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By J. E. Sepulveda

Tar sand deposits in the. Stare of Utah contain more than 25 billion barrels of in-place bitumen, Although thirty times smaller than the well-known Athabasca tar sands, Utah tar sands do represent a significant domestic energy resource comparable to the national crude oil reserves (31.3 billion barrels), The term "tar sand" refers to a consolidated mixture of bitumen and sand, Based upon a detailed analysis of the physical and chemical properties of both the bitumen and the sand, a hot-water extraction process for Utah tar sands is currently being developed in our laboratories at the University of Utah. This process involves intense agitation of the tar sand in a hot caustic solution and subsequent separation of the bitumen by a modified froth flotation technique., Experimental results indicated that, for a given tar sand sample, percent solids and caustic concentration were the two most important variables controlling the performance of the digestion stage, These variables were identified by means of an experimental, factorial design, in which coefficients of separation greater than 0.90 were realized. Although preliminary in nature, the experimental evidence gathered in this investigation seems to indicate that a hot-water extraction process for Utah tar sands would allow for the efficient utilization of this important energy resource.

Jan 1, 1978

By H. M. Brennecke

A new hydrometallurgical process has been developed to recover copper from sulfide ores. Copper is leached in a staged reactor system utilizing nitric and sulfuric acids at 105°C. Iron is removed from the pregnant liquor as a jarosite and cathode copper is electrowon directly from the purified pregnant liquor. The spent electrolyte is recycled. Nitrogen oxides evolved from the leach are reconverted to nitric acid and are also recycled. Sulfur is rejected as S°, jarosite and gypsum. The process is highly versatile and can recover precious metals, molybdenum and zinc, when these elements are present. Continuous, integrated, semi-pilot plant operations using chalcopyrite ores demonstrated 99% copper leaching and production of cathode grade copper. Economic evaluation shows that the process is competitive with pyrometallurgical and other hydrometallurgical processes.

Jan 1, 1978

By F. P. Haver

The Federal Bureau of Mines investigated aqueous electrolysis as a means for reducing lead chloride prepared by ferric chloride leaching of galena concentrate: NaC1 PbS + 2FeC13 ? PbC12 + 2FeC12 + S°. During electrolysis, metal was produced from solid lead chloride in contact with the cathode rather than from lead in solution. Relatively high current densities--up to 300 amp/ft2--were possible when operating in this way. A very simple cell, having a horizontal lead cathode at the bottom and a vertical graphite anode at the top, was employed. Lead chloride crystals, covering the cathode, were converted to metal powder during electrolysis, and chlorine gas or FeCls was produced at the anode, depending on the electrolyte composition. Electrolytes tried included aqueous solutions of HCI, NaCl, NH4Cl, and FeC12-NaC1. Optimum results (96-pct current efficiency, 0.23 kwhr/lb Pb) were obtained with 20 pct HC1 at 25° C, using a current density of 15 amp/ft2 and an electrode spacing of 1 inch. When the current density was increased, the energy requirement increased also but only to 0.41 kwhr/lb at 150 amp/fr3 and 0.58 kwhr/lb at 300 amp/ft2.

Jan 1, 1978

By Wm. I. Weisman

Sometimes in assessing where we are and where we are going it is informative to take a look at where we have been. Whether or not it adds to our understanding of the present, I think it may be interesting to review some of the past history of our industry. As a starting point I chose to use the famous Paley Commission Report, formally known as "The U. S. President's materials Policy Commission -Resources for Freedom."(l) The Paley Commission report said "Fluorspar is an essential raw material for the steel, aluminum, and chemical industries." Of course this statement is still true. It also said, "United States known reserves of fluorspar would be sufficient for some 15 years at present rates of consumption--about 426 000 short tons in 1960. Projected consumption for 1975, however, is several times as great, and reserves in other free countries do not appear adequate to supply United States deficiencies during the next 25 years." This simply demonstrates how even the most learned and competent people can observe all the facts avail-able to them at a given time and yet be unable to predict the future very accurately. We all know that reserves in other countries are more than adequate to supply the United States today, 25 years since the report was published. In fact, the report estimated free-world reserves at something over 36 million tonnes (40 million short tons). Contrast this with 246 million tonnes (271 million short tons) estimated as total world reserves from the section on fluorspar from Commodity Data Summaries of 1974, published by the Department of the Interior. (2) The Paley Report discusses other matters pertaining to fluorspar that are still of interest, such as improving mining methods. Furthermore, it certainly did a good forecasting job in noting that greater recycling should become possible in the aluminum industry in regard to fluorine lost in wastes and also concerning the substitution of fluorspar in the steel industry by other fluxing materials. It also suggested that non-fluorine containing propellants should be investigated as a replacement of those containing fluorine as a conservation matter. Some discussion was devoted to recovering the fluorine content of phosphate rock, which is being practiced today, but was in its infancy in 1950.

Jan 1, 1978

By Langtry E. Lynd

The titanium dioxide pigment industry in the United States has always relied to varying degrees on imported titanium concentrates. Dependence on foreign ilmenite was especially high (generally over 85% of consumption) until 1942, when large-scale U.S. production of ilmenite began, and has since ranged from 12% to 47%. Rutile import reliance was generally in the 45% to 80% range until the early 1960's, when increased use in the chloride pigment process raised dependence on imported rutile to over 90% in most years since 1963. Import reliance of zircon, obtained almost entirely as a byproduct of titanium mineral production, has generally ranged from about 30% to 65% of consumption. This paper will examine the history of U.S. sources of these heavy mineral commodities, and will discuss the potential U.S. future supply in view of changing industrial uses and processes and the anticipated development of new heavy-mineral-sand processing operations, such as those at Richards Bay in the Republic of South Africa and in Sierra Leone.

Jan 1, 1978

By S. E. Khalafalla

The ability of potentiometric, gas-sensing electrodes to reliably monitor free gaseous molecules in solution has been recently demonstrated. A gas such as sulfur dioxide from a dilute sample solution diffuses through a hydrophobic, gas-permeable membrane to an internal filling solution. The latter solution contains a sufficiently large excess of sodium bisulfite, the concentration of which can be considered constant regardless of the quantity of sulfur dioxide entering by diffusion. The electrode response is essentially due to the liberated hydrogen ions from the bisulfite-sulfur dioxide equilibrium. This Bureau of Mines report describes a new technique used to detect the formation, and to estimate the stability constant, of gas-molecule and gas-ion complexes in solution, as part of an effort to minimize the undesirable environmental impacts associated with mining and mineral processing. Although the unknown activity coefficients of the neutral and ionic species in the external solution complicate the quantitation of results, methods to circumvent these difficulties are presented. The technique is based on the isometric shift of the Nernst diagram of ion-selective electrodes to higher concentrations relative to the standard aqueous calibration curve. The method is applied to detect and estimate the formation constant of a sulfitocitrate complex, and agrees well with an independently determined stability constant of the disulfitomercu-rate complex.

Jan 1, 1978

By John M. Hird

Texasgu1f's Lee Creek Mine in Eastern North Carolina is usin8 a combination Dredge-Dragline method for mining deep phosphate ore at a rate of 8.5 million tons per year. The matrix is thick, uniform in grade, and is processed into agricultural products. As in many other good mineral deposits, there are tough obstacles to overcome in recovering the ore. The deposit is in an area with a land surface of about ten feet above sea level, is close to tidewater, is overlain with 90 to 130 feet of unconsolidated overburden, and is underlain by an artesian aquifer with over 140 feet of natural hydrostatic head at the bottom of the bed, The upper 40 feet of overburden will not support stripping equipment and is unstable when cast as spoil. Barriers are emplaced to prevent flooding from hurricane tides. The ground water problems have been successfully controlled by pumping 60 million gallons per day from the aquifer. Only recently have the severe ground problems been overcome by this unusual Dredge-Dragline combination of mining equipment.

Jan 1, 1978

By Rolf A. Knopp

This paper discusses how design differences in FLP diesel equipment in underground coal mines came about. "Design standards" tend to create differences between countries while fostering uniformity among products of competing manufacturers. "Performance requirements," on the other hand, tend to eliminate differences between countries while encouraging competitive development of better products. Examples of regulations from the U.S., Canada. Great Britain. Australia. South Africa, etc., are used to illustrate differences in the design and certification of diesel equipment for underground coal mines.

Jan 1, 1978

By S. O. Ogden

As most of you have probably surmised from the title of my paper, I am here today to talk with you about the use of diesel engines in the American mining industry and whether or not the free choice to use such equipment will continue to be available to mine operators. Of course, I will present to you my prepared remarks, however, these remarks may be essentially academic in light of a news release, parts of which I would like to read to you. Washington, D. C., The Department of Health, Education, and Welfare today announced proposed new regulations to reduce occupational health risks to workers in the U. S. mining industries by requiring the removal of all diesel powered equipment from American mines by December 31st "While we do not have complete and conclusive information to quantify these health risks we feel it is prudent to undertake this restriction on the use of diesel powered equipment without waiting for the completion of studies that are currently underway to identify and quantify these health risks," said a Department spokesman. HEW has been concerned about the health risks of diesel emissions in the underground coal mines for some time and have investigations underway designed to conclusively demonstrate the nature and magnitude of any health risks. However, HEW has decided to proceed with these regulations without waiting for the final results of these investigations. Further, HEW feels there is sufficient probability that diesel health risks do exist in all mining applications and consequently, the proposed regulations will apply to all surface and underground mining operations. It goes on a little further and indicates that due to the necessity of finalizing these regulations without delay, a period of fifteen days has been provided to receive comments regarding these proposed regulations.

Jan 1, 1978

By Gary L. Mowrey

Visible and sometimes audible indications of excessive underground rock pressure such as pillar fracturing, squeezes on chocks, and "roof talk" are familiar to mining engineers. Such signs often precede rock failure on a larger scale and therefore may be used as a warning. Nevertheless, these subjective observations do not provide an adequate means of evaluating the existing rock pressure conditions in a mine. One method which appears to be extremely promising in determining the stability of geologic structures in general is that of monitoring their associated micro seismic activity. Mining engineers generally agree that during the process of rock deformation and failure small-scale seismic ("microseismic") vibrations are produced in the rock itself. These transient vibrations propagate through the rock structure and may be detected at a considerable distance from the failed rock by employing suitable electronic monitoring equipment. Hardy (1) has presented a detailed review of microseismic research in the mining, petroleum, and geoscience areas, and it is apparent that relatively little application of micro seismic techniques have been made in coal mines. This is especially true in North America since here most coal mines are fairly shallow and consequently are not generally subjected to excessive stresses. Furthermore, strict Federal and State mining laws limit the use of electrical equipment in coal mines complicating the use of the necessary monitoring facilities. In terms of both mine safety and economics, monitoring microseismic activity appears to be invaluable in the detection and location of over-stressed pillars and unstable roof conditions caused by development and production work. In 1970 The Pennsylvania State University Rock Mechanics Laboratory became involved in a research project, sponsored by the U.S. Bureau of Mines, to investigate the feasibility of using microseismic techniques to detect and to locate potential regions of instability around a longwall coal-mine operation [Hardy and t10wrey (2); Mowrey (3)]. In this study geophones (velocity gages) located in an array of shallow boreholes drilled from the surface above the active area of the longwall were employed to detect microseismic activity, and a mobile micro-seismic monitoring facility was used to condition and record this data for later analysis. This project is unique in that measurements were made from near-surface geophones rather than geophones installed on the mine itself. Two advantages are apparent, namely that (1) there are no electrical limitations on the monitoring system and that (2) mining operations can continue normally because there is no monitoring equipment or cables in the mine.

Jan 1, 1978

By F. H. Buttner

Commodity currency intrigues most of us because of the problems it offers to solve for the Third and the First Worlds. What problems might be solved, if commodity currency were to be adopted in the Third World? That is really the question we are probing here right now. It would take a while to think through all their subtle consequences of this question, but, off the top, it might well have at least three important impacts. Most important of these to this audience is relief from unfair Third World competition. Second, it might well liberate Third World economies from financial indebtedness to the First World and give them freedom from the liquidity limitations. The third benefit is that it might help relieve World trade tensions. All three benefits are interrelated. We could start our speculations on the application of commodity currency from anyone of these starting points. But let us use the starting point most important to you, unfair competition to the U.S. mining industry. From there we might wind up with some thoughts on things you, yourselves, can do to improve things.

Jan 1, 1978

By R. D. Brown

In the spring of 1977, Revenue Canada announced its intention to proceed in 1978 with a plan to impute a taxable benefit on interest-free and low-interest loans provided to employees. Such loan arrangements are often an important aspect of the compensation packages provided by many companies to their employees. Since the original announcement, there have been many submissions to Revenue Canada opposing this change, and the Finance Minister has now brought down a compromise solution with the introduction of a proposed amendment to the Income Tax Act. The amendment, which would not take effect until the 1979 taxation year, would require an employee, a shareholder or a related person to include a benefit in income measured as the difference between the interest on any such loan computed at bank prime rate and any interest actually paid. Only the amount of such a benefit in excess of $500 in a particular year would be required to be included in income. Of particular interest is the exclusion from these benefit rules of loans up to $50,000 in respect of the purchase of a house on the relocation of an employee and loans provided for the purchase of shares of an employer corporation.

Jan 1, 1978

By Jr. Smith

Borates have been mined in the desert areas of California and Nevada for more than 100 years. To about 1890, playa surface mining provided the chief sources of boron minerals. Underground mining of colemanite and later of borax and kernite was predominate until about twenty years ago. Open pit mining of the large deposits of borax and kernite near Boron, California has been most significant for the past twenty years. Mining of colemanite in the Ryan, California area, near Death Valley, began in 1907. Following the discovery of the large deposits in the Boron area (about 1957), mining in the Death Valley area became nearly nonexistent. Only small tonnages were mined for special uses. Little mining was done in the Boraxo area near Ryan. The first claim was made in about 1915 In 1960 the area became the property of the Kern County Land Company, which was acquired by Tenneco Oil Company in 1967. In 1976 the various borate properties and claims in this region were acquired by American Borate Corporation. The open pit mine is now approximately 400 feet (121.9 m) deep, 3000 feet (914.4 m) long and 1000 feet (304.8 m) wide. The borates in the Boraxo pit consist primarily of three minerals. These are about 50% coiemanite (C2B6O11' 5H2O), about 40% probertite (NaCaB5O9.5H2O), and 10% ulexite (NaCaBcO9.8H2O). The colemanite, along with boric acid and high-grade coiemanite ore from Turkey provide the only sodium-free borates for production of textile grade fiberglas. When heated to its decomposition temperature, colemanite decrepitates to a fine powder. This provides the basis for the concentration process. The gangue minerals in this deposit are primarily calcite and clays, including bentonite. The ore body has a very low arsenic content.which is a desirable feature. Test work had been done with samples prior to the results discussed herein. This paper will discuss results of test work which were the basis for erection of a plant, and the subsequent plant operations.

Jan 1, 1978

By Joklik, G. F.

Most publicity about the copper industry nowadays is focused on the adequacy of ore reserves and on excessive mining capacity. These concerns, stemming from public awareness of actual and potential shortages and oversupplies, relate to production rather than consumption. Perhaps the reason for this one-sided view is that copper is thought of as a commodity which is conspicuously traded in world markets, rather than as one of many industrial materials that serve today's rapidly changing technology. Copper differs from other widely traded commodities in that its real cost of production has progressively increased since World War 11. The reasons for the increase are identifiable by analyzing operations in one of the world's large producing centres, the copper province of Arizona. Another respect in which copper differs from some other commodities is that increases in demand occur less automatically in the case of copper than they tend to in commodities whose consumption is more directly related to population growth. The copper industry's current inability to generate and attract needed investment capital is attributable to these differences between copper and other commodities; it suggests that the concept of copper purely as a commodity is outdated. The key to the problem is better integration between the activities of copper producers and users. Depending on circumstances, integration takes various forms- for example, investment tied to long-term sales con- tracts between producers in developing countries and consumers overseas; common ownership of producing and manufacturing facilities in industrialized nations like the U.S.; and consumer-oriented research and marketing by the copper producers.

Jan 1, 1978

By James R. Evans

Forecasting demand is an art as well as a science, and much personal judgment is required. National forecasts made for sand and gravel, crushed stone, and/or aggregate may be misleading or unhelpful locally. This is because of significant variation in demand within different geographic and/or political areas in the United States, and/or the use of an inadequate data base and forecasting methodology. The best forecasts may be made for local or regional market areas, irrespective of geographic or political boundaries, provided a proper data base is available. The Bureau of Mines compiles detailed statistics on commodities sold or used in the construction industries and, therefore, is in an advantageous position to make national aggregate demand forecasts.

Jan 1, 1978

By L. S. Rubin

The efficient and acceptable disposal of fine coal refuse (28MxO) is one of the highest priority problems facing the coal industry today. For many years the established system for the disposal of this fine refuse slurry has been to concentrate the solids in a static thickener and pump the resulting 20-40% solids underflow to lagoons or impoundments. Although this technique has served the coal industry well, increasing environmental concerns and refuse related disasters, such as Buffalo Creek, West Virginia and Aberfan, Wales, Great Britain have resulted in federal and state regulations which now control fine refuse disposal methods. As a consequence of these regulations, the capital costs of constructing, maintaining, and operating regulatory complying impoundments has become in many cases economically unattractive. Areas processing topologies similar to those coal preparation plants of the Appalachians are particularly burdened by these regulations and are consequently turning to alternatives for handling and disposal of their fine coal refuse. The basic requirements of impoundment alternatives as defined by environmental and plant demands are: (1) A relatively solids-free liquid (1000 ppm or less) to serve as plant make-up water in a "closed circuit" system, and (2) a sufficiently dewatered solids product which can be combined with the coarse refuse to form a compactable stable land-fill.

Jan 1, 1978

By F. L. Bazzanella

Cyprus Pima has two concentrators, one with a conventional crushing-grinding circuit and the other using semi-autogenous grinding followed by ball mills.

Jan 1, 1978

By Robert P. Vinson

The Bureau of Mines investigated the presence and extent of methane accumulations in mine roof cavities using a full-scale mine model. Methane was released at a constant rate into the roof of a cavity built onto a 700-ft wind tunnel. Two box-shaped roof cavities were used in the study: one had a volume of 114.7 cu ft; and the other had a volume of 57.3 cu ft. Methane concentration was measured at 28 sampling points in the cavities using 21 different combinations of gas emission rates and air velocities. Brattice hung in the cavity helped reduce methane concentrations without auxiliary ventilation. It was also found that the effective ventilation rate increased by a factor of 40 in the large cavity and by a factor of 20 in the small cavity when air velocity was increased from 100 to 600 fpm.

Jan 1, 1978

By J. L. Thompson

Lime made in a coal-fired, rotary kiln has two distinct parts: the interior of the pebble which constitutes about 90% to 95% of the mass, and the surface dust layer which is the remaining 5% to 10%. Uncalcined carbonate and impurities in the product may be present and will not contribute to the hydration reaction. Sulfur, in the form of calcium sulfate, inhibits the hydration reaction out of all proportion to its actual weigh-percent concentration (perhaps more than 100 times). If the stone contains dolomite, this will also inhibit the reaction as its rate of hydration may be nearly 3 orders of magnitude slower than that of calcium oxide. Early in the hydration reaction dolomite appears practically inert, but given sufficient time, it will hydrate. The heat of reaction is nearly the same as for calcium oxide, but the time necessary for complete hydration may be hours; whereas for calcium oxide it is only fractions of a second. The dust layer on the surface also inhibits hydration as it contains a collection of compounds which have low heats of hydration. This layer can tie up additional calcium and delay or prevent its reaction. In addition to these chemical processes, an important physical characteristic of the lime is its specific surface area. This is effected by the thermodynamics of calcination and the original stone grain chemistry. All of these factors are agglomerated in the gross slaking rate of lime. The total hydration of the chemical complex that is called commercial lime can be more easily understood by considering the individual reactions and combining them to form a more comprehensive picture of the situation. Calcium oxide and magnesium oxide hydrate similarly, differing only in their reaction kinetics. Dolomite, however, reacts differently than a simple mixture of calcium oxide and magnesium oxide as its hydration is strongly influenced by calcination thermo-dynamics and stone grain structure. Finally, the dust hydration and composition should be examined Understanding these reactions enables one to examine hydration reaction graphs with more insight into the factors which determine their shape.

Jan 1, 1978

By H. W. Parsons

Several low-temperature, dry chlorination processes for the treatment of sulphide minerals are reviewed, in a chronological order. These processes include the following: the Swinburne-Ashcroft, Baker-Burwell, Maim, Comstock-Wescott (Aldermac) and the Mitterburg Mining Process. Dry chlorination investigations at the Canadian Mines Branch (now CANMET) and the U.S. Bureau of Mines are discussed, as is a proposed process by the South Africa National Institute for Metallurgy. The techniques used in the process are discussed, as are the shortcomings, problems and failures of the methods.

Jan 1, 1978