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By A Fyans, B Ghahreman-Nejad

This paper discusses the method and results of an options study into selection of the optimal form for a 130 m high tailings/water retaining dam, located in a region of high seismicity in central Iran. The proposed dam is part of a planned expansion project for Sarcheshmeh Copper Mine (SCM), which after construction will provide 550 million tonnes of additional tailings storage over the next 27 years. Geotechnical investigation at the proposed site indicated that adequate suitable low permeability materials (i.e. clay) were not available in the immediate vicinity of the dam site and would need to be imported from a distance of well over 10 km (direct). Given the magnitude of the estimated quantity of material and construction cost it was considered prudent to compare the cost of alternative dam design options for the proposed storage. A total of five dam design options are considered including a conventional rockfill embankment dam with an upstream sloping earth core (ECRD), a geomembrane face rockfill embankment dam (GFRD), a sloping asphalt core rockfill embankment dam (ACRD), a roller compacted concrete dam (RCCD), and a filter rockfill embankment dam for tailings storage together with a separate smaller earthfill core rockfill dam (ECRD) located downstream for storage of decant water. The risks, costing and design of all options are discussed in detail and the outcome of the study is presented.CITATION:Ghahreman-Nejad, B and Fyans, A, 2018. Optimum embankment design for a tailings dam, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 427–438 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By K Seddon

Segregation of tailings on deposition can occur as a result of a) sub-aqueous deposition, and b) sub-aerial deposition at lower solids concentrations (i.e. when the solids concentration is less than the segregation threshold). The effects are likely to be more pronounced in the case of subaqueous deposition.This paper presents the results of an investigation of a sub-aqueous tailings facility.Data from the investigation show extreme variations in particle size and density compared to test results for non-segregated ‘all-in” tailings. The results indicate that on segregation both the fine and coarse splits tend towards a well sorted (poorly graded) mix, and both have significantly lower consolidated density than the all in tailings. This result is reasonably well known for the case of the segregated fines (“slimes ponds”) but less appreciated for the coarse fraction. The results suggest that if the effects of segregation are not allowed for, the overall density of the deposit can be seriously over-estimated at the design stage. Also the quantity of water retained in the tailings can significantly influence water recovery and water balance results.CITATION:Seddon, K, 2018. Segregating tailings – effects on density and water retention, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 299–308 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By A Marta

Geomembrane (GMB) liners are being used more frequently for the storage or capping of mine waste due to stricter regulatory requirements relating to environmental protection. The longevity of any liner system will be a function of environmental conditions, design (including materials selection), construction and condition monitoring during operations or closure. Based on experience and case studies, this paper presents a review, from design to handover, of some of the smaller and often overlooked details that can have significant impacts on the performance of the GMB and the project overall.The topics covered will include approaches to selecting and testing GMBs to ensure they are suitable. Design considerations to aid installation and quality assurance during construction. Understanding action leakage rates and the consequences of leakage when it creates whales. Construction quality control and assurance procedures, including a brief discussion on non-destructive liner integrity testing. CITATION:Marta, A, 2018. Geomembranes – from design to handover and some of the lessons learnt, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 190–207 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By E M. Gama, L Resende

The tailings are waste from mineral processing operations. The type of tailings of iron ore processing are classified into sandy tailings and mud. Already the overburden are showing significant levels of useful mineral. Both iron ore`s waste have in your composition phyllosilicates/clay that indicates the potential for use in niche markets as paving and cement. According to several studies, there are various technologies in bench and pilot levels that could be used on a large scale but there is not an economic environment, tax, regulatory and tax set. Many of these technologies are associated with the reuse of tailings and overburden in construction. All these factors influence for that so many initiatives remain in search formats and cannot advance to the new business format. There is no way to set goals of reuse of this waste, as already occurs in China, if there is not a fiscal, tax and economic structure to support such measures. The way to foster and ensure that reuse of tailings and overburden is an incentive for promoting a culture of circular economy that would allow the emergence of an ecosystem between the private, public and Government sectors with the objective of accelerating and subsidize the entire network of reuse of this waste. The closure of the mine could be the tool used to ensure and boost this ecosystem of reutilization to align it with the vocation of the area of the mining law. Following this model, the end of the mining activity could provide a financial return to the local population, a more effective environmental compensation and a reduction in costs related to the closure of the mine. In this study are shown how the Vale is working in the reuse of tailings and overburden.CITATION:Resende, L and Gama, E M, 2018. The challenges of the reuse of tailings and overburden, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 117–125 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D J. Williams

The majority of surface tailings storage facilities continue to employ sub-aerial tailings slurry deposition. Surface TSFs are typically sized and operated in a way to minimise the initial capital cost of the facility, driven largely by the net present value approach to accounting. This generally leads to too small a storage, too fast a rate of rise of the tailings, and difficulties in managing supernatant water. In turn, this results in wet and soft tailings deposits of high moisture content and low density, and the need for frequent and costly tailings dam raises. Further, such tailings deposits often do not facilitate closure and rehabilitation of the facility. Globally, there are on average over two failures annually of such tailings dams, resulting in loss of life, damage to infrastructure and environmental impact downstream, and the loss of company shareholder value and reputation. Recent high profile tailings dam failures are threatening the mining industry’s financial and social licence to operate.Among the physical processes that tailings undergo on sub-aerial deposition are beaching, hydraulic sorting down the beach according to particle size and specific gravity, settling, consolidation, and desiccation on exposure to the sun and wind. Beaching and hydraulic sorting have proved difficult to test at laboratory scale and difficult to model, and are best assessed in the field. Settling, consolidation and desiccation may be assessed at laboratory scale, but to date there has been an absence of tests to form the basis for the design and management of tailings deposition, and ultimate closure and rehabilitation. The paper describes recent advances in tailings testing methods, including a purpose-built slurry consolidometer that tests the settling and consolidation of tailings from a slurry consistency, simulating increasing tailings depth to about 50 m; and a purpose-built instrumented column that tests the settling, self-weight consolidation and desiccation of a surface layer of tailings, also from a slurry consistency. Selected test results from these two apparatus are presented in the paper, together with brief descriptions of how they may be used to better design tailings slurry deposition. In addition, planned further advances in tailings testing methods are briefly described.CITATION:Williams, D J, 2018. Recent advances in tailings testing methods, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 8–37 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Pamela Bogust, York R. Smith

Photovoltaic (PV) modules are becoming an ever increasingly larger part of our energy portfolio. As more and more PV modules are installed and come on-line, management of end-of-life (EOL) modules becomes an important issue. Currently, management of overburden EOL PV modules is not an issue, but is anticipated to be by 2030. Recovery and recycling of valuable metals in PV modules presents several environmental and economic advantages. In this brief review, we will describe processes for refurbishing and recycling of PV silicon. These processes involve some combination of mechanical, thermal, and chemical processing, all of which all have their oPV) modules have become wn respective challenges. Also, projections of PV module material streams are also highlighted.

Mar 1, 2018

By Feng Wang, Guojing Shi, Yangyang Xie, Zizong Zhu, Qiang Wu

The coal chars from northwestern part of China are characterized with high reactivity and low strength after reaction. Four type of coke-making coals selected from northwestern part of China were studied by proximate analysis, ultimate analysis, vitrinite reflectance analysis, and FTIR with curve-fitting analysis to obtain information on their chemical composition and chemical structure. The results show that the studied coals have relatively high values of final contraction of coke residue index (x) and relatively low values of maximum thickness of plastic layer (y) and average vitrinite reflectance. Based on the curve-fitting analysis of FTIR spectra, the aliphatic carbon (Cal), the aromatic carbon (Car), and the molecular structural parameters such as CH2/CH3, fa, Hal/Har, and (R/C)u are determined. The results of curve-fitting analysis indicate that the studied coals are characterized by a large amount of oxygen-containing functional groups and aliphatic side chains.

Mar 1, 2018

By Leizhang Gao, Zhengfeng Qu, Pingsheng Lai, Chenguang Bai, Meilong Hu

FFC process could be used to prepare titanium foams. The mixed oxides CaO-TiO2 with mole ratio 1:2 were sintered into CaTiO3-TiO2 mixture. CaTiO3-TiO2 was then used as cathode and electrolyzed in molten CaCl2 to prepare porous titanium. The porous titanium with the porosity of about 72.15% was first fabricated. The internal pores are in the presence of circular cavities and the pore size is in the range of 50–100 lm. Compared with the powder metallurgy technique using the space-holder this method promises to be lower cost and less processing. It is potential to fabricate titanium foams using FFC process.

Mar 1, 2018

By Kevin Trumble, David Johnson, Kyungjean Min

The electrolytic manganese dioxide (EMD) production through electrodeposition from manganese nodules by reduction leaching in H2SO4 medium using sucrose as reductant followed by purification through 2-stage precipitation methods is described. The purified leach liquor was the starting solution for electrodeposition. Influence of in situ addition of a cationic surfactant Cetyltri-methylammonium bromide (CTAB) (0–500 mg dm −3) on the surface morphology and electrochemical properties of the EMD was examined. The XRD patterns of the deposited material were indexed to the c-MnO2 phase. FESEM results demonstrated that in the presence of CTAB uniform nanofibrous type grains were formed. Higher concentration of CTAB in the electrolytic bath however, drastically decreased the current efficiency (CE) and increased the energy consumption (EC) during electrodeposition. Under the optimum CTAB concentration of 100 mg dm −3 the obtained CE and EC values were 87.64% and 1.70 kWh/Kg respectively.

Mar 1, 2018

By Metehan Erdogan, Mustafa Serdal Aras, Sedef Cift Karagul, Ishak Karakaya, Esra Karakaya, Merve Kolay Ersoy

Pickling is the treatment of metal surfaces by removing oxide layer, rust, scale, inorganic contaminants or other impurities from ferrous metals, copper or precious metals. A strong inorganic acid such as hydrochloric acid is used for plain carbon or low alloy steel pickling. When the concentration of copper in the pickling solution exceeds about 100 mg/L, reversion may take place and randomly plating of copper onto the steel strips which causes visual incompatibility occur. Furthermore, efficiency of pickling decreases with the increase of copper content. The reversion may be delayed to higher Cu concentrations by adding fresh acid to the line. Increased acid consumption only delays the time to discard the solution but increases the cost and hazardous nature effect on the environment. An experimental electrochemical procedure has been conducted to remove copper from pickling solution to reduce the concentration below 100 mg/L. Within this scope, effects of applied current density, copper concentration and electrolysis duration on copper deposition were studied. Current density was determined as the most effective parameter to remove copper from the regenerated pickling solutions of steel plants.

Mar 1, 2018

By Denise Crocce Romano Espinosa, Jorge Alberto Soares Tenorio, Amzy Tania Vallenas-Arevalo, Carlos Gonzalo Alvarez Rosario

Cyanideisatoxicchemicalusedinminingindustrytorecovergoldand silver in leaching process. Effluents containing cyanide can be treated by biore- mediation instead of physical and chemical processes which are often more expensive and less efficient. This study evaluated the capacity for free cyanide degradation of a Bacillus licheniformis strain previously isolated from an aban- donedgoldmine.First,bacterialgrowthinLBmediumthroughOD wasstudied. 600 Then,bacteriawasadaptedtogrowonalkalinemediumusingCAPSbuffertokeep pH10. Finally, cyanide degradation assays were performed using a 500 mgL −1 KCN pH10 50 mM CAPS solution. Free cyanide was measured using a polaro- graphicmethod.Temperatureinfluencewasevaluatedat27,32and37 °C.Results showedthat B. licheniformis was able todegrade 99% offree cyanide after 5 days of incubation and works better at 32 °C showing the strain potential for cyanide biotreatment in mining industry. (cid:1) (cid:1) (cid:1)

Mar 1, 2018

By Ming-Feng Ye, Jun Wang, Guang-liang Wu

In order to reduce the Al2O3 inclusions in 50Cr5MoV roller steel produced by EBT-LF-VD-VC process in a steelmaking plant, the LF refining slag was optimized and the influence of optimized slags with different w(CaO)/w(Al2O3) ratios on reducing inclusions were investigated in the laboratory. The results showed that, when w(CaO) = 50–55%, w(Al2O3) = 25–30% and w(CaO)/w(Al2O3) = 1.5–2.0, this optimized slag can not only reduce massive Al2O3 come from aluminium deoxidation, but also change the remain into plastic CaO-MgO-Al2O3 spherical compound inclusions with 1–5 lm diameter, the harm on the performance of the steel was minimized.

Mar 1, 2018

By Qingguo Xue, Jingsong Wang, Guang Wang, Yuanyuan Zhang

Due to complicated structure and composition of high-phosphorus iron ore, pure substances were used to simulate the chemical composition of high-phosphorus iron ore to study the reaction of fluorapatite at different temperatures and effect of additives. The gasification process of P during carbothermic reduction process was investigated using a quadrupole mass spectrometer gas analysis. It is found fluorapatite was reduced to phosphorus which diffused into iron and gas phase. From the gas analysis, it was observed that PO and P gas species were vaporized around 800 °C. As the reduction temperature increased, the diffusion of phosphorus into iron was enhanced. The presence of Ca(OH)2 as additives not only promoted the reduction of iron oxide, but also decreased the degree of fluorapatite reaction to inhibit P into iron.

Mar 1, 2018

By Zhengde Pang, Xue-wei Lv, Guibao Qiu, Chenguang Bai, Zhiming Yan

As a result of the consumption and the rising cost of raw materials for ironmaking, steel producers have increased their utilization of low-cost, low-grade raw materials such as high alumina iron ore. The effect of Al2O3 and the Al2O3/SiO2 ratio on the viscosity, surface tension and sulfide capacity of the CaO–SiO2–Al2O3–MgO–TiO2 blast furnace slag system were studied in the present work. At a fixed CaO/SiO2 ratio of 1.20, 9 mass pct MgO, and 1 mass pct TiO2, the viscosity increases with an increase in Al2O3 content at a range of 16–24 mass pct, and decreases when the Al2O3 is higher than 24 mass pct. Increasing Al2O3/SiO2 from 0.47 to 0.92 causes a slight decrease in viscosity of the slags and has an opposite effect when Al 2O3/SiO2 is more than 0.92. The surface tension increases with increasing Al2O3 content at a fixed Al2O3 content and Al2O3/SiO2 at a fixed CaO content. The desulfurizing capacity decreases with increasing of Al2O3 content, while increases with increasing Al2O3/SiO2 at a fixed CaO content.

Mar 1, 2018

By Chengyi Ding, Yangyang Xie, Xuewei Lv, Senwei Xuan, Chenguang Bai, Kai Tang, Gang Li

Dicalcium ferrite (2CaOFe2O3, C2F) is one of the most significant bonding phase of fluxed sinters. Reduction of C2F was investigated via thermal kinetics analysis. The isothermal reduction behavior of C2F by 30% H2 and 70% N2 at 1123 K (850 °C), 1173 K (900 °C), and 1223 K (950 °C) were discussed by thermogravimetric analysis in this paper. The results revealed that the C2F reduction was typical one-step reaction. The apparent activation energy of the C2F reduction was 27.40 kJ/mol. The rate-determining steps of the C2F reduction were the first inner gas diffusion, then the inner gas diffusion and interface chemical reaction mixed controlling. The ln-ln analysis implied that the C2F reduction was described by the Avrami–Erofeev (A-E) equation, thus appeared as a 2D A-E equation kinetics reaction.

Mar 1, 2018

By Lu-ming Zhao, Li Zhao, Yu Wang

Mould flux is a vital functional material which is based on silicate including flux and framework material. The effects of magnetic field intensity and frequency on viscosity of mould flux were tested by rotational viscosity tester and a measurement device for electromagnetic characteristics of mould flux viscosity under high temperature conditions. The results show that: with the magnetic field intensity rising (0 –30 mT), the viscosity of mould flux increases by 1.3–1.8 P. With the frequency rising (6–12 Hz), the viscosity of mould flux is increased by 1.2–1.4 P. When the binary basicity is 1.08, the viscous flow activation energy increases with the increase of the magnetic field intensity and frequency. It can be the main reason for the increase of mould flux viscosity that the electromagnetic forces disrupt the ordered structure of mould flux and make the ion migration rate increase.

Mar 1, 2018

By M. A. H. Shuva, M. A. Rhamdhani, G. A. Brooks, S. H. Masood, M. A. Reuter

Ferrous-calcium-silicate (FCS) based slag has been used in the copper industry over the last two decades. The FCS slag has also been used in a secondary copper processing such as in black copper smelting which has different operation conditions compared to that of typical primary copper processing. In the process, a variety of copper bearing scraps from sources such as industrial waste, consumer waste and electronic waste (e-waste) are used. The valuable metals in these sec- ondary resources are distributed in different phases during the process. Understanding the behaviour of the valuable elements at the relevant conditions is vital for optimizing the process and to maximize the recovery of the elements. In this study, we investigated the structure of Ge-containing FCS-based slag at different conditions (oxygen partial pressure and temperature) using Fourier-Transform Infrared (FTIR) spectroscopy to explore the effect of the polymerization on the behaviour of the valuable element Ge in the slag. It was found that experimental parameters significantly in fluence the slag structure, and therefore, the partitioning of Ge in the slag. A correlation between the distribution ratio of Ge and the slag structure has developed in the current study.

Mar 1, 2018

By Zhi Yang, Ahmad Ghahreman, Farzaneh Sadri

Impurity removal is a very important stage of the hydrometallurgical treatment of rare earth elements (REE) processing circuit, which is performed after water leaching of the acid baked REE concentrate. Lime neutralization has a high efficiency in removal of impurities and is the preferred process due to its economic advantage; however, the process has its own problems, such as the production of large volumes of gypsum and co-precipitation of REE with gypsum, i.e. REE loss. This work deals with the effect of several additives (cetryltrimethylammonium bromide (CTAB), polyvinylsulfonic acid (PVS) and polyacrylic acid (PAA)) on the uptake of REE by gypsum from synthesized acidic solutions. The main purpose of this study is to investigate the changes in the crystalline morphology of gypsum precipitated by the addition of crystal habit modifiers and to determine the crystal changes’ effects on the uptake of REE by gypsum. In this regard, different concentrations (0.2, 2 and 5 g L−1) of above-mentioned additives were studied at room temperature.

Mar 1, 2018

By Liguang Zhu, Yihua Han, Qingjun Zhang, Xiaoyan Wu, Pengcheng Xiao

The evolution of chemical composition, size, proportion, and morphology of the Al-Ti-Mg-O inclusions during the steelmaking process of Interstitial Free (IF) steel from the RH to the Continuous Casting (CC) slab were investigated by means of Auto-SEM. Results showed that many of Al2O3 and MgO-Al2O3 type inclusions are modified by TiOx, while most of their shapes are irregular due to the high melting temperature. The composition evolutions and melting characteristics of Al-Ti-Mg-O inclusions under different contents of [Al], [Ti] and [Mg] were estimated by using thermodynamic software Factsage 7.0. Results showed that estimated results are in good agreement with the analysis results of industrial samples. Both the Ti alloying and spontaneous enrichment would make a high Ti concentration environment that was in favor of the TiOx existence. Moreover, more TiOx component can modify MgO-Al2O3 spine inclusion into inclusions with a lower melting temperature.

Mar 1, 2018

By Tarek M. Hatem, Salah M. Bedair, Khaled H. Khafagy

Our understanding for intrinsic stresses and defects evolution in photovoltaic devices has became an essential part of new developments. In particular, Multi-Junction Photovoltaic (MJ-PV) modules depend on multi-layer structures that may suffer high dislocation-densities as a result of high lattice and thermal expansion coefficient mismatch. These defects limit the performance, reliability, and lifetime of PV devices. In the current study, a three-dimensional multiple-slip crystal-plasticity model and specialized finite-element formulations are used to investigate InGaN growth on Si substrates. The formulation is based on accounting for thermal and intrinsic stresses as a result of different processing conditions and microstructures. Furthermore, the formulation was used to investigate a recently developed technique, Embedded Void Approach (EVA), which can be used to address both the high density of defects and the cracking/bowing of InGaN growth on Si. The current work lays the groundwork for more extensive use of silicon in MJ-PV devices.

Mar 1, 2018