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By G. A. Smyres

The Bureau of Mines investigated a HCI-02 leaching procedure to recover Cu, Ni, and Co from a low-grade bulk sulfide flotation concentrate prepared from the Duluth gabbro complex. Since the Duluth gabbro complex is the largest known and unexploited Ni resource in the United States, the development of options for extracting the metal values from the flotation concentrate of this domestic resource is necessary. Conditions were determined for producing a pregnant solution low in Fe to facilitate recovery of the metal values. Leaching experiments were conducted at 15 pct solids, 1000 to 1200 C, 0.2 to 0.3 g HCI per gram concentrate in a 50-gal reactor pressurized to 50 pSig with 02. Base metal extractions from the concentrate were, in percent, 90 to 92 Cu, 99 Ni, 97 to 99 Co, and 0.1 .Fe. Precious metals extractions were erratic and unpredictable; at best their extractions were, in percent, 55 Au, 90 Ag, 40 Pt, and 45 Pd. The reaction time at 1200 C was 0.5 h. The use of compressed air instead of 02 as the oxidant was also investigated. Solvent extraction using LIX 622 was used to remove Cu from the pregnant solution. Cementation on Cu was tested for precious metals recovery, while sulfide precipitation was used to produce a Ni-Co product. A conceptual flowsheet for treating the Duluth gabbro concentrate is proposed.

Jan 1, 1985

By C. P. Mishra

The Bureau of Mines investigated the availability of mercury from 22 deposits in market economy countries. The 15 significant deposits evaluated have demonstrated resources of approximately 25 million metric tons of ore containing 5.3 million flasks of mercury and account for more than 85 pct of the demonstrated resources for market economy countries. Using data gathered as part of its Minerals Availability Program, the Bureau determined the mercury production potential of each deposit. At a January 1984 mercury market price of $300 per flask, the deposits evaluated could economically produce an estimated 2.5 million flasks of mercury from six mines operating at the time of this study; no mercury is available at this price from nonproducing operations. At $600 per flask, approximately 4.5 million flasks of mercury are available. For production costs up to $300 per flask, operating mines could supply mercury at the current production rate of 114,000 flasks per year until 1988, when the amount of mercury available from these deposits would decrease. This decline could be offset by the development of resources currently reported at the identified level (17 million flasks) at much higher production costs.

Jan 1, 1985

By Donald R. Fosnacht

An investigation was initiated to obtain the scope of the problems associated with recycling various waste oxide materials generated at Inland Steel and to identify and? test techniques that could possibly aid in increasing the amount of waste oxide materials recycled to primary. operations. Based on the results of this work, several new techniques were developed ?and tested on ?a plant or laboratory scale. These include the use of cold-bond agglomeration methods for producing waste oxide agglomerates for use as a cooling agent or scrap substitute in steelmaking operations, and the use of various techniques for beneficiating blast furnace flue dust and soaking pit rubble so that the upgraded materials can be utilized in sinter plant or ironmaking operations. The physical and chemical characteristics of the waste oxide materials and the results of the laboratory and plant testing are discussed in this paper.

Jan 1, 1985

By R. J. Weigel

The Santa Fe Railway serves the dominant U. S. potash producing region which is centered at Carlsbad, NM. This rail system extends over 12,000 miles stretching from Chicago to the Texas Gulf Coast to the state of California. (see Figure 1) Since Carlsbad mining operations began in the 1930?s, Santa Fe has been transporting potash to many of the important grain producing areas of the country and to the major ports in Texas and California. Santa Fe has maintained a close relationship with the potash companies and has adopted a marketing philosophy of attempting to maximize opportunities for the Carlsbad producers where it is mutually beneficial. Potash has been an important commodity for the Santa Fe. It accounted for 8% of our revenue in 1965 and 3% in 1984. In the 1950?s, Carlsbad became the second largest revenue producing point on the Santa Fe. But this prominent position has diminished as ore reserves became depleted, imports flooded the U. S. market, and truck transportation developed.

Jan 1, 1985

By David G. Adam

Syncrude Canada Ltd. is currently mining over 120 million tons per year of overburden and oil sands to produce 40 million barrels per year of synthetic crude oil. Production increases are planned. This paper reviews the technical and economic assessments of feeder breaker applications in both ore and waste mining which led to an extensive testing and development program and finally to the procurement of full scale production equipment.

Jan 1, 1985

By R. K. Singhal

In an underground coal mining environment, a frictional ignition may be defined as the ignition of an explosive air/ methane/coal dust mixture by mining machinery. As the use of power loading equipment has become more widespread, frictional ignition incidents have increased. There have been many fatalities and injuries from this cause including the death of eleven miners in Sydney coalfield of Nova Scotia, Canada in 1979. This paper reports on the findings of a preliminary study carried out under the auspices of the Coal Research Laboratories, Department of Energy, Mines and Resources Canada. The objective of this study has been to identify a Longwall face cutting system that is inherently safer than the conventional shearer loaders used in Nova Scotia.

Jan 1, 1985

By Rachel S. Prudhomme, Michael L. Jeremic

"The consolidation of mine backfill by free zing is a concept which has been under study in the mining engineering laboratories at Laurentian University during the past three years. The proposed underground application of freezing involves the artificial freezing of in-situ backfill by means of a refrigerated brine solution which would be circulated through a circuit off freeze pipes. The most interesting findings to date are: (I) The uniaxial compressive strength off frozen fill is considerably higher than that of cemented fill in a ratio of 20:1 (aggregate to cement), and (2) load deformation characteristics of the frozen fill suggest that a higher ice content results in more brittle failure and that samples which have initially failed can still support up 10 one-half the ultimate load without additional failure.Although at this early stage a derailed economic analysis of the procedure has not been possible, a general evaluation of the costs involved suggests that the method could be competitive with the hydraulic placement of cemented backfill. Results obtained from laboratory investigations indicate that the freezing of backfill is a structurally feasible option .IntroductionGround consolidation by freezing is based on the principle of transformation o f water contained in an aggregate-slurry into ice, which act s as a binding agent between the bulk particles, and which results in the transformation of a granular soil into a ""rock -type"" material. The abrasive nature of the particles enhance s the strength o f the ice by providing internal friction. As a result of this internal friction, the chances of plastic flow of the frozen mass when in a loaded condition are reduced(1). T he strength of a frozen aggregate is al so dependent on the grain shape of the aggregate particles which may or may not promote particle interlocking(2) and on the temperature since, below the freezing point of the water/aggregate mixture, the strength of the frozen mass increase s with decreasing temperatures.In the shaft sinking industry, artificial freezing of loose , unconsolidated soils has been in practice for several decades. Shafts for Saskatchewan 's potash industry have been sun k to depths of 3000 feet by employing artificial freezing to stabilize the Blairmore Formation(3). The common procedure for freezing ground for shaft sinking is summarized as follows(4,5): I) 150 mm diameter bore holes spaced on 1.5 m centres are drilled in a circular pattern with a radius of 1.5 m outside the periphery of the proposed shaft."

Jan 1, 1985

By R. M. Williams

Introduction Ring roller mills are efficient size reduction machines embodying the following machine functions: 1) Size Reduction: from a feed size of 2 in. to various size products as fine as 400 mesh, or granulation from 2 in. to 6 mesh containing a minimum of fines. 2) Drying: fluid bed drying of wet feed materials. 3) Conveying: negative pressure air system results in dust-free conveying. 4) Beneficiation: liberation and removal of foreign materials from the auxiliary bottom discharge simultaneously while grinding. Operation Operation of the roller mill system, Figs. 78 and 79, is completely automatic. A feeder introduces raw material into the grinding chamber in the base of the roller mill at a rate determined by pressure variations within the roller mill as material is ground and air conveyed away. The feeder will be activated by the reduced static pressure and introduce unground material into the system, thereby maintaining a constant differential pressure. Plows located ahead of each grinding roll direct the material upward and between the grinding rolls and the bull ring where it is ground to size. The grinding rolls are free to swing out centrifugally, which forces them to bear upon and grind the raw material. Being free to pivot axially, the rolls automatically assume the proper position for grinding and need no adjustment to compensate for wear. Rotation of the rolls is by rolling contact. Once ground to size, material is swept out of the mill by the controlled air flow from the centrifugal main mill fan. Air suspended, the ground material passing through the adjustable spinner separator. In the separator, an accurate size classification is made which allows product-size material to be conveyed away from the roller mill while oversize material is returned internally for additional grinding. By varying the speed of the separator drive, more or less cyclonic action is achieved at this location, effectively controlling product size. Product sized material is removed from the airstream by the cyclone collector. Typically, a conveyor or product storage bin will be located to accept the product as it exits from the bottom of the cyclone collector.

Jan 1, 1985

By J. E. Lawver, R. J. Haskin, A. Nussbaum, E. A. Laurila, W. J. Bronkala, D. M. Hopstock, J. H. Brophy, M. Wada, E. J. Tenpas, R. W. Salmi

Electrostatic separation is the selective sorting of solid species by means of utilizing forces acting on charged or polarized bodies in an electric field. Separation is effected by adjusting the electric and coacting forces, such as gravity or centrifugal force, and the time forces act on the particles, such that different species will have different trajectories at some predetermined time. Separations made in air are called electrostatic separation even though there is always some flow of current. Separations made using corona discharge devices are often called high tension separations. Separations made in liquids are termed separation by dielectrophesis if motion is due to polariza¬tion effects in nonuniform electric fields and termed electrophoresis if motion is due to free charge on species in an electric field. There are no industrial applications of mineral concentration by electropho¬resis or dielectrophesis; thus this section is limited to concentration in air. Typical Industrial Separations Typical applications of electrostatic separation are: 1) Beneficiation of ores, such as the concentration of the minerals ilmenite, rutile, zircon, apatite, asbestos, hematite, and many others. 2) Purification of foods, such as the removal of trash and rodent excrement from cereal seeds. 3) Sorting of reusable wastes, such as separating insulation from copper wire shreds. 4) Electrostatic sizing, namely, the sorting of solid particles ac¬cording to their size or shape. Table I is a partial list of industrial separations made by electrostat¬ics. The various types of electrostatic separators and the feasibility of commercial separations are most easily understood by reviewing pertinent basic electrostatic theory and the selected electrical proper¬ties of solids prior to describing the equipment and application. This is the sequence of presentation used in this section. Electrostatic Units One of the greatest sources of confusion and error is due to the multitude of units used in electrostatic literature. The system of units used throughout this section is the rationalized MKS, often called Systéme International (SI) units. In this system the mechanical units are the meter, kilogram, and the serond. The unit of force is the newton (N). This system is completed by the addition of the unit of charge, the coulomb (C). The fourth dimension, viz., the coulomb. could also be considered to be the ampere, since one ampere is the flow in a conductor of one coulomb per second. A more complete definition of the coulomb is given in Chap. 4, p. 6-11. The derived

Jan 1, 1985

By Basant L. Tiwari

An electrolytic process, based on a three-layer concentration cell, to extract magnesium from commercial aluminum alloy scrap has been examined. The process was repeatedly tested at 1025 K with two cells of d1fferent sizes, 0.6 kg and 5 kg feed aluminum, to have a better understanding of the opera ting parameters and evaluate the scale-up potential. In both cells, the magnesium content of the scrap was selectively reduced ?from 1. 1 to less than 0.1 wt.% at anodic current dens-Hy as high as 1. 1 A/cm2 with current efficiency exceeding 85%. Magnesium was recovered in the form of salt coated globules. Comparison of performances for the two cells suggests that the process can be scaled up. With further development, this process could become a viable alternative for demagging secondary aluminum.

Jan 1, 1985

By T. C. Bibb

Longwalls using shearers in seam heights of less than 1.2 m (48 inches) are relatively rare in the U.S. Westmoreland Coal Company is currently operating a shearer-equipped longwall at a cutting height of 1.17 m (46 inches) in its Bullitt Mine. This face has averaged 2795 metric tons/day of operation since its startup on April 3, 1984. Longwall productivity in thin seams is substantially impacted by equipment reliability and availability of useable working room for travel and access. This paper addresses the design criteria used in selecting this face equipment, with the goal of maximizing these two parameters. Equipment discussed includes shearers. face conveyor, shields, stageloader, and emulsion system.

Jan 1, 1985

By Rudolf Voigt

Lignite reserves occur all over the world in different climatic regions. This means, that the impact of the hydrologic regime upon mining activities and, vice versa, of the mining activities upon ground and surface water conditions will be different between any two mines. On the other hand, most economically important lignite deposits can be grouped according to principal depositional and structural features described briefly in the following section. These features do allow a preliminary assessments of the nature of ground water problems which may face the mine. The cost of protection against water which threatens a mine, the environmental impact of the appropriate measures to achieve this end and the restraints of population density which both might exclude the most cost-effective approach will govern the project expenditure for drainage work. Whether or not this expenditure can be borne by the project must be established during the feasi¬bility phases of mine planning. So, the somewhat provoking title of this paper does not mean that its question can be answered once for ever. It should rather serve to bring to the attention of the audience the major features of mine water control.

Jan 1, 1985

By Benjamin W. Haynes

The Bureau of Mines conducted research to provide technical information needed to devise waste management plans for the processing of manganese nodules. Studies included summary descriptions of Pacific manganese nodules, process options and flowsheets, methods for characterizing nodules and their tailings, and results of analyses of laboratory and pilot-plant generated tailings. This information is the result of a cooperative research effort of the Bureau of Mines and the National Oceanic and Atmospheric Administration (NOAA), with NOAA providing funding and the Bureau conducting the research. A summary of the extensive literature review is provided for manganese nodule mineralogy, chemistry, processing techniques, and methods of analyses. Characterizations and analyses of laboratory-generated tailings and slags are given, as well as the results of the leaching studies on these waste materials. Leachability was determined by three standard leachate tests- the Environmental Protection Agency (EPA) extraction procedure (EP) toxicity test, the American Society for Testing and Materials shake extraction test, and the U.S. Army Corps of Engineers-EPA seawater elutriant test. While the wastes generated in the laboratory may not be entirely representative of those to be generated in full-scale plants, results of these studies provide a positive indication that commercial recovery of cobalt, copper, manganese, and nickel from manganese nodules would be environmentally acceptable.

Jan 1, 1985

By A. Lloyd, Montgomery, J. Jorgesen, W. J.

"Coals are ranked according to their degree of metamorphism or progressive change in the natural series from lignite to anthracite. The reader is referred to ASTM Standard D-388, ""Standard Classification of Coals by Rank"" for a detailed description of the system in use throughout North America including Canada.Fixed carbon and calorific value (expressed in Btu/ lb) calculated to the mineral-matter-free basis have been chosen as the main characteristics from which rank is established. Higher rank coals are classified according to fixed carbon content, lower rank coals according to the calorific value on a ""moist"" mineral-matter-free basis. Certain adjacent groups are differentiated according to their agglomerating (caking) properties. ""Moist"" refers to inherent moisture. Referring to Table 1, coals having calorific values greater than 14,000 Btu/lb on a moist mineral-matter-free basis and fixed carbon of 69% or more on a dry mineral-matter-free basis are classified according to fixed carbon. Coals having calorific values of less than 14,000 Btu/lb on a moist mineralmatter-free basis are classified according to calorific value on a moist mineral-matter-free basis. Agglomerating coals having 69 to 86% fixed carbon on the dry mineral-matter-free basis are classified in the low or medium volatile group of the bituminous class according to their volatile matter content. Agglomerating coals having calorific values between 10,500 and 11,500 Btu/lb are classified in the high volatile C bituminous coal group; nonagglomerating coals in the same calorific value range are classified in the sub-bituminous A coal group."

Jan 1, 1985

By James J. Broderick

In the production of Pig Iron - Limestone, Coke and Iron Ore pellets are changed to the blast furnace and reacted at approximately 2,800 degrees F. The resultant products are molten iron and a molten slag - not unlike lava. The molten slag stream is channeled into open pits, cooled with water, crushed and sized for various industrial applications. The production of steel from pig iron in open hearth, B0P, BOF and electric furnaces results in somewhat similar slags: but since free lime is normally the flux, the resultant slags are not satisfactory for use in cement pastes. When exposed to water, the lime slakes, expands by 250% and ruptures the concrete. Thus, the slag discussed first is Blast Furnace Slag composed of 30 to 40% Silica (SiO2) Alumina (AL202) 7 to 16% Lime (CaO) 32 to 45% and Magnesia (MgO) 5 to 15%. The oxides do not exist as free oxides but rather as silicates and alumino silicates which are chemicall inert. Since transportation costs limit the area of use, blast furnace slag can only be found in concrete products produced within 60 to 100 miles of a blast furnace operation. Even within these areas where slag is in heavy supply, quite often the use of slag is minimal for concrete aggregate and the major outlet is road base.

Jan 1, 1985

By J. L. Whitlock

An attached growth aerobic biological treatment process has been developed at Homestake Mining Co.'s Lead operation which not only oxidizes free and complexed cyanides, including the stable iron complexed cyanides, but also thiocyanate, and the oxidation byproduct ammonia. Through the employment of a mutant strain of bacteria which has been gradually and specifically acclimated to the waste, these potential pollutants are mineralized to relatively harmless sulfates, carbonates, and nitrates. The resultant effluent, through toxicological testing, has been shown compatible with the receiving stream, which serves as a cold water marginal trout fishery.

Jan 1, 1985

By R. K. Komarek, F. E. Jr. Briber, G. M. Hanson, Fred D. DeVaney, J. H. Blake, C. L. Matson, T. E. Ban, N. E. Shields, R. D. Frans, R. B. Greenwalt

Metallurgically, the term agglomeration is used to describe processes whose goal is to form balls, briquettes, nodules, flakes, or other sized shaped particles from loose, usually fine, incoherent particles. In practice it includes such varying processes as the briquetting of coal dust and other substances, the balling and induration (heating) of such nonmetallics as cement, fluorspar, lightweight aggregates, etc. It includes such widely used processes as the sintering of nonferrous concentrates, such as those copper, lead, zinc, etc. The agglomeration of specific nonferrous metal concentrates is discussed in detail in the section of this handbook devoted to that particular metal. Agglomeration processes are of particular value to the iron and steel industry where the nature of the primary reduction process, the blast furnace, requires for best results a burden essentially free of fines. This is a change that has taken place since about 1960. Prior to that time many fine unsized ores were fed to the furnace. The development of the pelletizing process gave to the industry a chemically controlled closely sized product that increased the produc¬tion rate and reduced the costs so much that unsized fines are seldom used in modem furnaces. Steel plants produce many fine sized waste products such as fine dust (fine ore coke and gangue) and mill scale. These products, which have a valuable iron content, are usually sin¬tered directly at the plant for reuse. Fine sized ore concentrates are usually pelletized at the mine and shipped as pellets to the steel plant. Common practice in some areas producing natural high grade ores is to screen the ore at the mine to about 3/8 in. The oversize is shipped "as is" and constitutes blast furnace feed. The / in. may be shipped to the steel plant where it may be sintered or otherwise agglomerated. At some mines the fines may be pelletizied prior to shipment. With the development of large ocean ore carriers, and with the transportation of slurried concentrates or fines, a trend has developed of constructing large pelletizing plants or other types of agglomeration plants near large consumption centers (i.e., in the Netherlands or Japan) where ores of many types are brought together, ground if necessary, blended, and agglomerated. As an indication of tonnages of agglomerated materials produced, for iron materials alone (the largest share of the total) production in 1970 in the U.S. was Million gross ton Sinter 40.7 Pellets 43.1 Briquettes, nodules, & others 0.1 Total 83.9 During the 1960s, U.S. production of sinter rose from 40.3 million gross tons in 1961 to a high of 48.7 million in 1964, then settled back to almost the 1961 figure in 1970. Pellet production rose steadily from 14.4 million gross tons in 1961 to the 59.9 figure for 1975. Worldwide, sinter production in 1966 was estimated at 340 million mt (mainly in Europe, Russia, Japan, and the U.S.) and pellet produc¬tion the same year at 64 mt (primarily Canada and the U.S.). World pellet production capacity rose to 200 million tons in 1976.

Jan 1, 1985

Improve mine refrigeration system efficiency while providing free electrical energy to mines. Approach Convert the potential energy of incoming mine water falling down long vertical shafts into electrical energy by means of a turbine-generator system located at the bottom of the mine shaft. How it Works Converting the energy of falling water into useful work is a well-developed engineering concept. Water flowing down long vertical pipelines into deep mines develops high pressure that can be used to operate a turbine-generator system at the bottom of the pipeline. A thermal energy recovery system of this type offers three advantages: 1. In systems without turbines, the potential energy of the water is converted to heat. The water temper-ture will automatically

Jan 1, 1985

Solvent extraction-electro- winning appears to be one of the most important processes for the future in the North American copper industry and for this reason both the SX and EW steps are furtive areas for development. This paper has the objective of reviewing the present state of the electrowinning technology. It discusses some recent equipment developments and concludes by discussing the direction the technology will likely go fn the next decade.

Jan 1, 1985

By John A. Organiscak

The Bureau of Mines conducted a survey of eight shearer longwall operations to identify factors that affect respirable dust generation from longwall roof supports. The longwalls surveyed were in coal seams located in different geographic regions of the United States. Data were collected on mining (geologic) conditions, support design, operational characteristics, and amount of respirable dust generated from roof supports. Analysis indicated that mining conditions are the main factors that affect the generation of dust during roof support movement. Both roof strength and depth of cover above the coal seam showed relationships with the amount of support dust generated. Several practices are currently employed to effectively control roof support dust; however, some of these controls are limited. More research and development is needed to improve dust control technology for longwall roof supports.

Jan 1, 1985