regarding segregation, which is currently the focus of much research, new orientations are proposed. For correctness, which takes on a major importance when it comes to sampling devices, some new, important principles that have been put forth by recent research, are described in details.CITATION:François-Bongarçon, D, 2014. State of affairs and current research trends in theory of sampling fundamentals, including segregation and correctness, in Proceedings Sampling 2014 , pp 11–16 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By J Webb

"It is vitally important in projects where the cut-off grade is low that there is no contamination during the sampling and sample preparation process, both in the ore and the waste zones. Failure to identify contamination could have devastating financial consequences for a project. The use of a variety of blank types is essential for ensuring that contamination is identified and eliminated at every stage of the sampling and sample preparation process. This paper examines an instance where an effective assay quality assurance and quality control (QA/QC) program was able to identify and eliminate a source of significant multi-element contamination in the prefeasibility stages of an open pit project. This examination includes the: evidence for contamination findings of the investigation process of resolving the problem and correcting the data evidence for both addition of metal and dilution through contamination potential impact on the project had this issue not been dealt with. It was through the use of a combination of blank types that the QA/QC process at Mount Isa Mines (MIM) identified a contamination issue at the first crushing phase of sample preparation. Identification of the contamination allowed MIM to stop assaying activities and work with the laboratory to correct the problem. The sampling program could then be continued with no further doubts about the sample preparation process. Contaminated samples were resampled from retained core. With the continuous monitoring provided by the blanks program, it was possible to ensure that only clean results went into the resource modelling data set. CITATION:Webb, J, 2014. When nothing is what you need – the importance of using blanks at all stages of sample preparation, in Proceedings Sampling 2014 , pp 49–54 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 29, 2014

By d&apos, L. F. G. Assumpcao

Kaolin samples from Rio Capim resources were treated in conventional and superconducting magnetic separators to study the main variables that influence the color removal process. Coating clays and delaminated clay were tested. Retention time (or pulp injection velocity), magnetic field intensity and matrix type were the' variables studied. The feed brightness ranged from 84.7 to 87.6 % ISO for the coating clays and from 80.7 to 85.4 % ISO for the delaminated clay. The results showed unleached brightness values higher than 88 % ISO for coating products and higher than 87 % ISO for the delaminated product, using a conventional magnetic separator with an applied field of 1.5 to 2.0 Tesla. With a maximum field intensity in the superconducting machine of 5.0 Tesla, unleached brightness values higher than 88.5 % ISO for both coating and delaminated clays were attained.

Jan 1, 1995

By J. Wiedenroth

Since the end of the 1970s Pipe Conveyors have become increasingly important for conveying bulk materials because they have some specific advantages over conventional troughed belt conveyors. FLSmidth KOCH Pipe Conveyor represent the marked-leading know how of the former KOCH Transporttechnik GmbH, which belongs to the FLSmidth Group since January 2007. Pipe Conveyors from FLSmidth KOCH are already being used successfully at more than 260 locations around the world. Their special properties, their extreme flexibility, the horizontal and vertical changes in direction without transfer points, the small space requirement, the low-noise running and their optimum protection of environment and material without any additional casing mean that Pipe Conveyors can provide transport solutions that are often far superior to other conveying systems. The utilization of these many advantages will be illustrated in the following example of the world?s longest Pipe Conveyor at Cementos Lima, the Peruvian cement producer.

Jan 1, 2010

By Kazuki Morita

Dissolution mechanism and solubility of chlorine in the oxide melts, such as CaO-SiO2-Al2O3 (-Na2O), Na2O-SiO2-Al2O3 and CaO-SiO2-FeO systems, have been equilibrium technique was employed with controlled Po2 and PCl2, (Po2 = 10-6 -10 19 atm, PCl2 10-6 -10-13 atm at 1673-1748 K). The solubility of chlorine in the 40mass%CaO-40mass%SiO2- 20mass%Al2O3, slag was found to vary in proportion to Pb2/ w and pc/z/p' which proved that chlorine dissolved in the melts as C1 anion. Hence, the chloride capacity (CCI-), indicating the ability of molten oxide to absorb chlorine, has been defined as; The Ccl value was observed to increase with increasing slag basicity and temperature, and showed a reasonable relationship with that Of CS2-. Based on the result obtained in the present study, chlorine distribution during incineration with slags was predicted quantitatively.

Jan 1, 2003

By Nathan Deisman

Coupled reservoir geomechanical simulations have become a key component of caprock integrity assessments for SAGD operations. This work demonstrates the differences of stress evolution when considering coupled versus uncoupled reservoir simulation. Coupled simulation involves the use of a reservoir and a geomechanical simulator with feedback to each simulator to update reservoir or geomechanical variable (permeability, porosity, relative permeability, pressure, temperature, saturations). Uncoupled simulation only passes the pressure and temperature to the geomechanical simulation with no reservoir simulator updating. Therefore, it is possible to complete uncoupled simulations exclusively with no knowledge of geomechanical flow property evolution. However, it is important to understand the differences between the stress evolution in each model for caprock integrity analysis. A single geological model was selected and parametric analysis was completed while varying the geomechanical the production injection pressures (1600 kPa, 1900 kPa, 2200 kPa) for a reservoir with an initial pressure at the injector of 1300 kPa. The results of the six uncoupled and coupled models are compared through the changes in mean stress, shear stress, and strength with focus on geomechanical assessment of caprock integrity.

Jun 1, 2012

By Mark Flower

A 20L ignition test chamber has been used to test suspensions of 7 UK and world traded coals in air and O2/CO2 mixtures typical of oxy-combustion conditions. The coals varied in rank from sub-bituminous to bituminous and were tested in varying concentrations from the ignition limit to 400g/m3. Following each successful test the combustion residue was collected, weighed and analysed within a thermogravimetric analyser, allowing Q factors to be estimated. The ignition limit varied slightly in air, but was mostly around the 200g/m3 level. With the exception of Coal C, which was much harder to ignite, it correlated roughly with coal rank. The ignition limit changed significantly with O2 concentration when in mixed O2/CO2 gases. Only a few high volatile coals ignited in 21% O2/CO2 v/v, and then only with a 2500 J, rather than a 1000J, igniter. An increase in O2/CO2 levels to 30 or 35% gave ignition patterns similar to those carried out in air with a further increase to 40% having little additional effect. In addition the minimum ignition concentration decreased with increase in O2. Heterogeneous combustion or gasification of the coal by CO2 appears to be confirmed by comparing weight loss results for air and O2/CO2 mixtures respectively for an equivalent peak pressure rise.

Jan 1, 2009

By J. T. I. Poijärvi

The smelter off-gas cleaning and the weak acid treatment at Outokumpu Harjavalta Metals Oy are presented and described in this paper. The smelter consists of the copper and nickel smelters and the acid plant of three separate acid plants two of which are double contact and one single plant and of one liquid sulphur dioxide plant. The preliminary cooling and flue dust separation of the smelter off....,gases from the copper ?and nickel flash smelting furnaces and converters? in the waste heat boilers and in the hot electrostatic precipitators are described. The final cooling and cleaning of the gases in the scrubbers at the sulphuric acid plant and the treatment of the weak acid in the vacuum and in the submerged combustion evaporators for the removal of impurities are presented as well as the treatment of the condensates from the evaporators. The attention is paid to the generation of sulphur trioxide in the smelter off-gas.and to the treatment of that in the weak acid bleed-off and to the utilization of the treated acid.

Jan 1, 1992

By Zhenglong Li

A process has been developed to recover titanium from a blast-furnace slag which contains about 20-25% Ti02 and 12% Fe. In this process. "hot" slag from the blast furnace is directed to a separate furnace where it is reheated with additives to form two simple slag phases: one is titanium enriched anosovite (Ti3O5) and the other is a titanium lean non-crystal glass phase. The modified slag is then processed by conventional beneficiation techniques to produce a marketable titanium concentrate and a usable slag material. This paper focus on separating anosovite from glass by electrostatic separation and froth flotation.

Jan 1, 1996

By H. H. Hill

"The wide publicity that is given to the discover; of new oil fields has led many people to believe that our supply of crude petroleum is practically in- exhaustible and that in order to keep pace with the demand for petroleum products, it is only necessary to drill a few more wells in some of the south-western states. It is not generally realized that, although many famous fields have been developed in Oklahoma, Kansas, Texas and Louisiana during the past few years, the production of crude oil in 1919 was not sufficient to meet the demand and it was necessary to import approximately 53,000,000 barrels from Mexico.Continued efforts are being made to recover a larger percentage of the oil underground by improvements in methods of drilling and in handling producing properties. Improvements are also being made in methods for handling the oil after it has reached the surface which will result in reducing losses through leakage and through evaporation. These methods for cutting down waste in production and storage, if universally adopted, will no doubt result in appreciable increases in our supply of crude oil."

Nov 1, 1920

By Steven M. Puricelli

In recent times, smelter off gases treatment plants have become more efficient and environmentally friendly. Where in the past it was acceptable to process only high strength, treatable furnace gases, new smelters must now treat primary gases and abate dust and SO2 from secondary gases: Processing smelter gases can present some interesting challenges. Some equipment can see varying concentrations of sulfuric acid, up to the boiling point, with a periodic table of contaminates thrown in for good measure. Treating weaker secondary gases have, in the past, been cost prohibitive. Nowadays, new technology, like physical absorption or catalytic carbon, show promise for economically treating low strength secondary gases. Modem smelters do a much better job of treating the SO2 laden gases generated by the smelting process but significant challenges remain.

Jan 1, 1998

By K. C. Dean

A semiquantitative test for the presence and identification of cesium and rubidium in rocks, clays, and mineral waters has been developed by the Bureau of Mines. The test can be used in the field, as a guide for the prospector, geologist, or mining engineer engaged in location or development [w]ork. It comprises two simple spot tests of a solution prepared from the [m]ineral sample. Phosphomolybdic acid, added to a drop of the test solution, [d]etects cesium, rubidium, and potassium in quantities as low as 60 parts per [m]illion. Silicomolybdic acid, added to a second drop of test solution, enables the operator to distinguish between cesium and/or rubidium and potassium. Test procedures, equipment requirements, and limitations of the method are described in this report. Cesium and rubidium were discovered in 1860 and 1861 by Bunsen and Kirchhoff with a spectroscope. The elements usually occur together, particularly in granite and granitic pegmatites. Rubidium does not occur as an essential constituent of any known mineral, yet it is found as a minor element in so many minerals that rubidium is 16th in abundance in the earth's crust. Cesium, which ranks as the 37th most abundant element, is the principal component of pollucite and a minor element in a wide variety of minerals.

Jan 1, 1960

By N. B. Gray, I. F. Taylor

"Gas injection to promote chemical reactions or mixing is a feature of many metallurgical processes. Often the aim of gas injection is to bring about a chemical reaction between the gas and liquid but most of the past physical and mathematical modelling work has ignored the influence of such reactions. In the work reported here, cold model studies have been conducted in which gas reacts with the liquid into which it was injected. The rate of liquid mixing has been measured as an indication of the mechanical energy transfer. It has been found that gas generated chemically within the liquid is significantly less effective at promoting mixing than the equivalent volume of inert gas. The relative ineffectiveness of chemically produced gas is thought to be due to smaller bubble sizes in comparison to the inert gas case. Small bubbles characteristic of chemically generated gas move with low slip velocities relative to the liquid and lead to different turbulence generation mechanisms.IntroductionIn processes such as steelmaking, copper conversion, bath smelting and ladle steel finishing gas is injected into liquid metal where it reacts chemically or simply serves as a source of agitation. An understanding of fluid flow phenomena in such situations is an essential pre-requisite to the calculation of process intensity and the optimisation of vessel productivity. Traditional physical cold modelling approaches to prediction of liquid flow in such situations are now often augmented by the techniques of computational fluid dynamics. Even with the availability of numerical modelling techniques cold physical models continue to have an important role for validation because it is generally difficult to obtain quantitative data from high temperature processes.Almost all previous cold modelling work has been based on the injection of an inert gas into water or some other non-reactive liquid. Such models do not include the significant increase in gas volume inherent in some processes. For example the oxidation of carbon in steelmaking leads to a twofold increase in molar gas flux through the reaction:"

Jan 1, 1996

By A. Luszczkiewicz

This paper presents the beneficial effects of non-oxidative leaching of final and intermediate copper sulfide concentrates with sulfuric acid prior to the final cleaning stage of flotation. This unique process, combining leaching and flotation, appears to be advantageous for difficult-to-treat carbonate-bearing Polish copper ores, such as those processed in copper concentrators at KGHM Polish Copper. It was shown that after the chemical decomposition of about 70 % of the total carbonates naturally present in the flotation feed, a considerable enhancement of subsequent flotation results (both grade and recovery). The resulting products of non-oxidative leaching are solid hydrated calcium sulfate (gypsum), soluble magnesium sulfate and gaseous carbon dioxide. The beneficial effect established by the laboratory leaching tests was subsequently confirmed during a pilot plant operation treating final copper concentrate and a problematic intermediate concentrate at the Lubin concentrator.

Jan 1, 2007

By Tom Snyder, John Brulia

Part 4 is the final article by the authors on hazardous materials (HM)transportation safety and compliance for U.S. shippers and carriers who offer and transport commercial explosives in commerce on public highways. This article covers hazardous materials (HM) cargo segregation and securement of non-bulk packaged explosives.

Jan 1, 2015