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By Steven R. Munts

In 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 39,420 acres of the 60,960-acre Skedaddle Wilderness Study Area in order to evaluate its identified mineral resources. There are no known mines or mining operations in the study area. None of the prospects or claims in or within a 1 mile peripheral zone around the study area have recorded production. At least 276 recorded lode, 6 unrecorded lode, and 29 placer claims have been located in and within about 1 mile of the study area. Approximately 191 of the claims are in the study area. Four of these were current in 1985; all four are wholly or partly inside the study area. None of the study area was being explored by private industry in 1985. Metallic and nonmetallic commodities present in the study area consist of gold, mercury, perlite, basalt, pozzolan, stone, and sand and gravel. Perlite is represented by a single deposit which contains 184,000 tons of subeconomic resources in and adjacent to the study area. No other sites contained identified resources. There are no other identified nonmetallic resources in the study area. Occurrences in and near the study area contain small amounts of gold and mercury in vein-type deposits and show characteristics similar to bulk-tonnage, low-grade gold deposits. No base-metal resources were identified. The gold and mercury mineralization and perlite deposit are spatially related to a volcanic center located in the Skedaddle Mountains. Prospects in the Skedaddle Mountains may contain both precious metals and perlite resources, but additional work is required to adequately delineate these areas.

Jan 1, 1987

By L. W. Teal

The Paupers Dream Property is located in the northern Boulder Mountains, southwestern Montana, 30 km southwest of Helena. The property is situated in the central portion of the Butte-Helena gold belt, a NE trending lineament marking a zone of recurrent, late-Cretaceous to mid-Tertiary volcanic activity. Geology consists of a plutonic basement of late-Cretaceous quartz monzonite overlain by a pre-volcanic basal conglomerate and a complex sequence of Oligocene rhyolitic volcanics. Gold mineralization occurs in fracture-controlled quartz veins, silicified stockwork, and brecciated shear zones as auriferous pyrite, arsenopyrite, and disseminated free gold. An estimated 60,000 tonnes averaging 2.5 g/t was produced from the Porphyry Dike, Venus, and Paupers Dream Mines on the property. Current drill indicated reserves (May, 19861 are placed at 6,946,000 tonnes averaging 1.45 g/t gold.

Jan 1, 1987

Now that Japan has achieved a remarkable high growth and joined the ranks of economic powers, she is required to take a stance proper to her new position toward international co- operation among Western advanced countries, economic/technical aids to Southeast Asian and Pacific LDCs, and others. As a field subject to such international cooperation programs, the development/use of coal resources has been winning increasing attention in recent years. Coal is positioned as one of promising alternative energies. With Southeast Asia plus Japan and the EEC serving as the two nucleus polar regions, total coal demand in the free world is projected to jump 37% in the year 2000 from the present level and steaming coal imports in the world, primarily destined for power generation, almost double the 1983 level. Such being the situations, Japan's tech- nologies related to coal resource development, if successfully introduced into coal-producing countries to help them boost their production, can directly lead to international cooperation that Japan is now required to fulfill. At home, however, the Japanese coal industry has been just on the wane due to various press- ing problems, such as wider differentials between overseas and domestic coal and deeper/ remorter mining. The industry was named atop in a list of the industries requiring restruct- uring at a meeting of the Economic Structure Study Committee held prior to the decision- making of the 8th coal policy, which slashed coal production planned for the last fiscal year of its life to some 10 million tons, a drop of as much as 50% from nominal output planned in the 7th policy. Under such circumstances at home and abroad, a pioneer study has been under way since fiscal 1984 as part of Japan's energy cooperation in the Pacific. The study is based on the Pacific coal flow concept hammered out by the Agency of Natural Resources and Energy of the MITI.

Jan 1, 1987

By A. Broussaud

An original methodology has been developed for steady state simulation of selective grinding and mineral liberation in rod and ball mills. Three fundamental aspects of the methodology are presented successively : modeling ore texture, modeling grinding and its selectivity, and modeling mineral liberation. The methodology for modeling ore texture includes the conversion of 2D data into 3D reconstructed information and the use of the BILCO coherent material balance software. The models for grinding Simulation are classified into three levels, corresponding to three levels of available experimental data. All models account for grinding selectivity and for variations of engineering para-meters and operating conditions. An algorithm has been introduced to forecast mineral liberation, compatible with accurate simulation of selective grinding, which generates reasonable results.

Jan 1, 1987

By H. Knorre, A. Griffiths, R. Higgins, S. Gos

Hydrogen peroxide is gaining acceptance as a reagent for the treatment of mining effluents containing cyanide. In this paper some of the chemical and environmental aspects of treatment with hydrogen peroxide are discussed, and one way of improving the economics of the process is described. This is known as selective detoxification, which involves the oxidation of the less stable (cyanide) complexes while not affecting the more stable complexes, which contribute very little to the concentration of free cyanide or to the toxicity of the treated water.

Jan 1, 1987

By G. T. Fisher

The material requirements of carbide cutting tools for machining steel and cast iron are dependent on WC bonded with Co, with additions of TaCand TiC. The Bureau of Mines is conducting research to devise substi-tute materials, based on Ni-alloy-bonded TiC, for C-5-grade cutting tool applications. This substitution would result in less dependence on foreign sources for Co, Ta, and W, and use of lower cost materials. In this preliminary study, the Bureau investigated the effects of composition and processing variables on the transverse rupture strength and hardness of Ni-alloy-bonded TiC to identify compositions that exhibit promising mechanical properties. Further systematic modification of these compositions by soild-solution strengthening additions would subsequently be evaluated to obtain cutting tool materials with requisite properties and performance for C-5 applications. Compositions for evaluation were prepared by a powder metallurgy method of cold-pressing and liquid-phase sintering. Complementary analysis of compositions included chemical analysis, X-ray diffraction, energy-dispersive X-ray spectro-scopy, and density measurements. Based on results of this investigation, promising compositions were determined to be 59.37TiC-25Ni-5Mo-lO.63Mo2C, 59.68TiC-25Ni-3.33Mo-1.77Mo2C-6.67W-3.55WC, and 59.35TiC-25Ni-l.67Mo-3.54Mo2C-3.33W-7.1WC.

Jan 1, 1987

By M. J. Adam

The Bureau of Mines is investigating the feasibility of partitioning complex sulfide minerals to simpler sulfide phases by sulfidation reactions. Such partitioning can afford opportunity to improve selective extraction of mineral constituents of value. This report describes research involving sulfidation partitioning of byproduct chalcopyrite concentrates from Missouri lead ore processing, and a Utah chalcopyrite concentrate from Cu ore processing. Small chalcopyrite samples were sulfidized with elemental S in glass capsules sealed after evacuating and backfilling with He, by heating for 1 to 24 h at specific temperatures in the range of 250? to 500? C, extending from below to above the boiling point of S (-4450 C).

Jan 1, 1987

By S. L. Manske

The Mesquite gold deposit is a recent discovery of Gold Fields Mining Corporation lying 65 kilo- meters northeast of El Centro in Imperial County, California (Figure 1). The deposit is located on the southwestern flank of the Chocolate Mountains and is a bulk-minable, low grade "disseminated" orebody. Although the host rocks of the deposit are part of a regional high-grade metamorphic terrane, abundant brittle fractures, brecciation, and open-space vein fillings indicate that Mesquite mineralization is epithermal. Faulting which postdates the hydrothermal activity has complicated the original geometry of the orebody. Alluvium effectively hides most surface expression of the mineralization, but open-pit mining is now revealing the details of Mesquite geology.

Jan 1, 1987

By W. L. Cornell

Ore microscopy was used in support of both bench-and large-scale continuous beneficiation testing programs. Reflected light microscopy and Vickers hardness measurements were utilized to help identify problems relating to mineral identification, mineral association, mineral liberation, mineral distribution in product streams, and froth entrainment. Specimens studied were size fractions of concentrates and tailings resulting from Bureau of Mines research to recover a siegenite-enriched product by beneficiating chalcopyrite concentrates. Other specimens were size fractions of bulk sulfide concentrates recovered during the enhanced amine scavenging of final tailings by froth flotation. The findings from studies directly affected flowsheet development.

Jan 1, 1987

By T. G. Melkus

A Setaram C-80 heat flux micro- calorimeter was used to study the surface and interfacial properties of fine coal particles in water containing flotation agents via heat of immersion measurements. Heat of immersion (?Himm) is usually a small exothermic quantity and can be used' to characterize a solid in terms of its relative hydrophobicity or hydrophilicity. The effects of coal type, surface oxidation, mineral matter content, kerosene concentration, and pH on the wetting characteristics were investigated. Results obtained from the calorimetry experiments correlated well with results from independent flotation experiments.

Jan 1, 1987

By Richard A. Allwes

This Bureau of Mines report presents a procedure for the design of an arch canopy for use in rehabilitating a high-roof-fall area. Only dy-namic line loading of an unbackfilled arch canopy at its crown is considered, and the procedure does not account for an asymmetrical loading condition. The evaluation of whether an arch canopy is suitable for a particular installation depends on many variables, including in-mine conditions and the engineering properties of the structure. However, a general evaluation can be based on a comparison of the arch's maximum crown deflection and a prescribed allowable crown deflection. The design procedure is based on the concept that when an arch canopy is sub-jected to impact loading at its crown and deflects from its unloaded state to maximum crown deflection, the structure absorbs strain energy, both elastic and plastic. As a result, this strain energy can be calculated from a static load-displacement diagram for the structure. The significance of this design procedure is that it gives mine personnel an analytical tool to select an arch canopy to meet the dimensional and functional requirements of a mine entry and a prescribed allowable crown deflection.

Jan 1, 1987

By C. L. Lin

Transformation of linear grade distribution to volumetric grade distribution has been used to estimate the actual mineral liberation during wet, batch, ball mill grinding of a copper ore. The degree of liberation based on the multicomponent-multisize grinding liberation model using volumetric grade is lower than the apparent degree of liberation estimated from using King's linear intercept model.

Jan 1, 1987

By W. L. Cornell

Bulk sulfide concentrate produced from Missouri Pb ore concentrator tailings must be reground to liberate sulfide values for subsequent sepa-ration. Studies to determine grinding parameters for optimum liberation were carried out using optical microscopy coupled with image analysis. The major sulfide phases present in the ground mineral particulates are marca-site, pyrite, sphalerite, galena, chalcopyrite, siegenite. and bravoite. Results showed that the base metal minerals were liberated by grinding to 74 micrometers (200 mesh), but the siegenite and bravoite required grinding to 20 micrometers or less to achieve liberation. Both the experimental method and results are presented.

Jan 1, 1987

By S. Dallaire

With the attainment of high temperatures it becomes possible to process any kind of material (particularly ceramics) in their liquid state. In the plasma spraying process, the material to be sprayed is rapidly heated until it is molten and is propelled by high velocity gases onto a surface where it adheres, to give protective coatings for a wide range of applications. The method could be considered as one of the most versatile and rapid to build up thick deposits (of plastics, metals, ceramics, cermets) and also free-standing artifacts for particular requirements without resorting to lengthy forming and sintering studies. Although plasma spraying is at the production stage in industry, advanced processes have also been developed for economically producing a wide range of new materials. This paper illustrates the benefits of the process and evaluates the challenges it represents.

Jan 1, 1987

By H. Chu

Selective Agglomeration experiments carried out to clean ultra-fine coal are examined. Effect of feed size, pulp density, coalescing agent dosage, and mixing intensity and duration on the kinetics of agglomeration are principally evaluated. A computer coded population balance model governing agglomerate size distribution and composition utilizing coalescence and breakage mechanisms is developed. Model calibration, verification and extension are analyzed.

Jan 1, 1987

By William H. Pomroy

Spontaneous combustion fires involving high-sulfide-content ores are a relatively infrequent yet serious safety hazard in mining. They are also the cause of lengthy mine shutdowns because they typically occur in areas of a mine where abundant fuel material is present but which are inaccessible for fire fighting. This Bureau of Mines report describes research to design, fabricate, and test in the laboratory and field a system that warns of spontaneous combustion fires in metal mines. Overall performance of the detection system was found to be satisfactory, in that the system was capable of reliably detecting low levels of combustion products believed to indicate the preflaming stage of spontaneous combustion in metal mines. Installation of similar systems in mines with a high risk of spontaneous combustion is recommended. Principal operating problems and recommended corrective actions are also discussed.

Jan 1, 1987

By Caivin JS, Freeman CJ

The Fairbanks Mining District in central Alaska was discovered in 1902 and since then approximately 7.5 million troy oz of placer gold, 250,000 troy oz of lode gold, and several thousand short tons of antimony and tungsten hap been produced from an area of about 1000 km . Historic lode production was from high grade gold-quartz veins that averaged 1.3 OPT free milling gold. Five main types of mineral deposits' are recognized in the district. I. Conformable, stratabound volcanogenic zinc, antimony, lead, and copper sulfides in places containing gold, silver and tungsten in bimodal metavoleanics (Cleary Sequence). II. Complex precious metal-bearing lead sulfosalt-quartz veins in Cretaceous granitic intrusives. III. Tungsten skarns adjacent to granitic intrusives. IV. Gold-bearing polymetallic sulfide-quartz veins crosscutting metavolcanics and metasedimentary units of the Cleary Sequence. V. Antimony-bearing gash veins along axial plane shears in various lithologies of the Cleary Sequence. Type I and Type IV mineral occurrences are currently being evaluated as low. grade bulk tonnage (target model 16-20 'million tons of 0.05 to 0.15 OPT)'and high grade moderate tonnage (target model 0.5 to 2.5 million tons of 0.5 OPT) gold deposits. The host rocks for Type I mineralization occur over a 30 km strike length and are at least 300 meters thick. Stratigraphic, structural, fluid inclusion, and isotopic data suggest that the Type IV mineralization is related to remobilization of Type I

Jan 1, 1987

By M. C. Esposito

Seven pyrite samples purified from coal sources and one ore source pyrite (for comparative purposes) have been characterized by chemical and mineralogical analyses, inherent floatability, apparent specific gravity, surface area, semiconductor type, optical anisotropy, dissolution and oxidation rate. The data clearly demonstrate that pyrites from various coal sources differ not only from ore pyrite but from each other as well.

Jan 1, 1987

The Porgera gold deposit in the Papua New Guinea highlands contains about 387 tonnes of gold. The results of its exploration show the benefits of persistence and commitment to this difficult deposit. The mineralization consists of a complex intermix of auriferous and argentiferous sulphides, gold tellurides and free gold as disseminations, veins, stockworks and breccia matrix. Its deposition was structurally contolled within a system of mafic diorite intrusions and adjacent sediments. Two styles of alteration accompany the mineralization. Gold grades vary erratically throughout the deposit. Over a period of 22 years nine phases of exploration have been undertaken by six companies or consortia of companies. Surface rock chip sampling, geological mapping followed by scout and systematic grid diamond drilling have been the most successful exploration tools. Exhaustive metallurgical process investigations and economic evaluations of mining options have been invaluable in guiding the exploration towards defining the ore body. Impetus was given to the project during times of flagging enthusiasm by several important discoveries and a breakthrough in the metallurgical processing approach. The discovery of high grade ore deep in Zone VII in 1984 turned this marginal deposit into a potentially very large gold mine.

Jan 1, 1987

By Peter G. Kovalchik

To compare the viability of the new fuse wire arc test (FWAT) as a substitute for the comparative tracking index (CTI) for determining surface resistance to electrical tracking, the Bureau of Mines constructed a fuse wire arc tester and undertook a detailed testing program for testing insulating materials used on explosion-proof enclosures. This report describes the Bureau's apparatus, the two methods (CTI and FWAT), and the results of the Bureau's testing, showing comparisons of the FWAT with the CTI. Results showed strong correlation between the two methods, as all specimens tested that had CTI ratings of 400 V ac rms and above passed the 10-test sequence with the FWAT, whereas all specimens with lower CTI ratings failed, with the number of tests to failure corresponding roughly to the descending CTI rating order.

Jan 1, 1987