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By R. E. Chaney

This report summarizes the research on the Strategic and Critical Materials Program tasks conducted at the Idaho National Engineering Laboratory (INEL) between Mdy 1983 and April 1984. The work is divided into two areas: 1. Production Technologies - Tasks directed at developing advanced extraction technologies ? Biologically-Assisted Minerals Processing ? Metal/Gas Reactions and Thermal Plasmas ? Dehydration of Aluminum Chloride Hexahydrate. 2. Conservation/Substitution Technologies - Tasks directed toward establishing the technical processing base which will permit the use of advanced materials ? Joining of Rapidly Solidified Alloys (RSA) ? Joining of Silicon Nitride-Based Ceramics ? Nondestructive Evaluation of Ceramic and RSA Joints and Materials.

Jan 1, 1984

By Larry G. Stolarczyk

This report deals with information regarding a new Medium Frequency (MF) Wireless Communication System for underground mines. This new telecommunication system works on low loss electromagnetic wave propagation modes which allow it to provide quality radio communications almost anywhere in a mine. Tests show the MF system can provide improved safety and managerial control, increased productivity, better organizational team-work and reduced maintenance cost; furthermore, MF's unique design allows for easy installation at a minimum cost. This paper covers the following: 1) MF design plan, 2) Overview of mine radio communications systems, 3) Preparations needed for designing an MF system, 4) MF equipment, 5) MF installation, 6) MF design considerations, 7) MF design specifications, and 8) Recommendations dealing with MF system. Experiments in four mines are illustrated to demonstrate the success and viability of the MF system. The mines range from small (500 tons/day) to large (67,000 tons/day) capacity and represent several different mining methods. The MF Wireless Communication System represents an advancement in mining communication and the groundwork for other advanced mine systems.

Jan 1, 1984

By M. Yamine, R. J. Ring, D. J. Waters

"An experimental program has been carried out by the Australian Atomic Energy Commission to compare the effectiveness of Caro's acid as an alternative oxidant to pyrolusite in the leaching of uranium ores from the Alligator Rivers region of northern Australia. Batch leaching tests on Ranger, Nabarlek, Koongarra and Jabiluka ores showed that uranium extraction was unaffected by choice of oxidant, but that Caro's acid reduced acid requirements by 15 - 25%. Lime requirements for neutralization of tailings liquors were reduced by 20 - 30%.The batch studies were extended to a four-stage continuous leaching circuit with a capacity of 400 gore h-I. Comparative leaching tests confirmed the reagent savings obtained in the batch tests. Following these encouraging laboratory results, lnterox Chemicals Pty Ltd carried out plant trials using Caro's acid. Reagent savings in the mill were similar to, or better than, those obtained in laboratory test work. The trials also established that Caro's acid has a number of operational advantages over pyrolusite.IntroductionUranium is most commonly extracted from its ores by leaching in sulphuric acid. Simple hexavalent uranium oxides and compounds are readily soluble but uranium in the tetravalent form is insoluble and must be oxidized for dissolution to occur. The most commonly used oxidants have been sodium chlorate and manganese dioxide. They act indirectly by maintaining iron as the ferric ion which oxidizes uranium by a surface electro- chemical reaction. An Fe3+ concentration of about 1 - 2 g L-I is usually considered adequate for the effective dissolution of uraninite(1)."

Jan 1, 1984

By Lloyd W. Trevoy

Syncrude Canada Limited is presently studying commercial production of heavy minerals from plant tailings of the openpit A lhabasca tar sands operation. When tar sands are processed and upgraded to synthetic crude oil, heavy minerals can be removed f rom the extraction circuit and beneficiated to provide concentrates of zircon and titanium minerals. Calculated recovery rates indicate that crude oil production capabilities of 105,000 barrels per day would provide 26,000 tonnes of zircon and 114,000 tonnes of titanium minerals annually. The titanium minerals concentrate is a mixture of ilmenite, leucoxene and rutile; it could be used as recovered or upgraded to synthetic rutile. With the consrruction of further synthetic crude oil plants in Western Canada, a large reserve of heavy minerals will become available.

Jan 1, 1984

By PETER O. SANDVIK

The Cargill deposit, located 32 km south west of Kapuskasing, Ontario, was discovered by International Minerals and Chemical Corporation in 1975 and has been evaluated through an extensive program of drilling, chemical analyses, metallurgical tests and engineering and economic studies. The Cargill alkalic complex, comprising mainly carbonatite and pyroxenite-amphibolite rocks, was intruded into the rift system of the Kapuskasing magnetic-gravity high. Weathering and leaching under assumed temperate to cool climatic conditions plus faulting, shearing and/ or initial petrographic variations within the carbonatite developed a small, locally confined karst system. This resulted in a thick enriched leached carbonatite zone capped by troughs and sinks, and filled with a residuum of apatite, goethite, clay and other minerals. Residuum thickness ranges from nonexistent on ridges to 170 m in troughs and sinks. Apatite values are 5 to 15% in fresh carbonatite, 20 to 40% in leached carbonatite and 20 to 98% in residuum. A tentative open-pit mine designed for preliminary feasibility studies is estimated to contain 62.5 million tonnes averaging 19.6% P20 5.

Jan 1, 1984

By G. H. K. Pearse

Sulphur is derived from both 'voluntary' and 'involuntary' production. The former category includes sulphur obtained from elemental sulphur deposits and from pyrite and gypsumanhydrite deposits. Sulphur in the latter category is produced by pollution abatement at fossil Juel plants and from treatment of metallic sulphides. Canada is the world's largest sulphur exporter and third largest producer. Main resources of Canadian sulphur are sulphurous fossil fuels, metallic sulphides and native sulphur. Only the first two sources have produced sulphur in Canada 10 date; the first source accounts for over 85% of total Canadian production. Future sulphur sources will be derived increasingly through pollution abatement and decreasingly through voluntary production.

Jan 1, 1984

By RALPH R. STEA, John H. Fowler

Clay, quartz sand and lignite deposits overlie Carboniferous rocks in central mainland Nova Scotia. Recent evidence indicates that these deposits are fairly extensive. Sands consist of almost pure angular quartz grains. Clays are highly plastic and range in colour from black through grey and blue to mottled red and white. Palynologica/ information dates the sediments as Ear{y Cretaceous, and mineralogical studies show them to consist primarily of quartz, kaolinite and mica. There is not yet enough evidence for detailed stratigraphic description, but sequence and thickness of sediments are known to vary greatly over short distances. Drill logs from Musquodoboit Valley recorded Cretaceous sediments at 168 m thick. Of the three active pits in Cretaceous sediments of central Nova Scotia, two are for silica sand production and are located at Elmsvale and Brazil Lake while a third pit at Shubenacadie produces clay for manufacture of structural clay products.

Jan 1, 1984

By R. Bruce Graham

The formation, evolution and classification of peat bogs is discussed. Factors resulting in the internal and external morphological changes in a bog are described. The fibrous, absorptive and sterile properties of peat moss account for its widespread use in horticulture and related fields. These properties also account for its usefulness as a binder in pelletizing, as an insulating material in bat tons and in panel construction. Peat, the humijied product of peat moss is used in market gardening and sod growing. It is utilized in Europe as fuel. It is a source of activated carbon and gas. Potentially peat can be used to produce waxes, resins, tannins, cellulose, hemicellu/ ose, humic acids, lignin and hymatomelanic acid. At present other cheaper sources are available.

Jan 1, 1984

By Victor F. Hollister

Elemental sulphur occurs as aformational sedimentary deposit in Upper Devonian Wabamun evaporites near Coronation, Alberta. The deposit developed in a stratigraphic jacies-change lrap; it is assumed that petroleum reacted with anhydrite to form sulphur, calcite, hydrogen sulphide and other reaction products. The deposit contains about 362,800 tonnes of sulphur and lies at a depth of 1200 m. The Coronation deposit is expected to be geologically typical of such other native sulphur deposits as may be found in Wabamun Group sediments. Widespread sour gas sulphur production f rom the Wabamun suggests the possibility that additional native sulphur deposits will ·be found.

Jan 1, 1984

By PAULL. BROUGHTON

Commercial deposits of sodium sulphate are harvested from alkaline lakes that are widespread throughout semi-arid southern Saskatchewan and adjacent southeastern A lberta. Concentration of sodium sulphate occurs in undrained basins under semi-arid conditions. Precipitation runoff from land adjacen1 to 1hese basins leaches 1he mineral from the soils and carries it in solu1ion 10 the basins. The process may be largely subsurface, wherein spring seeps feed basins associated with buried (preg/acial) river valleys. Evapora1ion during summer concentrates salts in the brines, and chilling of water below sa/Uration poin1 during win1er resu//s in deposi1ion of sodium sulpha1e (mirabili1e) crystals on lake bo//oms. Sodium su/pha1e, commercially known as sa/1 cake, ranks second only 10 po1ash in cen1ral-wes1ern Canada's nonme1allic mineral production. // is recovered from su,face brines, directly from intermittenl salt beds, and, until recently, by solution mining of shallow subswface deposits. Sodium sulphate is extrac1ed from seven alkaline lakes and sail f/a1s in Saska1chewan and one in Alberta. Annual produc1ion is approxima1e/y a halfmillion tonnes. Manufacture of kraft paper is the mos1 significanl marke1 for salt cake, but addi1ional quantifies are used in the glass and detergent manufac1uring indus1ries.

Jan 1, 1984

By BARRY BANNATYNE

Gypsum in Manitoba is quarried from the Jurassic Amaranth Formation a1 Gypsumville and Harcus; it has been mined near Amaranth and Silver Plains. At Gypsumville, gypsum is carbonate- free but has thin clay laminae between gypsum layers; the rock is folded in places, and some anhydrite is present. At Harcus, gypsum contains scattered dolomite, both as patches in a penemosaic pattern and as thin layers; small chalcedonic concretions also can be found. The quarry at Harcus was opened late in 1978 and currently produces about 100,000 tonnes annually. The two inactive mines near Amaranth operated from 1932 lo 1963 and from 1967 to 1970, and contain a central anhydrite layer. The mine near Silver Plains was flooded from an underlying artesian aquifer in 1975 and has not been reopened. Manitoba gypsum is used in cemem plants in Mani1oba and Saskatchewan and in wallboard plants in the three Prairie Provinces.

Jan 1, 1984

By LUKE O. LINDOE

A major clay products industry in the Medicine Hat area since before 1910 has maintained a continued interest in the clays of the Cypress Hills. For the first forty years the materials used were local red-burning Cretaceous and Pleistocene clays and sands and high-quality stoneware clays of the Whitemud Formation at Eastend, Saskatchewan. Recently a much broader spectrum of raw materials has been brought into use. Including the exposures of the Eagle Butte structure, the Cypress Hills present a 1200 m section of clay-like sediments. Of this 1200 m about 94 per cent, the high montmorillonite shales of the Upper Cretaceous, can be considered useless, or nearly so; the remaining six per cent, all fresh-water beds, presents a wide variety of potentially useful materials. The development of these clay resources is complicated by deep surface creep on the south flank of the Cypress Hills, by largescale slumping on the north flank and by a structural complex in the Eagle Butte area.

Jan 1, 1984

By JOHN DUNFIELD

Good quality sphagnum peat bogs occur across Canada in areas of ample rainfall and cool, temperate climates. Early peat production techniques were restricted primarily to hand digging blocks of peat and piling them up to be dried by sun and wind. Suburban de velopment in the 1950s and the concomitant spread of home gardening triggered a dramatic growth in peat demand; labour costs rose in the same period. Peat production techniques had to alter accordingly. The three mechanical inno vations attempted were hydraulic mining, mechanical block digging and vacuum harvesting. Of these, the last method pro ved the most successful in Canada and is used to harvest 80% of Canadian peat production. Escalating transportation costs are the most important feature affecting future development of the Canadian peat industry.

Jan 1, 1984

By MAX VOS

Lithium is the lightest and electrochemically most reactive of all metals. Renewed interest in lithium coincides with research in lithium batteries and power generation by atomic fusion. Ontario lithium resources are contained in spodumene pegmatites that can form where medium- to high-grade metamorphic volcanic-sedimentary formations are intruded by pegmatite and porphyritic granitic rocks. Spodumene pegmatites occur in at least twelve locales throughout northern Ontario, all of which are in the Superior Province of the Precambrian Shield. Tantalum, cesium, rubidium, beryllium, niobium and tin also were noted with lithium in spodumene pegmatites. Considerable potential remains for discovery of additional lithium and rare-element pegmatites in northern Ontario.

Jan 1, 1984

By R. K. Collings

Mineral wastes from the mining, metallurgical and chemical processing industries in Canada amount to about 800 million tonnes annually. Such wastes often are largely non-metallic in composition and are of interest for traditional non-metallic mineral uses and applications. Mineral waste disposal and maintenance are costly; furthermore, these wastes may pollute groundwater, rivers and lakes. These factors and an increased appreciation of the potential utility of some mineral wastes have stimulated research in this area.

Jan 1, 1984

By ANNE FUZESY

Soluble potassium salts in bedded underground salt deposits supply most of The world demand for potassium f or agricultural and industrial use. The potassium salts, sylvite and carnallite, were f irs, noted in drillcores in southern Saskatchewan during The search for oil and gas in ihe early /940s. Problems in shafi sinking beset pioneering potash companies, however, and cominuous production did no, begin uniil 1962. Powsh deposits in southern Saskatchewan occur within ihe uppermost 60 111 of the Middle Devonian Prairie Evaporite a, depths in excess of 900 m. Four groups of po/ash-bearing haliie beds have been distinguished: the Esierha-::,y, White Bear, Belle Plaine and Paiience Lake members. Powsh deposiis extend a jell' kilomeires into Manitoba and south imo orth Dakoia and non heasiern Moniana. Individual potash-rich beds are extensive and consistent in grade and Th ickness. Local th ickening occurs where carnallite is the dominani poiash mineral. Th e preferred ore, sy lviniie, is a clean mixiure of sylvite and haliie. Carnalliie and insolubles are avoided wherever possible because of Their detrimenwl effects on mine stability, grade and refining. Sy lvin ite is exTracted by underground mining or brought TO swjace as brine in solution mining. Poiash is separaiedfrom halite byfloiation or sequential crystallization. The refined produci, potassium chloride, is employed as a fertilizer ingredient as well as in chemical and other industrial capaciiies. The ten poiash mines of Wesiern Canada all are in Saskatchewan and account for aboui 25 per cem of world production. Faciliiies are being expanded, and a new mine and refinery was planned for ihe Breden bury area. Deposiis in Manitoba also were being evaluaied.

Jan 1, 1984

By P. Trudel, M. A. . Cloutier

This lithogeochemical study demonstrates that the Gilman and Blondeau Formations in the Chibougamau area belong to a subalkaline suite of tholeiitic affinity poor in potassium. The Gilman Formation is composed mostly of basalts, with subordinate andesites and rare dacites, while the Blondeau Formation comprises all lithologies of the basalt-andesite-dacite-rhyodacite-rhyolite ensemble. Both AFM and Harker variation diagrams show that all these rocks originated by differentiation from the same magma reservoir, and are related to one volcanic episode, This study did not, however, identify hydrothermal alteration zones useful for regional geochemical prospect ion.

Jan 1, 1984

By P. Archer

The Blondeau Formation has been examined in a stratigraphic drill section at Barlow Lake. The formation contains pyroclastic flows and volcanogenic sediments throughout, but epiclastic sedimentary rocks dominate the upper parts of the section. Five distinct types of pyroclas tic flows are known in the section, as well as minor mafic lava flows. Volcanogenic sediments are commonly intercalated with the true volcanic rocks. Sedimentary rocks include fine-grained intraclastic sandstones, heterolithic sandstones and green and black shales. Interpretation of the origin and relative disposition of the volcanic and sedimentary rocks favours a model of near-emergent vulcanism in an upward shoaling environment.

Jan 1, 1984

By Y. Buro

The Bachelor Lake gold deposit occupies an ESE-trending, SW-dipping, silicified shear zone with hematitic alteration. It transects NE-trending, steeply dipping Archean volcanic formations and the O'Brien granite. Major W-SW and N- NE-trending faults have affected the ore zone and the emplacement of the granite intrusions. Movements along the WSW set may have opened the fractures filled by the mineralization. Gold is generally associated with pyrite. Its source, whether a granitic pluton or a volcanic sequence, is undetermined, but the granite probably provided the concentrating mechanisms through heat and hydrothermal solutions.

Jan 1, 1984

By A. Gauthier, J .. E. Muir, M. Cormier

Falconbridge's Lac Shortt gold deposit is located in Gand Township, some 25 km north-east of Desmaraisville, The deposit was outlined in i980 by a drilling program me conducted by Falconbridge Ltd. in a joint venture with Corporation Falconbridge Copper after three years of systematic exploration by Falconbridge Ltd. in the Desmaraisville area. The gold bearing structure had previously been drilled by three other exploration companies. As based on an underground development programme conducted by Corporation Falconbridge Copper, the "in-si tu" mineral inventory to a depth of 500 metres at a cut-off grade of 3.0 g/t is estimated at 1 937 605 tonnes at a grade of 6.4 g/t (uncut) and 6.0 g/t (cut). Regionally, the stratigraphy consists of thick sequences of volcanic and volcanosedimentary rocks intruded by numerous and voluminous mafic (gabbro), felsic (granodiorite, syenite) and anorthositic intrusions. Structurally, at least two fold sets and one major fault system (E-NE) are present. Minor fault systems oriented E-NE and N-NW also occur. Mine stratigraphy can be divided into 1) - the hangingwall; 2) - ore zone; 3) - footwall. Hanging wall rocks include: a) green lapilli and blocky tuff b) transition zone c) green mica crystal tuff and d) red dolomitic tuff. Ore zone rocks include: a) bleached mafic tuff b) barren carbonates, c) pyritic dolomitic tuff (?) and d) brick-red syenite. Footwall rocks include: a) magnetic lava (so-called diorite), b) mafic lapilli and blocky tuff and c) alkali basalt, Native gold is the only gold mineral so far identified and it occurs both as free grains in gangue and as micro-inclusions in pyrite. Two geochemical groups were identified in the main rock units: 1) Alkali-rich rocks cons is ting of the ore zone and foot wall rocks and 2) Subalkaline group consisting of the hanging wall rocks. Ore analysis also shows Ba, Sr, W, Zr, REE and F enrichment in the ore zone. Footwall rocks are enriched in Na20. Present geological and geochemical data do not permit a clear interpretation of the formation for the Lac Shortt gold deposit but suggest it is a volcanic-hosted stratabound type. The bulk of the mineralization is associated with an exhalative phase following alkalic, carbonic, hydrothermal activity and part of the mineralization is associated with a late intrusive phase.

Jan 1, 1984