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By E. G. Woods, A. G. Comer

A mathematical model is presented and solved for determinution of the saturation distribution and pressure in a radial gas-storage reservoir. The model consists basically of two parts: (I) the growing gas-bubble core, and (2) the surrounding aquifer. Since the total pressure at the injection well is a function of the two-phase flow in the gas bubble and the unsteady single-phase flow in the aquifer, the resistance to flow in both zones was taken into consideration. The assumptions involved for both the radial equivalent of the Buckley-Leverett two-phase-flow equation and the injection-pressure equation are as follows: (I) the geometry is radial, (2) the gas bubble is free to expand or contract, (3) compression or expansion of the gas within the bubble may occur at the beginning of a time step, (4) the fluids are immiscible, (5) water is incompressible within the gas-storage region whereas it is compressible outside of this region, (6) a stable gas-water interface exists and (7) gas injection occurs at a constant rate or a series of constant rates. The mathematical model was solved numerically using an IBM 650 computer. A comparison is presented between the predicted results of the model, the results assuming steady-state flow and the actual initial injection-pressure history of an operating reservoir. Using the initial field pressure for a basis, the average deviation between the predicted pressure and the actual field pressure was less than 4.3 per cent. INTRODUCTION Underground storage of natural gas in abandoned oil fields, in abandoned coal mines, in caverns and in aquifers has had varying degrees of success. The lack of these first three facilities in the vicinity of most major gas marketing areas is leading more and more to storage in virgin aquifers. For the most part, this storage in aquifers has led to the study upon which this paper is based. Several excellent papers have been published discussing the problems involved in the underground storage of natural gas; however, to these writers' knowledge, none of them considered the two-phase flow of fluids in the gas bubble and the fact that the gas bubble will grow or shrink in size depending upon the injection and withdrawal history of the reservoir. Not only will both of these factors influence the required injection pressure, but also they will have a definite bearing upon the amount of water production occurring upon withdrawal from the storage area. To solve this problem on an IBM 650 computer, several simplifying assumptions were made. Only the drainage portion of the relative-permeability curve was considered, thereby neglecting any hysteresis effects introduced during an imbibition cycle. The quantity of gas withdrawn during the period of the field study was only a small percentage of the total gas in place; therefore, this assumption is justified. For the problem studied in this case, the combined effects of capillarity and gravity were assumed to be negligible. This assumption becomes less valid as the formation thickness or the average pore diameter increases markedly. The justification of these assumptions should be studied in each case. THEORY This mathematical model for the prediction of saturation distribution and pressure for a radial gas-storage aquifer is based upon the equations for radial two-phase fluid flow'.' and for radial, unsteady-state, single-phase fluid flow.' The two-phase flow is considered to take place in a "core" whose radius is equal to the maximum radius that the gas zone will attain, as indicated in Fig. 1. The injection-withdrawal history is approximated by a series of constant flow rates. Within the "core", gas is assumed to behave as a semi-compressible fluid; that is, the gas is assumed to have a constant density based on the average gas-zone pressure for the flow period. Between each constant-rate time increment, the gas density is allowed to change. This involves an iterative solution of the pressure equation. The liquid phase in this zone is considered to be incompressible, whereas it behaves as a compressible liquid outside of this region. The equations of incompressible flow in the "core" may be written for the gas phase

By A. L. Hinde, A. A. Bradley, P. J. Lloyd

The results of slow crushing tests in a stiff testing machine for both small and large step reductions of particle size are given. The energy consumption required to produce a given weight of minus 74 um material was determined when both single-crystal quartz and Witwatersrand reef were crushed. For comparison the two materials tested were also comminuted in a ball mill under optimum conditions. There are indications that slow crushing under stiff conditions is the most efficient method of breakage that can be devised. The comparison with ball milling results thus yields a value for the efficiency of ball milling of approximately 80 per cent. These results confirm that the best current estimates of milling efficiency, which are based on the free boundary surface energy of the material being milled, are probably too low by at least one order of magnitude.

By Jafar Safarian

Bauxite is the main raw material used for the production of alumina (Al2O3) through the well-known commercial Bayer process. This process has significant challenges such as limitation in using low-grade bauxites as they contain significant amounts of impurities such as Fe, Si, Ti. The Bayer process residue, which is known as red mud, is also a global environmental challenge due to huge amount of this low value residue production. An alternative sustainable process with high potential to solve these problems and produce valuable and consumable by-products is a pyrometallurgical-hydrometallurgical process in which the low-grade bauxite ore is treated through a smelting-reduction process, yielding iron alloys and a calcium-aluminate slag. Alumina is then produced from the slag by hydrometallurgical treatment. In the present work, the reduction of pellets produced from different bauxite ores by hydrogen is studied and it is shown that complete iron oxides reduction is possible. Further smelting and smelting-aluminothermic reduction of the reduced pellets show that iron and silicon ferroalloys can be produced, in addition to a proper slag for alumina extraction.

By C. S. Griffith

Lithium Australia NL (ASX:LIT) and ANSTO Minerals have been working together since 2015 on the development of halide accelerated leaching for the extraction of lithium from lithium-bearing micas, spodumene and clays. This technology has been termed SiLeach® process. The driving force behind development of the SiLeach® process, initially, was to develop a hydrometallurgical process to extract lithium from micas and spodumene without the need for the energy intensive, high temperature processing conventionally applied to lithium extraction. This driving force remains today and continues to hold promise in realising the value of previously under-utilised lithium resources. A comprehensive understanding of the technology and its applicability to the processing of micas and spodumene currently exists, and the flowsheet has been rigorously piloted. Production of battery grade lithium carbonate has been demonstrate

By Benjamin Cebrián, María Gil, David Flores

In many occasions during the Mining operation life, blasting engineers find different and controversial results of fragmentation, dilution or wall control for the same geotechnical domain and blast design (pattern and explosive charge). Most of the times, the difference between same blast designs is not measured, not controlled. Once a blast designed is defined, the most important part of the process after that is the implementation of every step of the blast on site. Almost nobody is measuring it, controlling it, but just controlling implementation is possible to relate blast design with results in a consistent way, to optimize the full process of D&B. Controlling implementation not only per event but also to check and change trends and decision-making is paramount for optimization and saving millions of extra costs every year. The lack of resources and the hardness to manage all the info created every day in a blast make this process very tough and difficult to maintain in long term. The use of new technologies on site and software that allows a best, more consistent and continuous control of blast implementation have been proved to be the key for optimizations and cost saving. This document shows the evolution of drilling and blast digitization process, savings and trends in a mine, using new technologies that creates business opportunities and general improvement of D&B process.

By Yongjun Xian

The release of fluid inclusions has a strong potential for the unintentional activation of pyrite during flotation. The present study aims to characterize fluid inclusions in a natural pure pyrite. The results indicate that a certain amount of fluid inclusions exist in the pyrite. The fluid inclusions assume a variety of shapes, including long strips, oval shapes and irregular shapes, with sizes that range from a few microns to dozens of microns. From the EDS results of hollow positions that resulted from the fracture of the fluid inclusions on the pyrite surface, certain amounts of Al, Cr, C, O, Ag and Cu were clearly detected; these elements were not detected in FeS2 pyrite itself. The contents of the inclusions were released into solution when the sample was subjected to a grinding process. Under experimental conditions of 2 g of pyrite cleaned in 40 mL of pure deionized water under an inert atmosphere, the concentrations of Cu, Fe, Cl- and SO4 2- released from the inclusions reached concentrations of 3.29 × 10-6, 32.52 × 10-6, 51.57 × 10-6 and 75.90 × 10-6 mol/L, respectively. These values are significantly greater than those from the experimental nonoxidative and oxidative dissolution of the pyrite. The fluid inclusions of pyrite were, therefore, concluded to represent the dominant sources of Cu, Fe, Cl- and SO4 2- in the aqueous solution. The present investigation provides a new understanding of the source of the unavoidable metal ions in the pulp and may benefit understanding of the flotation theory and environmental geochemistry.

By Ángel Ruiz-Sánchez

Ethylene glycol additions to aqueous acid solutions for leaching copper sulfides increase both copper and iron extractions compared to a conventional sulfuric acid leach with hydrogen peroxide (H2O2). The role of ethylene glycol is to prevent peroxide destruction, which normally occurs in solutions that contain both cupric and ferric ions. However, despite this improvement, ethylene glycol and sulfuric acid concentrations must be high (3.5 M and 0.7 M, respectively) to obtain satisfactory conversion levels at room temperature. In the present investigation, EDTA was used as an additive to complex the cupric and ferrous ions, lowering the requirements of ethylene glycol and H2SO4 to 0.11 M and 0.007 M, respectively, while minimizing oxidant decomposition. The experimental results for a mainly chalcopyrite, copper concentrate showed complete copper extraction in 24 h at room temperature, with the stoichiometric quantity of EDTA for the copper and iron dissolved. Tests using seawater were equally as successful.

By G. Fazel Jahromi

Enargite, known as one of the major arsenic containing copper minerals, with approximately 19% arsenic, introduces challenges to typical processing options. In most hydrometallurgical processing methods, arsenic remediation occurs after the copper recovery in an autoclave or in a stepwise neutralization process. In this study, the in situ precipitation of scorodite was investigated during an atmospheric leaching process in the presence of carbon-based catalysts and chloride media. The effective parameters of initial ferric addition, temperature, catalyst addition, and oxygen sparging rate were studied and the ferric behaviour was monitored during the scorodite precipitation. The most influential parameters on efficient scorodite precipitation are found to be: initial ferric addition, catalyst to concentrate ratio, and temperature. A 99% scorodite precipitation yield was achieved in this process.

By G. Nazari

ERAMET, through its subsidiary COMILOG, have rights to a rich niobium and rare earth deposit inGabon. The Mabounié deposit, is located 50 kmfromthe town of Lambaréné, in a fairly remote location. ERAMET has been developing a process to recover value metals for several years, and approached Hatch Ltd. to design a sizeable Demonstration Plant to help them further optimize the process, and prove the flowsheet is technically viable. The process employs concentration techniques to recover an upgraded Nb/REE feed material for processing in the subsequent leach step. Rare earths and niobium are selectively leached, and subsequently precipitated. Following precipitation, rare earths undergo bulk separation and are purified to produce LRE and mixed MRE/HRE products, which will be further processed by Third Parties. This paper provides a high-level overview of the process, summarizes the motivation for a Demonstration Plant in the vicinity of the deposit, and discusses technical challenges faced during the flowsheet definition and design phase. Key challenges are focused on and summaries of the methodologies used to address each challenge, as well as the solutions to overcome the challenges, are discussed. The paper provides motivation for further process simplification and concludes with a project update.

By Valery Kaplan

Sulfur emission in the form of SO2 in flue gases is one of the most serious atmospheric pollutants associated with coal combustion and non-ferrous metals production. The carbonate eutectic method for removing SO2 from flue gases at 723–923 K was initially proposed in the 1970s but despite its great efficiency (SO2 concentration in the flue gas after purification reached 0.003 volume %), it could not be implemented by industry due to the complexity of the carbonate melt regeneration stage. Earlier we proposed a method suited to coal-firing power stations where the melt was regenerated using CO as a reducing agent. However, most metallurgical plants do not use coal and therefore lack a large source of CO. Here we propose a method for removing sulfur from the carbonate eutectic melt by purging it with natural gas or a natural gas/air mixture, which are available in the vast majority of metallurgical plants. This reaction leads to the reduction of sulfate to H2S gas that leaves the melt. The experiments we conducted show that nearly complete sulfur removal from the melt is possible at 823 K and that the reaction rate is sufficiently high for a large scale process. One can foresee that this carbonate melt-based SO2 removal technique may become a practical and economically attractive method for limiting sulfur emission to the atmosphere from non-ferrous metallurgical processing plants.

By A. Lubinski, J. L. Logan, W. S. Althouse

A4ost gas twells and flowing oil wells are completed and treated through a string of tubing and a packer. Changes in temperature and in pressure inside or outside the tubing will: (I) if free motion of the tubing inside the packer is permitted, increase or decrease the length of the rubing; or (2) if free motion is prevented, induce forces in the tubing and on the packer. If pressure inside the tubing is greater than outside, the tubing may buckle helically even in the presence of a packer-to-tubing tension. The tubing will always buckle, and much more severely, if free motion is permitted. The buckling may be prevented by pulling the tubing in sufficient tension. The prediction of these forces and tubing movement has here to fore been based upon calculations that did not inciude helical buckling. This paper preseitts means with which these length or force changes can be calculated while taking into account the effect of helical buckling. To avoid damaging formations, failure of remedial operations, or damage to the tubing or packer, application is made to practical problems involving calculations of the required length of seals, amount of sluckoff or tension, and prevention of permanent corkscrewing. INTRODUCTION Leakage of a packer may result in costly failures of such operations as squeeze cementing, hydraulic fracturing, etc. To avoid such failures, the authors are often asked questions pertaining to the length of necessary seals, the amount of necessary slackoff, etc. Published work' does not take into account helical buckling of tubing. Investigation of helical buckling was prompted by the fact that allowance must be made for this phenomenon in order to provide relevant answers. In the past, theoretical work on helical buckling was confined to conditions for which such buckling does not The mathematical treatment of behavior in a buckled condition, given in the Appendix, is novel. Assumptions upon which this investigation is based are listed and discussed in a special section. The following are a few of the many kinds of problems which may be solved with this paper. 1. Consider a packer in which tubing may move. Such movement will occur after pressures and temperature are changed. The paper provides means for: (a) calculating the amount of such movement and, therefore. the required length of seals; and (b) calculating the necessary amount of initial slackoff, for which there is no danger of unsealing the packer, if the length of seals is given. Such calculations, as well as those which follow, tully take into account the fact that part of the movement ib due to elastic helical buckling of the lower part of the string. This buckling may occur even in tubing under tension. Insufficient initial slackoff for a given length of seals, or insufficient length of seals for a given slackoff, may result in costly failures. A field case of such a failure will be given further in this paper. 2. In the case in which tubing cannot move in the packer, changes of pressure and temperature result in tubing-to-packer forces and forces in the tubing above the packer, both of which may be calculated. This knowledge is important because, if these forces are too large, the) could damage the packer or the tubing. 3. For wells in which wireline tools are to be run through the tubing, the paper provides means to keep the tubing from buckling, thereby permitting free passage of tools. 4. In deep wells, mainly in the presence of large casing, tubing may become "corkscrewed", i.e., take a permanent helical set. A field case is described further in the text. Using this paper, one may calculate in advance conditions under which permanent corkscrewing would occur, and then take preventive steps. HELICAL BUCKLING Consider a string of tubing, freely suspended in the absence of any fluid inside casing, as shown in Fig. I(a). Now consider an upward force F applied at the lower end of this tubing. This force compresses the string; and if the compression is large enough (which is always the case in actual problems), the lower portion of the string will buckle into a helix, as shown in Fig. 1 (b). The lower end of the tubing is subjected to a compression F. This compression decreases with the distance from the bottom and becomes nil (neither compression nor ten-

By M. L. Harris

Coal dust produced during the mining process is a prime explosion hazard in underground coal mines. To inert the coal dust and prevent a catastrophic propagating dust explosion, rock dust is applied to the roof, ribs, and floor surfaces of mine entries. Currently, one determination of whether a mine is adequately protected from the coal dust explosion hazard is made by analyzing collected mine dust samples for percent total incombustible content (% TIC). A minimum of 80% TIC is required per 30 CFR 75.403. The as-received moisture of the dust sample is included in the % TIC. Moisture and humidity within a coal mine vary greatly with the seasons, with explosions occurring more frequently during dry winter months. This paper will discuss the fluctuations of the as-received moisture content of the mine dust samples collected by U.S. Mine Safety and Health Administration inspectors in 2010 and the observed fluctuations of the moisture content of rock dust within the U.S. National Institute for Occupational Safety and Health Office of Mining Safety and Health Research Bruceton Experimental Mine and the Safety Research Coal Mine over a one-year period.

By Kenneth F. Whinery, John M. Campbell

Basically, the Buckley-Leverett theory involves two systems which are similar in nature but are differentiated by time. These systems may be described by the fractional flow and frontal advance equations which essentially characterize the mechanics of oil movement while being expelled from the reservoir. The fractional flow equation originally developed by Leverettl may be expressed in the more usable form The development of this equation is based on Darcy's law describing fluid flow through porous media and applies to the flow at only one point (it is a point function). For simplification, the fractional flow equation is written in the above form because the capillary forces always increase the fractional flow of the displacing phase regardless of the direction of flow or the displacing phase. If, for simplicity, the effects due to gravity and capillary pressure differences are neglected, the fraction of the displacing fluid, f, at any point in the flowing stream is related to the properties of the system by 1 Thus, it is seen that in the absence of capillary and gravitational effects, fd for a given sand and fluids varies only with saturation and pressure. The magnitude of the viscosity ratio, —a has an effective range (range of about 30) in the system where gas is displacing oil and a much smaller range for water displacing oil. In order to make the fractional flow equation more versatile, it is necessary to connect the fractional flow at a given point and saturation with time. This problem was approached by Buckley and Leverett" who developed the frontal advance equation, Eq. 3 states that the rate of advance of a plane that has a fixed saturation, Sd, is proportional to the change in composition of the flow stream caused by a small change in the saturation of the displacing fluid. It is, essentially, a transformation of a material balance equation representing the net rate of accumulation of the displacing phase within a homogeneous sand block. This accumulation is proportional to the difference between the rate at which the displacing fluid enters the sand and that at which it leaves. Eq. 3 describes the velocity with which a plane of constant displacing phase saturation advances through a porous system. Buckley and Leverett," Babson,' Kern," Welge, and others have adequately discussed the basic mechanism and application of the fractional flow and frontal advance equations. APPLICATIONS OF THE FRONTAL ADVANCE THEORY TO PETROLEUM RECOVERY Two general applications of the Buckley-Leverett frontal advance theory involve the system in which the oil is being displaced by an expanding gas cap overlying the oil zone and that in which the oil is being displaced by water. Displacement by Gas in the Presence of an Immobile Water Saturation A system in which gas is the displacing phase may be thought of as having two forces effecting the displacement process. These forces are the gravitational force and that force exerted by the displacing gas. The gravitational effects control the displacing efficiency of the gas. The gravitational effect will be less at higher rates of flow, thereby reducing the effectiveness of the displacement of the oil by the gas. The more efficient displacements occur at flow rates which are less than the gravity free fall rate. Capillary forces can be neglected without materially changing the magnitude of the gas saturation. The Mile Six pool is used herein to illustrate the calculating procedures in evaluating gas drive-gravity drainage field perfomlance. These calculations represent the determination of the gas-oil contact when the distribution of the hydrocarbon pore volume is considered. Two methods

By Rajashekhar Marthi

Lithium is a key component for future electric vehicle batteries and energy storage. The future availability of lithium to meet the growing demands remains in question. Around 60% of lithium resources exist in the form of continental brines. Traditional methods to recover lithium from brines use solar concentration with precipitation and have found limitations in lithium extraction due to interference of Mg in high Mg/Li brines. Thus, there is a need for highly selective adsorbents. Recently, spinel structured delithiated lithium manganese oxides have demonstrated promising results. However, due to the small particle sizes, it is economically difficult to recover the adsorbents and thereby limits industrial applications. In our work, LiMn2O4 ion sieve was synthesized and immobilized on diatomaceous earth. Fundamental adsorption studies were carried out in lithium buffer solutions to understand the nature of adsorption and kinetics. The adsorbents were also tested for recycle stability, as well as recovery of lithium from Great Salt Lake water samples.

By Songsong Wang

Recently, replacing Pierce-Smith converting process with the oxygen bottom-blowing continuous converting technology has become a new research focus. Based on the principle of Gibbs free energy minimization, the thermodynamic model of oxygen bottom-blowing continuous converting multiphase equilibrium system has been established. The elements distribution behavior is calculated at the same burden composition and operation parameters as the industrial production. The results show that the absolute errors of the mass fraction (wt%) of Cu, Fe, S, Pb, Zn, As, Sb, Bi in crude copper are 0.06, 0.0030, 0.070, 0.38, 0.39, 0.020, 0.017, 0.034, 0.010, respectively, and the absolute errors of the mass fraction (wt%) of Cu, Fe, S, Pb, Zn, As, Sb, Bi in slag are 0.53, 0.81, 0.020, 0.23, 2.5, 0.0048, 0.0010, 0.0030, 1.49, respectively. The calculated results agree well with the actual industrial production data, indicating that the model can be well applied in the oxygen bottom-blowing continuous converting practice.

By J. Grogan

Leaching of galvanized steel coatings allows the steel substrate to be used as a zinc-free scrap source to steel and iron furnaces. In this study the behaviors of sulfuric acid leaching solutions are investigated. The ranked significance of the variables are shown to be acid concentration > temperature > zinc concentration. Examination of the leaching mechanism finds the rate-limiting step to be the cathodic hydrogen reduction reaction. This rate is not only influenced by acid concentration, but also by the hydrogen reduction exchange current density. Dezincing leaching rates are improved by taking advantage of the higher exchange current density of the iron substrate versus the zinc coating. This is accomplished in practice by increasing the exposed interfacial zinc:iron surface area through shredding. Also, a leach control mechanism is proposed through online monitoring of the zinc-iron couple mixed potential.

By Zachery Zanetell

Flotation circuit performance has become increasingly more challenging due to the complexity of available ore sources. To optimize value mineral recovery, the mineralogical composition of the ore should be evaluated and understood. Utilizing a variety of mineralogical and analytical tools, flotation processing challenges can be overcome and potential limitations understood. In this paper, several case studies will be discussed in terms of the value that has been provided through the use of mineralogical analysis to optimize flotation performance.

By Anthony Harding

In a world of technology and electronic communication, it is easy to forget what engineers do best with a problem: sitting around a table, exchanging views and ideas with sketches and respecting everyone?s view. This was the approach adopted in the project to arrive at a solution for the cross passage opening sup-port for the Seattle University Link Extension. Schedule and space constraints usually impede concurrent cross passage excavation and tunnel boring machine (TBM) operation. And where the space is constrained, opening support solutions that maximize available cross sections are of great benefit. While there are a number of solutions that minimize space, some of these solutions can require expensive steelwork and extensive drilling and fixing. However, following a detailed round-the-table discussion of the options and constraints, it was identified that a shotcrete shell would not only limit obstruction of the space during installation, but also permit easy installation, particularly around services, and avoid costly steelwork and drilling and fixing.

By Karin Soldenhoff

Recovery of uranium in conventional ion exchange circuits, using strong base or weak base resins containing quaternary or tertiary amine functional groups, is based on an anion exchange mechanism. In saline liquors, chloride competes with uranium for the active resin sites and reduces resin loading. This results in significant negative impacts on the IX process in terms of plant throughput and operating costs. In this paper we present the results of a study on the recovery of uranium from an acidic in situ leach liquor containing approximately 9 g/L chloride. A range of resins was tested, and a high capacity strong base resin was identified with significantly enhanced loading compared to conventional resins. Other process-relevant criteria such as loading kinetics and elution efficacy are also discussed. The process developed was successfully tested during a recent ion exchange pilot plant operated in conjunction with a field-leach trial.

By Pekka Taskinen

The converter-less nickel matte smelting technology (DON) adopted more than 20 years ago in Boliden Harjavalta smelter has been since that applied successfully to the processing of large number of nickel sulphide concentrates of various Ni-to-Cu ratios and MgO contents. The operational point of the technology is far from the conventional primary nickel smelting in the smelting-converting route. Therefore, a careful scouting of distribution equilibria of the base and trace elements in the smelting conditions of DON process has been conducted, in order to obtain quantitative information about the equilibria and thermodynamic properties of the nickel mattes at low iron concentrations, less than 10 wt% [Fe] in matte. The series of investigations has included novel experimental and analytical techniques for increasing the reliability and sensitivity of the phase equilibria as well as the element distribution observations carried out in typical high-grade nickel matte smelting conditions.