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By George W. Bain

The area in Quebec immediately north of the Ottawa river is underlain by a large area of granite gneiss intruded in lit-par-lit fashion into Grenville sediments and low silica intrusives of the Buckingham Series. This complex of metamorphic rocks is intruded by a much later magma found, chiefly, as a very large stock about 20 miles in diameter and extending from Brownsburg to Grenville, and as dykes and small outliers at various places adjacent to its outer margin. 1A similar stock at Rigaud, Quebec, is situated south of the Ottawa river and has been described by O. E. Le Roy. The earliest representatives of the later magma are a series of granodiorite dykes characterized by abundant hornblende, along with primary magnetite and subordinate sulphides scattered as roundish grains through anorthoclase and aligoclase feldspars and subordinate quartz. The rock is found as narrow dykes and shows no prominent secondary structures, either in the field or in thin sections under the microscope.

Jan 1, 1926

By Claudio Rocha Rosales

"Peñoles is a mining group with integrated operations in the smelting and refining of non-ferrous metals, and is also a chemicals producer. Peñoles is the world’s foremost producer of refined silver, metallic bismuth and sodium sulphate and is the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Peñoles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y. Year after year the production has been increased, and at present, the production capacity is 240,000 t/y. In this paper, the leaching process,particularly the operation of the jarosite circuit is reviewed ,specifying process improvements to treat high iron calcines.INTRODUCTIONThe purpose of the leaching process is to recover the metals, mainly zinc,through a series of extraction stages with sulphuric acid solutions, which progressively increase the zinc recovery. After the series of acidification stages,the solution, which is rich in iron, is sent to the jarosite circuit to separate the zinc from the iron (Garcia & Valdez, 1996).The first step of the leaching process is the neutral leach circuit which produces a zinc sulphate solution that is sent to the purification section for the removal of impurities such as cadmium, cobalt and copper, after this solution is sent to the tankhouse to feed the electrolytic cells."

Jan 1, 2016

By Toshio Suzuki, Machiko Ode, Won Tae Kim, Seong Gyoon Kim

"The Ostwald ripening and growth and coarsening of the secondary dendrite arm are studied using a phase-field model. The phase-field parameters are obtained at a thin interface limit proposed by Kim et al. In Ostwald ripening analysis, the difference of the concentration due ·to· the curvature effect is shown. The third power of the average particle radius Rav is proportional to time and the ripening constant shows a good agreement with the value by Deppers et al. The particle radii distribution shows the transition behavior to attain a self-similar stationary shape. The growth and coarsening behavior of the secondary dendrite arm is also analyzed using a phase-field model. The estimated arm spacing and its dependence on time are in good agreements with experimental data.IntroductionThe ripening or coarsening process controls the microstructure during the late stage of solidification. The ripening phenomena are recognized firstly by the Ostwald [1]. The first quantitative analysis for the Ostwald ripening in the limit of vanishing solid fraction was provided by Lifshitz, Slyozov and Wagner (LSW) [2,3]. In their study, that the mean radius grows proportional to the cubic root of time and the size distribution of precipitations shows a ""self-similar"" shape are shown. Most of the studies for the Ostwald ripening confirm or predict these two general rules above. In case of finite solid fraction, the general rules are observed but the ripening constant is larger and the self-similar shape is wider than the LSW prediction respectively [4-6]. To analyze· the high solid fraction system, the theories that consider the solute field correlation are proposed [4,7-8]. In the theory, however, since the particle is treated as the point, the effect of the concentration field deviation from the monopole field should be taken into account. Recently the numerical simulation, in which not only diffusive transportation of solute but also convection effect is considered, has been done using a phase-field model [9]."

Jan 1, 2000

By WILLIAM SLOAN

B RITISH COLUMBIA in its mining activities is going ahead by leaps and bounds both in development and production. Mineral production for 1925 was $61,492,242 in value as compared to $48,704,- 604 in 1924, or an increase of about 26.2 per cent. This is a new record. It is the first time in the history of mining in British Columbia that we have gone over the fifty million mark. But we have got in the habit of making new records. The year 1924, with its mineral production of almost forty-nine million was a new record. And I am confident that when the mining history of 1926 is written it will be found that we have established yet another new record and that we can report another 25 per cent increase over 1925. What is the explanation? It is not only that the world is settling down, and settling up, after the war. It is not only that in the rebuilding, the refashioning in which all nations are busily engaged, the metals that come from our mines are needed. More than anything else, at least as far as we are concerned, it is because British Columbia has the resources and the fact that the province has been fortunate in recent years in finding men with the enterprise and the vision required to push ahead the labor of their development. From the ranks of our own people in Canada we have prospectors who have faith, energy and requisite knowledge. They are combing our hills season after season and they are of the type of manhood that does not know the meaning of the word quit. More and more these men are learning the importance of the guidance furnished by geological reports, and to an ever increasing extent such reports, thanks to the valuable work of the Canadian Geological Survey, covering areas little known to man, are made available to them-but it is recognized that in the opening up of our Province, containing within itself 372,000 square miles, it is essential that we should have the cooperation of our cousins on this side of the line as well as of our fellow citizens of the Dominion and of the Mother Country.

Jan 1, 1926

By J P. Tidman, I J. Kirby, G H. Harries

The SABREX computer model is based on the fact that both shock waves and gas pressure are important in describing a blast. The treatment of explosive-rock interactions includes the influence of non-ideal detonation to make use of recent advances in that field. Details of the blast layout are defined from a comprehensive list of conditions the blaster can control (drill pattern, charging and hook-up). The program gives practical and graphic information about fragmentation, muckpile, damage and costs.

Jan 1, 1987

By C. Grisanti, E. Prina Howald

The major of Swiss territory is occupied by mountains. Natural events as floods, debris flows, landslides, rockfalls, and avalanches regularly threaten the safety of people and properties. On the one hand, extreme weather events cause great damages, on the other hand, the enhancement of territory’s exploitation increases the risk. The Swiss Government makes many efforts to deal with the prevention of natural hazards, especially through measures of land management. As stated by federal law, Swiss cantons are obliged to establish hazard maps and to take the risk into account in the land management. Hazard maps are based on the hazard matrix, whose abscissa and ordinate are probability and intensity of the event on site. This project focuses on rockfalls. It consists of three main parts: the creation of a database to collect data on site, the creation of a catalog with all type of measures, and the development of a methodology for the analysis of the effectiveness of protective measures. The creation of the database allows us to collect information: about the site, about protective structures implemented on it, and about failures. With many multiple choice fields and few free text fields, it can collect data in a homogeneous way, without redundancy. The catalog has to be a tool that gives a basis to make decisions. It collects information about all types of protective measures implemented on Canton Vaud’s territory or available on the Swiss market. Free text fields allow for data storage of specifics, to give a complete view of structure’s characteristics and potentials. Methodology consists of four steps. The core of the procedure is the structure’s evaluation following a score system; it allows for calculation of reduction factors that have to be applied to intensity and probability parameters of the structure. Then it is necessary to convert the reduced structure’s intensity value into a residual site’s intensity value. Although the first step enables us to choose suitable measure for a specific site, it is not necessary to perform it. Second step allows us to evaluate structures under scenario 0, where structures are in best conditions. Third step allows us to evaluate structures under six scenarios of possible failings. Fourth step allows us to convert structure’s reduced intensity into event’s residual intensity and to establish the new point on hazard matrix. While the procedure has already been defined, details of score system and conversion have to be developed during the second phase of the project.

Jan 1, 2015

By G. Barr

"The Polymetallic Twin Metals Project deposits in Northern Minnesota are being developed by Twin Metals Minnesota. Amongst the flowsheet alternatives being examined at a prefeasibility study level is one involving flotation of a bulk concentrate followed by high temperature autoclaving of the concentrate using the PlatsolTM Process to solubilize all the valuable metals in the concentrate (Cu, Ni, Pt, Pd and Au). Autoclave operating conditions have been established in which recoveries of all the pay metals are in the 92 to 99% range, and the autoclave residence time has been reduced to an hour. The stability of the precious metals in solution after autoclaving has been assessed, as well as the impact of internally recycling process liquors to the feed to the autoclave.INTRODUCTIONPlatinum group metals (PGMs; platinum, palladium, rhodium, ruthenium, iridium and osmium) are traditionally recovered from their ores by production of a high-grade concentrate by flotation and/or gravity concentration followed by smelting of the concentrate. Concentrates are smelted to remove nonsulphide minerals and converted to remove iron and sulphur. The resulting high PGM grade matte is processed hydrometallurgically to leach the base metals, leaving a residue with a very high grade (20-40%) PGM concentrate for final refining to individual PGMs. Due to the complexity of this process and its high capital cost, this process can only be applied economically to high grade PGM ores. Lower grade PGM concentrates might be accepted as copper and nickel concentrates but may not yield attractive payment terms for the PGMs. The mineralized Duluth Gabbro region of Minnesota hosts several low grade base and PGM deposits and Twin Metals Minnesota is working to develop the Twin Metals Project deposits. Earlier studies at both pre-feasibility and feasibility level, by other mining companies, have failed to yield an economically viable project based on the traditional process. It is possible to produce a saleable copper concentrate from these ores, but economic recovery of nickel and PGMs into saleable concentrates proved elusive.In the late 1990’s and early 2000’s the Platsol™ process was developed at SGS in Lakefield, Ontario (at the time Lakefield Research Limited) for the NorthMet deposit (also within the Duluth Gabbro) owned by PolyMet Mining. The process developed was a high temperature chloride-assisted pressure oxidation process capable of dissolving simultaneously the base metals (Cu, Ni, Co, Zn), gold and the PGMs."

Jan 1, 2012

By M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterite ores typically extracts 95% of the nickel and 91% of the cobalt. Impurity elements in the feed, such as iron, aluminium and chromium, also dissolve and can be detrimental to downstream processes. Rejection of impurities within the autoclave is highly desirable. Aluminium and iron hydrolyze, and then precipitate in the autoclave leaving only small amounts that are subsequently removed by precipitation in a neutralization step. The concentration of dissolved chromium can range from 200 to 2000 ppm, depending on the feed composition. Chromium in the liquid phase, usually in the hexavalent state, introduces many problems and can limit refining options. For example, chromium poisons the organics in solvent extraction making SX an expensive option. Also, hexavalent chromium must be converted to the trivalent state before it can be precipitated along with iron and aluminium. Bench-scale work confirmed that mixing small amounts of carbon-base additives, such as coke, with the autoclave feed significantly reduced chromium concentration in the autoclave discharge without any detrimental effects on paymetals recoveries and selectivity.

Jan 1, 2004

By G. Ferrara

The paper describes the new design criteria and control strategies for multi-density dense medium separation (DMS) circuits. The role of the multi-density separation is discussed, and it is emphasized that for many processing problems -related to minerals and coals -it may be very important to perform two or more cuts at different densities in order to obtain a remarkable improvement in quality of products, process efficiency and economy. The two-density separation by dense medium cyclones was generally performed using two dense medium plants in sequence. In contrast to the former technology, the multi-density separation can now be performed by using a single medium circuit composed of different interconnected medium sumps. The sumps, one for each density, are fed with different medium streams selected according to their density, size composition and content in non-magnetic contaminant in such a way that the rheological properties of the media are optimized. This new technology is based on dynamic systems to density the medium, on the size-density segregation of the medium in the cyclones and separating devices and on accurate control systems for the density, viscosity and stability of the dense media of the different sumps. The present paper reports on the theoretical basis for the new, advanced medium circuits and on the systems for the control of the densities and of the rheological properties of the dense media. A typical circuit for a two-density separation is also described, and some industrial applications reported and discussed.

Jan 1, 1994

By A. R. Sorta, D. C. Sego

ABSTRACT Temperature, solute, texture, and thixotropic effects on time domain reflectometry (TDR) measurements of water content in oil sands tailings are investigated. Results indicate that TDR water content measurements are influenced by temperature, residual bitumen, and percent clay in the tailings. A correction of 0.03–0.10/ °C must be applied to the apparent dielectric constant (Ka) to account for the effect of temperature. The Ka-volumetric water content relationships of slurries differ significantly from the commonly used Topp calibration equation. The age of the tailings and the addition of phosphogypsum did not influence TDR water content measurements.

Jan 1, 2013

By R. H. Lien

The Bureau of Mines, U. S. Department of the Interior, is investigating chemical and biological decontamination of complex wastewaters such as tailings pond water containing 280 ppm CN and 5 ppm Se as well as significant concentrations of arsenic, copper, iron, silver, and zinc. The most effective chemical procedure involves cyanide oxidation using hydrogen peroxide or sodium hypochlorite followed by selenium reduction using ferrous hydroxide. The effluent contains <l ppm CN and 20 ppb Se; concentrations of other major contaminants meet EPA drinking water standards. Preliminary research indicates that biological cyanide oxidation is possible even in highly alkaline solutions (pH 10.5) containing high cyanide concentrations; indigenous bacteria destroyed 85 pet of the cyanide. Exploratory research shows that other bacteria removed up to 79 pet of the selenium from chemically oxidized, low-cyanide water. These promising results may lead to a final processing scheme that involves a combination of chemical and biological techniques.

Jan 1, 1990

By Caroline Gerwig, Joseph R. Wickline, Zach Agioutantis

In longwall mining, the progressive caving of the roof allows stored energy to dissipate over an extended time. However, in some cases, the roof strata above the longwall panel are unusually strong and do not break with the movement of the working face. Instead, the roof material bridges over the expanse of the longwall, forming an unstable beam. Later, when this beam breaks, the stored energy can release suddenly, causing a seismic event to propagate to surrounding mine workings. The focus of this paper is to estimate the size of beams that form over longwall panels to the seismic energy recorded by the mine. Analytical calculations are used to verify two-dimensional models of longwall roof beams to determine the strain energy and gravitational energy developed, which is then released upon strata failure to surrounding mine workings. Models are developed using RS2 to model the stress, strain, and deflection along the bottom of the longwall roof beam to calculate gravitational and strain energies. Gravitational energy is shown to be the main driving factor in energy release, except for the beams with low heights. Analyses allow the determination of beam characteristics based on seismic data. The analysis is refined using swelling factor to compare various beam drop heights. The models show an increase in seismic magnitude for higher drop heights. However, the actual data provided by the Buchanan mine displays a decrease in seismic magnitude with increasing drop height, indicating that energy is dissipated into the broken gob material as drop height increases.

Jul 1, 2023

By M. Z. Emad, Y. Majeed, G. Rehman

Massive deposits of rock salt are mined in the Salt Range area of Pakistan. The main export products of rock salt include salt lamps, blocks, and tiles, while local consumption includes the chemical industry and domestic use. The profitable production of salt for value addition depends on the quality, size, and shape of the block. Salt processing for value addition is easier when very few cracks are present in the blocks. The current salt mining practice involves drilling and blasting, which introduces undesired fractures in the material. This paper focuses on the extraction of rock salt blocks by applying conventional cuboidshaped block mining methods used in quarries. The techniques include wedges and feathers, expansion chemicals, and blasting with low-yield explosives. Experimental work involved both laboratory-scale and in-situ field testing. Laboratory experiments assisted with the determination of splitting force, loaddeformation curves, and other rock mechanics parameters. Regression analysis proposes a relationship for the estimation of radial strain from the load in the case of the wedges and feathers method. The splitting force obtained from the laboratory tests was used to confirm the accuracy of the already published empirical relationship. The results of the laboratory as well as in-situ tests showed that the wedges and feathers technique is the most suitable method for mining rock salt blocks of the desired size, shape, while minimizing cracking.

Mar 2, 2022

By Jack G. Hazan

The Critical Path Method is the modern scientific answer for solving the planning and scheduling problems inherent in today&apos;s complex projects. With this method, nothing is left to chance. All resources are controlled and kept to the minimum. The various phases are properly planned and strategically determined. Optimum conditions are evaluated for the most economical and fastest way to complete a definite project. The method must be fully understood and implemented with positive data and continuous feedback to obtain the best results. This paper covers the various aspects of the Critical Path Method and mentions some of its applications in the mining and metallurgical fields. T 0 progress to a higher state of human welfare necessarily involves sacrifices. The greatest sacrifice is to relinquish social freedom in favour of economic freedom. In the old days, for example, a cobbler was free to work at whatever time of the day he chose; today, he can&apos;t. He is now forced to adapt himself to environment and to work at stand-

Jan 1, 1965

Numerous underground coal mine ventilation seals have been installed in the United States of America prior to 2006 and after implementation of the Mine Improvement and New Emergency Response (MINER) Act. Seal engineering, design, placement, and construction is regulated in industry, but post-construction monitoring of seals is limited to visual inspection of the outby face and seal perimeter, convergence measurement, and atmospheric monitoring. To monitor seal integrity and to provide safe working conditions, a form of non-destructive testing (NDT) is necessary to accurately reflect the health of the seal by detecting post-construction changes, deterioration, or defects within in-situ seals in underground coal mines. Previous research from the National Institute of Safety and Health (NIOSH) has indicated the potential for utilizing ground penetrating radar (GPR) for assessing in-situ mine seals. This paper provides an update to the assessment of proposed NDT methods for seal evaluation using commercially available GPR technologies and systems. Full-scale free-standing seals and large-scale seal specimens were analyzed with an array of GPR units from various manufactures using multiple frequencies.

Feb 23, 2014

By A. Renton Amell

The rate of dissolution of U02 was measured in acid solutions similar to those used for in situ leaching, with S04 of 10-1.82 to 10-4 M, Fe(III) of 10-2 to 10-4 M and pH&apos;s of 1.1 to 2.3. The dependence of dissolution rate on pH was small and inconsistent, probably reflecting the combined effects of a very weakly polar oxidizing complex, probably FeSO4+, and a nearly neutral U02 surface. Differences in the state of the U02 surface may explain this variability as well as contrasts between these results and results reported in other work. Changing either S04 or Fe(III) concentrations significantly affects dissolution rates. Increasing low sulfate concentrations in solutions containing 10 2 M Fe(III) at pH 2 results in formation of FeSO4+. In such solutions, rates increased with (S04)/(Fe(III)) up to 1:30, thereby indicating that the oxidation of U02 by FeSO4 is more rapid than by Fe3+. However, the dissolution rate decreased at higher (SO4)/ (Fe(III)), due either to sorption of SO42- on the UO2 surface or to formation of other less reactive sulfate complexes such as Fe(S04)2 or FeHSO4+ However, Fe(III) concentration is the dominant factor in determining solution rates. The rate was directly proportional to ferric iron concentration, indicating that the rate-determining step of the dissolution reaction is a single-electron oxidation by a ferric complex. Dissolution rates were lower in solutions of 0.1 and 1.0% H202 (0.029 and 0.29 M) than at similar concentrations of ferric iron because of formation of an insoluble surface coating of uranium peroxide, UO4?4H20. This phase may limit the value of hydrogen peroxide as an oxidant in lixiviants, not only by its very low solubility, but perhaps also by filling pores and reducing permeability in the ore body.

Jan 1, 1978

By GEORGE S. POPE

This bulletin is a revision of Bulletin 63 and is published by the Bureau of Mines in order that purchasers of coal for Government, State, municipal, or private use may be informed regarding advances or refinements in sampling coal deliveries and preparing specifications for the purchase of coal. The purchase of coal by the Government under specifications depending on the heating value of the coal, its content of ash and of moisture, and other considerations, rather than upon the reputation or trade name of the coal, was based on the fuel investigations begun by the Technologic Branch of the United States Geological Survey in 1904. The plan was first adopted by the Treasury Department in 1906. Since then the plan, variously modified in form, but the same in principle, has been gradually adopted by other departments until, at present, of the coal used by the Government, the total value of which approximates $8,000,000 annually, more than half is purchased under specifications. The Government publications dealing with the adoption by the Government of the specification plan, the number of contracts awarded on that basis, and the quality of the coal delivered under such contracts in the several fiscal years covered by the reports are given in publioations a listed at the end of this bulletin. Under the authority of acts of Congress making appropriations for analyzing and testing fuels belonging to or for the use of the United States Government, a laboratory is maintained at the headquarters of the Bureau of Mines, Washington, D. C., where samples representing deliveries of coal purchased under specifications for Government use are analyzed and tested. At this laboratory more than 1,200 samples have been analyzed and tested in one month. With the complete equipment and the efficient force employed, the analytical work has been so perfected that the analyses and heating-value tests of the samples received are as accurate as may be reasonably expected in laboratory work of this nature. One of the serious drawbacks to the general adoption of the specification method for the purchase of coal is the difficulty of obtaining at reasonable cost samples of coal that can be considered fairly representative of the commercial product delivered in wagons, railroad cars, or ships. Therefore the method of taking and preparing samples for shipment to the laboratory has been given fully as much care as the making of the analyses and tests, and a general plan of collecting samples fairly representative of the delivered coal has been evolved through various modifications and improvements based on experience and increased knowledge of the physical and chemical characteristics of the various coals that are purchased by the Government. The method that is in general use by the Government is described in the following pages. In connection with studies of the coal deposits of the country, of the best methods of preventing waste in mining, and of increasing efficiency in the utilization of coal belonging to or for the use of the Government, geologists and engineers of the United States Geological Survey and of the Bureau of Mines have visited more than 2,500 coal mines scattered through all of the coal-producing States and Territories. From each mine 2 to 8 or more samples were taken, the number depending upon the size of the mine and its output. The analyses and descriptions of the samples collected up to the end of the fiscal year 1913 are published in Bureau of Mines bulletins 22 a and 85,b and those of samples collected in the fiscal years 1914 and 1915 are presented in a bulletin that will soon be published by the bureau. A study of the analyses of these samples and of the samples taken from cars shipped from a number of the same mines shows that the mine samples are as a rule of higher grade than the average commercial shipments, particularly with respect to containing a lower percentage of ash and having a correspondingly higher heating value. This difference is due to the fact that the Government inspector, proceeding on the basis of what can be done by a good miner, usually removes more of the partings of bone, slate, and other extraneous matter from his mine samples than the average miner does in ordinary practice, the aim of the miner being to get the maximum number of tons past the tipple inspection, as his earnings are based on his output. The average miner, therefore, does not always take as much care as he might in rejecting the impurities. The difference may be caused, too, by the presence of pieces of the mine roof and floor in commercial shipments. The Government inspector can readily

Jan 1, 1916

By G. E. Sreedhar, R. Kumar

The pockets of high silica blue dust across the entire high grade hematite deposits in the Bailadila sector bothers the excavation activity due their iron content, which is higher than the threshold value specified by the Indian Bureau of Mines and the agony of stacking them separately due to their fragile & powdery nature. The physical nature of blue dust and its negligible alumina content makes these a potential source of hematite, which is a blessing in disguise. As most of the particles are in the form of an independent grain making it appropriately suitable feed for dry magnetic separation and thus the dry beneficiation has turned a bane into boon by enabling to produce concentrate either suitable for using as DSO or amenable for blending. The emphasis on carrying out dry beneficiation studies in the present context serves the purpose of mineral conservation, mitigates the issues of excavation and stacking as well as conservation of water resource. This paper describes the laboratory and pilot scale dry beneficiation studies carried out on blue dust of 48 – 60%Fe and Silica up to 30% at 25 Kg/hour to 400 Kg/hour, resulting in production of concentrate assaying 60 – 65%Fe. INTRODUCTION High silica blue dust (HSBD) is associated with Banded Hematite Quartzite (BHQ) and is available in abundance in various pockets across the Iron ore body in the Bailadila region of Chhattisgarh state. High Silica Blue dust occurs in the form of free granular particles and also as friable lumps. The chemical quality of this falls under sub-grade category (45 – 55%Fe) and as per the guidelines of Indian Bureau of Mines, these are to be stacked and conserved as future resources of Iron if it can’t be utilized in the present circumstances. Due to its friable nature, stacking of HSBD is a challenge and it is also compounding the problem by polluting the air under high velocity wind conditions. Because of its physical nature and occurrence in pockets pose challenge to systematic mining. The existing processing set up of the operating mines is designed to treat either Direct Shipping ore (DSO) or Run-of-Mine (ROM) have grade >60% Fe. The present practice of beneficiating iron ore fines (<1 mm) comprise combination of two or more processes such as desliming, hydraulic classification, magnetic separation and flotation apart from requirement of grinding depending on liberation characteristics. The HSBD which is predominantly occur as free granular particles, is significantly low in its alumina content. This gives us an opportunity to utilize them by exploring a suitable beneficiation process so that the concentrate produced can be used as a sweetener for alumina rich iron ore/concentrate. Thus, in the present study, an attempt has been made to adopt dry high intensity magnetic separation technique to explore the amenability of the high silica blue dust for beneficiation.

Jan 1, 2019

By R. V. Lundquist

This report describes results of tests on the desilication of solutions resulting from the leaching of lime-soda sinters. Desilication was accomplished by heating the solutions in an autoclave. A liquor relatively free of silica was obtained after 30 minutes of heating at 200 p.s.i.g. in the presence of lime. The addition of lime improved desilication, but the rate and efficiency of desilication was effected by the quality of lime used. The optimum quantity of lime for effective desilication was about 6 grams per liter. A lesser quantity gave poorer desilication, and a greater quantity increased the alumina loss without improving desilication. The alumina loss was approximately proportional to the lime added. A complex structure, called artificial noselite in this report, was the only silica bearing compound detected in the desilication precipitate. Other compounds present were Ca(OH)2 (calcium hydroxide), CaCO3 (calcium carbonate), and Ca [A1(OH)6]2 (hydrated tricalcium aluminate). Sodium carbonate in the leach liquor retarded the formation of the calcium aluminate; hence it decreased the alumina lost to the precipitate. The extraction of alumina from aluminum silicate materials by the limestone soda-sinter process has been investigated by the Bureau of Mines for many years. The process consists of the following major operations: Blending the aluminum silicate with limestone and soda ash in such proportions that dicalcium silicate and sodium aluminate are formed on sintering; leaching the sinter in a carbonated caustic solution to extract the soluble alumina; purifying the leach liquor by the precipitation of soluble silica (this precipitate is designated desilication precipitate in this paper); precipitating alumina trihydrate from the purified liquors by carbonating with carbon dioxide gas; and calcining the trihydrate to alumina. Commercial grades of

Jan 1, 1962

By C. G. McLaughlan

The Noranda concentrator was placed in operation in October, 1928, and the object of this paper is to outline operations during the twelve months which have elapsed since that time. The ores milled are massive sulphides carrying copper and gold, and, in certain cases, zinc. These ores have a specific gravity of about 3.8. The average assay of the copper-gold ore so far treated has been 2.0 - 3.5 percent Cu; 0.10 - 0.20 oz. Au; 40 - 51 percent Fe; and 6 - 15 percent SiO2. In this ore the copper occurs almost entirely as chalcopyrite, and the iron which is not combined with the copper is present mainly as pyrite and pyrrhotite. ?some iron is also combined with the silica, the ratio being about 1 to 4, and a small percentage is present as magnetite. The occurrence of the gold has been shown by microscopic work carried out by Prof. L. C. Graton, of Harvard University, to be very variable. Some of it is free, and is included within the base-metal sulphides or occurs at their boundaries. A similar distribution also holds for a portion of the gold which is combined as a telluride. Little is so far known of the occurrence of the silver other than that some of it may be combined with the gold in the telluride, petzite. The copper-zinc ore contains up to 6 percent copper, and has a very variable zinc content. The copper in such ore is present as chalcopyrite, and the zinc as sphalerite. In starting the mill we had three conditions to face; the first of these was climatic, the second was the lack of skilled flotation operators, and the third was the ore itself." The last of these three proved much more difficult to contend with than the other two combined.

Jan 1, 1930