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By S. H. Seyedein, Hamed Tavakkoli, Mohammad Reza Aboutalebi, S. N. Asharafizadeh

The liquid–liquid extraction behavior of lutetium from different acidic solutions was investigated using two extractants, D2EHPA and PC88A, in kerosene. Lutetium extraction reactions with D2EHPA and PC88A from HNO3 and H2SO4 solutions were chemically and thermodynamically analyzed. It was found that each Lu cation was complexed with six monomers of the organic extractant and released three protons. Simultaneously, the Lu cation was instituted in the P–O–H group of the extractants. Thermodynamic analysis of reactions between extractants and acidic solutions showed that the D2EHPA-HNO3 system is the most favorable for extracting lutetium. It is noted that the calculated equilibrium constant of the reaction in this system was approximately six times larger than that of the D2EHPA-H2SO4 system. However, the value of the equilibrium constant for the D2EHPA-HNO3 system was evaluated to be approximately 200 times greater than that of the PC88A-HNO3 system. Therefore, one can conclude that the extraction behavior of lutetium is more influenced by the extractant type than the solutionmedium. The synergistic effect of different mixtures of extractants on the solvent extraction of lutetium was also examined, and the highest synergistic factor was obtained for a binary mixture of PC88A:D2EHPA at the ratio of 4:1 for both aqueous solutions.

Mar 15, 2021

By P. M. Tyroler

Inco operates a hydrometallurgical plant to treat the residue from the pressure carbonylation process. The main constituent in the residue is cop¬per. The residue is leached under pressure in an acid sulphate solution in two stages and the copper is recovered via electrowinning. The electrowinning tankhouse is fully integrated into the overall plant flowsheet as spent elect¬rolyte is required in upstream leaching steps. In recent years, the amount of residue had increased and copper removal capacity became the rate limiting factor for the entire plant. Consequently, a major program was undertaken to upgrade the tankhouse with regards to capacity, efficiency, cathode quality, working environment and structual integrity and appearance. This paper will describe current facilities and operation, and detail progress in our up¬grading efforts.

Jan 1, 1987

By F. W. Gray

Ideal utilization of the heat energy in coal should theoretically be secured by supplying each atom of combustible material present with the exact quantity of oxygen necessary for complete combination. An intimate and equal admixture of the fuel particles with air is therefore to be sought. Coal, or the combustible substances of which coal is composed, may be used in solid or liquid or gaseous form. The use of coal in small particles intimately mixed with air is, in effect, a specification of coal in pulverized or dust form. There has been much important development of this manner of using coal, which may be instanced as the outstanding advance in the use of coal as a solid. The completeness and efficiency of combustion in a properly designed dust-fired furnace permits the use of locally available coals of inferior quality, and enables them to be used commercially instead of imported coals of better quality. That is to say, some grades of coal of low calorific value, that are not economically useable in lump form on grates, are useable in pulverised form, because of the more complete combustion thereby obtained, and the consequent more efficient results. In the case of coals that are unsuitable for steam-raising in grate-fired furnaces, because of clinker troubles, (arising usually from a combination of high sulphur content and low-temperature fusibility of the ash content) use in pulverised form has obvious advantages, and in addition gives the benefit of any heat units that are contributed by free sulphur in the coal.

Jan 1, 1924

By Haskiel R. Shell

While the original purpose of the Bureau of Mines work on fluorine micas was to synthesize large single crystals or film suitable to replace natural muscovite or phlogopite, the objective was broadened to include development of the many possible fluorine micas as a class of new, unique materials. Several methods were developed for the synthesis of the fluorine micas at atmospheric pressure: Solid state reaction, melting in crucibles, internal resistance electric melting, and arc resistance electric melting. The latter two methods are now med commercially. A variety of fluoromicas were synthesized by isomorphic substitution including disilicic, trisilicic, and tetrasilicic. Fluorophlogopite, KMg3AlSi3O10F2, is the fluoromica most widely used. While most of the fluoromicas are completely stable to water, many water-swelling fluoromicas and fluoromontmorrilonoids were synthesized. Single crystals or film of the fluorine micas were grown to 2 inches or more by a number of methods, but none has as yet proved economical. In the report, detailed data and descriptions are given on compositions, syntheses, products, and uses, and on the properties including physical, dielectric, chemical, X-ray, optical, and structural.

Jan 1, 1969

By N. S. Dalal, X. Shi, V. Vallyathan

"INTRODUCTIONThis paper summarizes our recent investigations of the potential role of silicon-oxygen based free radical species in the biochemical mechanism of the lung injury caused by the inhalation of freshly fractured silica. The impetus for this study came from the following observations. Inhalation of crystalline silica is associated with the development of acute and chronic silicosis. Chronic silicosis is characterized by the development of sharply marked concentric fibrotic nodules in the lung. This occurs over a period of several decades with the development of progressive respiratory impairment. In contrast, acute silicosis is manifested by the filling of the alveoli with an amorphous lipoproteinaceous exudate within a short period after exposure, and rapid development of respiratory disability often leading to fatality. Most studies on the pathogenesis of silicosis have focused on the elucidation of cellular mechanisms of cell injury and the development of chronic silicosis. Because pulmonary responses to crystalline silica are distinctly different for · the acute and chronic silicosis, we hypothesized that the acute response is associated with some unique properties of ·freshly formed silica particle surfaces, due to the formation of some reactive chemical species caused by the rupturing or the silicon-oxygen bonds. In occupations involving drilling, tunneling and sandblasting operations acute silicosis can be correlated with this unique surface reactivity of silica. The formation or reactive species was demonstrated, using electron spin resonance (ESR) spectroscopy (Dalal et al., 1986; Fuibini et al., 1987; Hochstrasser and Antononi, 1972). Grinding of quartz crystals under ultra high vacuum (10-10 torr) leads to the formation of Si- and SiO• radicals and these radicals are quenched by exposure to air and other gases (Hochstrasser and Antonini, 1972). ESR signals have also been reported from micronized quartz samples that were evacuated at 413 K (Bolls et al., 1983). In order to find a more direct relationship of such radicals to acute silicosis, we made ESR measurements on quartz dusts freshly ground in ambient air and found- that indeed grinding under ambient environment leads to the formation of the Si• and SiO• type of radicals which decay on storing the dusts in air or in biological buffers (Dalai et al., 1986; Vallyathan et al., 1988). The Si• and SiO radical formation on grinding has also been reported by Fubini et al. (1987). In addition, we recently found that •OH radicals are generated in aqueous suspensions of freshly ground quartz (Dalai et al., 1988; Shi et al., 1988; Vallyathan et al., 1988). We have subsequently carried out detailed cytotoxicity and biological assays on freshly made as well as aged quartz dusts. As summarized below, the results provide new insight into the biochemical mechanism of acute silicosis."

Jan 1, 1988

Editor?s note: Each year, the June issue of Mining Engineering features an industrial minerals review. Several people put in a fair amount of time in developing the material for this issue, all the while doing their own jobs. Thank you to the industrial minerals annual review editor, to the Industrial Minerals and Aggregates Division technical committee chair and vice-chairs, and to the authors of the individual commodity profiles. Jim Norman, member SME, of Tetra Tech, is the industrial minerals annual review editor. Candace Trimble, member SME, of Oil-Dri Corporation of America, is chair of the Industrial Minerals and Aggregates Division?s Technical Committee.

Jan 1, 2012

By H. W. Earnest

This report covers the results of a two-phase study to determine the feasibility of underground disposal of retorted oil shale. Two mining methods, chamber and pillar mining and sublevel stoping, were specified for backfilling. Phase I of the study covered the evaluation of hydraulic, mechanical, and pneumatic transport and stowing systems, individually and in various combinations, and the selection of the most feasible methods. Conveyor transport and stowing and a combination conveyor transport and stowing with pneumatic topfilling were selected for detailed study of phase II. Phase II activities included detailed engineering analysis and design of the selected systems, an engineering economic analysis, and a cost comparison with total surface disposal of retorted oil shale. An extensive literature search was conducted and the bibliography is included in the report. Research done under Contract No. J0265052 by the Cleveland-Cliffs Iron Co. Available for reference at Bureau of Mines facilities in Denver, Colo., Twin Cities, Minn., Bruceton and Pittsburgh, Pa., and Spokane, Wash.; U.S. Department of Energy facilities in Carbondale, Ill., and Morgantown, W. Va.; National Mine Health and Safety Academy, Beckley, W. Va.; and National Library of Natural Resources, U.S. Department of the Interior, Washington, D.C. Order ONLY from NTIS:

Jan 1, 1978

By Sergey Ulianov, Arkady Senchenko, Alexey Shvets, Arkady Bakotin

"This paper contains description of research results of technology development for copper recovery from weathered tails of iron processing plant. The predominant host mineral that contains valuable component is chalcopyrite occurring in its free form and in associations with ore and rock-forming minerals. Copper grade is 0.26-0.30%. Emulsion inclusions of chalcopyrite in pyrite and sphalerite were noted. Major problem is low copper recovery (30-35%) by flotation. When studying chalcopyrite in primary concentrate it was determined that the surfaces of many chalcopyrite grains are covered with oxide films which prevented collector attachment onto them. Second issue was deep association of chalcopyrite with pyrite and sphalerite. Sulfidizing reagent addition did not help to reach the required level of copper recovery to concentrate. In the result of research performed the technological flowsheet was developed including preliminary treatment of head material in a special unit aiming at oxide films removal, followed by copper rougher flotation on head size tails, crude concentrate regrinding and a number of cleaner flotation operations. After the treatment of weathered tails according to the flowsheet developed, copper recovery to flotation concentrate became 71.53%, at 23.46% copper grade. The suggested technology allows one to solve the issue with treatment of technology-related copper-containing stockpile material, as well as to include the ores where copper is represented by sulfide minerals covered with oxide films into processing."

Jan 1, 2014

By Michael Rieber

Mineral economics interfaces the mineral sciences and engineering with finance and economics in the analysis of appropriate questions facing the minerals and energy industries. Its practitioners include those trained in the earth sciences; mining, petroleum, and geological engineering; metallurgy and mineral preparation; as well as finance, information systems, economics, and statistics-most usefully in one or more combinations. Allowing for some overlap, three general areas may be identified: evaluation, economic analysis, and resource appraisal. Evaluation begins with mine investment analysis (exemplified by Gentry and O'Neil, 1984) and process costing, for which the STRAMM Handbook (Anon., 1977) provides a well-known basis for mining and beneficiation. But it extends from property appraisal, often used for the determination of taxes and royalties, through the determination and comparison of transport costs (e.g., Richer and Soo, 1977), and to benefit/cost analyses of externalities. Economic analysis, the subject of this section, is displayed in rigor and extent both theoretically and as applied to commodity classes in Vogely (1985), but it is implicit though apparent throughout Lefond (1983). The text edited by Vogely places minerals in their aggregative context with economic growth and trade, proceeds to the theoretical analysis of minerals and their markets, analyzes the structure and performance of the major mineral sectors, and concludes with policy issues: fuel, nonfuel, and environmental. Resource appraisal employs quantitative methods for the estimation of mineral and energy resources. It moves through geologic, geophysical, and geochemical properties to the identification of estimation procedures for mineral endowment and for the economic measure of stocks and flows of specific minerals (Harris, 1984). It can be used to estimate the probable amount of a specific resource remaining in a given region and has been used to project sites in a specific

Jan 1, 2008

By Frank T. Duda

A U.S. Bureau of Mines interactive FORTRAN computer program can screen explosion-proof enclosures intended for underground service. The program incorporates important information and criteria to assist enclosure manufacturers and Mine Safety and Health Administration (MSHA) personnel by providing a first-order approximation of rectangular explosion-proof enclosure characteristics prior to actual certification testing. The program uses information and data that can be retrieved automatically during program execution. The program also performs the calculations for a series solution algorithm and various equations to evaluate the enclosure for both a static internal pressure and an internal explosion. The program writes the intermediate and final calculations and information concerning the status of the screening process to a summary file on a floppy disk. One data base contains MSHA certification requirements given in the Code of Federal Regulations (30 CFR 18). A second data base contains material properties of acceptable construction materials and weld joint efficiencies. A series algorithm determines bolt and cover stresses for a simply supported rectangular cover with arbitrary bolt locations. Limit and yield line analysis is used to calculate the strength of body panels.

Jan 1, 1989

By Bruce Pinkston

This report presents a description of the Prototype Demonstration Vehicle and Safety Guidelines developed under U.S. Bureau of Mines Contract No. JO 366003, ?Improving Man Transit Safety. This vehicle was constructed to assess the feasibility of a set of equipment related guidelines which were drafted in Phase I of the same contract. State-of-the-Art improvements are embodied in such areas as collision survivability, occupant comfort, and multiple mode (on and off rail) operation. The electric battery powered vehicle carries a twelve man section crew at speeds up to 12 mph. The description of the demonstration vehicle Is presented In Volume I. Safety Guidelines are presented in Volume II.

Jan 1, 1981

By Paul J. Guay

This report presents the results of evaluating a longwall mining system specifically designed to extract a very deep web (60 inches or deeper) from a longwall panel. The report includes a productivity and cost analysis comparing the new mining sys-tem with a high capacity conventional longwall operation taking a 30-inch wide web. The analysis shows the new system will increase annual production 44 percent and decrease cost per ton off the face 21 percent. The report also includes conceptual drawings and specifications for a high capacity four-drum shearer and a unique shield type of roof support specifically designed for very wide web operation. The advantages and problems associated with wide web mining are discussed in general and as they relate specifically to the equipment selected for the new mining system. The study concludes by recommending that surface coal loading tests be conducted as the follow-on work.

Jan 1, 1978

By Scott G. Britton

Mine exploitation is a broad subject whose focus is the technical skills or efforts needed for the extraction of mineral from a known ore body. Mine exploitation can be considered the very core of the mining engineering discipline. It begins at the conclusion of the exploration and development stages of mining and ends when the ore body is exhausted and the mine (or mines)closes and is reclaimed. Section 8 on mine exploitation is comprised of seven chapters: (1) classification of mining methods, (2) mine surveying and mapping, 3) systems engineering, (4) computer methods, (5) labor relations and training, (6) management and administration, and (7) mine closure, sealing, and abandonment. Each chapter focuses its efforts towards providing detailed and useful information for the engineer on basic mine exploitation principles. The information can be applied to a broad range of mining problems without regard to mineral type or mining method.

Jan 1, 2008

By B. W. Gandrud

To say that the treatment and handling of the "fines" is the most difficult phase of coal preparation is probably an understatement of facts. It is the fine sizes from about 1/16-inch to 0 that are mainly responsible for the inescapable sludge and slurry problems at plants using wet methods of preparation. Sludge and slurry are a problem from the standpoints of both cleaning and dewatering. They cannot be cleaned satisfactorily by "gravity" methods, which are used so extensively on coarser Sizes, due to the fact that fine sizes, particularly from 65-mesh to 0, do not follow the same laws of settling as do the coarser sizes. Although fine sizes are cleaned more successfully on wet-wash tables than in jigs, even tables as usually operated in coal-preparation plants fail on sizes below 100-mesh. As to other phases of the, sludge and slurry problem, wet coal preparation plants are almost universally beset with troubles in connection with the recovery and dewatering of the fine sizes from about 14-or 20-mesh to 0. The sizes finer than 100-mesh further complicate the problems in a wet preparation plant by their tendency to stay in suspension and build up a troublesome load of solids in the circulating water. In order to prevent too much trouble from this source, it is, customary at most plants to bleed a fair-sized stream out of the circulating system continuously and replace it by addition of fresh make-up water. The slurry water withdrawn from the circuit is usually run to waste, in which case it carries with it a considerable amount of fine coal, thus increasing the "washer loss." Another evil results from wasted slurry water in that quite often it finds its way into creeks and larger streams, creating stream-pollution problems.

Jan 1, 1948

By G. H. Damon

Since 1963, Bureau of Mines Information Circular 8179 has served the mining industry as a fundamental safety guide in the field of blasting agents. In the intervening 14 years, many changes have occurred, and this report presents revised and new recommendations which recognize these changes. For example, AN-FO is now supplied mostly premixed, whereas in 1963 much of it was mixed by the blaster; aluminum metal (A1) and other fuels are now often added to AN-FO to increase strength, and flake aluminum powder is used as a sensitizer in water gels; and water gels or slurries that are now extensively used were just coming into practical use in 1963. To provide the widest possible margin of safety, some of the Bureau's recommendations are more stringent than existing regulations,

Jan 1, 1977

By A. G. Roach

Introduction This paper deals with the operations and plant of the Craigmont Corundum Project, formerly of Wartime Metals Corporation but now under the Mines Section of the Resources Development Branch of the Department of Reconstruction and Supply. Corundum is recovered by the re-treatment of an old tailing deposit at Craigmont, Ontario. Crude concentrates so produced are shipped to the plant of the American Abrasives Company, Inc., at Westfield, Mass., for final processing and distribution to the abrasive industry. The plant was recently described in a paper entitled Craigmont Corundum which was presented by the writer before the Chicago meeting of the A.I .M.E. in February, 1946. General The Project is located on? lots 4 and 5, concession XVIII, township of Raglan, Renfrew county, Ontario, near the village of Combermere, which is on Highway 62. The property is about 135 miles from Ottawa. The general area enjoys a pleasant climate with moderate summer temperatures, though the winters are rather severe, the mercury frequently falling to - 35 deg. F. The excellent boating, fishing, and hunting have made the district a favourite resort for tourists. Lumbering is the main industry. Some farming is carried on, but the soil is poor and much of the land is hilly and rocky. There are no other operating mines in the immediate vicinity, though several 'industrial minerals', including mica, feldspar, nepheline, beryl, socialite, and others have been produced in the area. The district is drained by the York and Madawaska rivers and is generously dotted with large and small lakes. The general elevation is about 1,000 feet above sea level, though numerous hills rising several hundred feet give a rolling appearance to the landscape.

Jan 1, 1946

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

By J. B. Janus

This report, the 22d in a series, gives analytical data showing composition and quality of tipple and delivered samples of coal collected during fiscal year 1972. This coverage lists mines located in 20 States. Ultimate analyses are given for most of the coalbeds listed. Tipple samples were collected by Bureau of Mines engineers at tipples as coal was being loaded into railroad cars or trucks. The deliveries were sampled in accordance with instructions issued by the Bureau of Mines, and the samples were analyzed in the Bureau laboratory at Pittsburgh.

Jan 1, 1973

By T. E. Gray

This report describes the preparation characteristics of the significant coalbeds in Harrison County, W. Va. It is one in a series of Federal Bureau of Mines reports planned to determine coals suitable for the production of metallurgical coke, either as mined or after beneficiation. Over 6.5 million tons of coal was produced in Harrison County, W. Va., in 1958, of which over 3.7 million tons was cleaned mechanically in seven preparation plants. All of the coal cleaned was from the Pittsburgh bed. It has been estimated that more than 1,816 million tons of coal remains in the county in beds 12 inches or more thick. The Pittsburgh and Redstone beds were selected by the Bureau for a study based on current production rates and estimated minable reserves. Sample locations were selected following a study of the literature, conferences with mining engineers and mining company officials in the field, and examination of the available sites. Six samples were collected from the Pittsburgh bed, and three samples came from the Redstone bed, Float-and-sink tests of the samples collected from the Pittsburgh and Redstone beds showed that neither coal could be upgraded to a metallurgical fuel under the standards set up for this study, even after intensive preparation. Finer crushing of the samples moderately increased the yields and slightly reduced both the ash and the sulfur contents in the 1.30-specific-gravity float fractions. Finer crushing slightly decreased the yields in the 1.58-specific-gravity float fractions, whereas it reduced the sulfur content 0.11 percent for the Redstone sample and 0.46 for the Pittsburgh sample.

Jan 1, 1961

By William H. Waggaman

The United States not only is the largest producer of phosphate rock but also manufactures and consumes greater quantities of phosphate products than any other country. New and expanding uses will increase even further the demand for this basic raw material. Only a small proportion of the total quantity of phosphate rock mined and marketed is consumed directly in a raw or unprocessed state; the vast bulk is chemically treated and converted into [ertilizer] and a wide variety of finished products that play a vital role in [r] national economy. Three fundamental methods are employed in decomposing phosphate rock. 1. Reduction by carbon at high temperatures. 2. Treatment with one or more acids. 3. Calcination or fusion with silica, sodium salts, magnesium minerals, or small quantities of phosphoric acid.

Jan 1, 1960