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By L. J. Li, Q. Zhang, Z. H. Liu, Q. L. Chen

Phosphogypsum (PG) is an industrial waste from the production of phosphate fertilizer. The utilization of PG is restricted by its containing impurities, and the pretreatment is crucial to eliminating these impurities. The purpose of the research is to recycle pretreatment PG as raw material for preparation of a-calcium sulfate hemihydrate (a-HH) by salt solution method. The effect of pretreatment technologies of lime neutralization and washing on dehydration rate, phase composition and morphology evolution of a-HH were investigated by crystal water content analysis, XRD and SEM. Furthermore, the change of pH in the reaction process was also discussed in detail. The results show that the dehydration rate of conversion PG to a-HH increases and the corresponding induction period, crystal growth period and total time decrease with an increase in CaO dosage from 0.2% to 0.6%. In the presence of 0.4% CaO or 0.6% CaO, the a-HH presents a long hexagon-prism-shaped crystal with a purity of 94%, and the end face of a-HH presents polyhedron. The system pH sharply decreases with the reaction time under different CaO dosage, and the pH variation from the initial alkalinity to acidity. The main reason is that as the co-crystallized phosphorus dissolved and released HPO42-, and with the pH decreasing to 4-5, HPO42- transformed into H2PO4-. The dehydration rate of washing PG is lower than that of original PG. Compared with the original PG, a-HH with the larger width and smaller aspect ratio can be achieved from the pretreatment PG subjected to lime neutralization and washing, meanwhile the crystal surface is more smooth.

Jan 1, 2018

By M. Rudolph, E. Schach, M. Buchmann, T. Leißner, N. Krupko, U. Peuker, M. Kern

"In mineral processing, density and magnetic susceptibility are two very fundamental properties. For the beneficiation of valuables to produce a saleable concentrate a detailed understanding of these properties is essential. Especially when it comes to the processing of cassiterite, which is the main mineral for tin production, they become highly prominent. Due to the chemically inert character of cassiterite towards most industrial applied leaching agents, density and magnetic separation processes are mainly applied for its beneficiation. To guarantee an optimized utilization of the different operations not only cassiterite but also the different gangue minerals have to be considered. In this study, a skarn ore is characterized by density and magnetic susceptibility. Therefore, the material was first split into different density classes by heavy liquid separation. The obtained classes were further separated by their susceptibility to finally obtain a density-susceptibility matrix. For this purpose, an isodynamic separator was used. A more detailed characterization of the materials is done via gas pycnometer, magnetic susceptibility balance and vibrating sample magnetometer to estimate the characteristics of density and susceptibility for the various classes. Further, the determination of the chemical assay and the mineral intergrowth by mineral liberation analysis is used to generate a three dimensional database for detailed characterization of the present ore. The objective of this study is to estimate potential material streams for a modular processing plant via characterization of the material for the entire deposit by the two afore mentioned characteristic properties. The established multidimensional data matrix, enables predictions for the separation properties of the material and contributes to the characterization of the deposit within the context of geometallurgy."

Jan 1, 2018

By M. Kosugi, M. Kawata, J. V. Satur, K. Mitsuhashi, R. Kawarabuki, W. Kracht, Y. Ebisu

Copper concentration is becoming more difficult because remaining copper ores are more complex and of finer copper mineral grain size, making copper minerals harder to float because of the fine particle size required to liberate the valuable species. The purpose of this work was to study the flotation behavior of fine copper sulfide ores at different conditions of agitation and aeration. The experimental campaign was carried out in a laboratory Denvertype flotation cell of 1 L volume modified to be operated with forced air that allows decoupling air flow rate and agitation speed. Four ore samples from Chile were used, all of them containing copper sulfides such as chalcopyrite, bornite, chalcocite, and tennantite, but with varying grain sizes and compositions. Preliminary flotation tests for establishing the flotation conditions of grinding size and collector dosage were conducted before the kinetic flotation tests that were carried out at different agitation speeds varying from 900 to 1300 rpm for gas flow rate ranging from 1.6 to 7.2 L/min. The flotation products were analyzed by ICP-MS and MLA (Mineral Liberation Analyzer). The results showed that high agitation speeds with corresponding air flow rates resulted in better recovery than moderate agitation speed and air flow rate, and an excess in gas flow rate resulted in bad performances. The flotation rates of the fine copper minerals were improved despite the different improvement rates among the fine size fractions. The impact of these operational variables, however, was different when comparing the results for the four ore samples. While it was found that the order of floatability in the four samples was the same, that is, chalcocite > tennantite > bornite > chalcopyrite, the kinetic constants of the copper minerals in the samples were different, indicating that mineral composition in the sample affects the flotation kinetics.

Jan 1, 2018

By J. van Wijk

"Vertical material transport is one of the major challenges for the successful implementation of deep sea mining projects. The EU research project „Blue Mining” is focusing on sustainable solutions for deep sea mining operations, with one major goal being the advancement of Vertical Transport Systems (VTS). To investigate flow effects under realistic conditions, especially clogging effects, a 136 m high test facility for flow analysis in vertical transport has been constructed using available mining infrastructure. Tests are run in a closed circuit, using a system of downfall and riser pipelines connected to a compact sediment injection- and separation unit as well as the centrifugal pump. The riser is equipped with pressure sensors, as well as temperature sensors, flow meter, concentration meter and high speed camera to allow comprehensive analyses of the flow regime and behavior of transported material within the flow. Additional mobile measurement devices allow wear and tear analyses of pipe material. This paper focuses on the determining factors of the tests leading to the design as well as the installation and trial of the test facility itself and explains the used components and work principles. INTRODUCTION Since the 1970s several research projects had been conducted investigating in the possibility of deep sea mining. In recent times projects for deep sea mining operations have started again, considering the rising demand on natural resources, especially raw earth elements. Yet projects like the Nautilus project on the deposit Solwara 1 [1], or Japanese projects focusing on the region of Okinawa [2] and Chinese projects [3] planning on depths of “only” about 2,500 up to 3,000 m. Until now no economical deep sea mining project was realized, due to the enormous difficulties of deep sea environments. Vertical material transport is one of the major challenges for the successful implementation of deep sea mining projects, considering transportation heights up to 5 km. The EU research project „Blue Mining” is focusing on sustainable solutions for deep sea mining operations, with one major goal being the advancement of Vertical Transport Systems or VTS [4]. Critical parts of the system would be identified and investigated to deliver solutions and higher the technology readiness level to a level were planning of a pilot project can be considered. At first case examples for mining projects of seafloor massive sulfides (SMS, 1,600 m water depth) and manganese nodules (MnN, 5,000 m water depth) had been calculated on basis of economical frame conditions, such as planned production rates to be efficient. As depicted in Figure 1 two major possible systems had been used for comparison, airlift system and pump system, considering multiple pump stations or single pumps. Based on the results and comparisons for the calculated vertical transport systems critical components and flow effects had been identified."

Jan 1, 2018

By Ashok Kumar, Subhadra Sen Dr. Rashmi Kumari, D. P. Chakraborty, Ajay kumar Gupta

The blast furnace coke quality depends on the characteristics of coal blend, pre-carbonization techniques adopted such as stamping, vibro-compaction etc., and coking conditions. Of the above, coal blend plays a significant role in the production of quality coke. Furthermore, the quality of the blend depends on the quality of individual coals and their interaction making up the blend. During transportation and stockpiling, coal is in contact with air for periods of time that sometimes may exceed several months. During this time, reaction with oxygen in the presence of water, sunlight and possibly elevated temperatures may take place. The resulting weathered coal suffers some alteration in its technological properties, which in turn affects coke quality for Blast Furnace operation adversely. In this work, two coals belong two prime hard coking and hard coking categories, namely Illawarra & Tahmoor, were selected and kept in a separate stock pile for a period of 120 days. These coals were characterized in terms of proximate, rheological & petrography properties at a regular frequency. This report summarizes the impact of weathering on the coking behaviour of these two coals in terms of properties as mentioned above. However, the rate of loss depends on coal rank and storage conditions. This has been seen through this study that the loss depends on coal rank and storage conditions. Deterioration of rheological and petrographic properties were seen higher for low-rank coals, like in this study Tahmoor, which is a low rank coal, compared to Illawarra showed higher degree of coking property degradation within the same time period under identical environmental conditions. Low-rank coal deteriorates at a faster rate because low-rank coal is dominated by free radicals that easily react with oxygen, resulting in the creation of various carbonyl groups and weathered vitrinite. Based on the results obtained in this study, size of stock piles for different qualities of coals to be maintained, at a specific time, can be determined and recommended, so that target coke quality is always achieved.

Jan 1, 2018

By S. R. Clark

"INTRODUCTION Of all the natural resources being taxed by the needs of the modern world, perhaps the most important is the continually expanding demand for water resources. As water becomes scarcer, and increasingly important, new technologies are needed to find innovative ways to preserve this precious resource. In Chile, for example, the mining industry is investing billions of dollars to build desalination plants and pipelines; bringing ocean water as far as 200 kilometers inland to meet their demand and maintain operations. It is a full-blown crisis for that nation and a top priority for their government and economy. It has been reported that world water consumption will increase by 40 percent in the next 10 years, representing nearly exponential growth. In the U.S., as more and more communities continue to be built, more drain on the current water infrastructure is created. For 25 percent of people and operations that rely on water from aquifers, this source is being consumed at a rate that will create significant problems meeting the demand in as few as two generations.1 A PROACTIVE APPROACH When it comes to controlling dust at your operation, whether a landfill, a transfer station, a haul road or another ancillary area, what are the options? We know watering is not the answer, but at the same time, we need to prevent dust from flying to ensure a safe environment and keep our skies clear of pollution, for both regulatory requirements and neighbors. Creating a Dust Mitigation Program instead of looking to buy the first dust control product off the shelf is a first step to conserve water and, at the same time, maintain the operational demands and environmental standards for a given site. The program concept is straightforward enough. However, the process of effectively constructing and executing a program is quite involved. When undertaking a program, each manager needs to work with their team and their partners/vendors in analyzing the following elements: 1. Site Expectations—It is important to understand how to balance your internal standards with your regulatory requirements, as well as how to keep your neighbors satisfied. 2. Site Aggregate—Variations in native soil, such as clay content or gravel levels, greatly affect the approach that will yield the highest results. 3. Climate—Relative humidity and seasonal variations are critical to achieving predictable results through product choice, application frequency and timing. 4. Daily Traffic—The type and frequency of traffic is an essential variable for site management. 5. Environmental Responsibilities—If you have additional, specifically defined responsibilities, the approach to your site may vary. 6. Budget—While efficiency is the goal of any program, some sites will have more stringent restrictions than others. 7. Current Usage Rates—Document and understand where you’re starting from, both with water, supporting products, and maintenance so that effective measurement of results is possible."

Jan 1, 2018

By A. Demirag, F. Burat

"The most important metals in the jewelry sector are undoubtedly gold and silver. As a result of workmanship work done in the jewelry industry, the tiny metal and jewel fragments and metallic powders are scattered. Given the prices of gold and silver on the market, the dust that emanates from these workshops is of great importance. Gold recycling has become as important as raw material production within the mass market and gold production industry. In 2016, 29% of the world gold supply has been obtained through recycled gold production. Waste derived from jewelry activity is included in this category, and represents an essential component of this percentage. In the scope of this study, the recovery possibilities of Au and Ag from jewelry sweeps floor sample was investigated using flotation method. In the experiments, optimum pH value, particle size, the effect of dispersant, type and amount of reagent were investigated. As a result of these studies, it was determined that the optimum pH value was 6.5 and the particle size was -212 microns. It was observed that the most suitable reactive combination was Aero 242 and Aerophine 3418A and Na2SiO3 has no positive effect on recovery of Au and Ag as a dispersant agent. As a result of tests, a final concentrate containing 268 ppm Au and 2122 ppm Ag was obtained with 81.4% and 74.5% recovery respectively. INTRODUCTION Because of the softness of pure gold, it is usually alloyed with base metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. On the other hand, gold has some special chemical properties which in normal conditions, don’t react with water, dry or humid air, oxygen, ozone, nitrogen, hydrogen, fluorine, iodine, sulfur and hydrogen. In these days, gold is used in different sectors like jewelry, electronics, finances and investing, dentistry, medicine, aerospace, awards & status symbols. According to Deutsche Bank Research, the primary usage of gold is jewelry. It has been used to make ornament and jewelry for thousands of years. In this sector craftsmen learned that alloying gold with other metals like copper, platinum and silver to increase gold’s durability. Alloying gold with other metals changes the color of the products. Another significant sector of gold is electronics. Modern electronics want the use of noble metals, like gold, especially in the areas of information processing, telecommunications, and military and space electronics (Habashi, 1997). Electronic devices use very low voltages and currents which are easily interrupted by corrosion or tarnish at the contact points. Gold is the highly efficient conductor that can carry these tiny currents and remain free of corrosion. Electronic components made with gold are highly reliable. Gold is used in connectors, switch and relay contacts, soldered joints and connecting wires. Every sophisticated electronic device have a considerable amount of gold. This includes cell phones, calculators, personal digital assistants, GPS units, and other small electronic devices. Most large electronic appliances such as television sets also contain gold. Humankind has known silver since prehistoric times like gold because silver occurs in native form. The metal is found in the Earth's crust in the pure, free elemental form native, as an alloy with gold and other metals, and in mineral such as argentite. Most silver is produced as a byproduct of copper, gold, lead, and zinc refining. Silver is very soft metal like gold also, it is the highest electrical conductivity, thermal conductivity, and the lowest electrical contact resistance of all metals (Habashi, 1997). Silver is used in different sectors like industry, jewelry, electronics, photography silver good, and coins. The main usage of silver is supplied by electronics. Silver's unsurpassed thermal and electrical conductivity among metals means it cannot easily be replaced by cheaper materials. In addition to silver is using in ener"

Jan 1, 2018

By Kumar Ashish, Shukla Akhilesh, Kr. Rokkam Kiran, M. Sheeba, S. Sombhatla Sundar

"Purification of zinc leachate plays a predominate role in zinc leaching refineries, to produce impurity free cathode sheets. As a part of such purification sequences, copper cementation with zinc dust is the preliminary step, since the presence of copper will preferentially deposit during zinc electro deposition and has the effect of reducing current efficiency. The cake thus produced is being accumulated as an inventory, due to invariable market and leading to space constraints & hazardous ambience. Hence, a project has been taken up for in-house generation of copper sulphate solution through ammonical leach followed by solvent extraction process and utilizing it as an active promoter for zinc sulphide flotation in Hindustan Zinc’s own captive mines. Cold purification cake majorly contains copper (30-40%) along with zinc (10-20%) and cadmium (2%). Confirmation to the above statement, photomicrographs of purification cake also confirmed the major presence of copper in metallic or oxidized form. In present work ammoniacal carbonate leaching of purification cake followed by solvent extraction using diketone based solvent has been studied under the influence of various parameters viz., temperature, agitation, pulp density, ammonia, CO2 dosages, solvent concentration, and impact of w/s zinc on leaching and solvent extraction. Leaching kinetics determined based on shrinking core model. Chemical reaction at unreacted core was found to be the rate controlling step. The estimated activation energy was found to be 24 KJ/mol. Leached copper has been extracted by solvent extraction with a ß diketone based solvent and is stripped with sulfuric acid as concentrated copper sulfate solution. The above established R&D findings are successfully implemented in the Commercial plant with a treatment capacity of two tons of cold purification cake per batch. Till now 500 MT of Purification cake has been treated, and generated 6500 MT of copper sulphate (55 g/l Cu), with final Cu recoveries between 87-90%."

Jan 1, 2018

By Ahmad Amini, Hadi Abdollahi, Pouya Karimi

Due to detrimental effects of cyanidation process on the environment in gold industry, application of cyanide alternatives such as thiourea are being highly considered in recent projects. In this study, the extraction of gold from poly metal ore, using thiourea was precisely investigated. The representative sample contained 2.5 ppm Au and 160 ppm Ag. The sample was categorized as oxide gold ore, because the main part of its pyrite was changed to iron oxide and hydroxide such as goethite and lepidocrosite. According to mineralogy, the main gangue mineral was quartz. It shows that gold grains are free and interlocked with quartz matrix. Also, the presence of a high amount of silver in free and sulfide forms and also the low content of other sulfide minerals such as base metal sulfides is a remarkable point of these studies. In the gold extraction process with thiourea, there are several parameters that affect the rate of gold dissolution such as concentrations of thiourea as a gold lixiviant and ferric sulfate as an oxidant, pH and size fraction of feed and leaching time. The influence of these parameters on the gold dissolution rate were investigated and optimized. The results showed that the concentration of thiourea is the most influential parameter which could increase the gold recovery to 71% (at 10 g/kg sample). The optimal amount of ferric sulfate was determined as 6 g/kg sample. Also, the optimal levels of size fraction of feed and pH of solution were 88% under 75 micron and 2 as acidity; respectively. Leaching time was 6 hrs. In addition, this sample was leached with cyanide and the optimized values of size fraction of d88=75 microns, pH=10.45, 2500 ppm of sodium cyanide with time leaching of 24 hours were concluded for maximum recovery of gold in solution. Finally, the results of cyanidation tests were compared to the thiourea dissolution after optimizing all affected parameters in cyanidation process.

Jan 1, 2018

By A. Javadi

"Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Bama concentrator in Iran but with the addition i) Na2S reductant and ii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid.INTRODUCTIONOur recent studies have illustrated the formation of hydrogen peroxide (H2O2) by metal-sulphides during grinding in the presence and absence of oxygen (Javadi Nooshabadi & Hanumantha Rao, 2013a; Javadi Nooshabadi & Hanumantha Rao, 2013b; Javadi Nooshabadi & Hanumantha Rao, 2013c; Javadi Nooshabadi & Hanumantha Rao, 2014). In the absence of oxygen, it was found that pyrite surface is catalytically active and able to breakdown water molecules to form OH• free radical and thereby deriving oxygen in the formation of H2O2 from water molecules. The in-situ formation of H2O2 and its influence on sulphide flotation has not been addressed yet. The presence of strong H2O2 oxidant in the pulp liquid and its selective oxidation of pyrite would be beneficial in depressing pyrite flotation. Therefore, it is important to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp as well as to study possible ways of flexibly controlling the formation of these species through known chemical means for depressing the generation of the oxidant."

Jan 1, 2018

By G. Morin, F. Chiesa, B. Tougas, B. Duchesne, Jocelyn Baril, N. Giguère

"An aluminum A356 compressor impeller was sand cast using the Low Pressure technique. The casting was limited in size (170 mm in diameter, 1.2 kg in weight) and very intricate in shape thus making 3D mold printing particularly favorable; indeed, producing this part by the traditional pattern-core box route would involve mounting 12 cores inside the mold while stringent dimensional tolerances are required as the impeller blades are only 2 mm thick. Consequently the molds were produce on the X-One MFlex printer of Quebec Metallurgy Center - CMQ. A dozen castings were produced with different casting temperatures and filling times so that it was possible to assess under which conditions complete filling of the mold cavity would be achieved. Filling and solidification modeling allowed predicting misruns and metallurgical properties inside the A356 (AlSi7Mg04) casting.INTRODUCTION Recent advancements in additive manufacturing enable foundries to produce molds without the tooling (pattern and core boxes) necessary when conventional technology is used (Eyad, 2016). This is particularly advantageous when dealing with intricate shapes and/or when a limited number of parts must be produced within a few days rather than in 5 weeks. An additional advantage is gained when producing prototypes (Johnson, 2016) as changes are much less costly and time consuming when made on a numerical 3D drawing rather than on patterns and core boxes. 3D printing is normally economical for a small number of parts; however, if the part is not too big and very intricate in shape such as the part that will be studied in the present work, 3D printing can be economical even for an important number of castings to be produced. On the other hand, low pressure casting is a high integrity casting process in which the mold cavity is filled from the bottom via a transfer tube in which the liquid aluminum rises under the pressure applied at the surface of the melt as illustrated in Figure 1. The filling can thus be precisely controlled, eliminating the turbulence created when the mold is filled from the top (gravity casting). Also, the pressure applied on the melt during solidification results in excellent feeding of the casting when conditions of directional solidification are met. In the present work, the compressor impeller shown in Figure 2 will be sand cast by low pressure."

Jan 1, 2018

By Cees van Rhee, Rudy Helmons

INTRODUCTION Seafloor Massive Sulphides are typically found near the oceanic ridges at larger water depths (>1km). The physical properties of SMS, as shown in table 1, are comparable to the properties of weak rock. One of the technical challenges to enable extraction from these locations is the cutting or excavation process. Experiments have shown that the energy needed to excavate the material may increase with water depth (Alvarez Grima et al. 2015). Besides that, it is demonstrated that rock that fails brittle in atmospheric conditions can fail more or less in a plastic fashion when present in a high pressure environment, as would be the case at large water depths. The goal of this research is to identify the physics of the cutting process and to develop this into a model in which the effect of hydrostatic and pore pressures is included. The cutting of rock is initiated by pressing a tool into the rock. As a result, at the tip of the tool a high compressive pressure occurs, which leads to the formation of a crushed zone. Depending on the shape of the tool and the cutting depth, shear failures might emanate from the crushed zone, which will eventually expand as tensile fractures that can reach to the free rock surface. Through this process intact rock will be disintegrated to a granular medium. For an overview of the process (figure 1). Additionally, the presence of water in the pores of and surrounding the rock influences the cutting process through drainage effects. The most relevant effects are weakening when compaction and strengthening when dilation occurs in shearing and tension. Deformation of the rock causes the pore volume to change, resulting in a under or over pressure. As a result, the pore fluid needs to flow. The magnitude of the potential under pressure is limited through cavitation of the pore fluid, limiting further reduction of the pore pressure (figure 2). The drainage effects cause the rock cutting process in a submerged environment to show a stronger dependency of both the hydrostatic pressure as well as the deformation rate (figure 3).

Jan 1, 2018

By R. D. Clarke, E. De Souza

"A framework for ventilation planning, with a focus on planning to the end-of-mine life, was developed for the Diavik Diamond Mine, Northwest Territories. This framework was successfully used by Diavik’s mine engineers to select a cost-effective ventilation plan that met the life-of-mine requirements. The framework achieved this result by reconciling the production plan with the ventilation plan. A set of design acceptability criteria was created and a PICK (possible, implement, challenge, kill) chart was used to quickly narrow down the generated ideas for detailed assessment and economic analysis. RÉSUMÉ Un cadre de planification de l’aérage, qui met notamment l’accent sur la planification jusqu’à la fin de vie de la mine, a été développé pour la mine de diamants Diavik. Les ingénieurs miniers de Diavik ont su mettre à profit ce cadre pour sélectionner un plan d’aérage rentable qui répondait aux exigences propres à la durée de vie de la mine. C’est en conciliant le plan de production et le plan d’aérage que cet objectif a pu être atteint. Un ensemble de critères d’acceptabilité de la conception a été créé et un tableau PICK (de l’anglais possible, implement, challenge, kill, une méthode donnant la priorité à certaines actions proposées ou à des idées visant à résoudre des problèmes) a été utilisé pour rapidement limiter les idées générées et les soumettre à une évaluation et une analyse économique détaillées.INTRODUCTION The Diavik Diamond Mine, Northwest Territories, has been an underground-only operation since 2012 and has a remaining mine life of 8 years. In the first year of underground-only operations, the production rate increased from 60 kt of ore per month to more than 160 kt of ore per month. In subsequent years, this rate was continuously increased (Table 1) because the operation went through various improvement initiatives. By the end of 2016, Diavik’s total production was 0.41 Mt (+22.8%) ahead of the 2012 budget for 2016 production."

Jan 1, 2018

By G. Guiglionda, A. Deschamps, F. De Geuser, M. Langille, B. J. Diak

"Increased demand for light-weighting in passenger vehicles has created a need for strong, light, ductile materials to be used in body-in-white applications. The AA6xxx-series of aluminum alloys are suitable candidates meeting most requirements but can fall short of the formability demands of designers, necessitating an understanding of what controls the formability in this alloy series. This work examines the effect of copper alloying in AA6xxx on the pre-ageing and natural ageing responses of the microstructure and mechanical properties. The changes in microstructure observed by differential scanning calorimetry and hardness testing are related to the work-hardening and strain-rate sensitivity parameters for these alloys measured by tensile testing. An observed asymmetry in the measured strain-rate sensitivity associated with increasing versus decreasing strain rate changes suggests that a different mechanism operates for the two conditions. It is postulated how this asymmetry in strain-rate sensitivity will impact the necking and ductility behaviour of these alloys.INTRODUCTION The widespread use of AA6xxx series alloys in the form of sheets has provided the need for a more thorough understanding of the complex interactions between composition, processing, resulting microstructure and ultimately, the mechanical properties of the alloys. Conventional industrial practices involve the production of rolled AA6xxx sheet (typically 1 mm thick) to be used for body-in-white (BIW) applications for auto body panels (Hirsch, 2004, 2014). The final metallurgical step prior to the shipment of these panels to manufacturers involves a solution heat treatment (SHT) reverting the ageing products of the alloys into solid solution and the product is then shipped to the customer. During this shipping time and while sheets are waiting to be used, the natural ageing (NA) process occurs whereby the strength of the alloys increases resulting in reduced formability. This can result in a product that is unable to meet the formability demands of the automotive manufacturer. As a result, industry has moved towards performing pre-ageing (PA) treatments to prolong the “shelf-life” of the material prior to it having insufficient formability. Once formed into BIW panels, the parts are then painted and subsequently undergo the paint curing heat treatment which consists of a short period of time at medium temperature, typically 20 minutes at 170–190°C. This short artificial ageing (AA) treatment, known as the paint bake (PB), provides additional strength and improved dent resistance for the material, but reduced formability. The PB result is strongly dependent on the PA treatment performed prior to the forming operation. Furthermore, the addition of copper (Cu) to a base Al-Mg-Si composition is known to increase the alloy’s strength. The goal of this work is to study the effect of Cu on strength, strain hardening, and strain-rate sensitivity (SRS) of these alloys, to understand the strength-formability compromise, for two separate heat treatment schedules; one including and one excluding the PA treatment, both followed by NA."

Jan 1, 2018

By Jaeheon Lee, Jae-Chun Lee, Doyun Shin, Minseuk Kim, Hyunsik Park

"The appropriate treatment of cyanide waste water is becoming an emerging issue because of the toxic residue and large quantity produced from gold processing plants. In the present article, we designed and operated a continuous biological cyanide treatment system using domestic sewage sludge and various microorganisms including a cyanide-producing and degrading bacterium, Chromobacterium violaceum. The synthetic wastewater containing 50 mg/L of cyanide was pumped continuously into the reactor at a flow rate of 500 mL/d for 21 days. When 50 mg/L of cyanide was fed, the cyanide concentration in the effluent of the reactor inoculated with activated sludge (S-50) decreased by 7.5 mg/L in the effluent. The other reactors did not show significant cyanide degradation and the reactor inoculated with C. violaceum showed increased cyanide concentration in the effluent. The microbial community in the reactors was analyzed by 16S rRNA-gene based pyrosequencing technique to investigate microbial response to cyanide addition and operation time. The microbial community analysis shows that the phylum Proteobacteria was detected in the reactors showing significant cyanide degradation (S-50), while Firmicutes and Bacteroidetes was dominant in the other reactors with very low cyanide degradation. Proteobacteria could not compete when the other phyla Firmicutes or Bacteroidetes were inoculated. This study shows the feasibility of the biological cyanide treatment system for gold processing plants and contributes new fundamental knowledge about the microbial community in the biological cyanide treatment system. INTRODUCTION Cyanidation has been widely used to recover gold from ores or secondary resources since first proposed by MacArthur and Forrest in 1888 (MacArthur et al., 1888) and it is used in many states of the USA, including Nevada, Arizona, California, Colorado, and Idaho (Laitos, 2012). Cyanide compounds are highly toxic and create serious problems for wildlife and water management (Solomonson, 1981; Donato et al., 2007). Furthermore, because many countries have imposed strict standards for cyanide discharge (USEPA, 1985), it is essential to develop a cost-effective and environmentally friendly technology for treating cyanide-containing wastewater."

Jan 1, 2018

By Zhiyong Gao, Ruiying Fan

"Crushing and grinding are the prerequisite processes in many industries, such as minerals processing and powder technology. During crushing and grinding, minerals will cleave or fracture along the directions by broken the interlayer bonds (e.g., ionic bonds), generating some commonly exposed surfaces. The broken (or dangling) bonds at the generated surface makes the surface more active and determine the reactivity of the surface. In this work, the population of broken (or dangling) bonds on commonly exposed surfaces of fluorite mineral (a chosen model mineral) was calculated. Based on the calculated broken bonds information, the anisotropic surface reactivity of fluorite such as surface energy, surface relaxation, dissolution, wettability, surface charge and adsorbability, were discussed. The results show that the surface broken bonds density, which is positively related to the surface energy, can be used to predict the cleavage nature, surface relaxation degree and surface stability of fluorite crystal. The distribution characteristic and the number of broken (or unsaturated) bonds of surface active atoms (like Ca for fluorite crystal) can be used to predict and explain the anisotropic wettability, surface charge and adsorption mode and strength of organic molecules on different commonly exposed surfaces. It is easy to conclude that the calculation of surface broken bonds can serve as a fast and accurate way to start the mineral chemistry studies. These findings will be helpful to the mineral/material chemistry research in related interfacial science communities.INTRODUCTIONGrinding for mineral liberation is a prerequisite for a successful flotation separation. Also grinding for size reduction is a prior process for a favorable powder technology. During the grinding process, the minerals / materials will cleave and fracture along certain crystal directions with relatively weak interlayer chemical bonds1 to form a number of common exposed surfaces. Exposed surfaces are the outer boundary of a solid substance. In the mineral / material block, the bonding orbital of the atoms is filled with electrons and the atoms are in a steady state. Atoms on these exposed surfaces appear to show dangling bonds (or broken bonds) by losing chemical bonds to adjacent atoms in the previous block. Therefore, surface broken bonds serves as an initial property of a fresh surface. The lattice arrangement and crystal orientations causes differences in the number of dangling bonds on each exposed surface, i.e., anisotropic surface broken bonds2. The anisotropic dangling bonds enable the exposed surfaces to show varying degrees of surface reactivity (including surface energy, surface charge, surface relaxation, dissolution, wettability and adsorption behavior), known as anisotropic surface reactivity."

Jan 1, 2018

By Xiaoxu Sun, Jianchao Yao, Jiancheng He, Shijie Lu, Hongxi Zhou

"The ball mill performance relies on impact grinding, but it has disadvantage of the lower efficiency when the ore is finer; while tower mill relies on friction shear affection with high energy efficiency, which is considered to be one of the most potential fine grinding equipment all over the world. Generated by the agitator device, the internal media movement is complex because of comprehensive interaction of screw mechanism, cylinder structure and adjacent media, which is the key factor of grinding process. But the kinematics parameter ,such as speed, acceleration, stress and so on, of media motion cannot be obtained through traditional laboratory test method, which restricts deeply research on finer grinding mechanism seriously. In order to solve this problem, characteristics of media motion in tower mill is studied via the discrete element method. Coefficient of restitution, coefficient of static friction and coefficient of rolling friction are the key parameters affecting the media movement, which were calibrated by stacking angle test firstly. A 3kW tower mill is established as the model for simulation. At last one appropriate simulation strategy is selected to increase simulation accuracy. The characteristic of media motion is obtained based on the computer simulation analysis: macroscopically, the media in tower mill is a dynamic equilibrium state generally accompanied by spiral up and down movement all the time. And it has been found that the maximum lifting height is proportional to the rotation speed of agitator shaft. The velocity of media at the edge of screw stirrer is biggest, while the velocity of media near the cylinder wall is smaller, so the grinding performance between the two ring areas is the best. The rotational speed of agitator shaft and media filling ratio are the two most important operating parameters in tower mill. The impact curve of two main operating parameters on the grinding intensity and energy efficiency are obtained. All these can provide theoretical basis and technical support for operating parameters setting of industrial tower mill."

Jan 1, 2018

By Zhaohui Wang, Jiachen Wang

"Effective surrounding rock control is a prerequisite for realizing safe mining in underground longwall faces. In the past three decades, longwall top-coal caving mining (LTCC) and single pass large height longwall mining (SPLL) found expanded usage in extracting thick coal seams in China. The two mining methods lead to large void space left behind the working face, which increase the difficulty of ground control. Longwall face failure is a common problem in underground mining, which is induced due to low strength and high fracture density of the coal seam. Moreover, the stiffness of main components included in the surrounding rock system also greatly influences longwall face instability. Correspondingly, the surrounding rock system is developed for LTCC and SPLL faces in this paper. Mechanical conditions for simultaneous balance of roof structure and longwall face are put forward by taking the stiffness of coal seam, roof strata, and hydraulic support into account. The safety factor of the longwall face is defined as the ratio between its ultimate bearing capacity and the load imposed on it. The influence of coal strength, stiffness of the coal seam, roof strata, and hydraulic support, as well as the movement of roof structure, are analyzed. Finally, the key elements dominating longwall face stability are identified for improving surrounding rock control effectiveness in LTCC and SPLL faces.INTRODUCTIONThe concentration of coal mining in China is gradually shifting to the west region, and there are a large number of thick coal seams in the newly formed coal mining area. Therefore, the surrounding rock control problems related to mining of thick coal seams will become the focus of research in the field of mining engineering in the future. There are two kinds of mining methods for thick coal seams in China, including single pass large height longwall mining (SPLL) and longwall top-coal caving mining (LTCC). Both methods can accomplish the goal of excavating the full thickness of thick coal seams at one time. SPLL mining benefits from the improvement of the development level of associated equipment. The appearance of large hydraulic supports and high power shearers ensure that the height protected by the hydraulic supports and the height of the sheared coal are the same as the coal thickness. LTCC mining benefits from mining technology advantages. The thick coal seam is divided into two sub-layers, and the working face is normally installed in the bottom layer, while the top coal is caved under the compressive forces due to mining. Therefore, there is a scraper conveyor at the front of the hydraulic support for transporting the sheared coal and another one at the tail for transporting caved top coal. Both SPLL and LTCC methods realize one-off recovery of thick coal seams."

Jan 1, 2018

By J-S. Marois, F. Cappucitti, Y. Dodier, D. Downey, G. Matton

"The flotation processes of the Niobec Mine have been affected by a seasonal loss of recovery and a significant increase in reagent consumption over the past few winters. This paper discusses the problem-solving methodology that was used to identify the root causes, to develop solutions and to implement changes that resolved the problem to restore the process to summer-like conditions year-round. Mainly, it was found that the process water was contaminated by phosphates ions, which adversely affected the carbonate pre-flotation, and caused detrimental effects on the subsequent niobium flotation. The phosphate ions were being generated by the process itself, but were consumed by algae in summer conditions. It was determined in laboratory studies that concentrations as low as 5 ppm were enough to affect the circuit and that the multiple additions of process water throughout the circuit was worsening the effect. Also, temperature was found to have an impact on the reagent performance. The performance of the plant was restored by implementing a natural treatment of our process water with a simple cost-free rearrangement of our circuit streams. In addition to that, our extensive geometallurgical program was used to provide ore to the plant restricting phosphate generation in the process. Also, a modification of the collector was developed and introduced in the carbonate pre-flotation that provided improved performance during the periods of low pulp temperature.INTRODUCTION Niobec is one the three major global producers of niobium presently in operation. Situated in the Saguenay-Lac-St-Jean region of Quebec and in operation since 1976, the site produces ferroniobium (FeNb) to be used mainly in High Strength Low Alloy (HSLA) steel, which is known to have better mechanical properties than carbon steel. The Niobec operation consists of an underground mine, a concentrator and a converter plant. The concentrator concentrates niobium-bearing minerals, mainly pyrochlore and columbite, to produce a high-content Nb2O5 concentrate which is then converted to FeNb in the converter plant by an aluminothermic reaction. The Niobec concentrator flowsheet, which has gone through many expansions and optimisation over the years, consists of grinding, desliming, flotation and leaching steps. The flotation steps are numerous, sensitive and difficult to operate due to the non-selective nature of oxide mineral collectors. Thus, the pyrochlore concentration process at Niobec still faces many challenges and is constantly going through periods of continuous improvement."

Jan 1, 2018

By M. Javier

"Mining makes civilization possible. It also creates socio-economic problems surrounded by sustainability controversies yet continues extraction without considering the balance and finitude of nature. Nature requires restoration of equilibrium if mining and life on earth are to continue. Mining is still practiced according to Agricola’s views and the consequences it has wrought on our planet demand we critically reexamine it from its very core, to its metrics, to its design, to its technology, to how it is taught, and to reconsider its raison d'être in 2017. This paper offers tools to new mining engineers that are required to transform and solve new challenges. The task before us is to formulate an updated core curriculum that meets the demands and realities of the 21st Century. Mining professionals must rethink and reteach how to redesign mines before shovel hits dirt, how to mine with restoration of nature figured in to the mining design. Mining needs a new extractive technology in order to transform the results of its well-known liabilities. Mining has evolved and its future must be different than its past. Our industry is capable of doing this but it needs to be shown the way. INTRODUCTION The statement that ‘mining makes civilization possible’ is of the utmost importance and has the most value to us. We can examine the past and present appropriately to see the future that we are building. Mining must be addressed in a different way that makes a positive difference and improves upon rather than continues to get the negative impacts of the past. See Fig 1. Mining creates disequilibrium in Nature by producing ore, waste, tailing, dilution of resources, toxic, and pollution to its ecosystems. What is next for mining on a limited planet? Delaying the transformation of mining is not an option to developing an updated and modern mining business-as-usual paradigm. It is hurting the essentials of living in a civilization; our livelihood is in danger to the point of unrest in nature as we generate a lot of eco-print by present mining practices. So, we are urged to eliminate this bottleneck in life by employing a different design. This way, we will have a vision on how to sustain our civilization. [1]. This new design, with input from current and future generations, will be our contribution to posterity."

Jan 1, 2018