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By David B. Dreisinger

Mass and heat balance modeling is a powerful tool for the design and analysis of hydrometallurgical process flowsheets. In this first of two papers, we examine the basic fundamentals of mass and heat balance modeling, and apply these concepts to several flowsheets using a simple spreadsheet model. In this way, we aim to demonstrate how such models are not only easy to construct, but can also be indispensable for comparing various flowsheet alternatives, for making rational economic decisions, and for developing a basic understanding of existing process behaviour.

Jan 1, 2002

By Lex L. Udy

External detonation generated plasmas, highly ionized zones of reacting material ejected from the surface of detonating ex-plosive charges, are shown to be the cause of channel desensitization, i.e., the self-quenching of a detonating explosive column loaded in a borehole with an air annulus between the explosive and the borehole wall. The effects of this phenomenon on several explosive compositions and types are demonstrated and discussed. Explosives tested include aluminum sensitized and explosive sensitized slurries, ANFO, liquid explosives and dynamites. Various techniques are described that can be used to reduce or eliminate the plasma effect.

Jan 1, 1978

Halide media are considered as suitable alternatives to cyanide for extracting gold and have received much attention lately. The extraction of gold by iodide-iodine mixture has been patented and briefly studied without much attention given to the fundamental aspects of this process. This paper reports recent studies on the kinetics of gold extraction in iodide media, using hypochlorite, iodine and hydrogen peroxide oxidants. The kinetics of dissolution was found to be dependent on the solution pH, reagent concentration and most importantly the iodide- oxidant molar ratio. Without proper control, the gold surface can be passivated due to the formation of solid products. Thermodynamic modelling was carried out to determine the equilibria governing the dissolution process. The formation of AuI solid was also identified as a possible product during the dissolution.

Jan 1, 1992

By James M. Tantalla, Jr. Ellman

"Construction of the powerhouse for the Willow Island Hydroelectric Project, located at the Willow Island Lock and Dam, required a 120-ft deep temporary excavation inside the limits of a cellular cofferdam on the Ohio River side of the excavation and a soil-bentonite seepage cut-off wall on the landward side of the excavation. Stability analyses were performed for critical sections to evaluate the stability of the soil slopes and rock cuts using limit equilibrium, tension crack, and buckling analysis techniques. The stability analyses indicated adequate factors of safety through the landside embankment sections, and for the weighting berm soil slopes in front of the riverside cellular cofferdam. However, the results of deep-seated stability analyses through the rock supporting the riverside cellular cofferdam indicated marginal factors of safety for the 100-year flood condition. Consequently, the riverside portion of the excavation required enhanced stability measures, namely the installation of long, high-capacity rock anchors. Also, the dewatering system was modified to lower the site piezometric head to near the top of rock to improve the stability of the rock cuts.Thirty high-capacity rock anchors were installed on the upstream, riverside, and downstream sides of the cofferdam rock cut. The rock anchors consisted of multiple, seven-wire strands designed to provide the full-required design load at 60% of the strand capacity. Rock anchor loads varied from 1,968 to 2,074 kips. The maximum number of strands per anchor was 59. Bond lengths assumed an allowable bond stress of 100 psi based on the rock bond from pull-out tests.Project DescriptionAmerican Municipal Power, a nonprofit organization that owns and operates electric generation facilities for its member communities, has been in the process of constructing hydroelectric power plants adjacent to existing navigation locks and dams along the Ohio River. The Willow Island Hydroelectric Plant was recently completed on the West Virginia bank of the river adjacent to the US Army Corp of Engineers (USACE) Willow Island Lock and Dam. The plant is on the opposite river bank to the locks, and includes two turbine generating units with FERC rated capacity of 44MW at a 20-foot head differential. The Ruhlin Company of Sharon Center, Ohio was awarded contracts to construct both the cofferdam and the powerhouse. Construction began in mid-2011, and was completed in early 2016."

Jan 1, 2016

By J. C. White

"During the early development of the Mattabi Mine in 1970, discussions with the Ontario Government revealed their policy of prohibiting, as much as possible, the development of new, isolated, single-industry townsites. Subsequently, Mattabi located its first housing in the Township of Ignace, which is situated 50 miles from the site of the mine and plant. Over 200 employees now commute 100 miles daily to and from work.This paper describes the experience gained and discusses the advantages and disadvantages of a remote townsite."

Jan 1, 1976

By A. T. Yu

Technology and economies of scale have, in the past decade, brought about the emergence of giant vessels. Meanwhile, to answer the need for rapid dispatch, as a means of combating the proportionately far greater demurrage charges, shiploading and unloading speeds have soared (Ref. 1, 2, 3). As the loading and unloading rates have dramatically increased, so has the cloud of dust grown in unbearable proportions. It not only has threatened to be a real menace to machinery and men, but in certain instances has also seriously jeopardized fish and marine life (Ref. 4). In an era when ecology is king, dust in shiploading and unloading can no longer be shrugged off as a mere public nuisance, and its control is now duly recognized as of grave concern to all. Even if public outcry were not a problem, from the operator's own parochial point of view, dust can adversely affect productivity and the well-being of the operating personnel. Without adequate control, it can also result in costly equipment maintenance, particularly when the dust is micronic in size, and abrasive. The Hierarchy of Control Techniques Given the great fortune of not yet having to deal with gas and odors, in the jargon of pollution control, our problem is confined to having to control "particulates" only. To deal with "particulates", the myriad of dust control techniques can be utterly confusing to those who are not entirely well versed in the methodology. Our analysis of what is available to date results in the following hierarchy of logical preferences: 1. Prevention 2. Removal 3. Suppression 4. Containment 5. Dilution Since it deals with the root cause, prevention always outranks the cure. Once the dust is generated, removal nips it in the bud. Only when dust removal is

Jan 1, 1972

By K. Bunney

A high-pressure laboratory elution rig was commissioned to simulate industrial Zadra and AARL elution conditions for the stripping of gold, silver and mercury from loaded activated carbon. It was found that cyanide was essential for the efficient elution of both mercury and silver, while gold was found to elute most effectively in hot, low-ionic strength solutions. Therefore, the standard AARL-type elution, which implements a cyanide soak and water elution, results in a lower recovery of mercury and silver from the carbon. No single set of conditions was found whereby gold, silver and mercury can all be effectively eluted in a single step. However, sequential elution conditions can efficiently recover all metals and provide a potential approach for separating these metals.

Jan 1, 2010

By Lenny Winkel

With the aim to develop a solar-driven process for the extraction of copper from sulfide concentrates research on the decomposition of copper sulfides under inert atmospheres has been initiated. Thermogravimetric measurements on chalcocite,(Cu2S) revealed that copper is formed already at 1823 K. Chalcopyrite (CuFeS2) also disintegrates at this temperature, although at a lower rate. Copper and iron have been identified in the solid residue. The results confirm the feasibility of copper extraction by direct decomposition of sulfides under atmospheric pressure. The decomposition under inert atmosphere prevents generation of SO2, it also alters the behavior of volatile impurities during decomposition of copper sulfide concentrates. Chemical equilibrium calculations for chalcopyrite contaminated with enargite (Cu3AsS4) have shown that the absence of an oxidic slag allows for a complete evaporation of arsenic and subsequent separation from intermediate sulfides. The need to better assess the potential of direct sulfide decomposition has prompted the development of an experimental setup for studying the decomposition reactions. The experiment has been devised such that data on the decomposition kinetics and on impurity removal can be obtained at temperatures up to 2500 K.

Jan 1, 2003

By R. Khanna, K. Hyun Ko, A. J. Berkovich, J. Hook

"The co-pyrolysis of synthetic polymer polyethylene terephthalate (PET) and agricultural wastes (naturally occurring polymer-macadamia nut shell) was investigated in the temperature range 473K to 1273K using a horizontal furnace with an aim to understand their thermal degradation under isothermal conditions. In-depth characterization of pyrolysis residues was carried out using x-ray diffraction (XRD) and solid state nuclear magnetic resonance (NMR) for carbon structure, and through determination of the concentration of unpaired electrons using electron paramagnetic resonance (EPR). In previous studies, it has been found that PET thermally decomposes ~ 650K-700K, releasing (~80 wt % of initial weight) gaseous products due to random chain scission. In the case of macadamia nut shell, three types of byproduct can be obtained from pyrolysis: char, tar and gaseous products. In the co-pyrolysis of macadamia nut shell with PET in 50-50 wt% ratio, total product weight ratio could be modified with the addition of PET acting as a hydrogen source. This is because a recombination of thermal cracking products of cellulose could be suppressed by hydrogen from PET, which will later lead to an enhancement of tar formation. In addition, pyrolysis around 673K is sufficient for bond cleavage to occur in cellulose and lignin leading to the formation of negatively charged activated carbon with high surface area, providing bonding sites for volatiles evolving from PET. Therefore the co-pyrolysis may be able to enhance the product yield (tar/char/solid carbon residue) along with a reduction in the release of gaseous products. During the co-pyrolysis, temperature was found to have a significant influence on the kinetics of thermal degradation and solid residual by-products after co-pyrolysis.INTRODUCTIONPlastics are being used worldwide in a wide range of applications in the modern society; their usage has resulted in increasingly a massive waste problem. The production of most synthetic plastics requires hydrocarbons that are produced from petrochemicals derived from fossil oil and natural gas, a non-renewable source (Speight 2011). Currently, plastic manufacture utilizes ~4% of world oil and gas production, and it is expected to drive further increases in petroleum demand by 1-2% due to their large volume of manufacture (Hopewell, Dvorak et al. 2009). Landfilling and incineration of plastic waste are the two main routes to plastic waste management (Encinar and González 2008). In Australia, only 10% of waste plastics were recycled in 2006 (White and Hyde 2011). This means that large amount of fossil fuels from plastics has either been simply burned for energy recovery or buried in the ground. There is an urgent need for developing alternative avenues for recycling waste plastics. Our group at UNSW has carried out extensive research on the recycling of waste polymers as carbon resource in steelmaking including slag foaming and carbon dissolution from waste plastics into liquid steel at 1600°C; the effect of basic plastic characteristics such as chemical composition, structure, bonding network etc. was examined (Sahajwalla, Rahman et al. 2009)"

Jan 1, 2012

By J. Drelich

The flotation limit of fine particles has been re-examined based on the effect of bubble size on contact angle, and a new surface chemistry-limited relationship describing the minimum particle size which can be floated is proposed. In this analysis the critical value of bubble-solid contact radius (re) for which there is no effective attachment between particle and bubble has to be determined. The values of re determined by extrapolation of our experimental data for contact angle versus bubble-solid contact diameter permit the prediction of the flotation limit of methylated quartz particles, with fraction-al coverage of trimethylsilyl groups from 0.07 to 0.51. The limit of fine particle flotation as determined by this theoretical approach agrees well with experimental data reported in the literature.

Jan 1, 1994

By C. Gosselin, M. Rheault, M. Benoit, Y. Bouroubi, V. Sarago

The last three decades have seen significant mining development in northern regions of Canada, where the freeze and thaw cycle of permafrost and the corresponding surface subsidence and heave represent a significant challenge to the design and maintenance of infrastructures. Identifying areas at risk is of great assistance to reduce the impact of this issue. Over the past ten years, Synthetic Aperture Radar Interferometry (InSAR) has been widely used to monitor ground surface deformation. With this technique, changes in phase between two SAR acquisitions are used to detect centimeter to millimeter surface displacements over a large area and with high spatial resolution. InSAR can be used as a tool to assist the siting and design of new infrastructure as well as highlighting the risk to existing structures in areas of unstable terrain. This paper presents the results of a project carried out by Effigis, which made use of SAR interferometry in the context of monitoring terrain and infrastructure stability in a northern mining environment that is affected by permafrost seasonal and long term changes. TerraSAR-X images acquired during two periods, August to November 2012 and March to October 2013, were used to measure the deformations and/or movement of ground surface, infrastructure and stockpiles caused by seasonal changes in permafrost extent in and around a mining site located in Nunavik, Quebec. The results showed that spatial and temporal distributions of surface displacements are in accordance with scientific and terrain knowledge. Some displacements were observed in loose soil areas while, as expected, none were detected in bedrock and rock outcrop areas. The areas most affected by active layer changes showed surface subsidence in the thaw settlement period. This study confirms that SAR interferometry has a great potential for operational applications related to risks induced by surface deformation in mining environments. It shows that this technique can be used to produce reliable maps of surface movement and monitor the vertical displacement of important infrastructure.

Jan 1, 2015

By M. Westendorf, T. Banerjee, S. Kaushik, D. Tinney

"Cyclones are one of the most extensively used pieces of equipment within the mineral processing industry because of their simplistic operating and maintenance philosophies. They are commonly used as classifiers within the comminution circuit to control the grinding product particle size for satisfactory performance of downstream operations.Cyclones are a key contributor to the effective operation of the plant and have a significant impact on the mineral processing plant operations. If the cyclones are not performing as they should, the results are often a combination of lost recovery, grade, capacity and reduced throughput. Similarly, an inefficient cyclone operation may also lead to low or high recirculating loads that impact the efficiency of the comminution circuit. This highlights the importance of having proper stability in cyclone operation while implementing any plant-wide optimization strategy.One of the key challenges in cyclone operation is that cyclones are highly sensitive to changes in operating conditions and are affected by process fluctuations such as feed pressure, solids concentration and flow rates. Fluctuations in cyclone feed characteristics lead to unstable cyclone performance which affects mineral liberation. For such an impactful unit operation, cyclones have historically been under-instrumented in an otherwise highly instrumented process plant. Traditionally, mill operators have relied on visual observations of the apex discharge to determine the operating state of the cyclones. Visual cues corresponding to the different cyclone operating conditions have been discussed by Neesse et al. (2004) as shown in Fig. 1."

Jan 1, 2014

By Hans Lundberg

AFTER the war years, great activity has been shown in geophysical exploration for ore. The appreciation by mining and government geologists of geophysical techniques and results is largely responsible for the popularity of these methods. In Canada, plans are being made to study, by geophysical methods, the structure of a portion of the Pre-Cambrian shield in the hope that such studies will not only give a clearer picture of the geology, but will be of direct aid to the mining companies when selecting areas for detailed prospecting. Although geophysics thus has become more popular, some engineers are still reluctant to employ the methods to their full extent. Allotted funds are often rather low, so that the least expensive

Jan 1, 1947

By Kihong Park

A hygroscopicity tandem differential mobility analyzer (HTDMA) technique is used to determine size-effect of nanoparticles (NaCl, (NH4)2 SO4, KCl, NH4NO3, MgCl2,CaCl2) on their hygro­scopic properties (deliquescence relative humidity (DRH) and hygroscopic growth factor (GF)). The HTDMA system uses a combination of two nano DMAs and two regular DMAs to measure particle size change in a wide dynamic particle size range. Particles are subsequently analyzed with a transmission electron microscopy to investigate the potential effect of particle structure or morphology on the hygroscopic properties. We found that structural properties of NaCl and (NH4)2SO4 particles also play an important role in determination of the DRH and GF and are more pronounced at smaller diameters. Data show that the DRH of NaCl nanoparticles increased from *75% up to *83% RH at 8 nm and that their GF decreased with decreasing size. The extent to which the GF of NaCl nanoparticles decreased with decreasing size was greater than theoretically predicted with the Kelvin correction. The GF of furnace-generated NaCl nano­particles that have pores and aggregate shape was found to be smaller than that of atomizer-generated particles that are close to perfectly cubic. For the case of atomizer-generated (NH4)2SO4 nanoparticles, we observed no signi?cant size-effect on their DRH, and the measured GF agreed well with predicted values using the Kelvin correction. For furnace-generated (NH4)2SO4 nanoparticles, a gradual growth at moder­ate RH without noticeable deliquescence behavior occurred. Their TEM images showed that contrary to atomizer-generated (NH4)2SO4 nanoparticles the fur­nace-generated (NH4)2SO4 nanoparticles are not perfectly spherical and are often aggregates having pores and holes, which may favor holding residual water even in the dried condition. For atomizer-generated KCl, MgCl2, and CaCl2 nanoparticles, we observed no signi?cant size-effects on their DRH and GF for the mobility size as small as 20 nm.

Jan 1, 2008

By C. H. Lieb

ONE astounding fact in the production of petroleum is the comparatively recent realization by producers that flowing production is the cheapest crude produced. About 1910 or even later, operators actually endeavored to get a producing well to pumping as quickly as possible after completion. A well was not really considered to be completed until it was operating on the pump. Remarkable progress has been made since then. It was not until about 1920 that producers began to take a serious interest in pressures and to think a little about proper methods of handling oil wells. Pressure gauges were installed, and records of pressures maintained, which was quite an innovation. Desultory experiments were made with tubing of different sizes, as well as experiments with placing the bottom of the tubing string at different levels in the well. Probably the first important departure from customary procedure was about 1926, during the Seminole development, when gas lift

Jan 1, 1936

By Hajime Kitamura, Nobuharu Isago, Yuta Yamanishi, Kosuke Kawata, Hiroshi Yagi, Akira Matsuoka

Mountain tunnels are generally considered to be stable during earthquakes, however, it is known that the portal areas are prone to seismic damages. Characteristics in portals such as the location of the slope, modulus of ground deformation, and the change of overburden are different for each tunnel, and damage degrees are unclear. In this study, we reproduced the seismic behavior to investigate the effect on the tunnel portal by considering some parameters above, using simple static model tests and numerical analysis. As a result, the conditions of the slope condition and minimum distance from slope was confirmed to influence on the mechanical behavior of the tunnel portal during earthquakes.

Dec 1, 2022

By FREDERICW K. BRADLE

I HAVE been puzzled by two lines of thought'; one emanating from Washington, D. C., to the effect that we must all cheer up, that in a very short time, measured in terms of months, prices would begin to recover, business would become normal, and prosperity would continue on its way just as before the interruption of a year ago; and a second, coming from certain industrialists and economists, expressing fears that all commodity prices were in for a long downward trend, which would cause much unemployment, eventually drag down wages and so restrict purchasing power as to further aggravate the situation. One basis for the fear of a downward trend in commodity prices' is that ifter great wars a depression could last for something like 40 years-the downward trend to such a depression after our recent World War having been postponed for some reason or other; and the basis for another fear was that the production of gold was becoming less. I had 'also been trying for some time past to refresh my recollection as to how my ow11 particular lead interest climbed out of the depression of 1893; and as all the metals have had, and still have. relative values and prices, I can best express what I have in mind by talking principally about lead.

Jan 1, 1930

By John A. Mathews

D R. CHARLES W. ELIOT, the great educator and philosopher-he of the five-foot book shelf-recently gave expression to a thought I had long been cherishing as a private opinion, when he said: "It is obvious that standardization has become a dangerous adversary of progress in both education and industry." This idea must have been more widespread than either of us knew, for some five years ago a writer of verse for one of the comic papers dealt with it at great length. I will quote only a few of his stanzas to illustrate his understanding of "A Standardized Existence" : A visitor at large, I stand Beneath a standard sky- Where everything is standardized To please the standard eye. Each tree is of a standard height, Each building is the same; Each man is uniform in height, And has a standard name. Above there is a standard star Beside a standard cloud, And a standard weather here prevails To please a standard crowd. With standard joy, and standard gain, The standard people live; And if there is one bit of pain T?is such as standards give.

Jan 1, 1926

By Dong-dong Liu, Jian-ping Niu, Qi Liu, Shu-sen Cheng

A numerical model was developed to simulate the three-dimensional heat transfer in the belly and lower shaft region of the blast furnace wall consisting of copper steel composite stave, packing and shell. The temperature distribution of copper steel composite stave without the slag layer or refractory lining was investigated and then compared with the copper stave. The results showed that copper steel composite stave can satisfy the requirement of overheatingfree and had an analogous heat transfer behavior as copper stave but more stable cooling intensity. This model had been validated by the good agreement between the computed and measured temperature in the thermal test.

Jan 1, 2015

By Teuku A. R. Putra, Patrick R. Taylor

Various pyrometallurgical methods for treating copper concentrates that contain appreciable arsenic are reviewed. Various aspects of the engineering of these treatment methods are discussed. The methods discussed include: complete oxidation with arsenic fixation; selective volatilization of arsenic; acid baking, soda ash roasting, and others methods. Methods for the ultimate disposal, or marketing, of the arsenic are discussed.

Jan 1, 2014