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By J J. McNee and, J Crusius, T F. Pedersen

The use of water covers is a globally-applied method for minimising acid rock drainage (ARD) and metal leaching. Although the subaqueous disposal of potentially acid-generating materials has been shown to effectively limit ARD, under certain scenarios, metal remobilisation can occur at circum-neutral pH. The following paper presents data from four case studies in which metal mobility from submerged mine waste resulted in degradation to water quality in the overlying water cover. Subcentimetre resolution profiling of dissolved constituents across the tailings-water interface (dialysis arrays), in conjunction with mineralogical information, were used to elucidate the controls governing metal mobility. The data illustrate four pathways of metal remobilisation, including: the release of zinc via the oxidative remineralisation of metal-rich organics at the tailings-water interface; enhanced remobilisation of arsenic as a result of anthropogenic eutrophication; the release of copper resulting from the pH-driven dissolution of treatment sludges; and the release of radium from uranium mill tailings due to the dissolution of radiobarite [(Ra,Ba)SO4] by sulfate-reducing bacteria. The results highlight the conclusion that the chemical stability of submerged tailings reflects both: the solid-phase characteristics of the tailings material; and the physical, chemical and biological characteristics of the depositional environment. In particular, the data illustrate that rigorous characterisation of both the waste solids and receiving environment must be performed in order to assess their compatibility. The results have relevance to the management of tailings repositories including constructed impoundments, pit lakes and natural lakes.

Jan 1, 2003

By K. V. Godfrey

With the increasing need to exercise better control over mill circuits has come a requirement to develop rapid, accurate means of measuring circuit parameters. One of the most important parameters is the assay of the material in the circuit (or about to be introduced to the circuit). To date, most on-stream analysis has been performed using X-ray fluorescence equipment. Neutron activation offers an alternative method in certain circumstances, and one which has several interesting advantages. Recognizing the need for a simple, safe neutron activation unit suitable for on-stream analysis in the mineral industries, Atomic Energy of Canada Limited has designed, built and tested the SHERLOCK system. One prototype (SHERLOCK I) is located in Ottawa and is now used primarily in research. A second prototype (SHERLOCK III) is located in Vancouver at the laboratories of B.C. Research. This unit is being used for some development research and for evaluating the unit in specific applications. Most of the work completed to date has been aimed at proving the technique and in developing some of the parameters needed to design systems for a milling plant. Funding for the work has been through research grants and through sponsor¬ship by interested companies.

Jan 1, 1971

By W. E. Young

This paper describes operations of the Chief Consolidated Mining Co. at the Chief mine in the Tintic district, Juab County, Utah, where the outstanding problem is water control; the unique pumping methods employed are featured in this report. The ore bodies in this district occur as long, narrow shoots along fault fissures, usually in the Bluebell dolomite of Ordovician age. Oxide ores predominate above the 1800 level, which is also the natural water level. Sulfide ores containing lead, zinc, silver, and gold extend below the 1800 level. The mine is developed by vertical shafts and winzes, from which drifts are driven to the ore bodies. In the lower levels of the mine these drifts extend long distances from the shafts or winzes because of the relatively low dip of the ore shoots. The mine has been worked to the 2800 level and the 18-411 winze extends to the 3080 level.

Jan 1, 1958

By R. L. Solmer

During 1959-61, the Bureau of Mines investigated the strain and deformation induced in rock and concrete linings around mine openings by retreat panel caving at the Climax Molybdenum mine. Two concrete-lined slusher drifts on the Phillipson level of the mine were instrumented with both electrical strain gages and extensometers. Changes in strain and deformation were recorded over an 18-month period during the undercutting and caving of the mining panel. General agreement was found between the strain and deformation measurements and the hypothesis that the vertical component of the stress field on the openings is almost completely removed by undercutting. This phenomenon is a possible explanation for the structural failures that occur in the slusher drifts during the undercutting cycle.

Jan 1, 1965

By M. R. Geer

Samples of coal from six beds in the Roslyn-Cle Elum field of Washington were subjected to float-and-sink tests to determine their amenability to the production of high-ash boiler fuel for on-site power generation. Grindability tests and analyses of ash were made. All of the coals would require some degree of cleaning to insure a product of 25 percent ash. With two of the coals the entire size range would have to be washed. With the other four, it would suffice to clean only the coarse coal and bypass the raw fines.

Jan 1, 1965

By E. W. Lithgow

Commercial volumes of nickeliferous laterite ores overlie part of a 90 km long belt of peridotites in central Dominican Republic. Protores are serpentinized harzburgites and dunites, with lesser serpentinite. The ore mineralogy consists mostly of goethite, serpentine-group minerals, quartz and poorly crystallized, x- ray amorphous materials. Minor constituents are hematite, gibbsite, olivine and enstatite. In the Ore Dressing plant the mine feed is subjected initially to proper sizing and blending to produce a homogenized mix. Subsequent drying and upgrading, by selective crushing and screening of rock fragments through a Barmac circuit, complete preparation of the ore for pyrometallurgical processing.

Jan 1, 1993

By Allan E. Martin, George Glocker, C. E. Wood

"INTRODUCTION As part of a comprehensive investigation of the mechanism of defurization of iron and steel by slags, the Blast Furnace Studies Section, Metallurgical Division, Bureau of Mines, in cooperation with the Institute of Technology, University of Minnesota, has made a study of the forms in which sulfur occurs in blast-furnace slag. This report presents data on the three sulfides most important in iron smelting, namely, ferrous sulfide, manganous sulfide, and calcium sulfide. The tendency of these sulfides to form colloids in the molten slag was determined by an examination of quenched samples with an ultramicroscope.Vogt/ conducted experiments on sulfide silicate melts and examined synthetic blast-furnace slags in a partly crystallized condition. His conclusions were that FeS, CaS, and MnS, or isomorphous compounds, such as (FexCay)S and (MnxCaa)S, were precipitated from the melt, depending on the composition of the slag. In all specimens sulfides were visible and were spherical.Coloration of glass by sulfur also provides indirect information on the nature of sulfur in blast-furnace slags./ There seems to be a general agreement at present among the workers in the field of colored glasses that ferrous sulfide is a strong color producer. Colors that have been attributed to this compound include yellow, orange, brown, blue, and black. Apparently the ferrous sulfide is considered to be dissolved in these glasses. There is no indication that any of them have been examined for a colloidal phase.Lorenz 7/ investigated a single manganese slag in the glassy state and observed a Tyndall beam in an ultramicroscope. His conclusion was that either a manganese compound had precipitated in a finely divided condition or that metallic manganese had volatilized and penetrated into the slag as a vapor and thus formed colloidal particles."

Feb 1, 1941

By Nicole de Jager, Michael J. Nicol

"In order to liberate gold from refractory gold ores and concentrates it is generally necessary to oxidise the surrounding sulphide minerals, typically pyrite and arsenopyrite. Traditional methods of oxidation include pressure leaching, roasting and bacterial oxidation. In recent years, bacterial and pressure oxidation have found increasing favour, although these methods are by no means completely satisfactory and each is subject to particular disadvantages.A novel process has been developed as an alternative to the traditional methods whereby electro-generated ferrate(VI) ions in alkaline solution are used to oxidise a pyrite concentrate. This process has been observed to proceed fairly rapidly and could prove to be a more economically viable process, as well as being more environmentally acceptable. As an added benefit, operating in an alkaline environment is advantageous for downstream cyanidation processes.Ferrate(VI) is a relatively unknown species, due mainly to its instability in acidic solutions. However, in alkaline solution it has been observed to be sufficiently stable for use as an oxidant when used under favourable conditions. Ferrate(VI) is most conveniently manufactured electrolytically via the dissolution of high-carbon anodes in strongly alkaline solutions. Some literature has been published on the electrolytic generation of ferrate(VI) and relatively high efficiencies have been observed by both the authors and other researchers.This study utilises both electrochemical techniques and leaching experiments to examine the kinetics of the oxidation of pyrite by ferrate(VI), which is produced electrolytically. Cyclic voltammetry, rotating disk voltammetry and potential step experiments have been used to investigate the kinetics and mechanism of the oxidation process."

Jan 1, 1997

By K. Ramji

"The development curve in the extractive sector has become longer, steeper, and riskier due to increased social, legal, and political risks from various stakeholders. Indigenous peoples are a unique stakeholder because their growing legal rights to lands and resources can often determine a project’s outcome. A project will only be successful if it is able to obtain the legal permits, withstand any judicial reviews, and gain and maintain the social license to operate. Stakeholder identification, management, and engagement are key risk-mitigation tools required to successfully convert risks into opportunities.RÉSUMÉ La courbe de développement du secteur de l’extraction s’est allongée, elle est devenue plus abrupte et plus hasardeuse en raison de l’accroissement des risques sociaux, légaux et politiques venant des divers intervenants. Les peuples autochtones sont des intervenants uniques puisque leurs droits légaux croissants sur les terres et les ressources déterminent souvent ce qu’il adviendra d’un projet. Un projet ne pourra réussir que s’il est capable d’obtenir les permis légaux, passer à travers les analyses judiciaires, puis obtenir et maintenir le permis social d’exploitation. L’identification des intervenants, la direction et l’engagement constituent les outils clés de l’atténuation des risques nécessaires pour bien convertir les risques en possibilités."

Jan 1, 2016

By H. R. Manouchehri

The importance of the grinding environment and its effect on sulphide minerals flotation behavior has been known for many years. The grinding environment may play a role in controlling fine and coarse particle flotation along with dissociation of different chemical species in grinding environment. Dissociation of different chemical species and ions within the process water may result from changing the grinding environment. The mining and mineral processing industry undertakes activities that may impact on water resources. These include use and storage of chemical storm-water management, process water management, mine dewatering and management of tailings. In mineral flotation understanding and controlling water quality is paramount important not only because of its effect on flotation but also with respect to control the quality of the water which is released to the environment. Releasing of different anionic and/or cationic chemical species in the process water results from the interactions among different mineral within the ore, process water, and the milling environment. In fact grinding mill acts as an electrochemical reactor which affects the flotation performances of different value minerals as well as the quality of the tailing products. An increasing in antimony content in process/discharge water at Boliden?s Tara processing plant in Ireland to above limitation level was reported in April 2010 which needed to be controlled. An increase up to 6 times of the permitted level was reported which needed an immediate action to control due to environmental considerations. Therefore attempts were made to detect why this higher amount of Sb is released and how to control and minimize its release to the process/reclaim water. This paper discusses how/why Sb content in process/reclaim water was increased by changing the mill electrochemistry and the strategies were taken into considerations to control it. Different strategies, including electrochemical controlling of the milling section, Fenton process, using Bauxsol in treating the process water, etc., have been considered and tested which are described herein. All strategies taken into consideration for solving the problem were successful which indicated good understanding of the issue and good decision making. Furthermore, for each solution the capital and operational costs were roughly estimated. Accordingly, the Sb content in process/discharge water was controlled to a value lower than allowed limitation, i.e., 1 ppm. Keywords: antimony, water contamination, mill electrochemistry, ag milling, grinding media, eh-ph, sulfide minerals, fenton process, bauxsol, lime addition

Sep 1, 2012

By Graham A. Davis, Michael Samis

The dramatic fluctuation in metal and energy prices in the last few years is causing mining companies to consider alternative analytical methods for mine design and valuation. The goal is to improve insight into unforeseen changes in the economic and project environment and to design projects that take advantage of management's ability to respond to these changes. Such flexibly managed projects will contain value that cannot be measured using traditional engineering economic approaches, further motivating the used of alternative, modern valuation methods. This paper considers the valuation of an uneconomic low-grade resource at an open pit gold mine using two of the most popular modern valuation methods, Dynamic Discounted Cash Flow and Real Options. Our analysis demonstrates that the conventional valuation method may incorrectly represent the value and risk attached to mining this type of resource because it is unable to recognize management's ability to respond to future events in a manner that minimizes losses and exploits advantageous business conditions. The results of this paper highlight the importance of recognizing flexibility and business uncertainty in both mine design and valuation.

Jan 1, 2003

By Courtney E. Cleveland

THE gold deposits of the Pioneer and Bralorne mines, in the Bridge River district of British Columbia, are closely associated with a long, narrow intrusive body of extremely variable composition, outcropping on the northeast side of Cadwallader creek and lying almost entirely within the property boundaries of the two companies. Other masses of the same type of intrusive rock are found in the district, more or less along the line of the main axis of the Pioneer-Bralorne in trusive, and have associated with them variable amounts of gold-quartz mineralization (Figure 1). The ore deposits of the district have been the subject of investigation by officers of the Geological Survey of Canada at various times during the past 25 years, and articles on the geology and mines of the district have been published by various individuals in technical journals. A list of the more important re-ports follows: SELECTED BIBLIOGRAPHY

Jan 1, 1938

By F. Q. Cheng

Despite the successful industrial practice to recovery KCl by flotation, the adsorption state of collectors at KCl salt surfaces is still not fully understood. In this paper, the captive bubble contact angle measurements at KCl and NaCl crystal surfaces in their saturated solutions are reported. The influence of different collectors and their concentration are considered. The results show that both cationic and anionic collectors produce a hydrophobic state at the structure breaking KCl salt sur-face, with finite contact angle values of between 30o and 40o. In contrast, the contact angle at the structure making NaCl salt surface is zero at all collector concentrations, suggesting that no collec-tor adsorption occurs, a supposition that is supported by results from molecular dynamics simulation (MDS). Further, it appears that the presence of surface defects such as edges and corners promote the adsorption of collectors at the KCl surface, and that the flotation is achieved by bubble attachment at the edges/corners of KCl particles with the formation of aeroflocs.

Jan 1, 2014

By J. D. Brown

The electron optics, vacuum system, and sample stage assembly for the Bureau of Mines? electron probe X-ray spectrograph were purchased. Four scanning curved-crystal spectrometers, two reflection- and two transmission-type, were designed and constructed by the authors. The reflection spectrometers are placed in a vacuum chamber for measurement of long-wave-length X-radiation. Detection, pulse-amplitude discrimination, and recording circuits are provided for the simultaneous measurement of four X-ray spectral lines. Minimum spot size is approximately 2 microns in diameter at 30 kilovolts and a sample-to-ground current of 5 x 10-8 ampere. At this voltage and current the limit of detection with reflection spectrometers is less than 0.05 weight-percent for most elements. The limit of detection for elements determined by transmission-type spectrometers, evaluated at 35 kilovolts and 5 x 10-8 ampere, is approximately 0.1 weight--percent for all elements having excitation voltages below 20 kilovolts. In general, reflection spectrometers exhibited satisfactory but poorer resolution than the transmission type, resolution of the spectrometers being limited primarily by crystal imperfections, with greater mosaic structure being introduced by the grinding process for the reflection crystals. Several applications of the electron probe X-ray spectrograph are described. Analysis of a uranium-steel is discussed in detail to illustrate calculation of composition from measured X-ray intensities.

Jan 1, 1962

By Neng-Wen Yu, Shau-Jun Zhu, Ji-He Wei

The desulfurization process by powder injection and blowing in the RH refining of molten steel and its mechanism have been considered and analyzed. Based on the two-resistance mass transfer theory and the mass balance of sulfur in the system, a kinetic model for the process has been developed. The related parameters of the model, including the mass transfer coefficients and the effective amount of powder in the molten steel being treated for desulfurization, have been more reasonably determined. Modeling and predictions of the process of injecting and blowing the lime-based powder flux under assumed operating modes with the different initial contents of sulfur and amounts of powder injected and blown in a RH degasser of 300 t capacity have been carried out using the model. The relevant circulation rate of the liquid steel and the powder injection and blowing rate were taken to be 100 t/min and 150 kg/min, respectively. The initial contents of sulfur in the liquid steel to be treated and the amounts of powder injection and blowing were respectively assumed to be 0.007, 0.006, 0.005, 0.004, 0.003, 0.002 mass-% and 10, 8, 6, 5, 4, 3 kg/t-steel. The total treatment time for desulfurization under each mode was set up at 24 min, equivalent to eight circulation cycles of the liquid steel to be treated. The results indicated that the predictions made with this model are in good agreement with some data of the industrial experiments and practice. Injecting and blowing the lime-based powder flux with the composition of 85 mass-% lime (CaO) + 15 mass-% fluorspar (CaF2) of 3-5 kg/t-steel, it is possible to decrease the sulfur content in the molten steel to ultralow level below (5-10)x10·4 mass-% from (60-80)x 10·4 mass-%. The total treatment time needed will appropriately be 12-20 min. Intensifying the powder injection and blowing operation and increasing the circulation rate of the liquid steel may effectively' raise the rate of the process in RH refining. The model may be expected to offer some useful information and a reliable basis for determining the reasonable process parameters and help in optimizing the technology of desulfurization by powder injection and blowing in the RH refining of molten steel.

Jan 1, 2000

By Kevin Ashley

Because toxicities may differ for Cr(VI) compounds of varying solubility, some countries and organizations have promulgated different occupational exposure limits (OELs) for soluble and insoluble hexavalent chromium (Cr(VI)) compounds, and analytical methods are needed to determine these species in workplace air samples. To address this need, international standard methods ASTM D6832 and ISO 16740 have been published that describe sequential extraction techniques for soluble and insoluble Cr(VI) in samples collected from occupational settings. However, no published performance data were previously available for these Cr(VI) sequential extraction procedures. In this work, the sequential extraction methods outlined in the relevant international standards were investigated. The procedures tested involved the use of either deionized water or an ammonium sulfate/ ammonium hydroxide buffer solution to target soluble Cr(VI) species. This was followed by extraction in a sodium carbonate/sodium hydroxide buffer solution to dissolve insoluble Cr(VI) compounds. Three-step sequential extraction with (1) water, (2) sulfate buffer and (3) carbonate buffer was also investigated. Sequential extractions were carried out on spiked samples of soluble, sparingly soluble and insoluble Cr(VI) compounds, and analyses were then generally carried out by using the diphenylcarbazide method. Similar experiments were performed on paint pigment samples and on airborne particulate ?lter samples collected from stainless steel welding. Potential interferences from soluble and insoluble Cr(III) compounds, as well as from Fe(II), were investigated. Interferences from Cr(III) species were generally absent, while the presence of Fe(II) resulted in low Cr(VI) recoveries. Two-step sequential extraction of spiked samples with (?rst) either water or sulfate buffer, and then carbonate buffer, yielded quantitative recoveries of soluble Cr(VI) and insoluble Cr(VI), respectively. Three-step sequential extraction gave excessively high recoveries of soluble Cr(VI), low recoveries of sparingly soluble Cr(VI), and quantitative recoveries of insoluble Cr(VI). Experiments on paint pigment samples using two-step extraction with water and carbonate buffer yielded varying percentages of relative fractions of soluble and insoluble Cr(VI). Sequential extractions of stainless steel welding fume air ?lter samples demonstrated the predominance of soluble Cr(VI) compounds in such samples. The performance data obtained in this work support the Cr(VI) sequential extraction procedures described in the international standards.

Jan 1, 2009

By Calvin J. Konya

An investigation was performed to determine conditions which optimize fracture formation between blastholes used for purposes of pre-splitting. Experiments-involved high-speed photography in Plexiglas models and radiographs in sandstone models. Additionail data was obtained from full-scale pre-split blasts. Pre-split fractures between blastholes were found to form as a result of gas pressure and were affected little, if any, by stress wave interactions. Pre-splitting was effective with short period delays of 25 milliseconds or less, and did not require instantaneous initiation of blastholes. Significant reduction of ground vibration resulted with the use of delays

Jan 1, 1980

By Thomas M. Turner

Open pit mining, always a demanding task, faces two relatively new problems today: 1. Availability of equipment. Moderate to large draglines can take as long as 6 years from date of contract to date of operation. 2. Environmental restrictions. Strip mining in the minds of environmentalists compares unfavorably on the scale of social desirability to the activities of Jack the Ripper and Attila the Hun. Specifically, lowering of the water table to allow strip mining in the dry is being looked upon with increasing disfavor. The modern dredge offers relief in both problem areas. Delivery on a major dredge might run 18-24 months rather than 60; and lowering of the water table is precluded, thus minimizing environmental objections. In addition, a lower first cost and potentially increased efficiency may offer real advantages to the miner who is forced away from his traditional mining methods. This talk is dedicated to acquainting the miner with dredge types, advantages, and limitations.

Jan 1, 1975

By C. M. Palencia

The Bureau of Mines evaluated the potential availability of molybdenum resources from 88 mines and deposits that account for more than 90 pct of the demonstrated resource base in market economy countries (MEC's). For each property, tonnage-cost relationships were developed that indicate the molybdenum potentially available at different average production costs, including a 15-pct rate of return on invested capital. From the 23 MEC primary deposits, 2.5 billion 1b Mo was determined to be potentially available at a price of $411b, rising to 4.7 billion 1b Mo at $8/lb. Copper price-molybdenum tonnage relationships were developed for those mines and deposits from which molybdenum can be recovered as a byproduct of copper production. This analysis showed that another 3.4 billion lb Mo is potentially available based on a copper price of $0.7511b, rising to 4.3 billion lb Mo at $l.00/lb. The United States has been the world's largest molybdenum supplier since 1924. Its remaining resources are sufficient to meet the domestic demand of 57 million lb/yr Mo (averaged for a 10-yr period) through the end of the century. Production from primary domestic mines was suspended during most of 1983 because of oversupply of materials. A major concern is the cheap molybdenum byproducts from foreign copper operations in which employment and the need for hard currency override economics in meeting production goals.

Jan 1, 1985

By W. L. Crentz

The Black Mesa coal field is part of the Hopi and Navajo Indian Reservation in Apache, Navajo, and Coconino Counties, Ariz. The field is in an isolated area with the nearest railroad 70 to 90 miles to the south. Travel is restricted by roads that become impassable during inclement weather. The area is a mesa and rises from 500 to 2,000 feet above the surrounding territory. Water is very scarce, and the nearest stream of any consequence is the Colorado River about 90 miles northwest from the center of the field. Coal beds are found in the Mesaverde formation of the Cretaceous age, but they are uncorrelated and range from subbituminous to bituminous in rank. Huddle2/ estimates the reserves of subbituminous coal in Arizona at about 15 billion tons, most of which is in the Black Mesa field. The geology of the field has been reported by Campbell and Gregory.3/ Coal production is small, and the output is used almost exclusively for domestic fuel in the Indian schools, missions, and trading posts.

Jan 1, 1955