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By FHATUWANI SENGANI

The understanding of yielding pillar behavior has been well documented in terms of pillar strength using numerical simulations and empirical formulas, but the understanding of how fracture propagates in a matured yielding pillar is not well established. A new empirical summation chart of fracture distribution along the matured yielding pillar is presented in this paper. The chart was developed using ground penetrating radar (GPR) supported by borescope observations, focusing on monitoring the distribution of extension fracture.

By Paul F. Ziemkiewicz, Aaron Noble, Christopher R. Vass

The rare earth element (REE) industry has sought to develop ore deposits where geologic processes have produced mineralized zones with commercially attractive concentrations. These deposits are extremely uncommon, particularly in the United States. Given the criticality of these materials and the need for a sustainable domestic supply, the current research seeks to leverage the generation and treatment of acid mine drainage (AMD) as an autogenous process that can lead to concentrated REE resources. 

By Turan Uysal, Thierno Saidou Barry, MURAT ERDEMOGLU, Mustafa Birinci

Nonbauxite ores such as aluminum silicate clays and coal fly ashes have been widely considered as potential resources of alumina (Al2O3). The interest focused on these ores is due to their high alumina content. Over the years, in countries where there are little or no bauxite reserves or where the recovery of existing bauxite ores to produce alumina with the Bayer process is not economical, alternative processes have been explored. Among these processes, acid leaching is seen as the most attractive process. In the acid leaching process, heat treatment for thermal activation to destruct the refractory structure of the minerals in the ores is generally recommended as a pretreatment method. Recently, the applicability of high energy ball mills, which are useful for mechanical activation as a pretreatment method before leaching, has attracted much attention. This is a short summary of our previous review [1], giving the details of alumina manufacturing from thermally and mechanically activated clays and coal fly ashes by acid leaching.

By K. E. Yassin, A. Yehia, M. Amar

Phosphate ores are the source of many commodities, such as phosphorus element, P2O5 and fertilizers. Discarding a large percentage of fine phosphate particles produced as slimes during phosphate ore processing represents a severe environmental problem, besides making the beneficiation process uneconomical. The phosphate industry is interested in a process that is efficient, with high grade and high recovery; ensures economical feasibility, with low operating cost; and is environmentally sound, with low toxicity. Numerous investigations have been conducted to try to find better processing techniques and reagents. However, reagent requirements and recovery limitations may be so high that the end does not justify the means. Reagents of biological origin are of special interest because they offer specific interactions with minerals, reduced operating costs, environmental acceptability and flexibility in adaptation. Recently, there has been a growing interest in using microorganisms as flocculants for mineral fines and as flotation collectors. 

By H. Preßlinger, H. Hiebler, K. Klepp, W. Posch, M. Mayr

It was investigated in which form sulphur is bonded in ladle slags. For this purpose, the mineralogical phases of the ladle slags were qualitatively and quantitatively evaluated by means of a microprobe. This slag characterization allowed reconstructing the bonding of sulphur into the phases of the ladle slag. Moreover, the reaction process with regard to the ionic theory as well as the structural formula for the mechanism of sulphur bonding were discussed. The bonding of sulphur into calcium aluminate slags is determined by the sulphide ion content in the slag as well as by the ratio of (CaO)/(Al2O3). Calcium sulphide separates only if the slag contains a large number of sulphide ions. When Ca12Al14O33is separated, the sulphide ion is successively integrated into the lattice. The crystal lattice of Ca12Al14O33is characterized by an open, three-dimensional anionic network composed of aluminium-oxygen tetrahedrons linking the edges. In this network, large interstitial spaces are formed, which may be filled with calcium ions on the one hand and statistically with a free oxygen or sulphide ion on the other hand. Key Words: ladle slag, structure, phases, calcium sulphide, calcium aluminate, desulphurization

Jan 1, 2004

By A. Tsubouchi, F. Noguchi, T. Takasu

"A high current density operation is desired to improve the productivity in copper electrorefining. However, a lot of problems still remain such as passivation at anode, dendritic deposition at cathode and impurity behavior during the electro refining.Effects of the current densitY on the morphology of copper deposition on the cathode, and passivation at the anode were investigated at various fluid velocity of electrolyte in the present study.Although a granular appearance of the copper deposition was obtained with increasing high current density, it was depressed by an increase of the fluid velocity of the electrolyte. A uniform deposition on the cathode was also observed when the fluid velocity of the electrolyte become higher. It was ascertained that passivation at the anode was suppressed by circulating electrolyte during electrolysis. INTRODUCTIONIt is desirable to operate at high current density in copper electrorefining in order to improve plant productivity without enlarging the size of electrodes(1). However, there are many problems in copper electrorefining at high current density with the usual commercial practice, for example, anode passivation, dendritic deposition and an increase of impurities in the cathode.In general, it is effective to agitate the electrolyte in order to suppress these problems(2). Smith et a1.(3) have performed electro refining experiments at various current densities in the range of 8 to 32 Aldm2 and at electrolyte fluid velocities in the range of 40 to 120 mlmin, and they obtained well consolidated, void free copper even at high current density in a high electrolyte velocity. However, they did not discuss the recovery ratio and the passivation behaviour at the anode. Walsh et a1.(4)(5)(6) experimented with the rotating cylinder electrode, and ascertained that electrolysis can be carried out at high current densities under the condition of pure electrolyte.With regards to anode passivation, there are several papers by previous workers(7)(8). Our group ascertained the process of producing anode slime during electrolysis(9). However, these experiments were carried out without forced circulation of electrolyte. Therefore, in the present study, to solve these problems, we electrolyzed at current densities in the range of 4 to 50 Aldm2 with circulating electrolyte in the range of 0 to 48 mlrnin. The effect of electrolyte fluid velocity on the surface morphology of deposited copper at cathode and passivation at anode were investigated when electrolysis were carried out with circulating electrolyte at high fluid velocity and at high current density."

Jan 1, 1997

By V. P. Petrov

There is a great number of asbestos deposits in the USSR. Some of them are quite large ones. The main deposits of chrysotile asbestos can be seen in the sketch map (fig. 1). Bazhenovo deposit situated in Sverdlovsk region is the largest of them. It is on mining operations since year 1889. Systematical studies of asbestos deposits were begun from the first years of Soviet Government and connected with the names of K.E. Tarasov, P. M. Tatarinov, B. J. Merenkov, N.D. Sobolev, F. V. Syromjatnikov, V. N. Lodochnikov, V.P. Petrov, V.P. Eremeev, L.A. Sokolova, V. R. Artemov, V.F. Dybkov and many others. This investigations served the USSR to be one of the most important producers of asbestos in the world. In the limits of the report a characteristic of the main asbestos deposits of the USSR may be done in general outline, from the point of view of their genesis, and in order to show their common features and differences that must be taken into account for forecasting, exploration, and mining of asbestos. All chrysotile asbestos deposits of the USSR were formed of magnesium rock as a result of comparatively lower-grade temperature hydrothermal alteration and free crystallization of fibrous chrysotile in open cavities that served as catalyst As a matter of fact an important mineral for industry is not chrysotile in general, a widely distributed rock-forming mineral, but a long fibrous and mainly vein variety of chrysotile. It must serve for geologists as an important prospecting criteria. A geologist should search for the mineral not only places of possible chrysotile generations, but places where asbestos may be crystallized in its long fibers that could be fiberized well. The Soviet geologists distinguish two groups of chrysotile-asbestos deposits: (1) related to ultrabasic rocks and (2) related to sedimentary dolomite terranes, taking into account what the maternal rock was affected by hydrothermal solutions. The largest deposits related to ultrabasite. The largest deposits in dolomite are small ones but their asbestos contains almost no iron. So much asbestos is a better filler into insulating plastics. There is a few types of asbestos deposits in the limits of the ultrabasic group. The largest of them is a Bazhenovo type which the deposits of Urals are attributed, and Bazhenovo deposits is the first instance. The Bazhenovo type is characterized by the most complete zonality in disposition of various kinds of asbestization. This type of deposits is practically the only one to be in working now in the USSR.

Jan 1, 1978

By H. J. Thevik, A. K. Dahle

"A mathematical model that calculates the stress development in a coherent and stationary dendritic network due to interdendritic flow is proposed. The fluid flow is assumed to be related to the solidification shrinkage, and under the assumption of no porosity formation and unidirectional solidification, the shrinkage-induced flow within the mushy zone is calculated analytically. The interdendritic melt flow exerts a force on the solid network and an analytical expression for the stress build-up in the network is developed. Parameter studies illustrating the influence of cooling conditions, mushy zone length, dendrite coherency, fraction solid, volume fraction of eutectic, and solidification shrinkage upon the stress development within the solid network are presented. Comparing the magnitude of the calculated stresses to measurements of the strength in equiaxed mushy zones shows that it is possible for the stresses to exceed the strength, thereby resulting in reorientation or collapse of the dendritic network.IntroductionInterdendritic fluid flow is at present regarded as a very important mechanism for feeding of shrinkage during solidification of metal alloys. Solidification of many alloys is often characterised by heterogeneous nucleation of the primary phase on substrates in the melt with subsequent evolution of equiaxed dendrites. These equiaxed dendrites can initially grow freely, but impinge on each other and form a continuous dendritic network, ie. dendrite coherency, quite early in the solidification process. Measurements of the dendrite coherency point have shown that the dendritic network is established at solid fractions ranging between 0.1 and 0.5, and most often around about 0.2 [l]. Depending on the alloy composition this means that as much as 70 to 80% of the volumetric shrinkage has to be compensated by flow of liquid through the interdendritic network. Interdendritic flow occurs with a much larger resistance compared to free flow of the liquid and flow of a liquid with dispersed crystals. The pressure drop associated with the interdendritic flow increases rapidly with decreasing fraction ofliquid."

Jan 1, 1999

By R. O. Loutfy, J. C. Withers

"Titanium powder is produced from a small fraction of sieved sponge, HDH of sponge or gas blown from a melt produced billet. Ore from foreign sources is chlorinated in a very high temperature fluid bed to make TiCl4, then vacuum distilled purified and then reduced to sponge by Kroll processing. Domestic ores of ilmenite or perovskite can be carbothermically reduced to Ti2OC which can be chlorinated at low temperatures of 250–400°C to produce TiCl4 which can be electrolyzed in a fused salt to Ti powder, or the Ti2OC used as an anode in electrolysis to produce Ti powder. The electrolysis process can be operated continuously to produce Ti powder at a lower cost than Kroll processed sponge including produce control size powder. Electrolysis processing was scaled up and operated at the commercial demonstration stage on a continued basis that verifies the potential of a low cost process to produce Ti powder.INTRODUCTIONTitanium and alloys of titanium powder have been elevated to strategic status resulting from a focus of producing meltless titanium components as well as a feed for additive manufacturing processing. However, the high cost of titanium powder has limited wide scale implementation of using titanium powder as a feed to any process to produce titanium components. Titanium powder free of alloying is available as sponge fines from the Kroll process as illustrated in Figure 1. Titanium alloy powder is much more expensive, also illustrated in Figure 1 produced from an alloy ingot or mil product as the feed and then transformed into powder by one of several melt form processes which accounts for the high cost of titanium alloy powder at approximately $60–150/lb. Ton lots of titanium alloy powder (i.e. Ti-6Al-4V) from one source is quoted at $120/lb. in the U.S. It appears that alloy powder production cost by current processing is not sensitive to volume."

Jan 1, 2016

By P. Schumacher, M. Fein

"INTRODUCTION Newmont’s Twin Creeks operation, part of its Nevada operations, produces gold from two large open pit mines. Mined ore is processed at one of three on-site facilities: a refractory mill with two autoclaves, an oxide mill and heap leaching facilities. Twin Creeks also processes various off-site sourced concentrates and ore including high grade underground ore from the Turquoise Ridge joint venture with Barrick Gold Corporation. This paper discusses Twin Creeks’ strategic mine planning process which is part of an in-depth continuous improvement program called “Full Potential.” The process involves cost analysis, phase design validations, life-of-mine production scheduling optimization, mill blending strategy and stockpile management. Through this Full Potential strategic planning, Twin Creeks is creating significant value by increasing near term free cash flow and life of mine net present value (“NPV”) and achieving cost reductions. TWIN CREEKS OPERATION Twin Creeks is one of the major gold producers in Newmont’s Nevada operations (see Figure 1, 2 and 3). Located approximately 15 miles north of Golconda, Twin Creeks produced approximately 28 % of the Nevada operation’s 2013 gold production of 1.8 million ounces (Newmont 2014). The production included Turquoise Ridge sourced gold ore from the joint venture (75% Barrick Gold Corporation, 25% Newmont).At Twin Creeks, there are two large open pits, named Mega Pit and Vista Pit (see Figure 4, 5 and 6). There are 3 to 5 phases in Mega Pit and 2 to 5 phases in Vista Pit depending on the gold price assumption. There is also an underground exploration project at the bottom of the Vista Pit. Twin Creeks produces gold from a variety of ore types requiring different processing techniques depending on economic and metallurgical characteristics. To ensure the best use of processing assets, engineering and processing groups at Twin Creeks utilize a Mixed Integer Linear Programming (“MILP”) model to guide the flow of mine sequences and material routing to various process facilities (Kawahata, Schumacher and Hufford 2013)."

Jan 1, 2015

By Dale S. Preece

"Detonation delay timing has been an important aspect of quality rock blasting for decades. Detonators that enable delay timing have improved over the years especially with the recent advent of precision electronic detonators. The positive effects of precision delay timing have been observed repeatedly in the field with improved fragmentation, heave and overall blast control. Three-dimensional computational capabilities in terms of software, material models and computer speed have recently made possible the computer simulation of multiple blast holes in a bench configuration with precise delay timing between holes. Some of the key physical phenomena enabled by precise delay timing include: 1) collision and interaction of stress waves produced by adjacent blast holes, 2) reinforcement of stress waves from multiple holes as they reflect from the bench face and ground surface, 3) reflection of stress waves from “dynamic free surfaces” created by previously detonating holes, and 4) deformation induced fracturing, cracking and fragmentation. Simulating rock blasting in 3D has shed light on the physics involved and is resulting in an evolution of our understanding of fragmentation mechanisms. Routine use of these 3D computational tools will result in a much better understanding of the complex physics set in motion by the rock blasting process and allow predictionof improved blasting."

Jan 1, 2009

By M Fritz, B Ziegelaar

"For moisture samples, the International Standard for iron ore sampling states the following: Moisture samples shall be processed as soon as possible and test portions weighed immediately. If this is not possible, samples shall be stored in non-absorbent airtight containers with a minimum of free air space to minimise any change in moisture content, but should be prepared without delay. ISO 3082 (2009)Prescribing what to do is of course easy. Putting it in practice is, however, a little more problematic.The iron ore industry has seen quite some changes in the last ten to 15 years, such as: a large increase in the volume of seaborne trade new ore types and blends coming onto the market new mines, processing plants and port facilities producing more and loading faster an increase in wet processed ore products a dramatic rise and then equally dramatic fall in the iron ore price followed by a recent recovery.All of the above have had an effect on sampling facilities. The large increase in volume coupled with ambitions such as labour efficiency, safer operations and higher precision has driven the installation and retrofitting of automated sampling and robotic sampling preparation plants in order to keep up with increased quality control.Designers of sampling facilities are invariably instructed to build plants that comply with ISO 3082. In general this means that the plants are compliant in respect of the number of primary increments, gross sample masses and sample division rules. The clause at the beginning of this abstract is mostly overlooked as it only appears in a section (4.1) describing the basic requirements of a sampling system.An error of 0.1 per cent in moisture changes the value of 1 Mt of iron ore at US$50/t by US$50 000. At 700 Mt/a of Australian iron ore exports, this is US$35 M. Frequently, errors from 0.5 to 1 per cent in moisture measurements are encountered.In comparison an error of 0.1 per cent Fe is US$0.081 (US$50/t and 62 per cent Fe base) per tonne, that is US$81 000 per Mt or about US$51 M for the same Australian annual iron ore exports.It is somewhat mystifying that we in the ISO Technical committees spend extraordinary energy (= money and time) on improving measurement techniques, whilst the big costs are in sampling errors. This is particularly true for moisture measurement. Our paper quantifies some of the sources of moisture measurements errors and suggests mitigating actions.CITATION:Ziegelaar, B and Fritz, M, 2017. Sampling for the percentage moisture in the iron ore industry, in Proceedings Eighth World Conference on Sampling and Blending, pp 271–274 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

May 9, 2017

By Ling-yun Yi, Yuan-bo Zhang, Bing Hu, Zhu-Cheng Huang, Zhen-yuan Liao

"Nucleation and growth mechanism of iron crystal grain in coal-based shaft furnace direct reduction process by microwave heating were investigated by optical microscope, scanning electron microscope and EDX. The results indicate that microwave has selectivity on various minerals which absorb microwaves. The high temperature in certain area of pellets and thermal stress on the interface of minerals are formed, results in the wustite grain smashed along the joints, and iron crystal grains turned out a spherical shape obviously. The iron crystal nucleus is formed firstly at the edge of wustite, on the interface between grains and in the holes in pellets, and grows gradually while reduction carries on from surface layer to inner core. Microwave heating promotes the rate of transportation and accumulation of the iron crystal grain, increases growth rate of iron crystal grain and contributes to formation of dense iron-jointed crystal texture eventually.IntroductionMicrowave energy as a new energy, which selectively heating materials through internal energy dissipation, has the advantages of heating uniformity, high thermal efficiency, fast heating, clean and pollution-free compared to conventional heating motheds. Microwave energy also has obvious superiority in increasing productivity. Thus, it has been widely used in many areas, including electronics, food processing, chemical, medicine, environmental protection, and family life etc [1]. As a rapidly developed green metallurgical method, microwave heating also has been widely recognized by areas of grinding, pretreatment, pre-reduction, drying, furnacing, metal extraction, and waste materials processing and utilization. Some research achievements are gradually putting into practice, showing great potential in chemical and metallurgical industry [2-3]."

Jan 1, 2011

By W. E. Wallace, P. S. Mike, C. A. Hill, V. Vallyathan, M. J. Keane

Respirable quartz duet and a kaolin clay dust have been found to be of comparable cytotoxic potential in vitro on a specific surface area basis (Wallace, et a1,1985), despite the distinctly different potentials of quartz and clay for causing pneumoconiosis or pulmonary fibrosis (Sheers, 1984). A respired particle depositing in a respiratory bronchiole or alveolus will contact a pulmonary surfactant hypophase, of which a primary component is diacyl glycerophosphorylcholine, or diacyl lecithin (DPL) (Clements, et al, 1970). Several studies have found that adsorption of such surfactant suppresses in vitro cytotoxic effects of quartz dust (Marks, 1957). Subsequent phagocytosis and digestion by a macrophage may remove the coating, restoring cytotoxic potential and initiating disease processes (Iles, 1979). Adsorption of dipalmitoyl lecithin (DPL) from emulsion in physiologic saline by respirable sized quartz dust and kaolin dusts, and consequent diminution of the dusts' hemolytic and macrophage cytotoxic potential have been reported (Wallace, et al, 1985). This report presents additional data on the cell-free in vitro phospholipase A2 enzymatic digestion of dipalmitoyl lecithin adsorbed on a quartz and a kaolin respirable sized dust (Wallace, et al, 1988) to investigate mineral specific differences in the rates of digestion and of consequent restoration of dust membranolytic potential. Respirable crystalline alpha quarts used was eighty percent smaller than 5 micorometer aerodynamic diameter with a nitrogen adsorption specific surface area of 3.97 m2/g. Respirable kaolin dust was ninety percent smaller than 5 micrometer diameter and had a specific surface area of 13.25 m2/g.

Jan 1, 1988

By T. R. Taubert, D. H. Carlson, J. H. Johnson

"ObjectiveDevelop a portable emissions measurement apparatus to sample and measure tailpipe concentrations of diesel particulate matter (DPM), carbon monoxide (CO), carbon dioxide (COJ, nitric oxide (NO), and nitrogen dioxide (NOJ under steady-state engine load and speed conditions during a 1-minute test.BackgroundThe U.S. Bureau of Mines (USBM) has a comprehensive research program to develop ways to reduce exposure of miners to diesel exhaust pollutants. Engine maintenance has been shown to have important effects on such exposure.Accurate measurements of tailpipe emissions are becoming an essential part of a good maintenance program for underground mines that use diesel-powered vehicles. Past studies of particulates in U.S. underground coal mines have shown that DPM alone may be present at concentrations greater than 1 milligram per cubic meter (mg/m3), half the 2-mg/m3 limit for respirable coal mine dust. A poorly tuned (smoking) diesel engine may be the sole cause for respirable dust concentrations exceeding the limit. Although there is currently no standard specifically for DPM in U.S. mines, regulatory steps are underway, and significant reductions of DPM levels in both coal and metal mines will most likely be required.Tailpipe emission measurements can provide diagnostic information to identify engine malfunctions such as clogged air cleaners, faulty injectors, or incorrect injection timing. In some cases, mine vehicle tailpipe DPM concentrations have been reduced up to 50 percent by engine maintenance and adjustments.An accurate measuring instrument would also be useful for determining the effects of exhaust control devices on tailpipe emissions. Little information is currently available about the overall effectiveness of exhaust controls after long-term use. Raw exhaust concentrations with and without the control device can be measured in underground mines, and from these data a control efficiency can be calculated. Knowledge of the effectiveness of exhaust control devices over time is needed to make intelligent decisions on bow to use and maintain these devices, and when to replace them."

Dec 1, 1995

By S. Eugene Mills

Twenty-five years ago, when I began my sales life marketing minerals, there was little or no contact between sales people and production people. In those days, it was not uncommon for me, as a salesman, to learn of production problems existing in my company from my customers. Today, in my opinion, any successful mining company must keep production people fully aware of circumstances that effect service to the users of the product. Basically, feldspar is presently consumed by the glass and pottery industries the same as 100 years ago. The consuming public little realizes the origin of so many things they use daily and take for granted. Feldspar is utilized in the glass that contains our Coca-Cola, Pepsi, wines, liqueurs, beer and the assorted gob¬lets from which we drink these lovely brews, the industrial glass upon which all industry depends, the bathroom plumbing fixtures that make life so different from the days of the out-house, the beautiful and durable china we enjoy at mealtime. The electricity we use requires insulators that demand feldspar. In our home ap¬pliances, automobiles, toys and airplanes, we find feldspar. I could go on and on, hopefully soliciting your help in making our taxpaying and non-taxpaying fellow man aware of the burdens he may acquire when unthinking, over-enthusiastic environmentalists foist unnecessary hardships upon the mining industry. Feldspar is marketed primarily sized from 20 mesh to 325 mesh. The glass industry requires feldspar ground 20 mesh to 40 mesh size; the pottery industry requires material from 150 mesh to 325 mesh size. One large glass plant may require up to 100 tons per day and more, whereas a small plant may use less than 5 tons per year. A large pottery plant may require as much as 50 tons per day, a small potter only 500 lbs. per year. The feldspar

Jan 1, 1977

By L. Gutierrez, J. S. Castro S. Laskowski

Water is a medium in which flotation takes place, and flotation efficiency is highly dependent on water quality. Of the total water resources on Earth, less than 2.5 percent is fresh water. This water is used in agriculture, by households and by industry. Among the industrial users of fresh water, the mining industry occupies an important position. Furthermore, mining operations are often located in arid areas with very limited access to fresh water. The demand for and shortage of water in these parts of the world, such as the Atacama Desert in Chile, makes the use of seawater by the mining industry the only sustainable solution. 

By E. A. Holbrook

IN my thirty years of educational work in the mineral industries and other engineering fields, this past year has been the most unusual and difficult one. Contact with educators from other schools leads to the conclusion that the same situation is countrywide. The first of our difficulties came from the shortsighted policy of the Selective Service in taking out of the colleges, continuously, all engineering students as soon as they had reached their eighteenth birthday. England, Canada, and Russia, too, even in the midst of their critical war situations, had the good sense to keep their young engineering brains in college, for they realized the vital necessity of a steady flow of engineering graduates into the war industries and into the postwar peace industries. As a result of the policy of our Government, our engineering schools were left with only a handful of students who had been rejected for military service. Our colleges, faced with the prospect of several years without students and without income, hastened to give leave of absence to many of their competent teachers who quickly were taken into industry and in many instances are now being retained there at higher salaries than colleges are accustomed or able to pay their teaching personnel. We are finding it most difficult to induce these men to return to their former engineering teaching work. In my judgment, it will take us three or four years to restore our engineering departments to their former level in quality of instruction.

Jan 1, 1946

By GRANT COLLIGAN, BROCK O’KELLEY, Corby Anderson

With the world’s ever-growing push to expand technological capabilities, the need for specialized materials including rare earth elements has exploded. One source of rare earths found in the United States is bastnaesite, a rare-earth-bearing fluorocarbonate, mined at the Mountain Pass Mine in California. To increase production, it has been essential to optimize existing processes and create new ones to capture current reserves. This paper presents the results of a research program conducted to expand the understanding of the bastnaesite leaching system. With the help of prior knowledge and thermodynamic calculations, a novel single-stage hydrochloric acid leach system was created to optimize the extraction of rare earths from bastnaesite. Historically, this extraction has entailed the use of a two-stage leach system involving a high-temperature hydrochloric acid leach followed by a caustic crack. We ran a series of single-stage leach experiments by reacting locked-cycle flotation concentrate with hydrochloric acid to test common leaching parameters. The results of these single-stage tests showed significantly higher rare-earth recoveries than the reported recoveries of the historic two-stage caustic crack processes, all while decreasing the number and amount of reagents needed.

Feb 1, 2023

By C. V. Davis

In the lnvestlg::ìt1on of mAthods for aSS8.7ing platin",. conducted by the Bureau ot MinAs, reoent experiments have d~velopad tha~ with ce..tain orei, especially when thr, quantity Of platinum 1s eonlidarablfl, nit'!le acid w111 not etfßct a iepard-Han of platinum and pa11adium. 'lhe following m;lthod has been found to be accurate and to reiu1 t in a complete S''lun''ation of' th~3:l metals. It is therefo 1" '!eeommei:ed that 1 t ba followed rath::r- than the method of separation with nitrio acid, givèn in Technical Pape'! 270.* At line 22, pagi 14, of that paper, bAglnnlng with ~tarm th,~ metals '.'ith dilute¡ nitrio acid," strikE out the rest of the paragraph, and substttutt~ the pro_t cedure g1 ven below. ?lunder and Thuringer.. have developed mnt¡iods for th"i sflparation of palladium from all the platinum metals exoept platinum bj m ,ans of dlmethy- 19lyoxlme. They state that the~ is no action for several hours if an excess of dimeth¡lglyoxime is added to an aqueous solution of ohloroplatinic acid in the cold, alio that only on boiling is the platinum pTecipi ated ¡~d than only PST't of the platinum i srenoved from the sUut1on. They found that palladium 1s p~ecipi tated quati tat! vely in the oold as (CaH 4N40 Pd) which is insoluble tn water, dilute hydroohlorio acid, dilute acetIc aofd or in 50~ ethyl alcbhol. All of their pT'90ipi tations we~p Carl". ied out ~hile the solutions were being heated. This caused a pal"tia~recipltation of the platinum along wi th the

May 1, 1922