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By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By A. Mykytiuk, I. E. Puddington, W. D. Macleod, F. W. Meadus

"A laboratory-scale continuous procedure for the up-grading of naturally occurring tin ores, based on the principle of spherical agglomeration, is described. High recoveries are indicated. A proposed second stage suggests useful fractionation steps.IntroductionA LABORATORY-SCALE batch process for the upgrading of a tin ore using the principles of spherical agglomeration has already been described (1). This procedure consisted of milling, for about an hour, a precrushed ore with at least 200 per cent water, 0.2 per cent of a reagent such as tall oil (to render the de-sired ore particles hydrophobic) and about 3 per cent of a viscous petroleum oil. The feed material passed an 8-mesh Tyler sieve, and the percentages of re-agents are based on the dry weight of the feed. Du-ring the grinding, the hydrophobic particles transfer into the oil phase to produce coherent semi-solid bodies while the gangue stays preferentially in the aqueous phase. The concentrate can be separated from the gangue easily by a mechanical operation. Using an ore containing about 0.3 -0.5 per cent tin, grades of from 1.5 to 7.0 per cent were obtained by varying the pH of the system. Recoveries fell from about 80 per cent to as low as 50 per cent as the grade in-creased."

Jan 1, 1966

By Saieb Haddad, Henry Pate

"Building retaining walls in an urban area is becoming more diffi cult due to right-of-way restraints. Using standard concrete cantilever walls requires a construction easement behind the walls for installation, which for the most part is unavailable. To install these types of walls in a limited right-of-way requires extensive temporary walls to minimize the construction easement. Top-down construction walls utilizing tie-back anchors for support require either the purchase of the right-of-way or underground easements in the area of the anchors.These problems faced the Department on Interstate 75 widening in Knoxville, TN in an area of a large cut. A multi-story Insurance Building and a large commercial Retail Center were located at the top of the cut. To prevent any impact on the buildings, the walls had to be placed within a limited area. The option of buying the properties was prohibitively expensive. Due to the height of the two walls and the variability of the underling rock line, contiguous caisson pile cantilever walls were contemplated as the only wall type that would be appropriate. The cost of the two walls was estimated to be very close or even higher than the cost of purchasing the two buildings. The Department believed that there must be a better way to deal with the problem. A vertically tied-down pile frame wall constructed from the top-down with a concrete facing was developed. This allowed the construction of the walls to be restricted to the available limited area and provided substantial savings for the State. INTRODUCTIONThe widening of I-40/75 has been a major transportation project in the Knoxville area which is being constructed by the Tennessee Department of Transportation. The project includes 18 Retaining Walls and 13 Bridges. Two of the 18 Retaining Walls, refer to Figure 1, are to support two valuable properties, one being an insurance company housed in a multi-story offi ce building and the other a suburban shopping center which were appraised at $13.0 million and $5.0 million respectively. Due to the 31 ft. (9.5m) maximum height of each of the two Retaining Walls and the limited Right-of- Way of 15.0 feet (4.6m), a contiguous caisson pile cantilever wall was proposed for each of the two retaining wall sites with an estimated cost of $12.0 million each. The contiguous pile cantilever Wall is comprised of a line of caisson piles socketed into underlying competent bedrock. The design required that 4 ft. (1219mm) dia. piles be installed at 6 ft. (1.83m) centers, socketed into rock in order to provide lateral stability and restrict lateral wall movement to acceptable limits. The line of caissons would be fronted with a cast-in-place concrete face wall."

Jan 1, 2007

By Ian G. H. du Preez

It is illustrated how differences in the basic chemistry of individual metal ions can be exploited to develop new or improved separating agents. Factors like coordination number preferred by the specific metal ion, the degree of coordinate saturation reached by the metal ion and its relation to the phase transferability of the complex species, kinetic factors as opposed to thermodynamic factors controlling the success of the separation, the nature and type of the donor atom employed in a separating agent in relation to the preferences of the metal ion, the significance of stereochemical factors and the hydrophobicity of the media are some of the important factors which are discussed and applied for the development of pa1ladiwn(TI) and nickel(TI) specific separating agents, respectively.

Jan 1, 1999

By K. Yamaguchi

"This Precious metals content copper scrap is treated with a copper smelting process, and copper and precious metals are recovered. The precious metal lost in the slag is increasing with increasing of treated scrap amount. To determine the portion of the precious metals chemically dissolved and that associated with the mechanically trapped matte in the slag will be a key factor to improve the recovery of those metals. The distribution of precious metals between copper matte and FeOx-SiO2 slag phases is determined at 1300 oC and a fixed partial pressure of SO2 of 0.1 atm for the matte grades from 40 to 70 mass% of copper. The distribution ratios show a tendency to increase when the grade of matte is increased. In addition, the solubility of platinum and rhodium in the FeOx-SiO2-CaO slag under the air and the solubility of platinum in the FeOx-SiO2 slag equilibrated with a pure platinum or the Pt-Cu alloy were determined at 1300oC in the range of oxygen partial pressure from 10-9 to 10-7. The solubility of platinum and rhodium in the slag tends to increase with increasing content of copper in the slag and oxygen partial pressure. INTRODUCTIONThe stringency of the supply and demand of platinum group metal (PGM) intensifies by localization for resources and increase of the demand for PGM, furthermore, smelting and the recycling of PGM in the nonferrous smelting process take an important role. Scrap containing a precious metal for the purpose of collection of PGM is treated by copper smelting recently. With increase of the treatment amounts, loss of PGM in slags is the serious problem.In considering of PGM loss in slags, knowledge of the distribution behavior for PGM between slag and matte phases or slag and copper phases and the PGM solubility in slags is important. The distribution ratios of silver and gold between the FeOx-SiO2 slag and the Fe-Cu matte were reported by Roghani (Roghani et al., 2000), Shinha (Shinha et al., 1985) and Takeda (Takeda et al., 1993) However, there is no data for the PGM distribution ratio. On the other hand, the PGM solubility in slags was reported by Sano (Sano et al., 1997) However, there is very few report for the solubility of PGM in the nonferrous smelting slags."

Jan 1, 2012

By H. P. Greenwald

THE Committee on Rock-Dusting was formed after the fall meeting of the Coal Division in Chicago in 1938. Its primary task was to study the recommended American practice for rock- dusting coal mines to prevent coal-dust explosions as approved by the American Engineering Standards Committee. After approximately two years' work he committee concluded that although certain portions of the recommended practice could well be revised, information needed for a logical revision was not at hand, and it was inadvisable, therefore, to make revisions

Jan 1, 1943

By AIME AIME

THE annual meeting of the Woman's Auxiliary to the A.I. M.E. is always held in New York, in con- junction with the annual meeting of the Institute in February. Business sessions, teas, dances, a theater party, luncheons, excursions, and many other interesting activities filled the four days to overflowing. In all ,216 women were present, from all parts of the United ,/ mates, and there were several from Canada. On Mon- ' day not only the visitors, but the New York members also, gathered around the registration desks, where Mrs. E. N. Wolfes, Mrs. S. J. Jennings, and Miss Georgene Davis saw that everyone was properly registered and provided with tickets to whatever functions she desired to attend. Greetings were eagerly ex- changed as friends met at the luncheon on the fifth floor, where the hostesses of the day were Mrs. J. D. Handy, Mrs. T. T. Read, Mrs. Sidney Rolle and Mrs. H. J. Wolf. In the afternoon, there were visits to art galleries and other interesting exhibits, arranged by Mrs. Frederick Laist. Mrs. W. H. Bassett was the hostess at a very delightful Thé damant at the Italian Gardens of the Ambassador Hotel. Many of the men attended this function also. In the evening the visiting ladies were entertained at a theater party, with Mrs. Wilbur Judson as hostess. The play that was seen was Gorki's "At. the Bottom."

Jan 1, 1930

By P. P. Gregory

ESTIMATION of re- serves in prorated sand fields has been discussed by S. A. Judson, H. D. Easton, Jr., and W. A. Schaeffer, Jr., in a paper that appears in Vol. 114 (1935), of the A.I.M.E. TRANSACTIONS. The purpose of this present paper is to extend the investigation to prorated flush limestone fields and to outline a method of procedure in determining the amount of oil originally in place and the amount of oil that can be recovered from such fields. Although it is possible to use the decline curves to estimate the amount of recoverable oil in certain limestone fields that are allowed to produce the oil at or near capacity production, such a method cannot be used in fields under severely restricted production rates. The problem is exceedingly complex due to fluctuation in the allowable rates of oil production over a wide range and at frequent intervals, and especially because of the heterogeneous nature of the reservoir itself. A well completed in a large solution cavity, capable of producing great quantities of oil per day, may be offset by a well of very limited capacity. Also, it is di5cult to arrive at an average figure for porosity in a given limestone reservoir due to abrupt variations in the character of limestone, in many instances even between two ad- joining wells. It is a safe statement that uniformity of porosity and permeability in limestone reservoirs .is nonexistent. It is evident, therefore, that the method of estimation of re- serves on the basis of per-acre content can give only approximate results.

Jan 1, 1935

By Evan Just

DIRECT subsidies for mine production in this country began as an outgrowth of wartime 'price regulation. The price-fixing authorities realized that the volume of production to be required from domestic copper, lead, and zinc mines would invoke costs of production considerably higher than the established ceiling prices. Accordingly, beginning Feb. 1, 1942 the Premium Price Plan was set up, which undertook to pay premiums to mines for production in excess of quota, of 5¢ per lb of copper and 2Y4¢ per lb of zinc or lead. Quotas, except for small mines, were initially established at the average rate of production in 1941, but were later reduced arbitrarily on an individual basis. Subsequently, additional "B" premiums were set for lead and zinc of 2Y40 per lb and a further "C" zinc premium of 2%¢. Additional copper premiums were negotiated on an individual basis, mainly with small mines. Quotas under each of these successive categories were the production obtained at the next lower premium level. In other words, under ceiling prices of 12¢ for copper, 6,14¢ for lead, and 83¢ for zinc, it was possible for high-cost operations to receive prices plus premiums of 17¢ or more for copper, 12¢ for lead, and 16% 0 for zinc on a portion of their production. On the other hand, some of the larger operators received only slight premiums and in at least one instance none at all. The average price plus premium for copper was 12.25¢ in 1942 and rose to 13.65¢ in 1945. That for lead was 6.99¢ in 1942 and 8.73¢ in 1945, and for zinc it was 9.06¢ in 1942 and 11.200 in 1945.

Jan 1, 1948

By W. O. Crosby

INTRODUCTION. THE crystalline belt of the Atlantic Seaboard, south of New York, attains its maximum breadth of 220 miles on the northern border of North Carolina; and in this State it is most widely characterized by the occurrence of gold in workable deposits. Half a dozen auriferous belts have been recognized by Nitze and Hanna.1 These are, in the main, coincident in position and trend with the NE.-SW. zones of metamorphic slates and schists, which, more than any other feature, give character to the geological map of North Carolina. The central gold-belts, accompanying the main zone of slates and associated igneous rocks, are much the more important and persistent, and may be regarded as continuous northward across Virginia and southward into South Carolina. Tile eastern belt, on the other band, is the shortest and, economically, one of the least important. Its extreme length does not exceed 25 miles, the narrow band of slaty rocks to which it belongs passing, both NE. and SW., beneath the coastal-plain formations. But, although limited in area and production, this belt is, perhaps, comparable with the central belts or any part of the sea-board crystallines in the variety of conditions under which the gold occurs. It lies chiefly in the NE. part of Franklin county and the NW. part of Nash county, on the watershed of Fishing creek and other tributaries of Tar river. The elevation is between 400 and 500 ft. ; and the Tertiary peneplain has here an exceptionally perfect development, the reliefs separating the slightly incised stream-courses consisting of broad, flat-topped peneplain remnants, bounded by gentle lateral slopes.

Mar 1, 1908

By Shengli Wu, Laixin Wang, Minyin Kou, Xinliang Liu, Weidong Zhuang, Yujue Wang

COREX process has obvious advantages in environment protection but still has some disadvantages, for example, it has a higher sulfur content of hot metal than blast furnace. In this paper, the thermodynamics and dynamics of desulfurization have been investigated to obtain the main operation parameters related to the mass fraction of sulfur in the hot metal. In addition, statistical analyses have been carried out to study the relationship between operating parameters and sulfur content of COREX hot metal based on actual plant data. It has been found that the mass fraction of sulfur in hot metal is significantly influenced by the C content in hot metal, MgO/Al2O3 in slag, the concentration of MgO in slag, the temperature of hot metal and binary basicity (R2).A linear model has been developed and subsequently used for reducing the mass fraction of sulfur in hot metal, improve the quality of hot metal and contribute to low carbon ironmaking.

Jan 1, 2016

By Jiang Wenli, Zhang Yimin

In order to enhance the quality of iron concentrate from magnetic separation, reverse-flotation technology is often applied in an iron ore dressing plant.However, this technology has disadvantages in terms of operating cost,energy consumptionand environmental protection(Zhao, Wu& Wang,2005).Developing innovative equipment to process magnetite ore more-effectively is a way to get rid of these disadvantages of reverse flotation and improve the quality of iron concentrate.This paper describes the development of Complex Flashing-Field Magnetic Cleaner,a new kind of equipment based on the principle of combination of separation in magnetic field and separation in gravity field(Hao & Jiang, 2002).This innovative equipment possesses a tailor-made magnetic system and has the characteristics of a magneticfieldwhich can strengthen the formation of magnetic agglomerations and the dispersion of gangue mineralsto improvethe quality of separation.The automatic control system developed specifically for this equipment can further increase the accuracy of separation and stabilize the process.

Jan 1, 2014

By R. Koen, H. Visser, A. Roodt

"SynopsisThe tetraethylammonium salt of the mono-anionic coordination compound mer-oxidotrichlorido(thenoyltrifluoroacetylacetonato- K2O,O’)niobate(V) (NEt4)[NbOCl3](ttfa)], has been prepared under aerobic conditions and characterized by single-crystal X-ray diffraction. (NEt4)[NbOCl3](ttfa)] crystallized in the monoclinic P21/c space group, with a = 11.483 (5), b = 12.563 (5), c = 17.110(5) Å, and ß = 100.838 (5)o. The complex structure exists in a 50.0% (NbA) : 50.0% (NbB) positional disorder ratio.IntroductionComplexes containing organometallic type ß- diketone ligands with O,O and O,N donor atoms are used widely in coordination chemistry and have applications in catalysis, radiopharmaceuticals, etc. (Schutte et al., 2011; Roodt, Visser and Brink, 2011; Brink et al., 2010; Otto et al., 1998). These ligand systems are very useful because of their highly coordinative nature, high solubility, and also due to their ability to be functionalized with various substituents on the carbonyl carbon atoms (Schutte et al., 2011).Only a small number of ß-diketonate ligands have successfully been coordinated to a Nb(V) metal centre, with only a select few being characterized by X-ray crystallography (Viljoen, 2009; Bullen, Mason and Pauling, 1965; Preuss, Lamding and Mueller-Becker, 1994; Funk, 1934; Davies, Leedlam and Jones, 1999; Allen, 2002. The synthesis and crystal structure determination at room temperature of mer-oxidotrichlorido (thenoyltrifluoroacetylacetonato- k2O,O’)niobate(V) {(NEt4)[NbOCl3(ttfa)]} was first reported by Daran et al. in 1979. Accordingly, for this current investigation, (NEt4)[NbOCl3(ttfa)] was re-evaluated at 100 K to determine if the structural features might change with temperature."

Jan 1, 2015

By Karen Tempel

Newmont's Lone Tree Mine is located 30, miles east of Winnemucca in Humboldt County, Nevada. Starting in February 1994 a pressure oxidation circuit was commissioned to treat refractory gold ores. Gold is leached and recovered from the oxidized slurry in a six-stage carbon-in-leach (CIL) circuit. Lone Tree has been able to maintain tighter control' of cyanide addition and reduce cyanide consumption its CIL circuit through the installation of Degussa's Cyplus® CCS Cyanide Control System in the spring of 2000. 'The Cyplus® CCS, along with additional inputs' from plant sensors, has allowed tor a more efficient and effective control strategy over the manual control method used ,in the past. This paper documents the key aspects of the Cyplus® CCS installation; the development of the control strategy, and the benefits achieved from enhanced control.

Jan 1, 1998

By John W. Stevenson, Ted L. Sartain

Underground booster fan installations are currently employed in hundreds of coal mines throughout the world. Such installations, when properly designed and maintained, have proven to be safe and effective tools to provide desirable airflow volumes on sections or in areas of mines where the ventilation requirements exceed the capacity of the main fan system. In cases where an airshaft cannot be justified due to surface topography, depth of cover, or limited reserves a booster fan can serve the same purpose, be operational in a fraction of the time and at a substantially reduced cost. Booster fans are currently non-existent in U.S. coal mines. This is primarily due to lack of acceptance by the Mine Safety and Health Administration (MSHA), which has failed to acknowledge the merits of a booster fan system. Also, the absence of booster fan provisions in Part 75 of the federal regulations has led to the misconception that booster fans are legally prohibited in U.S. coal mines. In 1986, Jim Walter Resources, Inc. (JWR) developed and submitted to MSHA a plan to install and operate an underground booster fan at the No. 7 Mine. Detailed computer simulations were used to substantiate JWR1s position, that the booster fan could effectively provide the needed airflow on a developing section without adversely affecting ventilation in other areas of the mine. JWR also realized that numerous safeguards and operating procedures were essential for providing a safe system. Thus, safety features such as electrical interlocking, independent power supply, remote atmospheric monitoring, etc., were incorporated into the plan. This paper is a case-study that discusses JWR's proposed plan to install and operate an underground booster fan at No. 7 Mine. Unfortunately, MSHA's continued negative response has prevented implementation of the plan.

Jan 1, 1989

By S. N. Lekakh

Experimental work and thermodynamic simulations of cast iron refining were carried out using various additions of alkali and rare earth metals. The refining reactions for sulfur and oxygen removal were studied for melts treated with Mg, Ca, and Ce. The measured data and the results of the computer simulations were in agreement. Experimental kinetic data, together with the thermodynamic calculations, were used for optimization of the amount and sequence of the addition of nodulizers for ductile iron production.

Jan 1, 2009

By Marcos Paulo Kohler Caldas

A combinação do elevado volume gerado de resíduos de equipamentos eletroeletrônicos (REEE) com o aumento da obsolescência programada faz com que haja a necessidade de se pensar em alternativas para a disposição destes resíduos sem impacto ao meio ambiente e à saúde humana, como a reciclagem com posterior recuperação de metais. Para isso, é necessário conhecer a natureza dos materiais constituintes do resíduo. A Placa de Circuito Impresso (PCI) é um importante representante dos REEE, pois está presente em grande parte dos equipamentos eletrônicos, como nos computadores. Sua composição heterogênea possui um alto teor de metais, alguns deles preciosos, que representam quase a totalidade do valor intrínseco da placa, justificando a importância da reciclagem para recuperação dos mesmos. No presente trabalho foi realizada a caracterização de uma placa de memória de computadores obsoletos para a posterior recuperação dos metais preciosos nela contidos na forma de nanopartículas. Conclui-se que a placa de memória possui 18,9% de metais, 48,4% de cerâmicas e 32,7% de polímeros em massa. Dentre os metais o Cu é o que aparece de forma mais expressiva, constituindo 13,83% em massa da placa. Os metais preciosos Ag e Au constituem 0,053% e 0,069% em massa, respectivamente, porém seu alto valor de mercado justifica a viabilidade de sua recuperação.

Oct 30, 2017

By J Beniscelli

Some words to honour Pedro:Pedro was among the few persons with a very high level in geology modelling, resource and reserve estimation, geometallurgy development, sampling theory applications and a deep understanding of the mining industry needs. He had brilliant ideas about new developments on economic geology. He was always looking at the long-term and proposed challenging questions a decade in advance on their solution.The fundamental aim of geometallurgy is to add economic value to the mining of mine resources by timely providing information and knowledge about the relevant metallurgical variables represented by their space models. In this manner, geometallurgy allows obtaining the optimal design of a project, mitigating processing risks, optimising and supporting production plans and identifying and assessing mining business opportunities.This paper describes the conceptual framework and geometallurgical definitions and some of Codelco’s experience during the last 15 years.

Sep 5, 2011

Coal production from Coal & Allied's Hunter Valley No 1 open cut is presently hauled 10 km by road to washing and train loading facilities at Liddell. This road haul, using bottom dump trucks on a bitumen sealed road, presents some unique earthmover tyre problems. Sound tyre management has controlled one potentially serious problem, that of heat damage, implicit with such a long haul. Tread abrasion or wear is therefore the limiting tyre performance factor. Study of abrasion mechanisms and interpretation of abrasion patterns has facilitated an understanding of the wear processes involved. This understand- ing has highlighted the importance of front tyre wheel alignment. The development of irregular wear is shown to be related to the mildness of the abrasion and methods of remving irregular wear are presented. In conclusion haulage by large off highway trucks on long sealed haul roads has been eooncoically and technically successful at Hunter Valley No 1. INTRODUCTION Hunter Valley No 1 (HVl) is a major open cut coal mine, owned and operated by Coal & Allied Operations Ltd, and located in the Hunter Valley of New South Wales. Present

Jan 1, 1982

By Haibin Wang, Kaile Tang, Chenn Q. Zhou, Guangwu Tang, Zhixiang Cui, Ping Zhou, Armin K. Silaen, Hongjie Yan, Zhi Wang

Bath smelting technology, such as the submerged lance smelting furnace, is used in the modern copper making industry. The first submerged lance smelting furnace developed by Dongying Fangyuan Nonferrous Metals Co., Ltd has shown potential for high productivity and energy savings. In this study, computational fluid dynamics (CFD) was applied to investigate the current design of the furnace. A three-dimensional multiphase CFD model was developed to study the interaction between injected gas and the liquid bath. The multiphase Eulerian model was used for simulating gas/liquid two-phase flow. The flow pattern in the submerged lance smelting furnace indicated rapid flow development and strong turbulent interactions between the gas and liquid phases. The model was validated based on a water model experiment of the mixing process. Mixing times from the simulation results show good agreement with experimental data. Additionally, based on this model, the gas residence time and liquid copper matte splashing phenomena under varying gas flow rates were investigated.

Mar 1, 2017